5718bf9c96b271461239708mto23 Presentation EM Gargoyle SHC 80 POE PDF
5718bf9c96b271461239708mto23 Presentation EM Gargoyle SHC 80 POE PDF
5718bf9c96b271461239708mto23 Presentation EM Gargoyle SHC 80 POE PDF
October 2015
This presentation includes forward-looking statements. Actual future conditions (including economic conditions, energy demand, and energy supply) could differ materially due to changes in technology, the
development of new supply sources, political events, demographic changes, and other factors discussed herein (and in Item 1A of ExxonMobil’s latest report on Form 10-K or information set forth under
"factors affecting future results" on the "investors" page of our website at www.exxonmobil.com). This material is not to be reproduced without the permission of Exxon Mobil Corporation.
Instructions
• Use arrow keys to scroll into the Power Point presentation. To see a
specific item from the Overview Slide (i.e. Lubrication challenges) just
click on it.
• EU has taken a clear direction towards phasing down HFCs and is projected to
be the fastest-growing region in the market due to the high rate of natural
refrigerant adoption by the end users. Asia-Pacific is the second-largest market
for natural refrigerants.
• Ammonia refrigerants (R-717) dominated the market in 2015 and are estimated
to experience a steady growth on account of its wide usage in industrial
refrigeration and light-commercial refrigeration applications.
Criteria Properties
Cooling capacity Significantly higher volumetric capacity than
conventional refrigerants
Environmental properties Global Warming Potential (GWP) = 1, significantly
lower than for commonly used HFCs
Refrigerant cost Lower than for HFCs, but system costs are generally
higher
Safety Low toxicity and nonflammable: high-pressures and
associated hazards present additional challenges
Availability of Safety Standards EN378 & ISO 51491 include R744
appropriate standards
Composition Single molecule
Availability of refrigerant Varies globally but generally available
CO2 Properties and Application boundaries
Main Challenges
Impact on operation
Note: Summary based on one customer field trial on 4 CO2 reciprocating compressors from December 2013 to April
2015
Field Test Results
Field Test Description
• Site: Slaughterhouse
• Refrigeration System: Cascade System NH3/CO2 Subcritical, use of the
cold and heat generated
• Units: 4 reciprocating compressors, with variable power
• Previous oil: Conventional POE
• Analysis: Oil sampled from all 4 compressor at regular
intervals
Field Test Implementation Equipment Details
Compressor Filling date Equipment hours at start of test
Mobil
CP1 19/12/2013 Brand new compressor
End of Test : Dec.1st 2014, after 5600
hours
CP2 18/03/2014 7121, 2nd filling Oct. 30th 2014, 8765 hours
CP3 20/02/2014 6974
CP4 06/05/2014 7418
• Viscosity: Stable
• Maximum estimated contamination with previous oil: <2% (Dec. 1st 2014
sample)
CP1 – End of Test inspection
CP 1 inspection has been carried out on December 2nd 2014:
• Equipment age: 5,600 hours,
• Lubricant: Mobil SHC Gargoyle 80 POE
In presence of:
• Service provider
• Builder
• Customer
• ExxonMobil
CP1 – End of Test inspection – Parts Rating
Compressor part rating Conditions
Connecting rod:
Halves bearings Good condition, limited wear
Bushings Good condition, very limited wear
Piston Pin: Good condition, no wear
Piston Rings: No deposit, move easily & smoothly
Piston:
Thrust Side Acceptable, some visible scratches
Anti-Thrust Side Good conditions no scratches
Cylinder liner/sleeve:
Thrust Side Good condition, limited scratch area
Anti-Thrust Side Excellent condition, honing marks
Discharge Valve:
Plate Good condition
Seat Good condition
Crankshaft: Good condition
Crankcase: Clean, no deposits
CP1 – End of Test inspection – Summary
Mobil SHC Gargoyle 80 POE is exhibiting very good lubricating
performance:
• Wear trends through Signum analysis are remaining at low levels after
5,600 hours
Instant temperatures measured on the head cover plate of the pistons. Measurements were carried out on January
14th 2014
Low pressure CO2 High pressure CO2
Motor Compressor Instant power, kW
"Compressor 1" lubricated with: Date Graph receiver, bar receiver, bar
Speed, rpm load, %
Average Max Average Max Average Max
October 1st 2014, 2 PM Graph 5 1500 100 12,0 12,0 29,2 32,0 105,0 123,0
Conventional POE
October 2nd 2014, 2 PM Graph 6 1500 100 9,8 13,5 28,3 31,5 99,0 128,0
March 2nd 2015, 2 PM Graph 7 1500 100 9,3 11,5 26,2 28,0 97,0 100,0
Mobil SHC Gargoyle 80 POE
March 4th 2015, 1 PM Graph 8 1500 100 9,2 11,5 26,2 27,9 97,0 100,0
2. Drain hot oil as best as possible (to remove potential deposits and as
much remaining oil as possible)
31
Daniel Chart,
Miscibility, Density
Daniel Chart: Mobil SHC Gargoyle 80 POE with
R-744
Miscibility Profiles in R-744
Density Chart: Mobil SHC Gargoyle 80 POE
with R-744 1.08
10% CO2
2% CO2 5% CO2
0% - neat lub.
1.06
1.04
Density (g/cc)
1.02
1.00
0.98
0.96
20% CO2
30% CO2
0.94
-10 0 10 20 30 40 50 60 70 80 90 100 110 120
Temperature (°C)
Back Up Slides
CO2 Systems Safety
CO2 Phase Diagram
• Transcritical systems: Systems are called transcritical when heat rejection takes
place above the critical point of the refrigerant.
• Subcritical systems: Systems are called subcritical when heat rejection takes
place below the critical point of the refrigerant.
• Booster systems: Systems with two temperature levels (e.g., -35°C and -20°C
evaporating temperature) and with low-stage and medium stage compressors.
39
CO2 Refrigeration Systems - Safety
• Trapped Liquid: The coefficient of expansion for R744 is significantly higher than
for other refrigerants, as a rule of thumb, trapped R744 liquid will increase in
pressure by 10 bars for every 1°K temperature increase.
• Dry Ice: (solid R744) is formed when R744 pressure and temperature is reduced
to below the triple point (4.2 bar g, -56°C). If the dry ice is trapped within the
system, it will absorb heat from the surroundings and turn into gas. This will result
in a significant pressure increase.
• Freeze Burns: Contact with solid or liquid R744 will cause freeze burns.
Back Up Slide EM
Technology
Measuring the Lubricity Performance of
Lubricants with the Mini-Traction Machine
Load
Vball
Vdisk
• Viscosity: Stable
• Wear trends: Iron, low regular trend
Aluminum, very low to no trend
Copper and Tin, not detectable/low value
• Estimated contamination with previous oil: <2% (Dec. 1st 2014 sample)
16
85 14
12
80 10
8
75
6
4
70
2
65 0
0 1000 2000 3000 4000 5000 6000 0 1000 2000 3000 4000 5000 6000
Mobil SHC Gargoyle 80 POE cumulative hours – CP1 Mobil SHC Gargoyle 80 POE cumulative hours – CP1
Viscosity, LTS Iron, LTS Aluminum, LTS Copper, LTS Tin, LTS
• Viscosity: Stable
• Wear trends: Iron, new charge, low level
Aluminum, new charge, low level
Copper and Tin, not detectable/low value
• Estimated contamination with previous oil: <0.5% (Dec. 10th 2014
sample)
16
85
2nd filling 14
2nd filling
12
Kinematic viscosity, cSt
80
Wear contents, ppm 10
75 8
70 4
65 0
0 500 1000 1500 2000 0 500 1000 1500 2000
Mobil SHC Gargoyle 80 POE cumulative hours – CP2 Mobil SHC Gargoyle 80 POE cumulative hours – CP2
Viscosity, LTS Iron, LTS Aluminum, LTS Copper, LTS Tin, LTS
• Viscosity: Stable
• Wear trends: Iron, regular trend
Aluminum, low trend
Copper and Tin, not detectable/low value
• Estimated contamination with previous oil: 2% (Dec. 10th 2014 sample)
85 16
14
Kinematic viscosity, cSt
80 12
75 8
70 4
65 0
0 500 1000 1500 2000 0 200 400 600 800 1000 1200 1400 1600 1800
Mobil SHC Gargoyle 80 POE cumulative hours – CP3 Mobil SHC Gargoyle 80 POE cumulative hours – CP3
Viscosity, LTS Iron, LTS Aluminum, LTS Copper, LTS Tin, LTS
• Viscosity: Stable
• Wear trends: Iron, regular low trend
Aluminum, very low trend
Copper and Tin, not detectable/low value)
• Estimated contamination with previous oil: <1% (Dec. 10th 2014 sample)
85 16
14
Kinematic viscosity, cSt
80 12
75 8
6
70 4
2
65
0
0 500 1000 1500 2000 2500
0 500 1000 1500 2000 2500
Mobil SHC Gargoyle 80 POE cumulative hours – CP4
Mobil SHC Gargoyle 80 POE cumulative hours – CP4
Viscosity, LTS
Iron, LTS Aluminum, LTS Copper, LTS Tin, LTS
• Cylinder liner/sleeve:
• Discharge valve:
Plate Seat
Good condition Good condition
CP1 – End of Test inspection – Parts Rating &
Pictures
Piston 1 (Piston 1 is facing the most extreme temperature and pressure
operating conditions):
• Crankshaft: