Laws of Thermodynamics

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Laws of thermodynamics

Thermodynamics –study of energy

Bioenergetics – study of the movement of energy in the ecosystem.

laws of thermodynamics - describe the transport of heat and work in thermodynamic processes.
These laws have become some of the most important fundamental laws in physics and other
sciences associated with thermodynamics.

First law
conversation of energy
It states that energy cannot be created or destroyed; rather, the amount of energy lost in a steady
state process cannot be greater than the amount of energy gained.

. It refers to the two ways that a closed system transfers energy to and from its surroundings – by
the process of heat transfer and the process of mechanical work.

The rate of gain or loss in the stored energy of a system is determined by the rates of these two
processes. In open systems, the flow of matter is another energy transfer mechanism, and extra
terms must be included in the expression of the first law.

The First Law clarifies the nature of energy

Fundamental thermodynamic relation

Heat supplied to a system = increase in internal energy of the system + work done by the system

Increase in internal energy of a system = heat supplied to the system - work done by the system

where we know TdS=δQ and pdV=δW.

Therefore we can say δQ=dU+δW, where:

 U is internal energy
 T is temperature
 S is entropy
 p is pressure
 V is volume

This is a statement of conservation of energy: The net change in internal energy (dU) equals the
heat energy that flows in (TdS), minus the energy that flows out via the system performing work
(pdV).

Second law
Law of entropy
This law states "spontaneous natural processes increase entropy overall." Another is "heat can
spontaneously flow from a higher-temperature region to a lower-temperature region, but not the
other way around." Or there is no 100 percent utilization of energy.

Nevertheless, energy can be transferred from cold to hot,

Example, when a refrigerator cools its contents while warming the surrounding air, though still
all transfers as heat are from hot to cold.

Entropy - disorder

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