Revision date: 05/11/2019 Revision: 00

SAFETY DATA SHEET

NITOFLOR HARDTOP GREY

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name NITOFLOR HARDTOP GREY

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Monolithic surface hardening compound

1.3. Details of the supplier of the safety data sheet

Supplier Fosroc Chemical (India) Pvt. Ltd
Embassy Point, No 150, 2nd Floor,
Infantry Road,
Bangalore - 560001
+91 80 2355 1500/ 4252 1900
+91 80 2355 1510

1.4. Emergency telephone number

Emergency telephone +91 80 2355 1500/ 4252 1900

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Corr. 1A - H314 Eye Dam. 1 - H318 STOT SE 3 - H335

Environmental hazards Not Classified

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.

Precautionary statements P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P321 Specific treatment (see medical advice on this label).
P501 Dispose of contents/ container in accordance with national regulations.

Contains CEMENT

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Supplementary precautionary P260 Do not breathe dust.

statements P261 Avoid breathing dust.
P264 Wash contaminated skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P310 Immediately call a POISON CENTER/ doctor.
P312 Call a POISON CENTRE/doctor if you feel unwell.
P363 Wash contaminated clothing before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

CEMENT 30-60%
CAS number: 65997-15-1

Classification Classification (67/548/EEC or 1999/45/EC)

Skin Corr. 1A - H314 -
Eye Dam. 1 - H318
STOT SE 3 - H335

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Remove affected person from source of contamination. Move affected person to fresh air at
once. Get medical attention.

Ingestion Rinse mouth thoroughly with water. Get medical attention if any discomfort continues.

Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash
skin thoroughly with soap and water. Get medical attention if irritation persists after washing.

Eye contact Remove affected person from source of contamination. Remove any contact lenses and open
eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation Dust may irritate the respiratory system.

Ingestion May cause chemical burns in mouth and throat.

Skin contact May cause serious chemical burns to the skin.

Eye contact Eye contact may cause serious and potentially irreversible injuries.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

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Specific hazards No specific hazard known.

Hazardous combustion Does not decompose when used and stored as recommended.
products

5.3. Advice for firefighters

Protective actions during Move containers from fire area if it can be done without risk. Contain and collect extinguishing
firefighting water.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid inhalation of dust. Avoid contact with eyes and prolonged skin contact. Wear protective
clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Environmental precautions Avoid discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Avoid generation and spreading of dust. Collect and place in suitable waste disposal
containers and seal securely. Label the containers containing waste and contaminated
materials and remove from the area as soon as possible. Flush contaminated area with plenty
of water.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid inhalation of dust and contact with skin and eyes. Observe any occupational exposure
limits for the product or ingredients.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Corrosive storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
CEMENT
Long-term exposure limit (8-hour TWA): WEL 4 mg/m³
WEL = Workplace Exposure Limit

Ingredient comments WEL = Workplace Exposure Limits

8.2. Exposure controls

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Protective equipment

Appropriate engineering Provide adequate ventilation. Avoid inhalation of dust. Observe any occupational exposure
controls limits for the product or ingredients.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Dust-resistant, chemical
splash goggles. (conform EN 166)

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. It is recommended that gloves are made
of the following material: Polyvinyl chloride (PVC).

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Do not smoke in work area. Wash at the end of each work shift and before eating, smoking
and using the toilet. Wash promptly if skin becomes contaminated. Promptly remove any
clothing that becomes contaminated. When using do not eat, drink or smoke.

Respiratory protection Wear a suitable dust mask. Protection against nuisance dust must be used when the airborne
concentration exceeds 10 mg/m3. (EN 149) Dust filter P2 (for fine dust).

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Dusty powder.

Colour Pigmented

Odour Odourless.

pH > 12

Upper/lower flammability or The product is not flammable.

explosive limits

Relative density ~ 2.0 @ 25°C

Solubility(ies) Insoluble in water.

Explosive under the influence Not considered to be explosive.

of a flame

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

Other information Not determined.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity When mixed with water, hardens to form a stable mass that is not reactive in normal
conditions.

10.2. Chemical stability

Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

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Possibility of hazardous No potentially hazardous reactions known.

reactions

10.4. Conditions to avoid

Conditions to avoid Water, moisture.

10.5. Incompatible materials

Materials to avoid Acids. Chemically-active metals.

10.6. Hazardous decomposition products

Hazardous decomposition No known hazardous decomposition products.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Inhalation Dust may irritate the respiratory system.

Ingestion May cause chemical burns in mouth and throat.

Skin contact May cause serious chemical burns to the skin.

Eye contact Eye contact may cause serious and potentially irreversible injuries.

Toxicological information on ingredients.

CEMENT

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 2,000.0

mg/kg)

Species Rabbit

Serious eye damage/irritation

Serious eye Causes serious eye irritation.

damage/irritation

SECTION 12: Ecological information

12.1. Toxicity
Toxicity Not considered toxic to fish.

12.2. Persistence and degradability

Persistence and degradability The product is not expected to be biodegradable.

Ecological information on ingredients.

CEMENT

Persistence and Expected to be not readily biodegradable.

degradability

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

Ecological information on ingredients.

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CEMENT

Bioaccumulative potential No data available on bioaccumulation.

12.4. Mobility in soil

Mobility Insoluble in water.

Ecological information on ingredients.

CEMENT

Mobility Insoluble in water.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

Ecological information on ingredients.

CEMENT

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

Ecological information on ingredients.

CEMENT

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3262

UN No. (IMDG) 3262

UN No. (ICAO) 3262

UN No. (ADN) 3262

14.2. UN proper shipping name

Proper shipping name CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (CONTAINS CEMENT )
(ADR/RID)

Proper shipping name (IMDG) CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (CONTAINS CEMENT )

Proper shipping name (ICAO) CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (CONTAINS CEMENT )

Proper shipping name (ADN) CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (CONTAINS CEMENT )

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14.3. Transport hazard class(es)

ADR/RID class 8

ADR/RID classification code C6

ADR/RID label 8

IMDG class 8

ICAO class/division 8

ADN class 8

Transport labels

14.4. Packing group

ADR/RID packing group I

IMDG packing group I

ICAO packing group I

ADN packing group I

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

IMDG Code segregation 18. Alkalis
group

EmS F-A, S-B

ADR transport category 1

Emergency Action Code 2X

Hazard Identification Number 88

(ADR/RID)

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Manufacture, storage and import of hazardous chemicals rules 1989.

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EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information For professional use only. Only trained personnel should use this material.

Revision comments This is the first issue.

Revision date 05/11/2019

Revision 00

SDS number 28078

Hazard statements in full H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.

The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

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