Gas Laws

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CHAPTER 12

1. According to the Kinetic Molecular Theory:


a. Gas particles are in constant, random motion.
b. When gas particles collide with each other, they rebound and travel in new directions.
When they collide with the walls of the container, they exert a pressure.
c. The size of gas particles is small compared to the space between the particles.
d. The attractive forces among the particles of a gas are negligible.
e. The kinetic energy of gas particles increases with increasing temperature.

2. Pressure is the amount of force applied over a given area.

3. The standard unit for pressure is atmospheres (atm).


1 atm = 760 mmHg (millimeters of mercury) (exact)
1 atm = 760 torr (exact)
1 atm = 1.013 bar
1 atm = 14.7 psi (pounds per square inch)
1 atm = 1.013 x 105 Pa (Pascal)

4. Atmospheric pressure (or barometric pressure) is due to the downward pressure caused by
molecules of air in the atmosphere.

5. Boyle’s Law states that at constant temperature (T) and no. of moles of gas (n), the pressure
of a gas (P) is indirectly proportional to its volume (V).
P1V1 = P2V2

6. Charles’ Law states that at constant P and n, the V of a gas is directly proportional to the T.
V1 V
= 2
T1 T2

7. Combined Gas Law


P1V1 P2 V2
=
T1 T2

8. Avogadro’s Law states that at constant P and T, the V occupied by a gas is directly
proportional to n of gas.
V1 V2
=
n1 n2

9. Standard Temperature and Pressure (STP)


Temperature (T) = 273.15 K
Pressure (P) = 1 atm
1 mol = 22.4 L
10. Ideal Gas Law
PV = nRT
L i atm
R = 0.0821
mol i K

11. The ideal gas law can be used to calculate the molar mass of a gas.
a. Calculate the number of moles using PV=nRT.
b. Use the formula below to calculate the molar mass.
grams
MM =
moles
dRT
MM =
P

12. Dalton’s Law of Partial Pressure


The total pressure by a mixture of gases is equal to the sum of the partial pressures of the
gases in the mixture
PTOT = PA + PB + PC + ….

nA
XA =
nTOTAL

PA = X APTOTAL

13. The average kinetic energy of gaseous molecules is directly proportional to the absolute
temperature of the sample. The average kinetic energies of molecules of different gases are
equal at a given temperature.
3RT
u= u: average speed
MW

14. The rate of effusion of a gas is inversely proportional to the square root of its molecular weight.

15. Diffusion is a process that causes gases to spontaneously intermingle when they are brought
together.

16. Effusion is a process in which a gas escapes from a container through a small hole.
1

rate of effusion B ⎛ MW ⎞ 2
= ⎜⎜ A
⎟⎟
rate of effusion A ⎝ MWB ⎠

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