Spc-Env-001 QP Specifications For Waste Management
Spc-Env-001 QP Specifications For Waste Management
Spc-Env-001 QP Specifications For Waste Management
TABLE OF CONTENTS
Page No.
2.0 OBJECTIVE / INTRODUCTION........................................................................................................... 3
17.0 APPENDIX E, FORM 2, CERTIFICATE FOR THE TRANSPORT & DISPOSAL OF WASTES
(SCENR).......................................................................................................................................................... 53
18.0 APPENDIX F: ONSHORE WATER BASED DRILLING MUD & CUTTINGS ................................... 54
5.0 DEFINITIONS
5.1 ABBREVIATIONS
BOD Biochemical Oxygen Demand
COD Chemical Oxygen Demand
DA Director Administration
DDT Dichloro diphenyl trichloro ethane
DO Director Operations
DT Technical Director
DV Director New Ventures
EMS Environmental Management System
EPA Environmental Protection Agency, USA
EV Manager, Environmental Affairs Department
EVM Environmental Management
HSE Health Safety & Environment
ISO International Standards Organisation
LNG Liquefied Natural Gas
MIC Mesaieed Industrial City
MPN Minimum Probable Number
MSDS Material Safety Data Sheet
MSH Medical Services Occupational Health
NORM Naturally Occurring Radioactive Materials
OBM Oil-based Mud
ODP Ozone Depletion Potential
ODS Ozone-Depleting Substances
PCB Polychlorinated Biphenyl
PCT Polychlorinated Terphenyl
POP Persistent Organic Pollutants (a term used by UNEP)
QP Qatar Petroleum
RAA Ras Abu Aboud
RLC Ras Laffan Industrial City
ROPME Regional Organisation for the Protection of the Marine
Environment
SC Standards Committee
SCENR Supreme Council for the Environment & Natural Reserves
SQ Manager Safety Quality & Environmental Departments
STP Sewage Treatment Plant
TCLP Toxicity Characteristics Leaching Procedure
TPH Total Petroleum Hydrocarbon
UNEP United Nations Environment Programme
WHO World Health Organisation
Note that this Waste Management Specification replaces the requirements and
standards in section 6.0, Waste Management Criteria of Environment Protection
Management Standards, STD-ENV-002, Sept 1996.
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a) Explosive
An explosive substance or waste is a solid or liquid substance or
waste (or mixtures of substances or wastes) which is in itself
capable by chemical reaction of producing gas at such a
temperature and pressure and at such speed as to cause damage
to the surroundings.
b) Flammable
(i) Flammable liquids
Flammable liquids are liquids, or mixtures of liquids, or liquids
containing solids in solution or suspension (for example, paints,
varnishes, lacquers, etc., but not including substances or waste
otherwise classified on account of their dangerous characteristics)
which give off a flammable vapour at temperatures of not more than
60.5 deg. C, closed-cup test, or not more than 65.6 deg. C, open-
cup test. (Since the results of open-cup tests and of closed-cup test
are not strictly comparable and even individual results by the same
test are often variable, regulations varying from the above figures to
make allowance for such differences would be within the spirit of
this definition).
(ii) Flammable solids
Solids, or waste solids, other than those classed as explosives,
which under conditions encountered in transport are readily
combustible, or may cause or contribute to fire through friction.
(iii) Spontaneous combustion
Substances or wastes, which are liable to spontaneous heating
under normal conditions, encountered in transport, or to heating up
on contact with air, and being then liable to catch fire.
Flammable gases on contact with water
Substances or wastes, which, by interaction with water, are liable to
become spontaneously flammable or to give off flammable gases in
dangerous quantities.
c) Oxidising
Substances or wastes which, while in themselves not necessarily
combustible, may, generally by yielding oxygen cause, or contribute
to, the combustion of other materials.
d) Infectious Substances
Substances or wastes containing viable microorganisms or their
toxins, which are known or suspected to cause disease in animals
or humans.
e) Corrosive
Substances or wastes which, by chemical action, will cause severe
damage when in contact with living tissue, or, in the case of
(c) In cases other than those falling within (b) above, all liquids
leaked from the container will automatically be held on the
installation.
(vi) Guideline on the Voluntary Regulation of the Disposal of Drill
Cuttings on the Seabed.
(a) For all Drill Cuttings: No drill cuttings are
discharged/deposited on the seabed in a sensitive area
except in accordance with the approval of the Competent
State Authority (SCENR).
(b) Cuttings from drilling using Water-based Drilling Fluid. No
fluid should be regarded as water-based drilling fluid if any
kind of oil forms more than 10 % of the liquid phase of the
drilling fluid. Upon discharging drill cuttings resulting from
water-based drilling mud, due regard should be made to
the provisions of Article IX 4 (c).
(c) Cuttings from drilling in which Diesel Oil-Based Drilling
Fluid has been used. A drilling fluid is regarded as falling
within this category if diesel oil forms at least 25% of the
liquid phase of the fluid. Drill cuttings from drilling during
which diesel oil based drilling fluid has been used shall not
be deposited on the seabed without the express approval
of the Competent State Authority (SCENR).
(d) Cuttings from drilling when an Alternative Oil-Based Drilling
Fluid (or Low Toxicity Oil) is the one in which the liquid
phase contains over 40% of low aromatic content mineral
oil or alternative low toxicity oils. No drill cuttings produced
when alternative-based drilling fluid has been used shall be
deposited on the seabed without the express approval of
the Competent State Authority (SCENR).
(Reference: Protocol Concerning Marine Pollution
Resulting from Exploration and Exploitation of the
Continental Shelf, ROPME, Feb 17,1990 and the four
Implementing Guidelines)
d) Transboundary Movement of Hazardous Wastes
Transboundary movement of hazardous waste refer to movement
of hazardous wastes or other wastes from an area under the
national jurisdiction of one state to or through an area under the
national jurisdiction of another state or to or through an area not
under the national jurisdiction of any state, provided that at least
two states are involved.
The (SCENR) shall be consulted when a hazardous waste shall be
transported from the State of Qatar to another country or when
importing a hazardous waste into the State of Qatar. Various
provisions are imposed on these hazardous wastes and the
exporter or importer shall fulfil all the conditions imposed by the
(SCENR).
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Table 4: process wastewater effluent standards for onshore oil, LNG & gas
production
PARAMETER LIMIT
1 pH 6-9
2 Biochemical Oxygen Demand (BOD)5 50 mg/l
3 Chemical Oxygen Demand (COD) 250 mg/l
4 Total suspended solids 50 mg/l
5 Oil and grease 10 mg/l
6 Phenol 0.5 mg/l
7 Cyanide (total) 0.2 mg/l
8 Arsenic 0.1 mg/l
9 Cadmium 0.1 mg/l
10 Chromium (hexavalent) 0.1 mg/l
11 Lead 0.1 mg/l
12 Mercury 0.001 mg/l
13 Total metals. The metals would include 10 mg/l
nickel, copper, vanadium, beryllium and
zinc.
(References:
1. Section 2.5.0, Onshore Oil, LNG & Gas production, State of Qatar Environmental
Protection Standards, 1998.
2. Section 1.2.14: All industry-specific discharge standards are calendar monthly
averages or levels not to be exceeded during normal operating conditions)
Table 5: process wastewater effluent standards for offshore oil & gas production
PARAMETER LIMIT
1 pH 6-9
2 Total metals 10 mg/l
3 Oil & grease (in produced 40 mg/l (monthly average and a limit of 100
water) mg/l for any excursion.
4 Oil & grease (from 15 mg/l
machinery spaces)
(Reference: Section 2.6.0, Offshore oil, LNG & gas production, State of Qatar
Environmental Protection Standards, 1998.)
(Reference: Section 6.0, Water quality criteria, State of Qatar Environmental Protection
Standards, 1998.)
8.8 SEAWATER COOLING DISCHARGES
Water drawn from a cooling water canal for use as once-through, non-
contact cooling water may be discharged to a cooling water outfall provided
that the characteristics of the water meet the criteria prescribed in the table
below. Kindly note that although the temperature differential is 3 degrees C,
the minimum Dissolved Oxygen level is 2.0 mg/l and that the solubility of
oxygen decreases with increasing temperature.
Table 14: Quality Criteria for Once-through Sea Water Cooling Discharges (see
note 1)
PARAMETER UNITS MAXIMUM ALLOWABLE LIMIT
1 Temperature Difference, degree C 3
( T) (see note 2)
2 Floating Particles mg/m2 none
3 Chlorine residual mg/l 0.1
4 Dissolved Oxygen mg/l 2.0 (minimum)
(D.O.)
5 Oil & Grease differential mg/l 10
( G) (see notes 3 & 4)
NOTES:
1. The once-through cooling water would be discharged to sea at an appropriate
mixing zone.
2. The temperature differential would be measured between the water intake and
the edge of the agreed mixing zone where the initial dilution takes place. In
case no studies have been undertaken, the edge of the zone would be taken
as 100 meters from the point of discharge.
3. Oil & grease would be determined as per MOPAM method specified by the
(SCENR). MOPAM method is available from the EV department.
4. The increase over the level at the intake.
(Reference: Section 3.0, Non-Contact, Once-through Seawater Cooling
Discharges, State of Qatar Environmental Protection Standards, 1998)
8.9 DISCHARGE FROM MARINE VESSELS
Waste and ballast water discharges from ships, boats and barges operating
within Qatari waters shall conform to the following criteria:
NOTES:
1. In the case of segregated ballast tankers, discharging only segregated ballast,
there shall be a requirement only to comply with the oil and grease standard.
However, should there be any indication or suspicions that the ballast is in any
way contaminated, then the full analysis shall be required. Measurements may
be either using on board monitors, or suitably calibrated, portable instruments.
2. Samples shall be collected from all individual tanks on each vessel weighted by
volume of water in each tank.
3. The discharge of untreated contaminated shipboard wastes and refuse from
vessels into port or coastal waters is not permitted. Retention and storage of
refuse aboard ship for later transfer to onshore facilities is required.
4. Contaminated ballast water in excess of the limits in the table above shall not be
discharge into port or coastal waters.
5. Ballast sludge shall not be discharged to the gulf.
6. Slop oils or machinery drippings shall not be discharged into port or coastal
waters. These wastes shall be collected and discharged to appropriate onshore
facilities.
7. Catch pans shall be installed under valves and hose connections.
(Reference: Section 4.0, Discharge from Marine Vessels, State of Qatar
Environmental Protection Standards, 1998)
9.0 WASTE MANAGEMENT RESPONSIBILITIES
Notes:
• Disposal of Oil Based Mud and Oil Based Mud cuttings shall be
to a licensed hazardous waste complex capable of treating this
waste, such as, but not limited to a licensed landfarm. However
other acceptable treatment options can be used such as, but not
limited to a cement kiln.
Currently there is no licensed landfarm facility. However, the
MIC (Mesaieed Industrial City) has proposed to build a land
farm, capable of treating oily sludge based on a user-charge
system. Until the MIC landfarm becomes operational, all Oil
Based Mud and Oil Based Mud cuttings shall be stored.
b) Raw Sewage
Raw sewage is the effluents from toilets, bathrooms, domestic
washrooms and kitchens and must not be mixed with other
effluents and wastes. However within certain limits as specified
below, industrial waste streams may be connected to the sewer for
raw sewage leading to the cesspits, holding tanks, septic tanks
and/or any future sewage treatment plants.
It is often more economical to treat the mixture as a whole rather
than to treat the raw sewage and industrial waste streams
separately. However where toxic substances and/or biological
inhibitors are present in the industrial waste stream, prior treatment
or isolation and separate treatment is essential.
This section sets the prohibitions and limits for industrial waste
streams connected to the sewer, for raw sewage leading to the
cesspits, holding tanks, septic tanks and any future sewage
treatment plants.
Prohibitions:
No person shall discharge, or cause to be discharged, to the sewer
for raw sewage any of the following substances, materials, waters
or wastes:
interference with the proper operation of the Sewage Treatment Plant which
shall be prescribed by the Asset Manager when required.
7 Any liquid or solid hazardous waste described in the "Waste Management
Charts" of the waste management guidelines
All users of the sewer system must ensure that the above
prohibitions are complied with.
Limits:
An industrial waste stream may be discharged to the sewer for raw
sewage leading to the cesspits, holding tanks, septic tanks and
any future sewage treatment plants provided that it is not any of
the above mentioned prohibitions and within the limits set below:
1 The Asset Manager has the right to refuse connection of the industrial waste
water to the Sewage Treatment Plant if the subsequent overall total influent
to the Sewage Treatment Plant will exceed the design influent and organic
load in kg BOD/day as specified in the report approved by the (SCENR).
3 Any aqueous waste having a temperature not higher than 65 degrees C (150
degrees F).
4 Waste water from hand washing only containing residual hydrocarbon and
detergent only.
8 For combined drainage (sewage and industrial waste) an oil water separator
must be installed upstream the Sewage Treatment Plant which must be
capable of maintaining an effluent with not more than 100 ppm total oil and
grease at any one time.
9 Any other aqueous waste or sludge allowed to be discharged to the Sewage
Treatment Plant by the Asset Manager with concurrence from EV
Department.
c) Sewage sludge
Sewage sludge generation comes from three sources: (a)
untreated sludge from cesspits or holding tanks, (b) treated
sewage in semi-liquid form (e.g. septic tank sludge) or (c) in dried
form (e.g. dried sewage sludge from Sewage Treatment Plant
sludge drying beds). As stated in the Basel Convention
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Table 17: Waste lubricant quality criteria for recycling into the crude oil system
PARAMETER ANALYSIS
1 Flashpoint > 100 degree Centigrade
2 Lead < or = 50 ppm
3 PCBs < or = 50 ppm
4 Organic chloride < = 0.5% (w/w)
(Reference: Automotive Markets Environmental Guidelines, Shell Supply and
Marketing, Automotive Markets, SMDM, 1991).
TYPE OF
WASTE OIL
PREFERRED
2
OK
PREFERRED, not
PREFERRED, depends as a Temporary measure,
Contaminated less than 1,000 C,
on nature and levels of Reduce waste oil content
(No PCBs) adequate burn-out,
contaminants below 2% if necessary
treat flue gas
3
PREFERRED, Not
Contaminated less than 1200 C, 2
second residence
(PCBs > = 50 NOT RECOMMENDED
time, 3% excess
NOT RECOMMENDED
ppm) oxygen, treat flue
gases
2. Medical "Sharps"
• discarded syringes, needles and cartridges
• broken glass and other sharp instruments contaminated in
medical operations
Offshore Medical Wastes
The sources of medical wastes acceptable at the proposed Halul
Incinerator are limited to the following, provided that the storage
requirements, described herewith have been complied with:
• Offshore QP Platform Clinics
• QP Clinic in Halul Island
Segregation of Clinical Wastes. It is very important to collect
different types of wastes in identifiable colour-coded containers.
For medical wastes destined to the proposed Halul Incinerator,
these must be placed in "Yellow Boxes" approved by the QP
Medical Department to have complied with the U.N. Hazardous
Material Standard Number Din. U 30 739.
Storage, Collection and Transport of Clinical Wastes.
It must be emphasised to all who may handle medical wastes that
it is an infectious material and could be harmful to their health if
not handled properly. Therefore a short explanation by the Clinic
Nurse in charge to the handlers is essential. Any one handling
clinical wastes must wear rubber gloves.
Yellow-coloured containers:
All “Medical wastes” described above shall be placed in yellow
plastic bags approved by the QP Medical Department to have
complied to UN Hazardous Material Standard Number Din U 30
739. When the yellow plastic bag is filled to manufacturer's
instruction it shall be the duty of the Clinic Nurse in charge to
securely seal it as per manufacturer’s instructions, and then place
this inside the yellow box. Similarly, the specifications of the yellow
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Hazardous Waste Classification according to the Basel Convention, 1989, entered into
force on 5 May 1992 and updated focal points 1998:
UN UN
Row Characteristics Description
Class* Code
UN
= Corresponds to the hazard classification system included in the United Nations
Class*
Recommendations on the Transport of Dangerous Goods (ST/SG/AC.10/1/Rev.5,
United Nations, New York, 1988
UN UN
Row Characteristic Descriptio
Class* Code
Organic substances or wastes which contain the
o-o-structure are thermally unstable substances
7 5.2 H5.2 Organic Peroxides
may undergo exothermic or self-
decomposition
Substances or wastes liable either to cause death
8 6.1 H6.1 Poisonous (Acute) serious injury or to harm human health if
inhaled or by skin
Substances or wastes containing viable micro
9 6.2 H6.2 Infectious Substances or their toxins which are known or suspected to
disease in animals or
Substances or wastes which, by chemical action,
cause severe damage when in contact with living
10 8 H8 Corrosives or, in the case of leakage, will materially damage,
even destroy, other goods or the means of
they may also cause other
Liberation of toxic Sustances or wastes which, by interaction with
11 9 H10 gases in contact w/ air water, are liable to give off toxic gases in
or water quantities
Substances or wastes which, if they are inhaled
Toxic (Delayed or
12 9 H11 ingested or if they penetrate the skin, may
chronic) delayed or chronic effects, including
Substances or wastes which if released present or
present immediate or delayed adverse impacts to
13 9 H12 Ecotoxic
environment by means of bioaccumulation and/or
effects upon the biotic
Leachate w/ Capable, by any means, after disposal, of
14 9 H13 characteristics of any another material, e.g. leachate, which possesses any
above the characteristics listed
UN
= Corresponds to the hazard classification system included in the United
Class*
Recommendations on the Transport of Dangerous Goods
(S /SG/Nations,
United C / / New York,
UN
Hazardous waste
Row Category Description
Stream
Number
Clinical wastes from medical care in hospitals, medical
1 Y1 Clinical Wastes centres and clinics
Waste from
Wastes from the production and preparation of
2 Y2 pharmaceutical pharmaceutical products
products
Waste pharma
Waste drugs and medicines either expired,
3 Y3 ceuticals, drugs and contaminated, etc.
medicines
Biocides and Wastes from the production, formulation and use of
4 Y4 biocides and phytopharmaceuticals
phytopharmaceuticals
Wood preserving Wastes from the manufacture, formulation and use of
5 Y5 wood preserving chemicals
chemicals
Wastes from the production, formulation and use of
6 Y6 Organic solvents organic solvents
Heat treatment Wastes from heat treatment and tempering operations
7 Y7 containing cyanides.
containing cyanides
8 Y8 Waste mineral oil Waste mineral oil unfit for their originally intended use.
Waste oils/water,
Waste oils/water, hydrocarbons/water mixtures,
9 Y9 hydrocarbons/water emulsions
mixtures, emulsions
Waste substances and articles containing or
contaminated with polychlorinated biphynyls (PCBs),
10 Y10 PCBs, PCTs and PBBs and/or polychlorinated terphynyls (PCTs) and/or
polybrominated biphynels (PBBs).
Waste tarry residues arising from refining, distillation and
11 Y11 Waste tarry residues any pyrolytic treatment.
UN
Categories of hazardous wastes requiring
Row Category
special consideration
Number
Toxicity Criteria
( US Toxicity Criteria Leaching Procedure or TCLP)
Contaminant ppm
INORGANIC
1 Arsenic 5.0
2 Barium 100.0
3 Cadmium 1.0
4 Chromium (total) 5.0
5 Lead 5.0
6 Mercury 0.2
7 Selenium 1.0
8 Silver 5.0
others to be specified on case
9
to case
ORGANIC
1 Endrin 0.02
2 Lindane 0.4
3 Methoxychlor 10.0
4 Toxaphene 0.5
others to be specified on case
5
to case
4 Annex B, Group II
FROM:_______________________________________
TO: _________________________________________________________________________
Your Ref. No. ………………………………………
Decision:
1. Request accepted
2. Request accepted on the following conditions
A. …………………………………..
B. …………………………………..
3. Request refused due to the following reasons: _________________________________________________
Applicant’s name:_____________________________________ Signature: __________________________
Position: __________________________________ Date dd/mm/yy
……………………………
m3 L
kg
Waste Type (Place X in appropriate squares)
Soli Liqu Ine Poison Flamm Corrosi Od Acid Highl Liqui Infec
d id rt ous able ve oro y d/slu tious
us react dge
ive
Description of waste including identification of any hazardous components
Further comment:
______________________________________________________________
_________________________
I hereby declare that the above is true and correct in every respect:
Signature of waste producer: ______________________
Name: _______________________________________
Designation: __________________________________
Sponsor’s Name:
Sponsor’s Tel.:
Sponsor’s fax:
Signature: ……………………………………….
SAR = Na / [( Ca + Mg ) / 2 ]1/ 2
High sodium (Na) levels (SAR>12) in soil solution cause Ca and Mg deficiencies in
plants.
ESP is a measure of the degree to which the soil exchange sites are saturated with
sodium. When exchangeable sodium is in excess and the ESP exceeds 15%, there
is a general lack of structural stability among soil particles, and water infiltration is
impeded. The soil is termed sodic under these conditions.
ESP = 100( −0. 0216 + 0. 01475 SAR ) / 1 + ( −0. 0216 + 0. 01475 SAR )
F.2 Hydrocarbons
Crude oil from a producing formation and diesel or mineral oil added to drilling mud
is the typical hydrocarbons associated with E&P wastes. API (1997) recommends a
waste/soil mix containing oil and grease or total petroleum hydrocarbon (TPH)
concentrations of up to 1 percent by weight when land spreading. This is equivalent
to a TPH concentration of 10 000 mg/kg. This value has been found to be generally
protective of waters, plants, and soil microbes. At 1% or less of mixed
hydrocarbons, recovery of the site is expected after a few months to one growing
season, following a one-time application. Site-specific conditions may tolerate initial
waste/soil mixtures with higher TPH if they contain low levels of water-soluble
organic compounds.
F.3 pH
Under the U.S. Resource Conservation and Recovery Act (RCRA) enacted in 1976,
wastes having a pH ≤ 2 or ≥ 12.5 are considered hazardous by way of the
characteristic of corrosivity. Such waste may react to release potentially toxic levels
of heavy metals normally insoluble and have the potential to cause chemical burns.
API (1991b) recommends a pH range from 6 to 9 for road spreading and onsite
burial waste management techniques, while a pH range from 6 to 8 is suggested
when using the land spreading technique.
F.4 Metals
The metals of potential environmental concern found in E&P waste are arsenic (As),
barium (Ba), boron (B), cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb),
mercury (Hg), molybdenum (Mo), nickel (Ni), selenium (Se), and zinc (Zn). Table
A.2 presents the API (1997) guidance for metals. Deuel and Holliday (1994) also
recommend to screen for silver (Ag) when characterising a field for the first time but
out of 664 pits they tested, all contained silver levels below the permissible level of
10 ppm.
The availability of metals in soil is dependent upon pH, reduction/oxidation potential,
and total metal concentration. The controlling variable is pH. In general, solubility of
metals is directly related to pH, except for barium, whose solubility is directly related
to pH (Freeman and Deuel, 1984). If pH conditions change in the soil, significant
fractions of a heavy metal may be released in the environment.
2. Selenium: EPA using the risk-based multi pathway analysis generated the limiting
pathway concentration of 100 mg/kg. However, the potential for plant uptake of Se
may be high in alkaline soils under arid and semi-arid conditions. Plants that
accumulate Se in these soils may pose a threat to grazing animals. Therefore, if
elevated levels of Se are found in the waste, the operator should consider site
conditions that control its availability.