Glysantin G05 en
Glysantin G05 en
Glysantin G05 en
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 24.10.2019 Version: 7.1
Date previous version: 15.02.2019 Previous version: 7.0
Product: GLYSANTIN® G05® yellow
(ID no. 30177333/SDS_GEN_EU/EN)
Date of print 28.01.2021
1.2. Relevant identified uses of the substance or mixture and uses advised against
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Fuel and Lubricant Solutions
H302, H373
For the classifications not written out in full in this section the full text can be found in section 16.
Pictogram:
Signal Word:
Warning
Hazard Statement:
H302 Harmful if swallowed.
H373 May cause damage to organs (Kidney) through prolonged or repeated
exposure.
UFI: V20E-P128-P00W-JNR0
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture. The
product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or
the vPvB (very persistent/very bioaccumulative) criteria.
Not applicable
3.2. Mixtures
Chemical nature
ethanediol, inhibitors
This product contains (a) substance(s) included on the candidate list according to article 59 (1,10) of
regulation EC No. 1907/2006 ('REACH') in a concentration equal or above 0.1% w/w: disodium
tetraborate, anhydrous
ethanediol
Content (W/W): 85 % - 95 % Acute Tox. 4 (oral)
CAS Number: 107-21-1 STOT RE (Kidney) 2
EC-Number: 203-473-3 H302, H373
REACH registration number: 01-
2119456816-28
INDEX-Number: 603-027-00-1
Sodium benzoate
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 24.10.2019 Version: 7.1
Date previous version: 15.02.2019 Previous version: 7.0
Product: GLYSANTIN® G05® yellow
(ID no. 30177333/SDS_GEN_EU/EN)
Date of print 28.01.2021
Content (W/W): >= 2 % - <= 4 % Eye Dam./Irrit. 2
CAS Number: 532-32-1 H319
EC-Number: 208-534-8
REACH registration number: 01-
2119460683-35
sodium nitrite
Content (W/W): > 0.1 % - < 0.5 % Ox. Sol. 3
CAS Number: 7632-00-0 Acute Tox. 3 (oral)
EC-Number: 231-555-9 Eye Dam./Irrit. 2
REACH registration number: 01- Aquatic Acute 1
2119471836-27 M-factor acute: 1
H272, H319, H301, H400
For the classifications not written out in full in this section, including the hazard classes and the
hazard statements, the full text is listed in section 16.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 24.10.2019 Version: 7.1
Date previous version: 15.02.2019 Previous version: 7.0
Product: GLYSANTIN® G05® yellow
(ID no. 30177333/SDS_GEN_EU/EN)
Date of print 28.01.2021
On skin contact:
Immediately wash thoroughly with soap and water, seek medical attention.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention. Administer 50
ml of pure ethanol in a drinkable concentration.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: Additional information on symptoms and effects may be included in the GHS labeling
phrases available in Section 2 and in the Toxicological assessments available in Section 11.,
(Further) symptoms and / or effects are not known so far
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Symptomatic treatment (decontamination, vital functions).
Antidote: Administer ethanol.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.
107-21-1: ethanediol
Skin Designation (OEL (EU))
The substance can be absorbed through the skin.
STEL value 104 mg/m3 ; 40 ppm (OEL (EU))
indicative
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 24.10.2019 Version: 7.1
Date previous version: 15.02.2019 Previous version: 7.0
Product: GLYSANTIN® G05® yellow
(ID no. 30177333/SDS_GEN_EU/EN)
Date of print 28.01.2021
TWA value 52 mg/m3 ; 20 ppm (OEL (EU))
indicative
532-32-1: Sodium benzoate
1330-43-4: disodium tetraborate, anhydrous
7632-00-0: sodium nitrite
PNEC
No hazard identified.
DNEL
Data refer to the lead substances
107-21-1: ethanediol
worker: Long-term exposure - local effects, Inhalation: 35 mg/m3
worker: Long-term exposure- systemic effects, dermal: 106 mg/kg
consumer: Long-term exposure - local effects, Inhalation: 7 mg/m3
consumer: Long-term exposure- systemic effects, dermal: 53 mg/kg
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 24.10.2019 Version: 7.1
Date previous version: 15.02.2019 Previous version: 7.0
Product: GLYSANTIN® G05® yellow
(ID no. 30177333/SDS_GEN_EU/EN)
Date of print 28.01.2021
General safety and hygiene measures
Do not inhale gases/vapours/aerosols. Handle in accordance with good industrial hygiene and safety
practice. Wearing of closed work clothing is recommended. Handle in accordance with good
industrial hygiene and safety practice.
Form: liquid
Colour: yellow
Odour: product specific
Odour threshold:
not determined
pH value: 6.0 - 7.0
solidification temperature: approx. -15 °C (DIN ISO 3016)
boiling temperature: > 160 °C (ASTM D1120)
Flash point: 117 °C (DIN EN 22719; ISO 2719)
Evaporation rate:
not determined
Flammability: hardly combustible (derived from flash point)
Lower explosion limit:
For liquids not relevant for
classification and labelling., The
lower explosion point may be 5 - 15
°C below the flash point.
Upper explosion limit:
For liquids not relevant for
classification and labelling.
Ignition temperature: 445 °C (DIN 51794)
Vapour pressure: 0.3 hPa
(20 °C)
Density: 1.131 g/cm3
(20 °C)
Solubility (qualitative) solvent(s): polar solvents
soluble
Partitioning coefficient n-octanol/water (log Kow):
Study scientifically not justified.
Self ignition: not self-igniting
Substances to avoid:
strong oxidizing agents
Acute toxicity
Experimental/calculated data:
LD (human) (oral): approx. 1,600 mg/kg
Irritation
Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 24.10.2019 Version: 7.1
Date previous version: 15.02.2019 Previous version: 7.0
Product: GLYSANTIN® G05® yellow
(ID no. 30177333/SDS_GEN_EU/EN)
Date of print 28.01.2021
Respiratory/Skin sensitization
Assessment of sensitization:
Skin sensitizing effects were not observed in animal studies. Human data do not fully exclude a skin
sensitizing potential.
No data available.
Carcinogenicity
Reproductive toxicity
No data available.
Developmental toxicity
No data available.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Aspiration hazard
The product has not been tested. The statements on toxicology have been derived from the
properties of the individual components.
Toxicity to fish:
LC50 (96 h) > 100 mg/l, Leuciscus idus
Aquatic invertebrates:
EC50 (48 h) > 100 mg/l, Daphnia magna
Aquatic plants:
EC50 (72 h) > 100 mg/l, algae
Elimination information:
> 70 % DOC reduction (28 d) (OECD 301 A (new version)) Readily biodegradable.
According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance
fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very
bioaccumulative) criteria.
The waste codes are manufacturer's recommendations based on the designated use of the product.
Other use and special waste disposal treatment on customer's location may require different waste-
code assigments.
Waste key:
16 01 14¤ antifreeze fluids containing hazardous substances
Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
Land transport
ADR
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 24.10.2019 Version: 7.1
Date previous version: 15.02.2019 Previous version: 7.0
Product: GLYSANTIN® G05® yellow
(ID no. 30177333/SDS_GEN_EU/EN)
Date of print 28.01.2021
RID
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 24.10.2019 Version: 7.1
Date previous version: 15.02.2019 Previous version: 7.0
Product: GLYSANTIN® G05® yellow
(ID no. 30177333/SDS_GEN_EU/EN)
Date of print 28.01.2021
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
Assessment of the hazard classes according to UN GHS criteria (most recent version)
Full text of the classifications, including the hazard classes and the hazard statements, if mentioned
in section 2 or 3:
Acute Tox. Acute toxicity
STOT RE Specific target organ toxicity — repeated exposure
Eye Dam./Irrit. Serious eye damage/eye irritation
Repr. Reproductive toxicity
Ox. Sol. Oxidising solids
Aquatic Acute Hazardous to the aquatic environment - acute
H302 Harmful if swallowed.
H373 May cause damage to organs (Kidney) through prolonged or repeated
exposure.
H319 Causes serious eye irritation.
H360FD May damage fertility. May damage the unborn child.
H272 May intensify fire; oxidizer.
H301 Toxic if swallowed.
H400 Very toxic to aquatic life.
Abbreviations
ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road.
ADN = The European Agreement concerning the International Carriage of Dangerous Goods by Inland
waterways. ATE = Acute Toxicity Estimates. CAO = Cargo Aircraft Only. CAS = Chemical Abstract
Service. CLP = Classification, Labelling and Packaging of substances and mixtures. DIN = German
national organization for standardization. DNEL = Derived No Effect Level. EC50 = Effective
concentration median for 50% of the population. EC = European Community. EN = European Standards.
IARC = International Agency for Research on Cancer. IATA = International Air Transport Association.
IBC-Code = Intermediate Bulk Container code. IMDG = International Maritime Dangerous Goods Code.
ISO = International Organization for Standardization. STEL = Short-Term Exposure Limit. LC50 = Lethal
concentration median for 50% of the population. LD50 = Lethal dose median for 50% of the population.
TLV = Threshold Limit Value. MARPOL = The International Convention for the Prevention of Pollution
from Ships. NEN = Dutch Norm. NOEC = No Observed Effect Concentration. OEL = Occupational
Exposure Limit. OECD = Organization for Economic Cooperation and Development. PBT = Persistent,
Bioaccumulative and Toxic. PNEC = Predicted No Effect Level. PPM = Parts per million. RID = The
European Agreement concerning the International Carriage of Dangerous Goods by Rail. TWA = Time
Weight Average. UN-number = UN number at transport. vPvB = very Persistent and very
Bioaccumulative.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 24.10.2019 Version: 7.1
Date previous version: 15.02.2019 Previous version: 7.0
Product: GLYSANTIN® G05® yellow
(ID no. 30177333/SDS_GEN_EU/EN)
Date of print 28.01.2021
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.