First Law of Thermodynamics
First Law of Thermodynamics
First Law of Thermodynamics
Law applications
Thermal systems
1- The closed system: is the one in which there is no mass transfer
between the sample and the surrounding medium, but a heat
transfer can occur between them.
2- The open system: is the one in which a mass transfer and a heat
transfer occurs between the sample and the surrounding medium.
3- Isolated system: It is the one in which heat transfer does not
occur, in which a heat transfer does not occur between the sample
and the mean media
Thermodynamics: A sample present in a surrounding environment.
An example is a sample: a glass of water, and the surrounding
environment: the room. For example, if we put a piece of ice in a
cup of water, heat moves from the room’s atmosphere to a cup of
water, and the piece of ice melts. The heat transfer between the
room and the cup remains until the temperature is equal in them.
This system is considered an open system.
T1
Surrounding medium
T2
If constant temperature
T2=T1 dT=0
U=0 , H=0 , Q=-W
P1/P2=V2/V1
W=-PdV = -RTdV/V=-RT Ln(V2/V1) or –RT Ln(P1/P2)
If adiabatic process
Q=0, U=W , T2/T1= (V2/V1) ^ (1-t)
T2/T1=(P2/P1) ^ (1-1/t) , t=Cp/Cv
Heat engines
1-The most common practical application of the First Law is the heat
engine. Heat engines convert thermal energy into mechanical
energy and vice versa. Heat engines fall into the category of open
systems.
3-This cold gas can then absorb heat energy from its environment.