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    Review Material For Exam #3

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    quimicosorio
    The document provides a review of material for Exam #3 covering topics in atomic structure, quantum mechanics, periodic trends, and chemical bonding. It includes 18 problems involving calculations of wavelengths, frequencies, energies, ionization energies, atomic radii, electron configurations, and drawing Lewis structures. Sample problems include calculating the wavelength of light emitted during an electron transition in hydrogen and determining the missing energy in a Born-Haber cycle for the formation of lithium oxide.

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    Review Material For Exam #3

    Uploaded by

    quimicosorio
    39 views3 pages
    The document provides a review of material for Exam #3 covering topics in atomic structure, quantum mechanics, periodic trends, and chemical bonding. It includes 18 problems involving calculations of wavelengths, frequencies, energies, ionization energies, atomic radii, electron configurations, and drawing Lewis structures. Sample problems include calculating the wavelength of light emitted during an electron transition in hydrogen and determining the missing energy in a Born-Haber cycle for the formation of lithium oxide.

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    The document provides a review of material for Exam #3 covering topics in atomic structure, quantum mechanics, periodic trends, and chemical bonding. It includes 18 problems involving calculations of wavelengths, frequencies, energies, ionization energies, atomic radii, electron configurations, and drawing Lewis structures. Sample problems include calculating the wavelength of light emitted during an electron transition in hydrogen and determining the missing energy in a Born-Haber cycle for the formation of lithium oxide.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    39 views3 pages

    Review Material For Exam #3

    Uploaded by

    quimicosorio
    The document provides a review of material for Exam #3 covering topics in atomic structure, quantum mechanics, periodic trends, and chemical bonding. It includes 18 problems involving calculations of wavelengths, frequencies, energies, ionization energies, atomic radii, electron configurations, and drawing Lewis structures. Sample problems include calculating the wavelength of light emitted during an electron transition in hydrogen and determining the missing energy in a Born-Haber cycle for the formation of lithium oxide.

    Copyright:

    © All Rights Reserved
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    of 3

    Review Material for Exam #3

    1. Radio waves for Rocket 101 are emitted at a frequency of 100.9 MHz (or s –1). Calculate
    the wavelength, in m, of this radiation.

    2. Light with a wavelength of 465 nm lies in the blue region of the visible spectrum.
    Calculate the frequency of this light. What is the energy associated with this
    wavelength?

    3. The green line in the atomic spectrum of thallium has a wavelength of 535 nm.
    Calculate the energy of 2.00 moles of photons of this light.

    4. The electron in the 5th energy level of Be3+ goes down to the first level. Calculate:

    a. The change in energy (J) of the electron.


    b. The frequency of light emitted (s–1).
    c. The wavelength of light emitted, in m and nm.

    5. Calculate the frequency of electromagnetic radiation emitted by the hydrogen atom in


    the electron transition from n = 4 to n = 3. What is the wavelength (in nm) emitted?

    6. State whether the following are valid sets of quantum numbers and if not why:

    n ℓ mℓ ms

    a. 2 0 0 +1/2
    b. 1 1 –1 –1/2
    c. 3 2 –2 +1/2
    d. 2 1 0 –1/2
    e. 2 0 1 –1/2
    f. 4 2 –3 +1/2
    g. –4 1 0 +1/2

    7. Draw the shapes (including the orientation) of all the s, p and d orbitals.

    8. Give the ground state electron configuration for the following:


    S2–, Te+, V5+, Nb2+, Cu, Zn+, Cl–, Ba, Re, F, As3–, Cr

    9. What is the atomic number and the complete ground state electron configuration of the
    yet undiscovered element directly below Fr in the periodic table?

    10. Which of the following atoms, Na, Mg, S, or K has the

    a. smallest atomic radius


    b. lowest ionization energy
    11. Which of the following atoms, Ca, As, Br, or Rb has the

    a. largest atomic radius


    b. highest ionization energy

    12. Which of the following are larger than an N atom?

    a. N3– b. N5+ c. O d. C e. P

    13. On the basis of their position on the periodic table, select the atom with the larger atomic
    radius in each of the following pairs:

    a. Na, Cs e. Ne, Xe
    b. Be, Ba f. Na, P
    c. N, Sb g. K, Ge
    d. F, Br h. Al, Cl

    14. Explain why it is unusual for IE1 of S to be lower then IE1 of P. Give a possible
    explanation.

    15. Identify each ion:

    a. 3+ ion: 1s22s22p6
    b. 3+ ion: 1s22s22p63s23p63d3
    c. 2+ ion: 1s22s22p63s23p64s23d104p65s24d10
    d. 2– ion: 1s22s22p63s23p64s23d104p6

    16. Write the reaction of each of the oxides with water: K2O, MgO, P2O5, SO2, CO2.

    17. Use a Born-Haber Cycle to calculate the missing energy (bold) of the following:

    a. ΔHfo BeI2(s) –208 kJ/mole BeI2


    Hsublimation Be(s) +302 kJ/mole
    Be(g) IE1 +903 kJ/mole
    IE2 +1757 kJ/mole
    Hdissociation I2(s) +107 kJ/mole I
    EA I(g) –295 kJ/mole
    Hlattice BeI2(s) ? kJ/mole BeI2

    b. Li(g) Li+(g) + e–  = +540 kJ/mole


    Li(s) Li(g) Hsublimation = +162 kJ/mole
    1/2 O2(g) O(g) Hdissociation = ? kJ/mole O
    O(g) + 2 e –
    O2–(g)  = +598 kJ/mole
    + 2–
    2 Li (g) + O (g) Li2O(s) Hlattice = –2800 kJ/mole Li2O
    2 Li(s) + 1/2 O2(g) Li2O(s) Hfº = –554 kJ/mole Li2O
    c. ΔHfo MnS(s) –212 kJ/mole MnS
    Hsublimation Mn(s) ? kJ/mole
    Mn(g) IE1 +721 kJ/mole
    IE2 +1509 kJ/mole
    Hsublimation S(s) +264 kJ
    S(g) EA1 –200 kJ/mole
    EA2 +446 kJ/mole
    Hlattice MnS(s) –3176 kJ/mole MnS

    d. ΔHfo Th2S3(s) ? kJ/mole


    Hsublimation Th(s) +528 kJ/mole
    Th(g) IE1 +590 kJ/mole
    IE2 +1110 kJ/mole
    IE3 +1930 kJ/mole
    IE4 +2780 kJ/mole
    Hdissociation S8(s) +279 kJ/mole S
    S(g) EA1 –200 kJ/mole
    EA2 +589 kJ/mole
    Hlattice Th2S3(s) –10397 kJ/mole

    18. Draw the best Lewis structure of each of the following. Include all lone-pair electrons
    and non-zero formal charges on each atom:

    CCl4, PH3, O3, CO32–, NO3–, H2CO, C2H4, N2, SiF4, HCN, NH4+

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