Instructions:: University of Pune Polymer/Petroleum/Petrochemical) Momentum Transfer
Instructions:: University of Pune Polymer/Petroleum/Petrochemical) Momentum Transfer
Instructions:: University of Pune Polymer/Petroleum/Petrochemical) Momentum Transfer
[4362]-204
S. E. ( Polymer/Petroleum/Petrochemical)
MOMENTUM TRANSFER
(2008 Pattern)
Total No. of Questions : 12 [Total No. of Printed Pages :5]
[Time : 3 Hours] [Max. Marks : 100]
Instructions :
(1) Attempt Q.1 or Q.2, Q.3 or Q.4, Q.5 OR Q.6,Q.7 or Q.8, Q.9
or Q.10, Q.11 or Q.12
(2) Figures to the right indicate full marks
(3) Use of electronic calculator is allowed.
(4) Draw neat sketch where ever necessary
SECTION ONE
Q1.
a) Define the following fluid properties and state their units. [4]
(1) Specific weight (2) Dynamic Viscosity(3) Surface tension(4) Bulk
Modulus of Elasticity
b) Define the following fluid properties with their significance in momentum
transfer [6]
1) Capillarity 2) Vapor Pressure 3) Elasticity
c) State Newton’s law of viscosity. Explain the variation of viscosity of liquids
and gasses with temperature with justification [6]
OR
Q2.
a) A glass tube of internal diameter 2 mm is partially dipped in glycerin with
its lower end 20 mm deep below surface. Air is blown in the tube so as to
form an air bubble at its bottom end of the diameter of the tube. If specific
weight and surface tension of glycerin are 12.356 kN/m2 and 0.0637 N/m,
find the pressure inside the bubble. [6]
3
b) If density of a liquid is 850 kg/m , find its specific weight, specific gravity
and specific volume. If Kinematic viscosity of this liquid is 1.75 cm2/sec,
find its dynamic viscosity [5]
c) The bulk modulus of elasticity of water is given as K=2.2 X109 Pa. what
pressure is required to reduce its volume by 0.5%? [5]
Q3.
a) With the help of a neat diagram define the terms: Absolute pressure, Gauge
pressure and Vacuum pressure. [4]
b) Define the following: Path line, stream line, stream tube, streak line, velocity
of a fluid and local acceleration of fluid particle [6]
c) In a three dimensional fluid flow, two velocity components u and v are
u=2x2 and v=2 xyz. Find the third component ‘w’ such that the continuity
equation is satisfied. [6]
OR
Q4.
a) A ‘U’ tube mercury manometer is used to measure pressure of oil (sp.gr.
0.8) in a pipeline. The difference shown by manometer is 500 mm. the
mercury oil interface is 1.5 m above the centre line of the pipe. Find the
pressure of oil pipeline. [6]
b) State whether the flow of liquid given by u=3x and v=-3y is
1) Continuous 2) Rotational [4]
c) Distinguish between ‘U’ Tube Manometer and Differential Manometer with
the help of neat diagram [6]
Q5.
a) The water is flowing through a pipe having diameters 20 cm and 10 cm at
section 1 and 2 respectively. The rate of flow through pipe is 35 lit/sec. The
section 1 is 6 m above Datum and a section 2 is 4m above datum, if the
pressure at section 1 is 39.24N/cm2, find intensity of pressure at section 2 [8]
b) Define the following hydraulics coefficients of an Orifice. [10]
1) Coefficient of contraction
2) Coefficient of Velocity
3) Coefficient of Discharge
4) Coefficient of Resistance
OR
Q6.
a) State and express Bernoulli Equation. With respect to Bernoulli equation
explain the following [12]
1) Assumptions made in the derivation
2) Significance of the terms involved
3) Limitations of the equation
4) Modifications for head and energy
5) Kinetic energy correction factor
b) A fluid of density 1000 kg/m3 is flowing through a pipe of diameter 40 cm is
suddenly contracted to a diameter of 20 cm. the pressure in the larger pipe is
160 kN/m2 and pressure in the smaller pipe is 150 kN/m2. Head lost due to
sudden contraction of pipe cross section is 0.34 m. determine the coefficient
of contraction if the velocity of fluid in the larger pipe is 0.98 m/s [6]
SECTION TWO
Q7.
a) Explain the Hydrodynamics development of a fluid flow in a pipe. Explain
the Laminar and turbulent flow velocity profiles with the help of neat sketch
[8]
3
b) A fluid is flowing through a pipe of 60 cm diameter at the rate of 0.05 m /s.
the length of the pipe is 600 m. density of fluid is 900 kg/m3 and viscosity of
fluid is 0.006 Ns/m2. Determine the head lost due to friction. Friction factor
is given by f=0.046 Re-0.2 [8]
OR
Q8.
a) What are major and minor losses in a flow through pipe? What is equivalent
length of a pipe? Water flows through a Pipe of 100 mm diameter at the rate
of 15.71 liters per sec. the straight length of pipe is 50 m and ne open globe
valve, a ‘T’ through side outlet and an elbow is provided in it. If the loss co
efficient of these fittings of these fittings are 10,1.8 and 0.9 respectively,
what is the total length of the pipe and total head loss in it? Take friction
factors as 0.022 [12]
b) Discuss the variation of friction factor with Reynolds number for different
values of roughness for flow of fluid in pipe? [4]
Q9.
a) What are the characteristics of a turbulent flow? Explain the utility of
turbulent flow characteristics in process industry. [8]
b) Explain with the help of neat sketch various multiphase flow regimes in
Horizontal pipe. What is the flow regime map? [8]
OR
Q10.
a) Draw a neat sketch of a boundary layer. Define the following with respect to
boundary layer: [10]
1) Laminar Sublayer
2) Hydrodynamic Smooth and rough boundaries
3) Boundary layer thickness
b) Express the following and give its utility [6]
1) Dracy’s law 2) Ergun’s Equation
Q11.
a) A centrifugal pump is used to deliver liquid at a rate of 0.003 m3/s from a
reservoir at atmospheric pressure. The gauge pressure at the end of delivery
pipe is 300kN/ m2 . The delivery is 3.5 m and the pump suction is 1.5 m
above the level in the reservoir. The delivery pipe is 40 mm in diameter. The
friction in the suction pipe is 3.5KN/ m2 and the friction in the delivery pipe
is 41 KN/ m2. The overall efficiency of the pump is 60 percent. The vapor
pressure of the liquid is 26 KN/ m2. Density of liquid is 900 kg/ m3.
Calculate 1) Head Developed by the pump 2) Work done per second by the
pump and 3) Net positive suction head of the pump [12]
b) Explain the following with respect to Dimensional Analysis: [6]
1) Selection of repeating variables
2) Utility of Dimensional analysis
OR
Q12.
a) Explain the classification of a Pump, blower, compressor and a Fan. Draw
the operating characteristics of a centrifugal pump. [10]
3
b) A centrifugal pump is used to deliver a liquid at a rate of 0.3 m /s. the
distance between liquid level in the reservoir and the suction pipe is 1.8 m.
the vapor pressure of the liquid is 50 KN/m2. The pressure on the liquid
surface in the reservoir is 100 KN/ m2. The diameter of the pipe is 30 cm and
the length of pipe 50 m. Determine the NPSH. Density of liquid=900 kg/ m3
and Viscosity of liquid = 0.5*10 -3Ns/ m2 [8]
[Total No. of Questions: 12] [Total No. o f Pr i n t ed Pag es : 5]
UNIVERSITY OF PUNE
[4364]-207
Instructions:
SECTION -I
Q.1 A An Aluminum (k = 200 W/m °C) 2.5cm in diameter and 10cm 8
long protrudes from a wall which is maintained at 250°C. the rod
is exposed to an environment at 15°C. The convective heat transfer
coefficient is 15 W/m2 °C. Assume rod end is insulated. Determine
the heat loss by rod. Also find Fin efficiency and temperature at
the end of fin.
Page 1 of 5
at inner and outer surface. Neglect the resistance of steel plate.
OR
B Derive the necessary expression for Heat flow rate, Fin Efficiency 12
from an Infinitely long fin.
Q. 3 A Define the terms Solid angle and intensity of Radiation and derive 8
the necessary expression between Emissive power and Intensity of
Radiation.
B Find out the heat transfer rate per unit area due to radiation 8
between two infinitely long parallel planes. The first plane has
emissivity = 0.4 and it is maintained at 200°C. The emissivity of
second plane is 0.2 and is maintained at 30°C. A radiation shield
having emissivity 0.5 is introduced between the given planes. Find
the percentage reduction in heat transfer rate and the steady state
temperature attained by the shield.
OR
B Explain the term Shape Factor and discuss the laws of Shape Factor. 6
Npr=0.013,
Page 2 of 5
Average Nusselt number is given by:
(NNu)Avg=4.82+0.0185 (Pe)0.827
OR
(NNu)D=1.18(NGr.NPr)1/8
SECTION II
Q. 7 A Derive the expression for Logarithmic Mean Temperature 12
Difference for Counter current type of Heat Exchanger.
OR
Page 3 of 5
B Write a note on i) Classification of Heat Exchanger 8
OR
OR
Page 4 of 5
Enthalpy of product = 298 kJ/kg.
Page 5 of 5
PUNE UNIVERSITY
[4362]-205
S. E.(Polymer/Petroleum/Petrochem)
Examination-2013
Strength of Materials
(2008 Course)
[Total No. of Questions: 12] [Total No. of Printed Pages: 5]
[Time: 3 Hours] [Max. Marks: 100]
Instructions:
(1) Answer Q.1 or Q.2,Q.3 or Q.4,Q.5 or Q.6 questions from
each section.
(2) Answers to the two sections should be written in separate
answer-books.
(3) Black figures to the right indicate full marks.
(4) Neat diagrams must be drawn wherever necessary.
(5) Your answer will be valued as a whole.
(5) Use of logarithmic tables, slide rule, Mollier charts,
electronic pocket calculator and steam tables is allowed.
(6) Assume suitable data, if necessary.
(7) All questions are compulsory.
SECTION-I
Q. 1. A) Derive the relationship between the stresses developed due to gradually(4)
& suddenly applied loads.
B) Find the elongation of a bar under the action of its own weight having (6)
a uniform cross sectional area A and weighing wo per unit length.
C) A vertical steel bar 15 mm diameter & 3000mm length is provided (8)
With a collar, at the lower end. find the maximum weight that can be
Dropped through a height of 100mm on the collar if the maximum
Permissible stress is 150MPa. Assume for steel is 200 GPa.
OR
Q. 2. A) Define the following
i) Strain energy ii) Proof Renlience iii) Modules of Renlience (5)
iv) Thermal stress v) Thermal strain
B) Define the constant of material & state the relationship between them. (5)
C) A square bar 25mm × 25mm is subjected to axial forces as show in (8)
Figure no. 2(c).Find the total elongation of the bar.
1
Take E=200 GPa.
Q. 3. A) At a point in a material there are normal stresses 30MPa & 60MPa, (8)
Both tenale together with a shearing stress od 22.5 MPa. Find the value
Of principle stress & inclination of principle planes to the direction of
60MPa stress.
B) A steel shaft of solid circular section has to transmit 375KW at 210 (8)
r.p.m. the maximum shear stress is not to exceed 50 MPa & the angle
of twist must be note more than 1º in a length at 3m. Design a suitable
diameter of the shaft Take G=80GPa.
OR
Q. 4. A) At a point in a strained material under two dimensional stress (8)
Condition, the normal stress and certain plane is 80 MPa compressive
& shear stress at 56 MPa. On a plane right angles to this plane, there is
No normal stress. Find principle stress.
B) A solid shaft 54mm in diameter is to transmit a torque at 1100Nm. (8)
The maximum torque is 1.3 times the average torque. Twist allowed is
1.2º/meter length of the shaft. Calculate the maximum shear stress induced.
Q. 5. A) For a thin cylinder, derive the expression for increase in diameter (8)
increase in length & decrease in thickness due to fluid pressure.
B) A pipe of 200mm. internal diameter and 100mm. thickness contains
a fluid at a pressure of 6 N/mm2. Find the maximum & minimum hoop
Stress across the section.
OR
Q. 6. A) Find the thickness of metal necessary for a steel cylindrical thick (8)
Shell of internal diameter 200mm to withstand an internal pressure of
50 MPa. The Maximum hoop stress in the section is not to exceed 150MPa.
2
B) A cylindrical thin drum 800mm in diameter and 3 meter long has a (8)
Shell thickness of 10mm If the drum is subjected to internal pressure at
2.5 MPa. Determine
i. The change in diameter
ii. The change in length
Take E=2×105 MPa & passon’s Ratio=1 4
SECTION-II
Q. 7. A) A 10m long supported beam carries loads and a couple. (8)
Ref fig.Q.7 (A) Draw the shear force diagram and bending moment
Diagram for the beam showing all important values.
3
B) A simply supported cast iron square beam of 800mm span and (12)
15mm×15mm in section faith or applying a load of 360N at the medspan.
Find the maximum uniformly distributed load that can be applied safely
to a 40mm wide,75mm deep and1.6 long cantilever made of the same
material.
Q. 9. A) A 320mm×160mm I section joint has 20mm thick flanges and a (8)
15mm thick web. At a certain cross section it is acted upon by a shear
Force of 200KN. Sketch the shear stress distribution across the section
showing all important values.
B) A 4m long follow alloy tube with inside and outside diameter (8)
Are 36mm and 48mm elongates by 3mm under a tensile force of 50KN
Determine the buckling load for the tube when it is used as a column with
Both ends fixed and a factor of safety of 5.
OR
𝑆𝐴𝑦
Q. 10 A) Derive the expression 𝑧 = for a beam in bending using (8)
𝑏𝐼
usual notations
B) List out the orsamptions used in the Euler’s theory for columns. (8)
Write the Limitations of Euler’s formula.
Q. 11.A) A short column of rectangular section 160mm×120mm carries a (8)
Load of 200KN the lad point is at a point 40mm from the longer side and
70mm from the shorter side. Determine the maximum tensile and
Compression stresses in the section.
B) A beam of length ‘l’ henged at ends carries a clockwise couple M at (10)
‘a’ from the left end determine the slope at each and the defection at
The point of application of the couple.
4
OR
Q.12. A) A simply supported beam of 8m length catties two point loads of (8)
64KN and 48KN at 1m and 4m respectively from the left end. Deduce the
General expression to find the defecation at any section of the beam.
B) Determine the maximum stress in the both for the bracket shown in (10)
Fig.Q.12 (B) Diameter of both=20mm.
5
UNIVERSITY OF PUNE
[4362]-191
S.E Engineering Examinations 2013
MATHAEMATICS – III
(2008 COURSE)
[Total No. of Question=12] [Total no. of printed pages= 7]
[Time : 3 Hours] [Max. Marks : 100]
Instructions :
(i) Attempt q. No. 1 or q. no2, Q. No. 2, Q. No. 3 or Q. No. 4, Q. No. 5 or
Q. No. 6 from Section I and Q No. 7 or Q. No. 8, Q. No. 9 or Q. No. 10.
Q. No. 11 or Q No. 12 from section II.
ii) Answer to the two Sections should be written in separate answer-
books.
iii) Figures to the right indicates full marks.
iv) Use of electronic pocket calculator is allowed.
v) Assume suitable data, if necessary.
1
Q. 2 a) Solve any three [12]
𝑑 2𝑦 𝑑𝑦 1 1
1) − − 2𝑦 = 2𝑙𝑜𝑔𝑥 + +
𝑑𝑥 2 𝑑𝑥 𝑥 𝑥2
𝑑 2𝑦 2
2) −𝑦 =
𝑑𝑥 2 1+𝑒 𝑥
𝑑 2𝑦
3) + 4𝑦 = 𝑥 sin 𝑥
𝑑𝑥 2
𝑑𝑥
+ 𝑦 = 𝑒𝑡
𝑑𝑡
𝑑𝑦
- + 𝑥 = et
𝑑𝑡
b) A string is stretched and fastened to two points ‘λ’ apart. Motion is started by
𝜋𝑥
displacing the string in the from u= a sin from which it is released at time
λ
t=0 . Find the displacement u(x, t) from one end.
𝜆
[8]
OR
Q.4 a) In a heat exchange the temperatures x and y of two liquids satisfy the
equations
𝑑𝑥
+ 5𝑥 − 2𝑦 = 𝑡
𝑑𝑡
𝑑𝑦
+ 2𝑥 + 𝑦 = 0
𝑑𝑡
2
Find the temperatures x & y as a function of time, given that x=0 and y=0 at
time t = 0
𝜕𝑢 𝜕2𝑢
b) Solve the equation = 𝑎2 [8]
𝜕𝑡 𝜕𝑥 2
2 /2
b) Show that the Fourier transform of f(x) = 𝑒 −𝑥 is 𝑒 𝜆2/2 [5]
2, 1≤𝜆<2
0, 𝜆≥2
OR
3
Q.6 a) Using Fourier integral equation show that [7]
∞ 𝑐𝑜𝑠𝜆𝑥 +𝜆𝑠𝑖𝑛𝜆𝑥
𝑑𝜆 = 0, 𝑥<0
0 1+𝜆 2
π/2 , x=0
π𝑒 𝑥 , 𝑥>0
4
Section-II
Q.7 a) Obtain Laplace transform of (any three): [12]
𝑒 𝑎𝑡 −𝑒 𝑏𝑡
i)
𝑡
𝑡
ii) 𝑒 −4𝑡 0 𝑡 sin 3𝑡 𝑑𝑡
𝑡 2 𝑒 𝑡 𝑠𝑖𝑛𝑡 𝑑𝑡
0
OR
Q.8 a) Obtain inverse Laplace transform of (any three): [12]
𝑠
i)
(𝑠 2 +𝑎 2 )2
1 𝑠 2 +𝑎 2
ii) log( )
𝑠 𝑠 2 +𝑏 2
2𝑠 2 −6𝑠+5
ii)
𝑠 3− 6𝑠 2 +11𝑠−6
𝑒 3𝑠
iv)
𝑠 2 +8𝑠+25
5
Q.9 a) Find the directional derivative of [5]
Ø = 4 x z 3 − 3𝑥 2 𝑦 2 z 𝑎𝑡 2, −1, 2 along tangent to the curve x=et cos t,
y = et sin t, ᵶ = et at t = 0
OR
𝑥𝑖 +𝑦𝑗 +z𝑘
Q.10 a) Evaluate 𝑠 . 𝑑𝑠 Where S is the surface of the sphere [6]
𝑟2
x2 + y2 + z2 = a2
1 n(n−2)
ii) ∇. r ∇ =
rn r n +1
aXr 3(a.r ) 𝑎
iii) ∇ X = 𝑟−
r3 r5 𝑟3
6
𝑑𝑦 𝑡
Q.11 a) Solve + 2𝑦 𝑡 + 0
𝑦 𝑡 𝑑𝑡 = 𝑠𝑖𝑛𝑡, given y(0) =1 using Laplace [5]
𝑑𝑡
transform.
C) Find the equations of stream line passing through the point (1,1,2) in case of
steady motion of fluid defined by : 𝑞 = −𝑥𝑖 + 2𝑦𝑗 + (3 − 𝑧)𝑘. [6]
OR
7
UNIVERSITY OF PUNE
[4362-201]
S.E.(Polymer/Petroleum/Petrochemical Engineering)
Examination-2013
Engineering Chemistry-I
(2008 pattern)
Time-Three hours Maximum Marks-100
[Total No. of Question=12] [Total no. of printed pages= 4]
Instructions:
(1)Answer three questions from Section-I and three questions from Section-II.
(2)Answers to the two sections should be written in separate answer books.
(3)Neat diagram must be drawn necessary.
(4)Figures to the right indicate full marks.
(5)Use of logarithmic tables,slide-rule,Molleir charts,calculator and steam tables
is allowed.
(6)Assume suitable data wherever necessary.
SECTION-I
(c)Explain. (4)
(i)Trichloroacetic acid is stronger than acetic acid
(ii)Pyridine is weaker base
1
OR
Q.2 (a)Write a short note on mesomeric effect. (6)
OR
Q.4 (a)Explain aldol condensation shown by acetaldehyde. (6)
2
OR
Q.6 (a)Explain electrophilic substitution reactions shown by pyrrole. (6)
SECTION-II
Q.7 (a)Derive PV=nRT using Boyle's law and Charle's law. (6)
OR
Q.8 (a)Define. (6)
(i)Boiling point of liquid
(ii)Melting point of solid
Also explain process of evaporation.
3
Explain different types of cells giving one example of each type. (6)
OR
Q.10 (a)Explain working and construction of fuel cell. (6)
(b)Explain 'lead acid' battery. Give reactions at cathode and anode. (6)
4
[Total No. of Questions: 12] [Total No. of Printed Pages:3 ]
UNIVERSITY OF PUNE
[4362]-202
S. E. (Poly./Petro) Examination - 2013
ENGINEERING MATERIALS SCIENCE AND TECHNOLOY
(2008 Course)
[Time: 3 Hours] [Max. Marks: 100]
Instructions:
1 Answers to the two sections should be written in separate answer-
books.
2 Black figures to the right indicate full marks.
3 Neat diagrams must be drawn wherever necessary.
4 Assume suitable data, if necessary.
5 Answer three questions from Section I and three questions from
Section II
SECTION -I
Q.1 Differentiate between the following (any four). [16]
i) Ceramics and Polymers
ii) Metallic bond and Covalent bond
iii) Screw dislocation and Edge Dislocation
iv) Glass transition and Crystallization temperature
v) BCC structure and FCC structure of crystals
OR
Q.2 Write short notes on the following (any four) [16]
i) Biomaterials
ii) Smart materials
iii) Nano materials
iv) Liquid crystal polymers
v) Ionic bonds
Q. 3 A) Draw phase equilibrium diagram for water. Show “Invariant point” [6]
on it, also explain its significance.
B) Draw Fe-Fe3C phase equilibrium diagram. Explain significance of [6]
𝛼 phase and 𝛾 phase.
C) Draw micro-structure of a Tin bronze. [4]
OR
Q. 4 A) Differentiate between Hardening and Annealing of steel, with their [8]
micro-structures.
B) What are different types of strengthening mechanisms? Explain [8]
Page 1 of 3
any one in detail with diagram.
Q. 5 Explain the following with the help of diagram (any three) [18]
i) Different types of magnetic materials
ii) Linear coefficient of thermal expansion
iii) The “MOSFET”
iv) Ruby Laser
OR
Q. 6 A) A cylindrical specimen of a titanium alloy is tested by applying [6]
2040 N tensile load within the elastic limit. Its elastic modulus is
107 GPa. Its original diameter is 3.8 mm and observed 0.42 mm
elongation at above load. Calculate original length of the specimen.
B) The flow stress of copper alloy increases from 2MPa to 55MPa, [6]
when dislocation density increases from 107/cm2 to 1010/cm2.
Calculate the flow stress for a similar heavily deformed copper
alloy with a dislocation density 1012/cm2.
C) What are the different methods to evaluate toughness of a material? [6]
Explain any one in detail.
SECTION II
Page 2 of 3
example.
C) Explain Adhesive wear, when the two solid surfaces slide over one [5]
another.
Q.11 A) Explain the following processing with the help of sketch(any three) [18]
i) Pre-stressed Cement Concrete Blocks
ii) Atomization for powder production
iii) Electrostatic Painting
iv) Welding of two metal parts
OR
Q. 12 A) What is Sintering process? Illustrate with the help of sketches. [6]
What are its applications?
B) How is glass tubing or rods manufactured? [6]
C) Explain Hot rolling of metals and alloys. [6]
Page 3 of 3
UNIVERSITY OF PUNE
[4362]-203
S. E. (Petroleum/ Petrochemical/ Polymer)
Examination - 2013
CHEMICAL PROCESS CALCULATIONS
(2008 Pattern)
SECTION I
Q1) a) Explain fundamental and derived quantities. Enlist two quantities from each [08]
type with SI units.
b) The volumetric flow rate of kerosene in a pipe is 75 Imperial gallons per [08]
minute. Calculate the mass flow of kerosene in kg/s having density of
0.8 kg/d𝑚2 .
OR
Q2) a) Find the equivalent weights of: [08]
i) C𝑂3 radical ii) N𝑎2 C𝑂3
b) Glycerin, weighing 600mg is dissolved in pure water to make a final solution [08]
of one litre. Find the TOC and ThOD of the solution.
Q3) a) Explain the classification of general material balance problems. Discuss the [08]
three general methods of solving material balance problems for non-reacting
systems.
b) In a polymer processing plant, a double effect evaporator system concentrates [08]
1
weak liquor containing 4% (by weight) caustic soda to produce a lye
containing 25% solids (by weight). Calculate the evaporation of water per
100 kg feed in the evaporator.
OR
Q4) A 100 kg mixture of 27.8% of Acetone (A) and 72.2% of Chloroform (B) by [16]
weight is to be batch-extracted with a mixed solvent at 298 K. The mixed
solvent of an unknown composition is known to contain water (𝑆1 ) and acetic
acid (𝑆2 ). The mixture of the original mixture and the mixed solvent is shaken
well, allowed to attain equilibrium and separated into two layers.
The compositions of the two layers are as below:
Composition, weight %
Layer A B 𝑆1 𝑆2
Upper Layer 7.5 3.5 57.4 31.6
Lower Layer 20.3 67.3 2.8 9.6
Q9) Toluene is heated form 290K to 350K at the rate of 0.25 kg/s. Calculate the [18]
heat required to be added to toluene using constants provided and generate the
% difference.
Set a b × 103 c × 106 d × 109
I 1.8083 812.223 -1512.67 1630.01
II -56.3627 1768.423 -5192.623 5497.39
OR
Q10) a) Write the Watson and Riedel Equations for heat of vaporization. [18]
For O-xylene, Calculate:
i) Latent heat of vaporization at 298 K using Watson eq.
ii) Latent heat of vaporization at 𝑇𝐵 using Riedel eq.
Given : 𝑃𝐶 = 3730 kPa , 𝑇𝐶 = 630.3 K , 𝑇𝐵 = 417.5 K
Q11) a) The heat absorbed when 𝑁𝑎2 𝐶𝑂3 . 10 𝐻2 O. is dissolved isothermally at [16]
291 K in a large quantity of water is 67.91 KJ per mole solute. Calculate the heat of
crystallization of 1 Kg 𝑁𝑎2 𝐶𝑂3 . 10 𝐻2 O.
OR
Q12) Calculate the heat of hydration of 𝑁𝑎2 𝑆𝑂4 . 10 𝐻2 O using the given data of [16]
heat of formation:
Compound Standard heat of formation, KJ/mol
𝑁𝑎2 𝑆𝑂4 -1387.08
𝐻2 O -285.82
𝑁𝑎2 𝑆𝑂4 . 10 𝐻2 O -4327.26
3
[Total No. of Questions: 12] [Total No. of Printed Pages: 4]
UNIVERSITY OF PUNE
[4362]-206
S. E. (Poly/Petro/Petrochem.) Examination - 2013
ENGINEERING CHEMISTRY-II (2008 Course)
SECTION -I
Q.1 A Draw Haworth’s projection formula for following 6
carbohydrates.
i) Amylopectine
ii) Cellulose
iii) Amylose.
B Explain primary and secondary structural of Protein. 6
C Give classification of carbohydrates. 4
OR
Q.2 A Explain oxidation of glucose by- 6
i) Bromine water
ii) Nitric acid
iii) Fehling solution
B Explain three characteristic reactions each of amino group and 6
carboxyl group amino acids.
C Give classification of enzymes. 4
Page 1 of 4
Q. 5 A Explain following terms with suitable examples 6
i) Chromophore
ii) Auxochrome
iii) Bathochromic shift
B Calculate U.V. absorption maxima for following clearly show 6
your calculations.
i)
ii)
iii)
Page 2 of 4
ii)
A B C
SECTION II
Q. 7 A Give valance-bond representation of ammonia molecule. Why 6
bond angle is 107.50?
B Draw molecular orbital diagram for nitrogen molecule. 6
Explain triple bonding of nitrogen molecule
Page 3 of 4
[Ni[ Ni(CO)4] ; K4[Fe(CN)6]
GIVEN-
Symboly → Sc Ti Cr Fe Co Ni Cu
At Wts → 21 22 24 26 27 28 29
Page 4 of 4
UNIVERSITY OF PUNE
[4362]-208
S. E.(Petroleum/Polymer/Petrochemical)Examination - 2013
PARTICULATE TECHNOLOGY
(2008 Pattern)
[Total No. of Questions:12] [Total No. of Printed Pages 5]
[Time : 3 Hours] [Max. Marks : 100]
Instructions :
(1) Answer Q1 or Q2, Q3 or Q4, Q5 or Q6 from section I and
Q7 or Q8, Q9 or Q10, Q11 or Q12 from section II.
(2) Answers to the two sections should be written in
separate answer-books.
(3) Black figures to the right indicate full marks.
(4) Neat diagrams must be drawn wherever necessary.
(5) Use of logarithmic tables, slide rule, electronics pocket
calculator is allowed.
(6) Assume suitable data, if necessary.
SECTION-I
OR
the rate of 20 tons/hour. At this rate, the mill takes 9 HP of power and 0.46
Page 1 of 5
i) What would be the power consumption for same capacity, if average
ii) How much power would be required under conditions by kick’s law?
b) Derive the relationship between critical speed of ball mill with radius [6]
face. They are set so that crushing surfaces are 1.25cm apart at the narrowest
point. The manufacture recommends that they may be run at 50 to 100 rpm.
They are to crush a rock having a specific gravity of 2.35 and angle of nip
30°. What are the maximum permissible size of feed and maximum actual
capacity in tons per hour, if the actual capacity is 12% of the theoretical.
OR
Q4 a) State and explain various size reduction laws by giving mathematical [6]
expressions.
b) A material is crushed in Blake Jaw crusher and the average particle [6]
Calculate the energy required to crush the same material with average
particle size from 8cm to 3cm by using Rittinger’s and kick’s laws. Assume
Page 2 of 5
sketch.
OR
Laboratory tests using five different concentrations of the slurry yielded the
following data:
thickener.
SECTION-II
terminal settling velocity for free flowing particles. Define the range of
operation.
i) Petroleum Refining
Page 3 of 5
ii) Biochemical reactions
c) Explain in brief what is mean by fluidization with its advantages and [4]
disadvantages.
OR
Q8 a) Calculate the minimum fluidization velocity for the bed of sharp sand [8]
particles of 𝜀𝑚𝑓 =0.54 particles of diameter 180 𝜇m and density 2.6 gm/cc
0.00018 g/cm.s. Also calculate the minimum fluidization velocity by (i) Wen
& Yu and (ii) Chitester co-relations and determine the percentage error.
representation.
Q9 a) A sample of slurry had previously been tested with a leaf filter of [10]
0.05m2 filtering surface giving a pressure difference of 71.3 kN/m2. The volume
of filtrate collected in first 300 seconds was 250 cm3 and after further 300
seconds an additional 150 cm3 was collected. Determine the time required to
filter out 900 cm3 of liquid through same filter surface area.
stopped. Estimate the washing time if 5m3 of wash water is used. The
Page 4 of 5
resistance of cloth may be neglected and a constant pressure is used
throughout.
OR
Q10 a) Derive the relation for constant rate and constant pressure filtration [10]
for the flow of filtrate through cloth & cake resistance combined.
Q11 a) Estimate the terminal settling velocity for 150 to 230 mesh particles of [8]
Data: 150 mesh = 0.104 mm, 230 mesh = 0.063mm, viscocity=0.801 cp,
b) Describe in detail with neat diagram the principle, construction and [8]
applications.
OR
Page 5 of 5
[Total No. of Questions: 6] [Total No. of Printed Pages: 2]
UNIVERSITY OF PUNE
[4362]-209
S. E. (Poly/Petro/Petrochemical Engg) Sem II Examination - 2013
ELEMENTS OF SOCIAL SCIENCES (2008 Course)
[Time: 3 Hours] [Max. Marks: 100]
Instructions:
1 Answer three question from each section
2 Answer any three questions from Section I and any three
questions from Section II
3 Answers to the two sections should be written in separate
answer-books.
4 Neat diagrams must be drawn wherever necessary.
5 Black figures to the right indicate full marks.
SECTION -I
Q.1 A Explain the merits and demerits of Mixed Economies. 8
B Explain the problems of Economic Organizations. 8
OR
Q.1 A State and Explain different types of Markets. 8
B Explain Law of Demand. 8
Page 1 of 2
iii) LPG model for Economic Development
SECTION II
Q. 4 A Explain in brief
i) Cultural Diversity of India 8
ii) Modern families in India 8
OR
Q. 4 A Explain the importance of Study of Civilizations in 6
details.
B Discuss the Socio Economic impact of Globalization 10
on India Society.
Page 2 of 2