MCQ’S QUESTION

Bold option is the answer of the each question

1) According to the Boyle’s law the volume of a fixed mass of a gas, at constant temperature, is
a) Directly proportional to its pressure b) inversely proportional to its pressure
c) The square root of its pressure d) none of these
2) Mathematically, Boyle’s law can be represented as
a) V b) c) VP = k d) all of these
3) At constant temperature, the pressure of the gas is reduced to one third, the volume
a)reduces to one third b) increases by three times
b) remains the same d) cannot be predicted
4) At constant pressure, the volume of a fixed mass of a gas is
a) Directly proportional to its temperature
b) directly proportional to its absolute temperature
c) Inversely proportional to its temperature
d) inversely proportional to its absolute temperature
5) Which of the following is the correct mathematical relation for charle’s law at constant
pressure?
a) Vα t b) V α T c) V = kt d) none of these
6) According to Gay Lussac’s law for a fixed volume of a given gas
a) = a constant b) P c) P= d) PT = k
7) Equal volume of all gases at the same temperature and pressure contain equal number of
molecules is the statements of
a) Combined gas law b) charle’s law
c) Avogadro’s law d) Boyle’s law
8) For one mole of a gas, the ideal gas equation is
a) PV = RT b) PV = RT c) PV = RT d) PV = RT
9) The unit of R , the gas constant are
a) ergK-1 mol-1 b) cal K-1 mol-1 c) joule K-1 mol-1 d) all of these

10) In lit atm K-1 mol-1 the numerical value of R, the gas constant is
a) 0.821 b) 0.0821 c) 0.00821 d) 0.000821
11) The total pressure of a mixture of gases is equal to the sum of the partial pressure of all the
gases prsent is the statement of
a) Graham’s law of diffusion b) Dalton’s law of partial pressures
c) Avogadro’s law of partial pressure d) none of these
12) Under same conditions of temperature and pressure, the rates of diffusion of different gases
are
a) Directly proportional to the square root of the molecular masses
b) Directly proportional to the square root of the vapour densities
c) Inversely proportional to the square roots of theirs molecular masses
d) Inversely proportional to the square roots of their molar volumes.
13) The average kinetics energy of the gas molecule is
a) Inversely proportional to its absolute temperature
b) Directly proportional to its absolute temperature
c) Equal to square of its absolute temperature
d) Directly proportional to square root of its absolute temperature
14) For one moles of a gas the kinetics energy is given by the equation
a) E = ½ RT b) E = 3/2 RT c) E = 5/2 RT d) E = 7/2 RT
15) The kinetic gas equation is given by the relation
a) PV = 1/3 mNµ2 b) PV = 1/2 mNµ2
c) PV = 1/4 mNµ2 d) PV = 2/3 mNµ2
16) The average velocity of a gas is given by the equation
a) v = b) v =
c) v = d) v =
17) The root mean square velocity of gas molecules is given by the relation
a) µ = b) µ =
c) µ = d) µ =
18) The root mean square velocity of gas molecules is given by the relation
a) µ = b) µ = c) µ = d) all of these
19) The free path is the distance travelled by the molecules
a) Before collision b) in one second
c) after collision d) in one minute
20) The mean free path is
a) directly proportional to the pressure of a gas
b) directly proportional to the mean square velocity of the gas
c) directly proportional to the temperature of the gas
d) directly proportional to the absolute temperature of the gas
21) The collision frequency of a gas is
a) directly proportional to the square root of absolute temperature of
b) directly proportional to the absolute temperature
c) directly proportional to the pressure of the gas
d) inversely proportional to the absolute temperature
22) The value of γ, the specific heat ratio ,for a monoatomic gas is
a) 0 b)1.40 c) 1.667 d)1.33
23) The compressibility factor z, i.e.the extent to which a real gas deviates from ideal behaviour
is given by
a) z = b) z = c) z = d) z =
24) The real gases show nearly ideal behaviour at
a) low pressure and low temperature b) high pressure and low temperatures
c) high pressures and high temperatures d) low pressures and high temperatures
25) Excluded volume is ......... times the actual volume of molecules
a) Half b) two c) three d) four
26) The pressure P in ideal gas equation is replaced by
a)p + b) p - c) p + d) p +
27) The unit of a the van der Waals constant are
a) atm lit mol-1 b) atm lit-1 mol-1 c) atm lit-2 mol-2 d) atm lit-1 mol-2

28) Which of the following is incorrect?

a) the critical temperature of the gas is that temperature above which it can be liquefied
no matter how pressure is applied
b) the critical pressure is the minimum pressure required to liquefy the gas at its critical
temperature
c) the critical volume is the volume occupied by one mole of the gas at critical
temperature and critical volume
 d) none of these
29) Which of the following relation is correct?
a) Vc = 3b b) Pc = a /27Rb2 c) Tc = 8a /27Rb d) none of these
30) The van der Waals reduced equation of state is
a)[ π+3/ɸ2](3ɸ-1) = 8Ɵ b)[ π+3/ɸ](3ɸ+1) = 8Ɵ
c)[ π-3/ɸ2](3ɸ+1) = 8Ɵ d)[ π+3/ɸ2]( ɸ/3+1) = 8Ɵ
31) How many molecules present in 0.2g of hydrogen molecule?
a)6.023×1023 b) 6.023×1022 c) 3.0125×1023 d) 3.0125×1022
32) Gas A diffuses twice as fast as another gas B. If the vapour density of gas A is 2 ,the
molecular mass of gas B is
a) 2 b) 4 c) 8 d) 16
33) A container contain a gas at 1 atm pressure .to compress it to 1/3 of its initial volume,
pressure to be applied is
a) 1 atm b) 2 atm c) 3 atm d) 6 atm
34) The ratio of most probable velocity, average velocity and root mean square velocity of
molecules of gas is
a) 1.28: 1:1.224 b) 1.28:1.224:1
c) 1:1.28:1.224 d) 1:1.224:1.28
35) Which of the following gases will have the highest rate diffusion?
a) Methane b) ammonia c) nitrogen d) carbon dioxide
36) 290 ml of gas at 17 degree Celsius is cooled at -13degree Celsius at constant pressure .The
new volume of the gas will be
a)260ml b) 270 ml c) 280 ml d) 290 ml
37) The volume of a gas at zero degrees Celsius is 273 ml .its volume at 12 degree Celsius and
the same pressure will be
a)273+12/273 ml b)273 + 273/12m
c)273+12 ml d) 273 -12ml
38) If the pressure and absolute temperature of 3 litre of a gas are doubled, its volume would be
a)2 litre b) 3 litre c) 6 litre d) 12 litre
39) The mass of 2240ml of carbon dioxide at NTP will be
a)4 g b) 4.4g c)8.8g d)8 g
40) The mass of 224 ml of nitrogen molecule on liquefaction will be
a) 28 g b) 14g c) 1.4g d) 2.8g
41) The root mean square velocity of a certain gas at 27 degree Celsius is y cm sec-1 .the
temperature at which its velocity will be 2y is
a)54 degree Celsius b) 108 degree Celsius c) 600 K d) 1200K
42) Out of the following pairs of gases, which will diffuse through a porous plug with the same
rate of diffusion?
a) NO,CO b) CH4 , O2 c) NO2,CO2 d) NO, C2H6
43) 8 g of methane and 2g of hydrogen are mixed and kept at 760 mm pressure at 273 K. the
total volume occupied by the mixture will be
a) 11.2 lit b) 22.4 lit c) 33.6 lit d) 44.8 lit.
44) The root mean square velocity of a certain gas at 27oC is a m sec-1. Its root mean square
velocity at 927oC
a) a/2 m sec-1 b) 2a m sec-1 c) 3a m sec-1 d) 6a m sec-1
45) In a closed flask of one litre, 2g of hydrogen gas is heated from 27 C to 327oC .which of the
o

following is incorrect?
a) The pressure of the gas increases
b) the kinetic energy of gaseous molecules increases
c) the rate of collision increases
 d) The number of moles of the gas increases
46) Which of the following gases will have the lowest rate of diffusion?
a) H2 b) F2 c) N2 d) O2
47) A gas is heated at constant temperature then
a) The number of molecules of the gas increases
b) The kinetic energy of gas decrease
c) The kinetic energy of gas remains unaltered
d) The kinetic energy of gas increases
48) Equal volume of methane and ethane are mixed in an empty container at 25oC.the fraction of
total pressure exerted by ethane is
a) 1/2 b) 2/3 c) 1/4 d) 3/2
49) In van der Waals equation of state for a non ideal gas the net force of attraction among the
molecules is given by
a) an2/v2 b) p+an2/v2 c) p-an2/v2 d) -an2/v2
50) The compressibility factor, z, for an ideal gas is
a) Zero b) less than one c) greater than one d) equal to one

LIQUID STATE
1) The molecules which have partial positive charge at one end and a partial negative charge at
the other are called
a) ion pairs b) charged molecules c) dipoles d) electric molecules
2) the momentary attractions between the molecules of a liquid caused by instantaneous dipoles
and induced dipole attractions are called
a)van der waals forces b)polar forces
c)French forces d) London forces
3) The strength of hydrogen bonding is about ................ as that of a covalent bond.
a)1/2 b) 1/3 c) 1/10 d)1/100
4) Which of the following statement is incorrect?
a) the pressure exerted by the vapour in equilibrium with the liquid at a fixed temperature
is called vapour pressure
b) the vapour pressure increases with rise in temperature
c) at equilibrium liquid and vapour
d) at equilibrium ,the rate of evaporation is not equal to the rate of condensation
5) The boiling point of a liquid is that temperature at which
a) the vapour pressure of the liquid is equal to the atmospheric pressure
b) the vapour pressure of the liquid is less than the atmospheric pressure
c) the vapour pressure of the liquid is greater than the atmospheric pressure
d)the vapour pressure of the liquid is equal to the square root of the atmospheric pressure
6) The unit in which surface tension is measured is
a) dyne per centimetre b) dyne centimetre
c) per dyne centimetre d) per dyne per centimetre
7) With rise in temperature, the surface tension is measured is
a) Increases b) decreases c) remains same d) none of the above
8) The formula used for the determination of surface tension by capillary rise method is
a) 2γ = hrdg b) 2γ = hr2 dg c) 2γ = πr cos θ d) 2γ = πhr2 dg
9) In drop weight method for determination of surface tension of liquids, the formula used is
a) = b) = c) = d) none of the above

10) Viscosity of a given liquid is a measure of

a) Repulsive forces between the liquid molecules
b) Frictional resistance
c) Intermolecular forces between the molecules
d) None of the above
11) The reciprocal of the viscosity is called
a) surface tension b)frictional resistance
c) fluidity d)none of the above
12) The dimension in which coefficient of viscosity is expressed are
a) Mass length time -1 b) mass length-1 time -1
c) mass length-1 time d) mass-1 length-1 time -1
13) The SI unit of coefficient of viscosity is
a) kg m2 sec b) kg m sec-1 c)kg m-1 sec d) kg m-1 sec-1
14) The formula used for the determination of relative viscosity by Ostwald method is
a) b) c) d)

15) In general ,the viscosity.................with temperature

a)decreases b)increases
c) remains the same d)none of the above
16 ) association of molecules in water is due to
a) surface tension b) viscosity
c) hydrogen bonding d) optical activity
17) With the increasing molecular mass of a liquid, the viscosity
a) Increases b) decreases c) no effect d) none of these
18) Which of the following liquids has the maximum viscosity
a)water b) acetone c) ethyl alcohol d) glycerine
19) The fluidity of liquid ..............with increase in temperature
a) decreases b) remains the same
c) increases d) none of these
20) a liquid rises in a capillary tube .it is due to
a) surface tension b)viscosity c) osmosis d) effusion
21) A liquid in equilibrium with its vapours at its boiling point. On the average ,the molecuales
in the two phases have equal
 a) potential energy b) kinetic energy
c) van der Waals forces d) total energy
22) The rate of evaporation of a liquid depends upon
a) surface tension b) temperature
c) nature of liquid d)all of these
23) The highest temperature at which vapour pressure of a liquid can be measured is
a) boiling point of the liquid b) freezing point of the liquid
c) inversion temperature d) critical temperature
24) Small droplets are spherical in shape .It is due to
a) High viscosity
b) their tendency to acquire minimum surface area
c) their tendency to acquire maximum surface area
d) less viscosity
25) Insects can walk on the surface of water due to
a) Viscosity b) surface tension
c) refractivity d) optical activity
26) The cleaning action of soaps and detergents due to
a) Internal friction b) high hydrogen bonding
c) viscosity d) surface tension
27) The work in ergs required to be done to increases the surface area by one sq. Cm is called
a) surface tension b) internal friction
c) fluidity d) surface energy
28) While determining viscosity of a liquid with the help of a viscometer, the liquid was sucked
with great difficulty . the liquid may be
a) water b) acetone c) ether d) glycerine
29) The vapour pressure of a liquid at a given temperature is given by
a) RT b) RT2 c) RT d) RT3

30) Which of the following is correct?

a) the rate of condensation is equal to the rate of evaporation at equilibrium in a closed
container
b) the concentration of the molecules in vapour phase decreases continuously
c) the concentration of the molecules in vapour phase remains unchanged at equllibrium
d) none of the above
31) The vapour pressure of non polar liquids is
a) fairly high as compared to polar liquids
b) fairly low as compared to polar liquids
c) the same as that of a liquids
d) none of the above
32) The boiling point of a liquid .......... with external pressure
a) Changes b) always increases
c) always decreases d) remains the same
33) The unit of coefficient of viscosity are
a) dyne cm-2 sec b) poise c) centipoise d) all of these
34) Liquid with high molecular masses has.............. Viscosity
a) Greater b) lesser c) zero d) none of these
35) The liquids with high intermolecular attractive forces have ..................... viscosity
a) low b) intermediate c) high d) none of these

SOLID STATE
1) Which of the not true about the solid state?
a) They have definite shape and volume
b) they have high density and low compressibility
c) they have high attractive forces among molecules
d) they have high vapour pressure
2) The melting point is that temperature at which
a) solid and liquid forms of the substances do not co-exist at equilibrium
b) solid and liquid forms of the substances have same vapour pressure
c) vapour pressure is equal to one atmospheric pressure
d) none of the above
3) Amorphous solids do not have
a) sharp melting point b) characteristics geometrical shapes
c) regularity of the structure d) all of these
4) A crystalline solid has
a) definite geometrical shape b) flat faces
c) sharp edges d) all of these
5) Amorphous substances are isotropic because
a) they have same value of any property in all directions
b) they have different value of physical properties in different directions
c) they have definite geometrical shape
d) none of the above
6) The elements of symmetry are
a) Plane of symmetry b) axis of symmetry
c) centre of symmetry d) all of these
7) The amorphous solid among the following is
a) Table salt b) diamond c) plastic d) graphite
8) A crystalline solid does not have one of the following properties it is
a) Anisotropy b) sharp melting points
c) isotropy d) definite and regular geometry
9) For tetragonal crystal system, which of the following is not true?
a) b)
c) d)none of these
10) For a orthorhombic crystal system ,which is incorrect?
a) b)
c) c)none of these
11) Na+Cl-, Cs+ Cl- are the example of
a) cubic crystal system b) tetragonal crystal system
c)orthorhombic crystal system d) rhombohedral crystal system
12) The total number of atoms in a body centred cubic unit cell is
a) 1 b) 2 c) 3 d) 4
13) If there are four atoms in unit cell in a cubic system, it is an example of
a)simple cubic unit cell b) body centred cubic unit cell
c) face centred cubic cell d) none of these
14) Which is incorrect for hexagonal crystal system?
a) b)
c) d)none of these
15) The co-ordination number of Na+in Na+Cl- crystal is
a) 2 b) 4 c) 6 d) 8
16) The co-ordination number of body centred cubic lattice is
a) 2 b) 4 c) 6 d)8
17) the bragg’s equation for diffraction of X-ray is
a) n b) n
c) n d) n

18) In braggs equation n ‘n’ represents

a) the number of moles b) the principle quantum number
c) the Avogadro’s numbers d) the order of reflection
19) The change in enthalpy that occurs when one mole of a solid crystalline substance is formed
from the gaseous ions
a) Lattice energy b) ionic energy
b) Born Haber cycle d) crystalline energy
20) In cubic close packed (ccp) pattern of a metallic crystal, the co-ordination number is
a) 12 b) 8 c) 6 d) 4
21) In an ionic crystal, a cation and an anion leave the lattice to cause two vacancies .This defect
is called
a) Schottky defect b) Frenkel defect
c) interstitial defect d) none of these
22) Which of the following defects is generally found in sodium chloride and cesium chloride?
a) Schottky defect b) frenkel defect
c) interstitial defect d) none of these
23) In solid lattice , a cation has left a lattice site and is present in interstitial position, the lattice
defect is
a) Schottky defect b) Frenkel defect
c) vacancy defect d) interstitial defect
24) In Frenkel defect
a) some of the lattice sites are vacant
b) an ion occupies interstitial position
c) some of the cations are replaced by foreign ions
d) none of the above
25) A device used for convert of light energy into electrical energy is called
a) a semiconductor b) a solar cell
c) an irreversible cell d) an electrochemical cell
26) For an ionic crystal of formula AX, the radius ratio lies between 0.732 and 0.414. Its co-
ordination number is
a) 4 b) 6 c) 8 d)12
27) The radius ratio in an ionic crystal lies between 0.732-1.000, the co-ordination number is
a) 3 b) 4 c) 6 d) 8
28) The permitted co-ordination number in an ionic crystal is 6, the arrangement of anions the
cation will be
a) plane triangular b) tetrahedral
c) octahedral d) body centred cubic
29) A solid AB has the NaCl structure .if the radius of the cation is 120 pm, the minimum value
of radius of the anion B will be
a) b) c) d)

30) The number of atoms per unit cell in a simple cubic ,fcc and bcc are
a) 1,2,3 b) 1,4,2 c) 4,2,1 d) 2,4,1
31) In a crystal , the atoms are located at the position where potential energy is
a) maximum b) zero c) minimum d) infinite
32) Potassium crystallises in a bcc structure. The co-ordination number of potassium in
potassium metal is
a) 2 b) 4 c) 6 d) 8
33) In an ionic crystal of general formula AX, the co-ordination number is six. The value if
radius ratio is in the range
a) 0.155-0.215 b) 0.215-0.414 c) 0.414-0.732 d) 0.7320-1
34) The number of atoms in a unit cell of a cube is
a) 0 b) 1 c)2 d)3
35) The number of atoms in a unit cell of a face centred cube is
a) 2 b) 4 c)6 d)8
36) NaCl is an example of
a) covalent solid b) metallic solid
c) ionic solid d) molecular solid
37) Which of the following defects result in the decrease of density of crystal
a) Schottky defect b) Frenkel defect
c) interstitial defect d) impurity defect
38) Which of the following is a non crystalline solid?
a) Rubber b) ZnS c) HgS d) PbI
39) Particles of quartz are packed by
a) ionic bonds b) van der Waals forces
c) hydrogen bonds d) covalent bonds
40) LiF is an example of
a) molecular crystal b) covalent crystal
c) ionic crystal d)metallic crystal
41) In silicon crystal each silicon atom is covalently bonded to ............. neighbour atoms.
a) 2 b) 4 c) 6 d) 8
42) Silicon is an example of
a) non conductors b) good conductors
c) semi conductors d) metallic conductors
43) Semiconductors which exhibit conductivity due to the flow of excess negative electrons are
called
a) n- type conductors b) p-type conductors
c) good conductors d) none of these
44) In p-type conductors, the conductivity is due to
a) negative holes b) positive holes
c) mobile electrons d) valence electrons
45) Super conductors are the substances which
a) conduct electricity in liquid crystal state b) conduct electricity at low temperature
c) conduct electricity at high temperature d) offer no resistance to the flow of current
46) The liquid crystal have
a) properties of super cooled liquid
b) properties of amorphous solids
c) the fluidity of a liquid and optical properties of a solid
d) none of these
47) Silicon and Germanium in the pure state are
a) non conductors b) good conductors
c) metallic conductors d) metal complexes
48) p-Ozoxyanisole is an example of
a) semi conductors b) super conductors
c) liquid crystal d) none of these
49) When an arsenic atom is introduced in place of silicon in a crystal lattice , the conductivity
a) increase b) decreases
c) remains the same d) sometimes increase and sometimes decreases
50) The voltage of a solar cell is
a) very high b) high c) not very large d) none of these
51) In solid the constituent particles may be
a) Atoms b) Ions c) Molecules d) Any one of the above three
52) A single substance that exists in two or more form is called
a) Isomorphous b) Amorphous
c) Polymorphous d) Mono Morphous
53) Graphite and Diamond is a
a) Covalent crystal b) Metallic crystal
c) ionic crystal d) molecular crystal
54) The ratio of close packed atom to tetrahedral holes in the cubic packing is
a) 1:1 b) 2:1 c) 1:2 d)1:3
55) The ratio of close packed atom to tetrahedral holes in the hexagonal close packing is
a) 2:1 b) 1:2 c) 1:1 d)1:3
56) The major binding force of diamond is
a) Ionic bond b) dipole- dipole induced attraction
c) dipole- dipole attraction d) covalent bond.
57) The major binding force in silicon is a
a) Ionic bond b) dipole-dipole induced attraction
c) dipole-dipole attraction d) covalent bond
58) The major binding force in graphite is
a) Ionic bond b) London force
c) hydrogen bond d) covalent bond
59) The number of tetrahedral sites per sphere in ccp structure is,
a) 1 b)2 c)3 d)4
60) The number of octahedral sites per sphere in fcc structure is,
a) 1 b)2 c)3 d)4
61) The packing efficiency for a body centred cubic structure is,
a) 0.42 b) 0.53 c) 0.68 d) 0.82
62) Due to the frenkel defect the density of the ionic solid
a) Increases b) decreases c) remains constant d) fluctuates
63) An ionic crystal lattice has r+/r- radius ratio of 0.524.its coordination number is
a) 2 b) 4 c) 6 d) 8
64) An ionic compound AxBy occurs in FCC type crystal structure with B ion at the centre of
Each face and A ion occupying corners of the cube give the formula of AxBy
a) AB3 b) AB4 c ) A3B d) A4B
65) In crystalline solid few of the cations moved from their positions into the interstitial
position. The defect is called as
a) Interstitial b) frenkel c) schottky d) line defect
66) Semi conductor are manufactured by the addition of impurities of
 a) p- block elements b) actinoids
c) lanthanoids d) s- blocks elements.
67) p-type semi conductor is formed when trace amount of impurity is added to silicon . The
number of valence electrons in the impurity atom must be
a)3 b) 5 c) 1 d) 2
68) n-type semi conductor is formed when trace amount of impurity is added to silicon . The
number of valence electrons in the impurity atom must be
a)3 b) 5 c) 1 d) 2

SOLUTION AND ITS COLLEGATIVE PROPERTIES

1)The concentration of a solution is defined as
a) the amount of solvent present in a given amount of solution
b) the amount of solute present in a given amount of solution
c) the amount of solute present in a given amount of solvent
d) the amount of solvent present in a given amount of solute
2) If n number of moles of a solute and N represents the number of moles of a solvent ,the
mole fraction of the solvent is given by
a) b) c) d)
3)The molarity is defined as the number of moles of solute present in
a) one litre of the solvent b) one litre of the solution
c) one kilogram of the solvent d) one kilogram of the solution
4)Normality of a solution is the number of ............. of solute per litre of the solution
a)moles b)equivalents
c) formula weight d) mole fraction
5) The molality of a solution is defined as the number of moles of solute present in
a) one litre of the solvent b) one litre of the solution
c) one kilogram of the solvent d) one kilogram of the solution
6) For the gas in contact with a solvent at a constant temperature ,the concentration of the
gas that dissolve in the solvent is directly proportional to the pressure ,This law is
a) Henry’s law b) Raoult’s law
c) Dalton’s law d) van’t Hoff’s law
7)The weight percent of a solute in a solution is given by

a) b)

c) d)

8) The Henry’s law is applicable if

a) the temperature and pressure are molecules
b) the solubility of the gas in the solvent is low
c) the gas does not react with the solvent to form a new species
d) all of the above
9)The temperature at which two conjugate solution merge into one another to form one layer
is called the
a) critical temperature b) critical solution temperature
b) distillation temperature d) Dalton’s temperature
10) A saturated solution is defined as one which is .............. with the excess of solid at a
particular temperature
a) in contact b) in equllibrium
c) contains impurities d) none of these
11) In a super saturated solution, the amount of solute is ................. in comparison to
saturated solution
a) more b) less c) equal to d) none of these
12) The solubility generally rises with
a) increase in temperature b) decrease in temperature
c) increase in volume of the solvent d) none of these
13) A saturated solution of KCl on heating becomes
a) unsaturated b) supersaturated
c) hydrated d) none of these
14) Mathematically , Henry’s law can be expressed as
a) C b) c) C = k P d) all of these
15) The Henry’s law gives the relationship between \
a) the pressure and solubility of a gas in a particular solvent
b) the temperature and solubility of a gas in a particular solvent
c) the composition of the mixture and solubility of a gas in a particular solvent
d) none of these
16) When two non reacting gas mixed with each it form...................... mixture
a) homogeneous b) heterogeneous
c) equilibrium d) none of these
17) The completely miscible solution can be separated by
a) separating funnel b) fractional distillation
c) evaporation d) none of these
18) The liquid mixture which distil with a change in composition are called
a) azeotropic mixture b) equilibrium mixtures
b) zeotropic misture d) non equilibrium mixtures
19) The organic liquid which are steam volatile and immiscible to water can be separated by
a) distillation b) fractional distillation
c) steam distillation d)evaporation
20) Sugar dissolves in water due to the formation of
a) covalent bonds b) ionic bonds
c) hydrogen bonds d) co-ordianting bonds
21) The rate of crystallisation is the rate at which the
a) solid molecules go into the solvent
b) solute molecules return to the crystal surface and are deposited on it
c) solute molecules leave the surface of the solution
d) solute molecules condense on the surface of the solution
22) When a saturated solution prepared at a higher temperature is cooled , we get
a) super cooled solution b) super saturated solution
c) an equilibrium mixture d) one molar solution
23) An alloy is a homogeneous mixture of
a) two solid b) two liquids
c) two metal d) two non metal
24) The organic liquid which decompose at the boiling point are separated by
a) distillation b) steam distillation
c) fractional distillation d) none of these
25) In a saturated solution there exists an equilibrium between
a) solvent and excess of solid b) solution and excess of solid
c) solid and excess of solvent d) solid and excess of solution
26) In one molal solution that contain 0.5 mole of a solute there is
a) 1000 g of solvent b) 1000 ml of solvent
b) 500 ml of solvent d) 500 g of solvent
27) Which of the following does not depends upon the temperature
a) molarity b) normality
c) formality d) molality
28) 36 g of glucose is present in 500 g of water , the molality of the solution is
a)0.2 b) 0.4 c) 0.8 d) 1.0
29) The number of moles of a solute per kilogram of the solvent is called
a) formality b) normality c) molarity d) molality
30) The mole fraction of ethyl alcohol in a solution containing 36 g of water and 46 g
of ethyl alcohol is
a) b) c) d)
31) The molarities of 0.1 N HCl solution and 0.1N H2SO4 solution are respectively
a) 0.1 M and 0.1 M b) 0.1M and 0.05 M
c) 0.05 M and 0.1 M d) 0.1M and 0.2 M
32) For the preparation of 100 ml of 0.1 N solution of sulphuric acid ,the amount of sulphuric
acid needed is
a) 4.9 g b) 9.8 g c) 14.7 g d) 19.6 g
33) The normality of one molar hydrochloric acid ,one molar sulphuric acid and one molar
of phosphoric acid respectively
a) 1N,2N and 3N b) 2N,3N and 1N
c) 0.1 N ,0.2 N and 0.3 N d) 3N ,2N and 1N
34) How many grams of glucose are present in 100 ml of 0.1 M solution
a) 180 g b) 18 g
c) 1.8 g d) 3.6 g
35) In one molar solution of sulphuric acid the moles of hydrogen ion present will be
a) one molar b) two molar c) three molar d) four molar
36) A solution of KCl contains 74. 5 g of it in 90 g of water .the mole fraction of KCl will be
a) 1/6 b) 1/5 c) 1/4 d) 74.5/90
37) 49 g of sulphuric acid are dissolved in 250 ml of the solution ,the molarity will be
a) 0.5 M b) 1.0 M c) 1.5 M d) 2.0 M
38) The amount of Na+ in 0.1 M Na2SO4 is
a) 2.3 g b) 4.6 g c) 23 g d) 46 g
39) 45g of glucose is dissolved in500g of water .the molality of the solution is
a) 0.25 b) 0.5 c) 0.75 d) 1.0
40) How many grams of water present in 100 ml of 0.1 m solution of sulphuric acid ?
a) 10 g b) 20 g c) 50 g d) 100 g
41) The total weight of 100 ml of 2 M solution of HCl will be
a) 1073 g b) 107.3g c) 10.73g d) 1.073g
42) 1 kg of a solution of CaCO3 contains 1 g of calcium carbonate .the concentration of the
solution will be
a) 1 ppm b) 10 ppm c) 100 ppm d) 1000 ppm
43) A solution contains 180 g glucose in 180 g of water . the total number of moles of both
solute and solvent in the solution will be ( hint one mole glucose and 10 mole water)
a) 1 b) 10 c) 11 d) 21
44) A sample of H2O2 used for bleaching of hair contains 5.1 g of H2O2 in 90 g of water ,the
mole fraction of H2O2 will be
a) b) c) d)
45) Which of the following has molality equal to one
a) 36.5 g of HCl in 500 ml of water b) 36.5 g of HCl in 1000 ml of water
c) 36.5 g of HCl in 500 g of water d) 36.5 g of HCl in 1000 g of water
46) Which weighs the most ?
a) 1M solution of HCl b) 25 g of H2SO4
c) 2 moles of water d) 1 kg of CaCO3
47) The weight of urea required to prepare 200 ml of 2 M solution will be
a) 12 g b) 24 g c) 20 g d) 60 g
48) What is molality of solution prepared by dissolving 9.2 g of toluene in 500 g of benzene
a)1/2 b) 1/4 c) 1/5 d) 1/10
49) A solution of urea is prepared by dissolving 180 g of it in one kg of water. the mole
fraction of urea in the solution
a) b) c) d) 1.8
50) The normality o a solution of sulphuric acid is 0.1 N. Its molarity will be
a) b) c) d)
51) A colligative properties depends upon
a) chemical nature of the particle b) size of the particles
c) number of particles d) temperature of the solution
52) When a non volatile solute is dissolved in a pure solvent ,the vapour pressure of the pure
solvent
a) increases b) decreases
c) remains the same d) none of these
53) The relative lowering of vapour pressure represented by
a) p - ps/p b) ps – p/ p
c) ps + p / p d) p/ ps +p
54) Mathematically ,Raoult’s law can be expressed as
a) = b) =
c) = d) =
55) A real solution is that which
a) obeys Raoult’s law b) does not obey Raoult’s law
c) obeys Hnery’s law d) does not obey Henry’s law
56) The molecular weight of the solute can be calculated by measuring the lowering of
vapour pressure using the formula
a) b)

d) d)
57) A liquid boils when its vapour pressure becomes equal to
a) one atmospheric pressure b) zero
c) very high d) very low
58) The addition of a non-volatile solute ................ the vapour pressure
a) enhances b) lowers
c) diminishes d) none of these
59) The elevation in boiling point is given by the formula

where is called
a) boiling point constant b) ebulioscopic constant
c) molal elevation constant d) all of these
60) Molal elevation constant is the boiling point elevation when .......... of the solute is
dissolved in one kg of the solvent
a) one gram b) one kg
c) one mole d) none of these
61) When a non volatile solute is added to a solvent ,the freezing point of the solvent .............
a) increases b) remains the same
c) decreases d) none of these
62) The depression in freezing point is measured by using the formula

where is called
a) freezing point depression constant b) cryoscopic constant
c) molal depression constant d) all of these
63) Freezing point of depression is measured by
a) Beckmenn’s method b) Rast’s camphor method
c) both a & b d) none of these
64) The colligative effect of an electrolyte is always ......................... that of a non-electrolyte
of the same molal concentration.
a) Greater b)smaller c) equal to d) none of these
65) The ratio of the colligative effect produced by an electrolyte solution to the
corresponding effect for the same concentration of a non-electrolyte solution is known
as a) degree of dissociation b) degree of association
c) activity of coefficient d) van’t hoff factor
66) Abnormal molecular masses are obtained when there exists
a) dissociation of molecules b) association of molecules
c) either of the two d) none of these
67) The degree of dissociation is the fraction of an electrolyte which
a) is associated to from bigger molecules b) is dissociated into ions
c) does not pass into solution d) none of these
68) The law of the relative lowering of vapour pressure was given by
a) van’t Hoff b) Ostwald c) Raoult d) Henry
69) The vapour pressure of a dilute solution of glucose is 140 mm of mercury at 373K. The
mole of fraction of the solute is
a) b) c) d)
70) Which of the following is a colligative property?
a) molar refractive b) optical rotation
c) depression in freezing point d) viscosity
71) Which of the following is not a colligative property?
a) relative lowering of vapour pressure b) surface tension
c) elevation in boiling point d) depression in freezing point
72) The mole fraction of the solvent in a solution of non-volatile solute is 0.95. the relative
lowering of vapour pressure is
a)0.05 b)0.02 c)0.01 d)0.095
73) An aqueous solution of Sodium chloride in water has vapour pressure
a)equal to that of water b) more than that of water
c) less than that of water d) none of these
74) Which of the following is a colligative property?
a) Kb b) Kf c) Tf d) degree of ionisation
75) The ratio of the value of colligative property of K2SO4 solution to that of KCl solution at
the same concentration is nearly
a) 1.25 b) 1.5 c) 2 d) 2.5
76) The freezing point of one mole of K2SO4 solution assuming K2SO4 to be 100% ionised
water is
a) -1.86C b) -3.72C c) -5.58C d)5.58C
77) Which of the following 0.05 M aqueous solution will have the highest boiling point?
a) glucose b) NaCl c) K2SO4 d) Al(NO3)3
78) The depression in freezing point of an unknown solution is equal to the depression in
freezing point of 0.1 molal aqueous solution of urea. The concentration of the unknown
solution is
a) 0.1 M b) 0.2 M b) 0.5 M d) 1.0 M
79) The study of depression in freezing point of a solution is called
a) osmotic pressure b) ebullioscopy
c) cryoscopy d) none of these
80) The freezing point of two percent aqueous solution of potassium nitrate is
a) equal to zero degree Celsius b) less than zero degree Celsius
c) higher than zero degree Celsius d) none of these
81) The molal depression constant is given by the expression
a) Tf × M b) Tf × m c) Tf M d) Tf m
82) Ebullioscopy deals with study of
a) osmotic pressure and membrane b) depression in freezing point
c) relative lowering of vapour pressure d) elevation in boiling point
83) The depression in freezing point for 1M urea,1M glucose and 1M NaCl are in the ratio
a) 1:2:2 b)1:2:1 c) 1:1:1 d) 1:1:2
84) One mole of sugar is dissolved in three moles of water. The relative lowering of vapour
pressure is
a) ½ b)1/3 c)1/4 d)1/5
85) Which one of the following salt would have the same value of the van’t Hoff as that of
Al(NO3)3 ?
a) KCl b) K2SO4 c) Al2(SO4)3 d) K3[Fe(CN)6]
86) Which of the following is true for the van’t Hoff factor,i?
a) i = Tf /[Tf ] b) i = Tb /[Tb ]
c) i = p /[p ] d) all of these
87) The colligative effect of an electrolyte solution is always ...................... that of a non
electrolyte of the same molal concentration.
a) equal to b) lesser than
c) greater than d) non of these
88) The degree of dissociation is related to the van’t Hoff factor by the expression

a)  b) 

c)  d) 
89) Which of the solution will boil at highest temperature?
a) 1 % glucose b) 1% urea
c) 1 % potassium chloride d) 1% potassium sulphate
90) Which one of the following solution would produce maximum elevation in boiling
point?
a) 0.1 M glucose b) 0.2 M sucrose
c) 0.1 M Barium Nitrate d) 0.1 M Magnesium Sulphate
91) At high altitudes, water boils at a temperature which is
a) higher than the normal boiling point
b) lower than the normal boiling point
c) is equal to normal boiling point
d) none of these
92) The value of van’t Hoff factor is ............... for an electrolyte
a) greater than one b) less than one
c) equal to one d) equal to zero
93) The ratio of the value of elevation in boiling point for NaCl solution to that of urea
solution is nearly
a) half b) zero c) double d) equal
94) On dissolving common salt in water it is observed that
a) boiling point of solution increase b) boiling point of solution decrease
c) vapour pressure increases d) freezing point is raised
95) The highest boiling point will be observed in 1% solution of which the following
substances?
a) urea b) sugar c) sodium chloride d) sodium sulphate
96) Benzoic acid when dissolved in benzene undergoes
a) dissociation b) association c) no change d) none of these
97) The value of van’t Hoff factor i in case of dimerisation benzoic acid in benzene is given
by the expression
a) i = 1- b) i = 1 + 
c) i = 1 - /2 d) i = 1 + /2
98) The ratio between effective concentration and actual concentration molecule or ion in a
solution is called as
a) van’t Hoff factor b) colligative property
c) active concentration d) activity coefficient
99) The activity coefficient of a strong electrolyte is
a) always equal to zero b) always equal to one
c) always less than one d) always greater than one

OSMOTIC PRESSURE AND OSMOSIS

1) A semipermeable membrane allows the passage of ............through it
a) solvent only b) solute only
c) solvent and solute both d) either solvent or solute
2)The flow of solvent through a semipermeable membrane from pure solvent to solution is
called
a) diffusion b) osmosis
c) effusion d) none of these
3)The flow of solvent molecules can take place from
a) dilute to concentration solution b) concentration to dilute solution
c) anyone solution to the other d) none of these
4)The external pressure applied to the solution in order to stop the passage of solvent
molecules into solution by a semipermeable membrane is called
a) osmosis b) osmotic pressure
c) optical pressure d) none of these
5) Osmotic pressure can be measured by an instrument called
a) manometer b) barometer
c) osmometer d) nanometer
6) Isotonic solutions have the same
a) vapour pressure b) osmotic pressure
c) atmospheric pressure d) internal pressure
7)Which of the following is a colligative property?
a) atmospheric pressure b) osmotic pressure
c) critical pressure d) none of these
8) The isotonic solution have
a) equimolar concentration b) different osmotic pressure
c) different colligative properties d) same chemical properties
9)Two solutions are separated by semipermeable membrane. The one which is of lower
osmotic pressure is called
a) hypotonic b) hypertonic
c) iso- osmotic d) isomorphic
10) A hypertonic solution is the one which has .................. osmotic pressure than the other
a) lower b) equal c) higher d) none of these
11) The osmosis takes place from solution to pure water by application of pressure greater
than osmotic pressure on the solution is called
a) equilibrium osmosis b) irreversible osmosis
c) reversible osmosis d) reverse osmosis
12) The osmotic pressure of the given solution is directly proportional to
a) atmospheric pressure b) concentration
c) internal energy d) volume of solution
13) The osmotic pressure of a given concentration solution is directly proportional to
a) room temperature b) atmospheric pressure
c) absolute temperature d) critical temperature
14) The van’t Hoff equation for n moles of solute dissolved in V litre of solution is
a) π = n RT b) π V = RT
c) π p = n RT d) π P = n RT/V
15) When osmotic pressure and temperature are the same, equal volume of solution would
contain equal numbers of moles of the solute. This relationship is called
a) van’t Hoff law for solution
b) Avogadro’s law for solution
c) Boyle’s van’t Hoff law for solution
d) Avogadro’s- van’t Hoff law for solution
16) The osmotic pressure of a solution containing one mole of solute in 22.4 litre would be
equal to
a) 1 atm b) ½ atm c) 2 atm d) 22.4 atm
17) Osmotic pressure is directly proportional to
a) vapour pressure of the pure solvent
b) lowering of vapour pressure
c) relative lowering of vapour pressure
d) none of these
18) The molar mass of ‘M’ of the solute can be calculated by using the formula
a) b)

c) d)
19) The van’t Hoff i factor is related to the osmotic pressure by the formula
a) i = π/π b) i = π/π
c) i = π- π /π d) i = π-π/π
20) The value of van’t Hoff factor, i will be equal to 2 for
a) urea b) glucose c) sucrose d) NaCl
21) The value of van’t Hoff factor i for the electrolyte which are partially ionised in aqueous
solution will be
a)equal to 1 b) less than 1
c) between 1 and 2 d)greater than 2
22) Two solution with equal osmotic pressure are called
a) molar solution b) molal solution
c) isotonic solution d) isomorphic solution
23) The osmotic pressure of a solution increases if
a) volume of the solution is increased
b) the no. of the solute particle in solution increases
c) the no. Of solute particle in solution decreases
d) the temperature of the solution increases
24) The highest osmotic pressure will be observed in
a) 0.1 M urea b) 0.1 M glucose
c) 0.1 M NaCl d) 0.1 M Al2( SO4)3
25) The osmotic pressure of equimolar solution of BaCl2, NaCl and urea will be in order
a) BaCl2 > NaCl > urea b) BaCl2< NaCl < urea
c) urea > BaCl2 >NaCl d) BaCl2 > urea> NaCl
26) The ratio of osmotic pressure of BaCl2, NaCl and urea will be
a) 3:2:1 b) 1:2:3 c) 2:1:3 d) 3:1:2
[Hint 3Cl 2Ba and 1Na]
27) The osmotic pressure of equimolar solution of CaCl2 , NaCl and urea will be in order
a) CaCl2 > NaCl > urea b) CaCl2< NaCl < urea
c) urea > CaCl2 >NaCl d) CaCl2 > urea> NaCl
28) The osmotic pressure of a solution containing 0.02 mole of solute at 300 K will be
a) b) atm

c) atm d)
29) The outer hard shell of two eggs of the same size is removed by dissolving in dil. HCl.
One is placed in water and other in saturated NaCl solution. It will be observed after few
hours that
a) the first one shrinks while the other swells
b)the first one swells while the other shrinks
c) both egg swell
d) both egg shrink
30) The blood is isotonic with
a) 0.16 M sodium chloride solution b) 0.31 M sodium chloride solution
c) 0.4 M sodium chloride solution d) 0.8 M sodium chloride solution
31) The osmotic pressure of a solution of urea containing 8.6 g lit-1 is equal to that of 5 %
solution of non volatile solute. The molecular mass of the solute will be
a) 349 b) 34.9 c) 430 d) 860
32) Osmotic pressure of 2% of solution of urea ( mol. Mass = 60) at 27C would be
a) 0.0821 atm b) 0.821 atm
c) 8.21 atm d) none of these
33) Which of the following order will be correct for the solution of urea regards its osmotic
pressure
a) 5%< 3% < 2% < 1% b) 1% < 2% > 3% > 5%
c) 5% > 3% >2% >1% d) 3% >2% >1% >5%
34) Which of the following inorganic precipitates acts as a semipermeable membrane?
a) Al(OH)3 b) BaCO3 c) CuSO4 d) Cu2[Fe(CN)6]
35) The osmotic pressure of a solution increases if
a) temperature is lowered
b) volume is increased
c) concentration of solute particles is increased
d) solution constant is increased
36) The concentration in gram per litre of a solution of cane sugar (M. Wt. = 342) is isotonic
with a solution containing 3 grams of urea per litre. The concentration of cane sugar is
a) 17.1 g lit-1 b) 34.2 g lit-1 c) 3.42 g lit-1 d) 1.71 g lit-1
37) The osmotic pressure of 10% cane sugar solution at 69C is
a) 0.0821 atm b) 0.821 atm c) 8.21 atm d) 16.42 atm
38) Osmotic pressure not determined by
a) Pfeffer’s method b) Berkly and Hertley’s method
c) Abbe’s refractometer method d) all of these
39) Which of the following is not correct
a) in osmosis solvent molecule flow in one directions
b) in diffusion solute and solvent molecule flow in opposite direction
c) for osmosis a semipermeable membrane is required
d) for diffusion , a semipermeable membrane is required
40) The osmotic pressure of a solution of cane sugar [M.Wt.= 342] at 69C is 8.21 atm. The
concentration of the solution is
a) 1% b) 2% c) 5% d) 10%
41) The volume of the solution containing one mole of solute that shows an osmotic pressure
1 atm is
a) 22.4 litre b) 2.24 litre c)0.224 litre d)1 litre
42) Which of the following type of compounds will have van’t Hoff factor =1 ?
a) strong electrolytes b) weak electrolytes
c) non electrolytes d) none of these
43) For binary electrolytes of the type AB, the abnormal mol. Mass is given by

a) b)
 

c) d)
 

44) Which one of the following is not correct?

a) the equimolar solutions have same osmotic pressure at different temp.
b) the equimolar solutions have same osmotic pressure at same temperature
c) the osmotic pressure is directly proportional to the number of moles
d) the osmotic pressure is directly proportional to lowering of vapour pressure
45) Which of the following statements is true?
a) osmosis can be reversed by application of pressure on the solution
b) Beckmann thermometer can be used to measure elevation in boiling point
c) Osmosis and diffusion are same in solutions
d) Barometer can be measure osmotic pressure
46) The van’t Hoff factor for dilute aqueous solutions of urea and NaCl respectively are
a) 1, greater than 1 b) 1,0 c) 0,1 d) greater than 1,1
47) The observed molecular mass in case of electrolytes of the type AB2 is
a) equal to the normal molecular mass
b) less than the normal molecular mass
c) greater than the normal molecular mass
d) none of these
48) The compounds which undergo association in solutions have observed molecular mass
always
a) equal to their normal molecular mass
b) less than their normal molecular mass
c) greater than their normal molecular mass
d) none of these
49) The van’t Hoff factors for urea, sucrose and glucose are in the ratio
a) 1:2:1 b) 1:1:2 c) 2:1:1 d) 1:1:1
50) The value of van’t Hoff factor is more than one in dissociation and less than one in
association. This statements is
a) false b) true
c) sometimes false, sometimes true d) none of these
51) For electrolytes of type A2B or AB2 the abnormal molecular mass is given by
a) b)
 
c) d)
 
 CHEMICAL EQUILIBRIUM
Reversible reactions
Not all chemical reaction proceed to completion. In most reactions two or more substances react
to form products which themselves react to give back the original substances. thus A and B may
react to form C and D which react together to reform A and B .
“A reaction which can go in the foreward and backward direction simultaneously is called
a reversible reaction”
Such a reaction is represented by writing a pair of arrows between the reactant and products. The
arrows pointing indicate the forward reaction, while that pointing left shows the reverse reaction.
Nature of chemical equilibrium
Let us consider the reaction, when reactant A and B react with each other to form product C and
D. if we start with A and B in closed vessel, the forward reaction proceeds to form C and D. The
concentration of A and B decrease and those of C and D increase continuously. As a result the
rate of forward reaction also decreases and the rate of the reverse reaction increases. Eventually,
the rate of the two opposing reactions equals and the system attain a state of equilibrium.

“Thus chemical equilibrium may be defined as the state of a reversible

reaction when the two opposing reactions occur at the same rate and the
concentration of reactants and products do not change with time”.
The true equilibrium of a reaction can be attained from both sides. Thus the equilibrium
concentration of the reactants and products are the same whether we start with a and B, or c and
c
1) A chemical system is at equilibrium
a) when the rate of the forward reaction becomes zero
b) when the rate of the forward reaction and the reverse reaction are equal
c) when all of the reactants have been used up
d) when the rates of the forward reaction and reverse reaction are both zero
2)Equilibrium reactions are characterised by
a) going to completion
b) being non spontaneous
c) the presence of both reactants and products in a definite proportion
d) both a and b
3) Which of the following represents equilibrium constant?
a) weak acids or weak base dissociation constant
b) Kc for reaction
c) concentrations of strong acids in water
d) (a) and (b) represent equilibrium constant
4) If the equilibrium constant for a reaction is large, what can be said about reaction?
a) very little product formed
b) very little reactant remains at equilibrium
c) the reaction goes to completion
d) large quantities of reactant remains at equilibrium
5) A dynamic equilibrium
a) is when therate of forward reaction is equal to the rate of reverse reaction
 b) is a form of static equilibrium
c) only occurs in chemical equilibrium
d) involves radioactivity
6)Which of the following will change the equilibrium constant for a reaction mixture?
a) changing temperature b) by adding an inert gas
c) increasing pressure by decreasing volume d) all of these
7) A reaction is at equilibrium. What happens to the value of the equilibrium constant if an
additional quantity of reactant is added to the reaction mixture?
a) the equilibrium constant is shifted to favour production of more reactant
b) the equilibrium constant is shifted to favour production of more product
c) the equilibrium constant is increased
d) the equilibrium constant stays the same
8) What effect does a catalyst have on the equilibrium position of a reaction?
a) a catalyst favours the formation of products
b) a catalyst favours the formation of reactants
c) a catalyst does not change the equilibrium position of a reactions
d) a catalyst may favours reactants or product formation
9) Which of the following can change the value of the equilibrium constant for a reaction?
a) changing the concentration of the reactants
b) adding a catalyst
c) changing the solvent
d) removing the products as they are formed
10) Which of the following change the value of K?
a) adding reactant b) adding products
c) changing temperature d) adding catalyst
11) What is the expression for Keq for the reaction 2 N2O (g) + O2(g) ––––– 4 NO (g) ?
a) b) c)
12) In written equilibrium constant expression, which of the following quantities used
represent the amount of reactant and products?
a) concentration b) partial pressure
c) mole fraction d) a and b both
13) Which of the following is the incorrect?
a) adding reactant shifts the equilibrium to the right
b) adding product shifts the equilibrium to the left
c) exothermic reaction shift the equilibrium to the left with increasing temp.
d) adding a catalyst shifts the equilibrium to the right
14) For which of the following reaction the value of Keq dependent on only one substance in
the reaction?
a) C (s) + CO2 (g) ––––––– 2CO(g)
b) H2(g) + Cl2(g) ––––––––2 HCl (g)
c) CaCO3(s) –––––––––– CaO(S) + CO2
d) N2O4 (g) ––––––––––– 2NO2(g)
15) Which of the following reaction goes to completion because of gas is evolved?
a) b)
c) d)
16) A catalyst will increase the rate of a chemical reaction by
a) shifting the equilibrium in the right b) increasing the activation energy
c) shifting the equilibrium in the left d) lowering the activation energy
17)