Glysantin G05 en

Safety data sheet
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 24.10.2019 Version: 7.1
Date previous version: 15.02.2019 Previous version: 7.0
Product: GLYSANTIN® G05® yellow
(ID no. 30177333/SDS_GEN_EU/EN)
Date of print 28.01.2021
SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier
GLYSANTIN® G05® yellow

UFI: V20E-P128-P00W-JNR0
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: engine coolant
1.3. Details of the supplier of the safety data sheet
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Fuel and Lubricant Solutions
Telephone: +49 621 60-51555

E-mail address: [email protected]
1.4. Emergency telephone number
International emergency number:

Telephone: +49 180 2273-112
SECTION 2: Hazards Identification
2.1. Classification of the substance or mixture

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For the classification of the mixture the following methods have been applied: extrapolation on the
concentration levels of the hazardous substances, on basis of test results and after evaluation of
experts. The methodologies used are mentioned at the respective test results.
According to Regulation (EC) No 1272/2008 [CLP]
Acute Tox. 4 (oral)

STOT RE (Kidney) 2
H302, H373
For the classifications not written out in full in this section the full text can be found in section 16.
2.2. Label elements
Globally Harmonized System, EU (GHS)
Pictogram:
Signal Word:
Warning
Hazard Statement:
H302 Harmful if swallowed.
H373 May cause damage to organs (Kidney) through prolonged or repeated
exposure.
Precautionary Statements (Prevention):

P260 Do not breathe dust/gas/mist/vapours.
P270 Do not eat, drink or smoke when using this product.
Precautionary Statements (Response):

P314 Get medical advice/attention if you feel unwell.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you
feel unwell.
P330 Rinse mouth.
Precautionary Statements (Disposal):

P501 Dispose of contents/container to hazardous or special waste collection
point.

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Hazard determining component(s) for labelling: ethanediol
UFI: V20E-P128-P00W-JNR0
2.3. Other hazards
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture. The
product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or
the vPvB (very persistent/very bioaccumulative) criteria.
SECTION 3: Composition/Information on Ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Chemical nature
ethanediol, inhibitors
This product contains (a) substance(s) included on the candidate list according to article 59 (1,10) of
regulation EC No. 1907/2006 ('REACH') in a concentration equal or above 0.1% w/w: disodium
tetraborate, anhydrous
Hazardous ingredients (GHS)

according to Regulation (EC) No. 1272/2008
ethanediol
Content (W/W): 85 % - 95 % Acute Tox. 4 (oral)
CAS Number: 107-21-1 STOT RE (Kidney) 2
EC-Number: 203-473-3 H302, H373
REACH registration number: 01-
2119456816-28
INDEX-Number: 603-027-00-1
Sodium benzoate
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Content (W/W): >= 2 % - <= 4 % Eye Dam./Irrit. 2
CAS Number: 532-32-1 H319
EC-Number: 208-534-8
REACH registration number: 01-
2119460683-35
disodium tetraborate, anhydrous

Content (W/W): >= 1 % - <= 2 % Eye Dam./Irrit. 2
CAS Number: 1330-43-4 Repr. 1B (fertility)
EC-Number: 215-540-4 Repr. 1B (unborn child)
REACH registration number: 01- H319, H360FD
2119490790-32
INDEX-Number: 005-011-00-4 Specific concentration limit:
Repr. 1B, fertility: >= 4.5 %
Repr. 1B, unborn child: >= 4.5 %
sodium nitrite
Content (W/W): > 0.1 % - < 0.5 % Ox. Sol. 3
CAS Number: 7632-00-0 Acute Tox. 3 (oral)
EC-Number: 231-555-9 Eye Dam./Irrit. 2
REACH registration number: 01- Aquatic Acute 1
2119471836-27 M-factor acute: 1
H272, H319, H301, H400
Differing classification according to current

knowledge and the criteria given in Annex I of
Regulation (EC) No. 1272/2008
Ox. Sol. 2
Acute Tox. 3 (oral)
Eye Dam./Irrit. 2
Aquatic Acute 1
For the classifications not written out in full in this section, including the hazard classes and the
hazard statements, the full text is listed in section 16.
SECTION 4: First-Aid Measures

4.1. Description of first aid measures
Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and
transport in stable sideways position (recovery position). First aid personnel should pay attention to
their own safety.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
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On skin contact:
Immediately wash thoroughly with soap and water, seek medical attention.
On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention. Administer 50
ml of pure ethanol in a drinkable concentration.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: Additional information on symptoms and effects may be included in the GHS labeling
phrases available in Section 2 and in the Toxicological assessments available in Section 11.,
(Further) symptoms and / or effects are not known so far
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Symptomatic treatment (decontamination, vital functions).
Antidote: Administer ethanol.
SECTION 5: Fire-Fighting Measures

5.1. Extinguishing media
Suitable extinguishing media:
dry powder, alcohol-resistant foam, water spray, carbon dioxide
5.2. Special hazards arising from the substance or mixture

harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.
5.3. Advice for fire-fighters

Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.
SECTION 6: Accidental Release Measures

High risk of slipping due to leakage/spillage of product.
6.1. Personal precautions, protective equipment and emergency procedures

Use personal protective clothing.
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6.2. Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
6.3. Methods and material for containment and cleaning up

For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance
with regulations.
6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.
SECTION 7: Handling and Storage

7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Shut containers immediately after taking
product because product takes up the humidity of air.
Protection against fire and explosion:

Sources of ignition should be kept well clear.
Exposure estimate and reference to its source

Do not inhale vapours / aerosols.
7.2. Conditions for safe storage, including any incompatibilities

Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Storage in galvanized containers is not recommended.
7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.
SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters
Components with occupational exposure limits
107-21-1: ethanediol
Skin Designation (OEL (EU))
The substance can be absorbed through the skin.
STEL value 104 mg/m3 ; 40 ppm (OEL (EU))
indicative
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TWA value 52 mg/m3 ; 20 ppm (OEL (EU))
indicative
532-32-1: Sodium benzoate
1330-43-4: disodium tetraborate, anhydrous
7632-00-0: sodium nitrite
PNEC
No hazard identified.
DNEL
Data refer to the lead substances
Components with DNEL
107-21-1: ethanediol
worker: Long-term exposure - local effects, Inhalation: 35 mg/m3
worker: Long-term exposure- systemic effects, dermal: 106 mg/kg
consumer: Long-term exposure - local effects, Inhalation: 7 mg/m3
consumer: Long-term exposure- systemic effects, dermal: 53 mg/kg
7632-00-0: sodium nitrite

worker: Long- and short-term exposure - systemic effects, Inhalation: 2 mg/m3
8.2. Exposure controls

Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Combination filter for gases/vapours of
organic compounds and solid and liquid particles (f.e. EN 14387 Type A-P2)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
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General safety and hygiene measures
Do not inhale gases/vapours/aerosols. Handle in accordance with good industrial hygiene and safety
practice. Wearing of closed work clothing is recommended. Handle in accordance with good
industrial hygiene and safety practice.
SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties
Form: liquid
Colour: yellow
Odour: product specific
Odour threshold:
not determined
pH value: 6.0 - 7.0
solidification temperature: approx. -15 °C (DIN ISO 3016)
boiling temperature: > 160 °C (ASTM D1120)
Flash point: 117 °C (DIN EN 22719; ISO 2719)
Evaporation rate:
not determined
Flammability: hardly combustible (derived from flash point)
Lower explosion limit:
For liquids not relevant for
classification and labelling., The
lower explosion point may be 5 - 15
°C below the flash point.
Upper explosion limit:
For liquids not relevant for
classification and labelling.
Ignition temperature: 445 °C (DIN 51794)
Vapour pressure: 0.3 hPa
(20 °C)
Density: 1.131 g/cm3
(20 °C)
Solubility (qualitative) solvent(s): polar solvents
soluble
Partitioning coefficient n-octanol/water (log Kow):
Study scientifically not justified.
Self ignition: not self-igniting
Thermal decomposition: No decomposition if correctly stored and handled.

Viscosity, kinematic: 20 - 30 mm2/s (DIN 51562)
(20 °C)
Explosion hazard: not explosive
Fire promoting properties: not fire-propagating
9.2. Other information

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Miscibility with water:
miscible in all proportions
Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.
SECTION 10: Stability and Reactivity

10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions

The substance/product may react with secondary and tertiary amines to form nitrosamines.
10.4. Conditions to avoid

Avoid humidity. Avoid sources of ignition.
10.5. Incompatible materials
Substances to avoid:
strong oxidizing agents
10.6. Hazardous decomposition products
Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.
SECTION 11: Toxicological Information

11.1. Information on toxicological effects
Acute toxicity
Assessment of acute toxicity:

Of moderate toxicity after single ingestion. Of low toxicity after short-term skin contact.
Experimental/calculated data:
LD (human) (oral): approx. 1,600 mg/kg
Irritation
Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant
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Serious eye damage/irritation rabbit: non-irritant
Respiratory/Skin sensitization
Assessment of sensitization:
Skin sensitizing effects were not observed in animal studies. Human data do not fully exclude a skin
sensitizing potential.
Germ cell mutagenicity
No data available.
Carcinogenicity
Information on: sodium nitrite

Assessment of carcinogenicity:
Under certain conditions the substance can form nitrosamines. Nitrosamines are carcinogenic in
animal studies.
----------------------------------
Reproductive toxicity
No data available.
Developmental toxicity
Information on: ethanediol

Assessment of teratogenicity:
Developmental toxicity was observed after oral ingestion of high doses in studies with rats and mice,
but this effect was not seen in a study with rabbits. Mechanistic studies show that the rabbit is the
relevant species for the classification for human health. As such, and since ethylene glycol is not a
developmental toxicant in the rabbit, no classification is warranted.
----------------------------------
Specific target organ toxicity (single exposure)
No data available.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Information on: ethanediol

Assessment of repeated dose toxicity:
The substance may cause damage to the kidney after repeated ingestion. The substance may cause
damage to the kidney after repeated skin contact with high doses.
----------------------------------
Aspiration hazard
No aspiration hazard expected.

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Other relevant toxicity information
The product has not been tested. The statements on toxicology have been derived from the
properties of the individual components.
SECTION 12: Ecological Information

12.1. Toxicity
Toxicity to fish:
LC50 (96 h) > 100 mg/l, Leuciscus idus
Aquatic invertebrates:
EC50 (48 h) > 100 mg/l, Daphnia magna
Aquatic plants:
EC50 (72 h) > 100 mg/l, algae
Microorganisms/Effect on activated sludge:

Inhibition of degradation activity in activated sludge is not to be anticipated during correct
introduction of low concentrations.
12.2. Persistence and degradability
Elimination information:
> 70 % DOC reduction (28 d) (OECD 301 A (new version)) Readily biodegradable.
12.3. Bioaccumulative potential
Assessment bioaccumulation potential:

Significant accumulation in organisms is not to be expected.
12.4. Mobility in soil
Assessment transport between environmental compartments:

Adsorption in soil: No data available.
12.5. Results of PBT and vPvB assessment
According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance
fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very
bioaccumulative) criteria.
12.6. Other adverse effects

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The product does not contain substances that are listed in Regulation (EC) 1005/2009 on
substances that deplete the ozone layer.
12.7. Additional information
Adsorbable organically-bound halogen (AOX):

This product contains no organically-bound halogen.
Other ecotoxicological advice:

The product has not been tested. The statement has been derived from the properties of the
individual components.
Do not release untreated into natural waters.
SECTION 13: Disposal Considerations
13.1. Waste treatment methods
Must be disposed of or incinerated in accordance with local regulations.
The waste codes are manufacturer's recommendations based on the designated use of the product.
Other use and special waste disposal treatment on customer's location may require different waste-
code assigments.
Waste key:
16 01 14¤ antifreeze fluids containing hazardous substances
Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
SECTION 14: Transport Information
Land transport
ADR
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
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RID
user
Inland waterway transport

ADN
user:
Transport in inland waterway vessel

Not evaluated
Sea transport
IMDG
user
Air transport
IATA/ICAO
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user
14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.
14.2. UN proper shipping name

See corresponding entries for “UN proper shipping name” for the respective regulations in the tables
above.
14.3. Transport hazard class(es)

See corresponding entries for “Transport hazard class(es)” for the respective regulations in the
tables above.
14.4. Packing group

See corresponding entries for “Packing group” for the respective regulations in the tables above.
14.5. Environmental hazards

See corresponding entries for “Environmental hazards” for the respective regulations in the tables
above.
14.6. Special precautions for user

See corresponding entries for “Special precautions for user” for the respective regulations in the
tables above.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
SECTION 15: Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Prohibitions, Restrictions and Authorizations
Annex XVII of Regulation (EC) No 1907/2006: Number on List: 3, 30
15.2. Chemical Safety Assessment

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Assessment of safe use has been performed for the mixture and the result is documented in section
7 and 8 of the SDS
SECTION 16: Other Information
Assessment of the hazard classes according to UN GHS criteria (most recent version)
Acute Tox. 4 (oral)

STOT RE (Kidney) 2
Full text of the classifications, including the hazard classes and the hazard statements, if mentioned
in section 2 or 3:
Acute Tox. Acute toxicity
STOT RE Specific target organ toxicity — repeated exposure
Eye Dam./Irrit. Serious eye damage/eye irritation
Repr. Reproductive toxicity
Ox. Sol. Oxidising solids
Aquatic Acute Hazardous to the aquatic environment - acute
H302 Harmful if swallowed.
H373 May cause damage to organs (Kidney) through prolonged or repeated
exposure.
H319 Causes serious eye irritation.
H360FD May damage fertility. May damage the unborn child.
H272 May intensify fire; oxidizer.
H301 Toxic if swallowed.
H400 Very toxic to aquatic life.
Abbreviations
ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road.
ADN = The European Agreement concerning the International Carriage of Dangerous Goods by Inland
waterways. ATE = Acute Toxicity Estimates. CAO = Cargo Aircraft Only. CAS = Chemical Abstract
Service. CLP = Classification, Labelling and Packaging of substances and mixtures. DIN = German
national organization for standardization. DNEL = Derived No Effect Level. EC50 = Effective
concentration median for 50% of the population. EC = European Community. EN = European Standards.
IARC = International Agency for Research on Cancer. IATA = International Air Transport Association.
IBC-Code = Intermediate Bulk Container code. IMDG = International Maritime Dangerous Goods Code.
ISO = International Organization for Standardization. STEL = Short-Term Exposure Limit. LC50 = Lethal
concentration median for 50% of the population. LD50 = Lethal dose median for 50% of the population.
TLV = Threshold Limit Value. MARPOL = The International Convention for the Prevention of Pollution
from Ships. NEN = Dutch Norm. NOEC = No Observed Effect Concentration. OEL = Occupational
Exposure Limit. OECD = Organization for Economic Cooperation and Development. PBT = Persistent,
Bioaccumulative and Toxic. PNEC = Predicted No Effect Level. PPM = Parts per million. RID = The
European Agreement concerning the International Carriage of Dangerous Goods by Rail. TWA = Time
Weight Average. UN-number = UN number at transport. vPvB = very Persistent and very
Bioaccumulative.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Page: 16/16
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.

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Safety data sheet

SECTION 1: Identification of the substance/mixture and of the

GLYSANTIN® G05® yellow

Relevant identified uses: engine coolant

1.3. Details of the supplier of the safety data sheet

Telephone: +49 621 60-51555

1.4. Emergency telephone number

International emergency number:

SECTION 2: Hazards Identification

2.1. Classification of the substance or mixture

According to Regulation (EC) No 1272/2008 [CLP]

Acute Tox. 4 (oral)

2.2. Label elements

Globally Harmonized System, EU (GHS)

Precautionary Statements (Prevention):

Precautionary Statements (Response):

Precautionary Statements (Disposal):

According to Regulation (EC) No 1272/2008 [CLP]

2.3. Other hazards

According to Regulation (EC) No 1272/2008 [CLP]

SECTION 3: Composition/Information on Ingredients

Hazardous ingredients (GHS)

disodium tetraborate, anhydrous

Differing classification according to current

SECTION 4: First-Aid Measures

On contact with eyes:

SECTION 5: Fire-Fighting Measures

5.2. Special hazards arising from the substance or mixture

5.3. Advice for fire-fighters

SECTION 6: Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and Storage

Protection against fire and explosion:

Exposure estimate and reference to its source

7.2. Conditions for safe storage, including any incompatibilities

7.3. Specific end use(s)

SECTION 8: Exposure Controls/Personal Protection

Components with occupational exposure limits

Components with DNEL

7632-00-0: sodium nitrite

8.2. Exposure controls

SECTION 9: Physical and Chemical Properties

Thermal decomposition: No decomposition if correctly stored and handled.

9.2. Other information

SECTION 10: Stability and Reactivity

10.2. Chemical stability

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

10.5. Incompatible materials

10.6. Hazardous decomposition products

Hazardous decomposition products:

SECTION 11: Toxicological Information

Assessment of acute toxicity:

Serious eye damage/irritation rabbit: non-irritant

Germ cell mutagenicity

Information on: sodium nitrite

Information on: ethanediol