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First Law of Thermodynamics

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First law of thermodynamics

It is an expression of the principle of energy conservation, that is,


that energy changes from one state to another and from potential
energy to active energy, in other words that energy is neither
destroyed nor created, but rather transformed from one image to
another.
The law identifies heat transfer between systems as a form of
energy transfer. The height of the internal energy of a particular
thermodynamic system is equal to the amount of added thermal
energy of the system, minus the mechanical work is done from the
system to the surrounding medium.

Law applications
Thermal systems
1- The closed system: is the one in which there is no mass transfer
between the sample and the surrounding medium, but a heat
transfer can occur between them.
2- The open system: is the one in which a mass transfer and a heat
transfer occurs between the sample and the surrounding medium.
3- Isolated system: It is the one in which heat transfer does not
occur, in which a heat transfer does not occur between the sample
and the mean media
Thermodynamics: A sample present in a surrounding environment.
An example is a sample: a glass of water, and the surrounding
environment: the room. For example, if we put a piece of ice in a
cup of water, heat moves from the room’s atmosphere to a cup of
water, and the piece of ice melts. The heat transfer between the
room and the cup remains until the temperature is equal in them.
This system is considered an open system.
T1
Surrounding medium

T2

System T1 > T2 then T1 = T2

The first law of thermodynamics of the closed system


dU= dQ + dW
dQ The amount of heat that is transferred to the system or from the
system
dU The change in internal energy
dW It is the work done on or from the system
The first law of thermodynamics of the open system
dQ-dW = dH +dKin+dPot
dH change in heaters (heat content)
dKin Change in kinetic energy
dPot The change in Potential energy

If constant pressure process


P1=P2
W=PdV = p (V2-V1)
U=Q + w
Q=U-P (V2-V1) =H
Q=H
V1/V2 = T1/T2
If constant volume process
V1=V2 W=PdV = 0 U=Q=H
H=Cp (T2-T1), U=Cv (T2-T1)
P1/P2=T1/T2

If constant temperature

T2=T1 dT=0
U=0 , H=0 , Q=-W
P1/P2=V2/V1
W=-PdV = -RTdV/V=-RT Ln(V2/V1) or –RT Ln(P1/P2)
If adiabatic process
Q=0, U=W , T2/T1= (V2/V1) ^ (1-t)
T2/T1=(P2/P1) ^ (1-1/t) , t=Cp/Cv
Heat engines
1-The most common practical application of the First Law is the heat
engine. Heat engines convert thermal energy into mechanical
energy and vice versa. Heat engines fall into the category of open
systems.

2-The basic principle of a heat engine exploits the relationships


among heat, volume and pressure of a working fluid.

3- This fluid is typically a gas, but in some cases it may undergo


phase changes from gas to liquid and back to a gas during a cycle.

4-When gas is heated, it expands; however, when that gas is


confined, it increases in pressure. If the bottom wall of the
confinement chamber is the top of a movable piston, this pressure
exerts a force on the surface of the piston causing it to move
downward.

5-This movement can then be harnessed to do work equal to the


total force applied to the top of the piston times the distance that
the piston moves.

There are numerous variations on the basic heat engine. For


instance, steam engines rely on external combustion to heat a boiler
tank containing the working fluid, typically water. The water is
converted to steam, and the pressure is then used to drive a piston
that converts heat energy to mechanical energy. Automobile
engines, however, use internal combustion, where liquid fuel is
vaporized, mixed with air and ignited inside a cylinder above a
movable piston driving it downward.

Refrigerators, air conditioners and heat


pumps
1-Refrigerators and heat pumps are heat engines that convert
mechanical energy to heat. Most of these fall into the category of
closed systems.

2-When a gas is compressed its temperature increases. This hot gas


can then transfer heat to its surrounding environment. Then, when
the compressed gas is allowed to expand, its temperature becomes
colder than it was before it was compressed because some of its
heat energy was removed during the hot cycle.

3-This cold gas can then absorb heat energy from its environment.

4-This is the working principle behind an air conditioner. Air


conditioners don’t actually produce cold; they remove heat. The
working fluid is transferred outdoors by a mechanical pump where it
is heated by compression. Next, it transfers that heat to the outdoor
environment, usually through an air-cooled heat exchanger. Then, it
is brought back indoors, where it is allowed to expand and cool so it
can absorb heat from the indoor air through another heat
exchanger.

5- A heat pump is simply an air conditioner run in reverse. The heat


from the compressed working fluid is used to warm the building. It is
then transferred outside where it expands and becomes cold, thereby
allowing it to absorb heat from the outside air, which even in winter is
usually warmer than the cold working fluid.

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