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Nuclear Energy

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Chapter 18

Nuclear Chemistry
Chapter
Map
Nuclides

• Nuclide = a particular type of


nucleus, characterized by a
specific atomic number and
nucleon number
• Nucleon number or mass number
= the number of nucleons
(protons and neutrons) in the
nucleus of a nuclide.
Nuclide Symbolism
Nuclear Stability
• Electrostatic force = the force that
causes opposite electrical charges
to attract each other.
• Strong force = the force between
nucleons (protons and neutrons).
• Neutrons increase the attraction
from the strong force without
increasing electrostatic repulsion
between nucleons.
Band of
Stability
Alpha Emission
Beta Emission
Positron Emission
Electron Capture
Gamma Emission
Nuclear Reactions
• Nuclear reactions involve changes
in the nucleus, whereas chemical
reactions involve the loss, gain,
and sharing of electrons.
• Different isotopes of the same
element may undergo very
different nuclear reactions, even
though an element’s isotopes all
share the same chemical
characteristics.
Nuclear Reactions
(cont.)
• Unlike chemical reactions, the rates
of nuclear reactions are unaffected
by temperature, pressure, and the
presence of other atoms to which
the radioactive atom may be
bonded.
• Nuclear reactions, in general, give
off much more energy than
chemical reactions
Nuclear
Equations
General Nuclear Equations
Half-life = the time it takes for
one-half of a sample to disappear.
Radioactive Decay Series
Radiation Effect on
Body
• Radioactive emissions ionize atoms and
molecules. This also leads to free
radicals (particles with unpaired
electrons).
H2O → H2O●+ + e−
H2O●+ + H2O → H3O+ + ●OH
H2O + e− → H● + OH−
• These reactive particles react with
important substances in the body,
leading to immediate damage and
delayed problems, such as cancer.
Uses for Radioactive
Nuclides
• Cancer radiation treatment
• Computer imaging techniques
• Radiocarbon dating
• Smoke detectors
• Food irradiation
• Radioactive tracers
Nuclear Energy
• Binding energy = the amount of energy
released when a nucleus is formed.
• Binding energy per nucleon generally
increases from small atoms to atoms with
a mass number around 56. Thus fusing
small atoms to form medium-sized atoms
(nuclear fusion) releases energy.
• Binding energy per nucleon generally
decreases from atoms with a mass
number around 56 to larger atoms. Thus
splitting large atoms to form medium-
sized atoms (nuclear fission) also
releases energy.
Binding
Energy
per Nucleon
Nuclear Fission
Chain
Reaction
Nuclear Reactor
Nuclear Fusion Powers the Sun

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