ML ML ML N ML N ML N ML N: Appendix B Calculations & Computations
ML ML ML N ML N ML N ML N: Appendix B Calculations & Computations
ML ML ML N ML N ML N ML N: Appendix B Calculations & Computations
1N HAc
0.5N HAc
Water Layer
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0.25NHAc
Computation of Kc & n
ln Kc = n lnC2 -lnCl
1N - 0.5N
For 1N:
C1 = 0.8912N
C2 = 0.0286N
For 0.5N:
C1 = 0.4188N
C2 = 8.989x10^-3N
Kc = 0.1104
n = 0.6525
0.5N - 0.25N
For 0.5N:
C1 = 0.4188N
C2 = 8.989x10^-3N
For 0.25N:
C1 = 0.2204N
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C2 = 3.3835x10^-3N
Kc = 0.1080
n = 0.6570
1N - 0.25N
For 1N:
C1 = 0.8912N
C2 = 0.0286N
For 0.25N:
C1 = 0.2204N
C2 = 3.3835x10^-3N
Kc = 0.1096
n = 0.6545
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APPENDIX C
List of Apparatus
Beaker
Wash Bottle
Reagent Bottle
Stirring Rod
Watch Glass
Volumetric Flask
Pipette
Pipetol
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Base buret
It is used as container for the titrant where accurate volume measurements can be
read.
Iron Stand
Erlenmeyer Flask
Separatory Funnel
It is used separate immiscible liquids by discharging the lower layer from the
stopcock and pouring out the upper layer from the mouth.
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APPENDIX D
Documentation
PRE LAB
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Figure 5.2.2: Addition of Carbon Tetrachloride
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TITRATION
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APPENDIX E
cc of H2O. When equilibrium was established, the CHCl3 contained 0.14 moles of SO2
and the H2O layer 0.05 moles. What is the distribution coefficient of SO2 between H2O
VH2O = 75 cc = 0.075 L
SOLUTION:
In Kc = n In NH2O – In NCHCl3
4.1592
64.06 18 18.5471
0.05
average MW in H2O layer=
0.05 4.1592 0.05 4.1592
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average MW in CHCl3 layer= YSO2(MWSO2) + YCHCl3(MW CHCl3)
2.4913
64.06 119.35 119.5873
0.14
average MW in CHCl3 layer=
0.14 2.4913 0.14 2.4913
18.5471
In Kc = In (0.14/0.2) – In (0.05/0/075)
119.5873
Kc = 1.4193
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2. A) Show the following data for the distribution of benzoic acid between water
C H2O C C6H6
0.0150 0.242
0.0195 0.412
0.0289 0.970
a) k = 0.0150/0/242 = 0.0620
b) k= 0.0195/0.412 = 0.0473
c) k= 0.0289/0.970 = 0.0298
B) Show that the following relation can be obtained on the assumptions: (1) that
the dissociation of benzoic acid in water is slight and (2) that the acid is partially
k= H2O/C6H6 k= C6H6/H2O
Therefore if benzoic acid is the extracting solvent meaning the value of k is greater
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3. At 25 °C the distribution coefficient of H2S between H2O and C6H6, defined as
to extract in a single step 90% of the H2S from 1 liter of 0.1 molar aqueous solution of
H2S?
k= 0.167
VH2S = 1 L
W = 0.1 molar
n=1
SOLUTION:
VC6H6 = 0.0186 L
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4. Use the data of the preceding problem to find what total volume of C6H6 would
be necessary to remove 90% of the H2S from the given aqueous solution in three
k= 0.167
VH2S = 1 L
W = 0.1 molar
n=3
SOLUTION:
VC6H6 = 5.9693 x 10 3 L
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5. At 25°C the distribution coefficient of C2H5OH between CCl4 and H2O k =
W= 1g
k= 0.0244
V1 = 20 cc
V2= 50 cc
n=1
SOLUTION:
Wn = 0.9903 g
Therefore, 0.9903g of the solute will go to water and the remaining 0.0097g will go
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