Page 1/13

Safety Data Sheet

according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name: FERTAN Rust Converter
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Rust converting product.
· Uses advised against Contact manufacturer.
· 1.3 Details of the supplier of the Safety Data Sheet
· Manufacturer/Supplier:
CRP Industries
35 Commerce Dr.
Cranbury, NJ 08512
(609) 578-4100
· 1.4 Emergency telephone number:
ChemTel Inc.
(800)255-3924, +1 (813)248-0585
ChemTel Inc.
(800)255-3924, +1 (813)248-0585

Poison Control Centres:

In the United Kingdom: 844 892 0111
In Australia: 131126
In New Zealand: +0800 764 766

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
Classifications listed are applicable to the OSHA GHS Hazard Communication Standard
(29CFR1910.1200).
The following Hazard Statements are applicable only to the EU regulations and not the US GHS
regulation: H411.
Hazard Statement H411 is not applicable to the OSHA US regulations.

corrosion

Eye Dam. 1 H318 Causes serious eye damage.

environment

Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.

Skin Irrit. 2 H315 Causes skin irritation.

(Cont'd. on page 2)

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

Trade name: FERTAN Rust Converter

(Cont'd. from page 1)

STOT SE 3 H336 May cause drowsiness or dizziness.
· Additional information:
There are no other hazards not otherwise classified that have been identified.
0 % of the mixture consists of component(s) of unknown toxicity.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is additionally classified and labelled according to the Globally Harmonized System within the
United States (GHS).
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS05 GHS07 GHS09

· Signal word Danger

· Hazard-determining components of labelling:
propan-2-ol
phosphoric acid
1-ethoxypropan-2-ol
· Hazard statements
The following Hazard Statements are applicable only to the EU regulations and not the US GHS
regulation: H411.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statements
P264 Wash thoroughly after handling.
P280 Wear protective gloves / eye protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P302+P352 IF ON SKIN: Wash with plenty of water.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· NFPA ratings (scale 0 - 4)
Health = 2
0 Fire = 0
2 0 Reactivity = 0

· HMIS-ratings (scale 0 - 4)

HEALTH 2 Health = 2
FIRE 0 Fire = 0
REACTIVITY 0 Reactivity = 0
(Cont'd. on page 3)

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

Trade name: FERTAN Rust Converter

(Cont'd. from page 2)

· HMIS Long Term Health Hazard Substances
None of the ingredients are listed.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

· 3.2 Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 67-63-0 propan-2-ol 5-15%
EINECS: 200-661-7 Flam. Liq. 2, H225
Index number: 603-117-00-0 Eye Irrit. 2, H319; STOT SE 3, H336
CAS: 1569-02-4 1-ethoxypropan-2-ol 1-5%
EINECS: 216-374-5 Flam. Liq. 3, H226
Index number: 603-177-00-8 STOT SE 3, H336
CAS: 7664-38-2 phosphoric acid 1-5%
EINECS: 231-633-2 Skin Corr. 1B, H314
Index number: 015-011-00-6
CAS: 7779-88-6 zinc nitrate 1-5%
EINECS: 231-943-8 Ox. Liq. 2, H272
Aquatic Acute 1, H400; Aquatic Chronic 1, H410
Acute Tox. 4, H302
CAS: 13598-37-3 Zinc bis ( dihydrogen phosphate ) 1-5%
EINECS: 237-067-2 Aquatic Acute 1, H400
Acute Tox. 4, H302
· Additional information:
For the wording of the listed Hazard Statements refer to section 16.
For the listed ingredients, the identity and exact percentages are being withheld as a trade secret.

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. Then consult a doctor.
(Cont'd. on page 4)

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

Trade name: FERTAN Rust Converter

(Cont'd. from page 3)

· After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
Dizziness
Coughing
Nausea in case of ingestion.
Irritant to skin and mucous membranes.
Strong irritant with the danger of severe eye injury.
· Hazards Causes serious eye damage.
· 4.3 Indication of any immediate medical attention and special treatment needed
Contains nitrates. Consult literature for specific antidotes.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.
· For safety reasons unsuitable extinguishing agents: None.
· 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
· 5.3 Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
· Additional information Eliminate all ignition sources if safe to do so.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
· 6.2 Environmental precautions: Dilute with plenty of water.
· 6.3 Methods and material for containment and cleaning up:
Use limestone to neutralize and absorb spill.
Send for recovery or disposal in suitable receptacles.
Dispose contaminated material as waste according to section 13.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

(Cont'd. on page 5)

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

Trade name: FERTAN Rust Converter

(Cont'd. from page 4)

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
Avoid splashes or spray in enclosed areas.
Use only in well ventilated areas.
Prevent formation of aerosols.
· Information about fire - and explosion protection: No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store only in the original receptacle.
· Information about storage in one common storage facility:
Store away from foodstuffs.
Do not store together with alkalis (caustic solutions).
Store away from metals.
· Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles.
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see section 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
67-63-0 propan-2-ol
PEL (USA) Long-term value: 980 mg/m³, 400 ppm
REL (USA) Short-term value: 1225 mg/m³, 500 ppm
Long-term value: 980 mg/m³, 400 ppm
TLV (USA) Short-term value: 984 mg/m³, 400 ppm
Long-term value: 492 mg/m³, 200 ppm
BEI
EL (Canada) Short-term value: 400 ppm
Long-term value: 200 ppm
EV (Canada) Short-term value: 400 ppm
Long-term value: 200 ppm
78-92-2 butanol
PEL (USA) Long-term value: 450 mg/m³, 150 ppm
REL (USA) Short-term value: 455 mg/m³, 150 ppm
Long-term value: 305 mg/m³, 100 ppm
TLV (USA) Long-term value: 300 mg/m³, 100 ppm
EL (Canada) Long-term value: 100 ppm
EV (Canada) Short-term value: 150 ppm
Long-term value: 100 ppm
(Cont'd. on page 6)

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

Trade name: FERTAN Rust Converter

(Cont'd. from page 5)

7664-38-2 phosphoric acid
IOELV (EU) Short-term value: 2 mg/m³
Long-term value: 1 mg/m³
PEL (USA) Long-term value: 1 mg/m³
REL (USA) Short-term value: 3 mg/m³
Long-term value: 1 mg/m³
TLV (USA) Short-term value: 3 mg/m³
Long-term value: 1 mg/m³
EL (Canada) Short-term value: 3 mg/m³
Long-term value: 1 mg/m³
EV (Canada) Short-term value: 3 mg/m³
Long-term value: 1 mg/m³
· DNELs No further relevant information available.
· PNECs No further relevant information available.
· Ingredients with biological limit values:
67-63-0 propan-2-ol
BEI (USA) 40 mg/L
Medium: urine
Time: end of shift at end of workweek
Parameter: Acetone (background, nonspecific)
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
For spills, respiratory protection may be advisable.
Use suitable respiratory protective device when aerosol or mist is formed.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
(Cont'd. on page 7)

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

Trade name: FERTAN Rust Converter

(Cont'd. from page 6)

· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
· For the permanent contact gloves made of the following materials are suitable:
Neoprene gloves
Butyl rubber, BR
· Eye protection:
Contact lenses should not be worn.

Safety glasses

· Body protection: Protective work clothing

· Limitation and supervision of exposure into the environment
No further relevant information available.
· Risk management measures
See Section 7 for additional information.
No further relevant information available.

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Colour: Dark brown
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value at 20 °C (68 °F): 1,4 - 2,0 (as furnished)
· Change in condition
Melting point/Melting range: Not Determined.
Boiling point/Boiling range: 100 °C (212 °F)
· Flash point: Not applicable.
· Flammability (solid, gaseous): Not applicable.
· Auto/Self-ignition temperature: 255 °C (491 °F)
· Decomposition temperature: Not determined.
· Self-igniting: Product is not self-igniting.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits:
Lower: 2,0 Vol %
Upper: 12,0 Vol %
· Vapour pressure at 20 °C (68 °F): 43 hPa (32 mm Hg)
(Cont'd. on page 8)

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

Trade name: FERTAN Rust Converter

(Cont'd. from page 7)

· Density at 20 °C (68 °F): 1,10 ± 0,05 g/cm³ (9,18 ± 0,417 lbs/gal)

· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Fully miscible.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
· 10.3 Possibility of hazardous reactions
Toxic fumes may be released if heated above the decomposition point.
Reacts with alkali (lyes).
Reacts with certain metals.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Toxic metal oxide smoke
Phosphorus oxides (e.g. P2O5)
Nitrogen oxides

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity
· LD/LC50 values relevant for classification: None.
· Primary irritant effect:
· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation
Causes serious eye damage.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Acute effects (acute toxicity, irritation and corrosivity): May be harmful if swallowed.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction):
· Germ cell mutagenicity
Based on available data, the classification criteria are not met.
(Cont'd. on page 9)

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

Trade name: FERTAN Rust Converter

(Cont'd. from page 8)

· Carcinogenicity
Based on available data, the classification criteria are not met.
· Reproductive toxicity
Based on available data, the classification criteria are not met.
· STOT-single exposure
May cause drowsiness or dizziness.
· STOT-repeated exposure
Based on available data, the classification criteria are not met.
· Aspiration hazard
Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Danger to drinking water if even small quantities leak into the ground.
The product contains heavy metals. Avoid transfer into the environment. Specific preliminary treatments
are necessary
Due to available data on eliminability/decomposition and bioaccumulation potential prolonged term
damage of the environment can not be excluded.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Hand over to hazardous waste disposers.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to local official regulations.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.

SECTION 14: Transport information

· 14.1 UN-Number
· DOT Not Regulated
· ADR, IMDG, IATA UN3082
· 14.2 UN proper shipping name
· DOT Not Regulated
(Cont'd. on page 10)

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

Trade name: FERTAN Rust Converter

(Cont'd. from page 9)

· ADR 3082 ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. (ZINC NITRATE, Zinc
bis ( dihydrogen phosphate ))
· IMDG, IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (ZINC NITRATE, Zinc bis ( dihydrogen
phosphate ))
· 14.3 Transport hazard class(es)
· DOT
· Class Not Regulated
· ADR

· Class 9 (M6) Miscellaneous dangerous substances and

articles.
· Label 9
· IMDG

· Class 9 Miscellaneous dangerous substances and articles.

· Label 9
· IATA

· Class 9 Miscellaneous dangerous substances and articles.

· Label 9
· 14.4 Packing group
· DOT Not Regulated
· ADR, IMDG, IATA III
· 14.5 Environmental hazards:
· Marine pollutant: No
· Special marking (ADR): Symbol (fish and tree)
· Special marking (IATA): Symbol (fish and tree)
· 14.6 Special precautions for user Warning: Miscellaneous dangerous substances and
articles.
· Danger code (Kemler): 90
· EMS Number: F-A,S-F
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
(Cont'd. on page 11)

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

Trade name: FERTAN Rust Converter

(Cont'd. from page 10)

· Transport/Additional information:
· ADR
· Limited quantities (LQ) 5L
· Transport category 3
· Tunnel restriction code E
· UN "Model Regulation": U N 3 0 8 2 , EN V IR O N M E N T A L L Y H A Z AR D O U S
SUBSTANCE, LIQUID, N.O.S. (ZINC NITRATE, Zinc
bis ( dihydrogen phosphate )), 9, III

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· United States (USA)
· SARA
· Section 355 (extremely hazardous substances):
None of the ingredients are listed.
· Section 313 (Specific toxic chemical listings):
Substance / component not listed individually, but listed under family group as Zinc salts.
67-63-0 propan-2-ol
7779-88-6 zinc nitrate
7664-38-2 phosphoric acid
· TSCA (Toxic Substances Control Act):
All ingredients are listed.
· Proposition 65 (California):
· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients are listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients are listed.
· Carcinogenic Categories
· EPA (Environmental Protection Agency)
None of the ingredients are listed.
· IARC (International Agency for Research on Cancer)
67-63-0 propan-2-ol 3
· TLV (Threshold Limit Value established by ACGIH)
67-63-0 propan-2-ol A4
(Cont'd. on page 12)

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

Trade name: FERTAN Rust Converter

(Cont'd. from page 11)

· NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients are listed.
· Canada
· Canadian Domestic Substances List (DSL)
All ingredients are listed.
· Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients are listed.
· Canadian Ingredient Disclosure list (limit 1%)
67-63-0 propan-2-ol
7664-38-2 phosphoric acid
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57
None of the ingredients are listed.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H272 May intensify fire; oxidiser.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
(Cont'd. on page 13)

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
OSHA GHS
Printing date 14.07.2015 Revision: 14.07.2015

Trade name: FERTAN Rust Converter

(Cont'd. from page 12)

PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids, Hazard Category 2
Flam. Liq. 3: Flammable liquids, Hazard Category 3
Ox. Liq. 2: Oxidising Liquids, Hazard Category 2
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - Chronic Hazard, Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2
· Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com

41.1.0