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    1.3.5 Important Physico-Chemical Constants 1.3.6 Conversion Factors

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    Harik C
    This document contains tables of important physical constants, conversion factors, thermodynamic properties of select substances, and formulae. Table 1.6 lists physical constants such as the speed of light, elementary charge, and Boltzmann's constant. Tables 1.7 and 1.8 provide conversion factors for energy, pressure, and temperature. Table 1.9 gives thermodynamic data including enthalpy of formation and heat capacity for substances like carbon, water, and oxygen. Table 1.10 outlines fundamental thermodynamic equations including Boyle's, Charles', and Gay-Lussac's laws.

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    1.3.5 Important Physico-Chemical Constants 1.3.6 Conversion Factors

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    Harik C
    19 views2 pages
    This document contains tables of important physical constants, conversion factors, thermodynamic properties of select substances, and formulae. Table 1.6 lists physical constants such as the speed of light, elementary charge, and Boltzmann's constant. Tables 1.7 and 1.8 provide conversion factors for energy, pressure, and temperature. Table 1.9 gives thermodynamic data including enthalpy of formation and heat capacity for substances like carbon, water, and oxygen. Table 1.10 outlines fundamental thermodynamic equations including Boyle's, Charles', and Gay-Lussac's laws.

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    This document contains tables of important physical constants, conversion factors, thermodynamic properties of select substances, and formulae. Table 1.6 lists physical constants such as the speed of light, elementary charge, and Boltzmann's constant. Tables 1.7 and 1.8 provide conversion factors for energy, pressure, and temperature. Table 1.9 gives thermodynamic data including enthalpy of formation and heat capacity for substances like carbon, water, and oxygen. Table 1.10 outlines fundamental thermodynamic equations including Boyle's, Charles', and Gay-Lussac's laws.

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    1.3.5 Important Physico-Chemical Constants 1.3.6 Conversion Factors

    Uploaded by

    Harik C
    This document contains tables of important physical constants, conversion factors, thermodynamic properties of select substances, and formulae. Table 1.6 lists physical constants such as the speed of light, elementary charge, and Boltzmann's constant. Tables 1.7 and 1.8 provide conversion factors for energy, pressure, and temperature. Table 1.9 gives thermodynamic data including enthalpy of formation and heat capacity for substances like carbon, water, and oxygen. Table 1.10 outlines fundamental thermodynamic equations including Boyle's, Charles', and Gay-Lussac's laws.

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    of 2

    1.3.

    5 Important Physico-chemical Constants


    1.3.6 Conversion Factors
    Table 1.6 Important physico-chemical constants
    Symbol Constant Value
    c Speed of light in vacuo 2.99792458_108 m s_1
    e Elementary charge 1.6021892_10_19 C
    ε0 ¼ (μ0_c2)_1 Permittivity in vacuo 8.85418782_10_12 A2 s4 m_3 kg_1
    F ¼ e_NA Faraday’s constant 9.648456_104 C mol_1
    g Earth’s gravity near surface 9.81 m s_2
    ge ¼ 2 μe/μB Landé factor of free electron 2.0023193134
    γp Gyromagnetic ratio of proton 2.6751987_108 s_1 T_1
    h Planck’s constant 6.626176_10_34 J s
    kB ¼ R/NA Boltzmann’s constant 1.380662_10_23 J K_1
    me Mass of electron 9.109534_10_31 kg
    mn Mass of neutron 1.6749543_10_27 kg
    mp Mass of proton 1.6726485_10_27 kg
    μ0 Magnetic field constant 4π_10_7 m kg s_2 A_2
    μB ¼ e_h/(4π_me) Bohr magneton 9.274078_10_24 J T_1
    με Magnetic moment of electron 9.284832_10_24 J T_1
    μN ¼ e_h/(4π_mp) Nuclear magneton 5.050824_10_27 J T_1
    NA, L Avogadro’s (Loschmidt’s) constant 6.022045_1023 mol_1
    pø Standard pressure (IUPAC) 1.00_105 Pa
    pnormal Normal pressure (NIST) 1 atm ¼ 1013.25 hPa
    R Gas constant 8.31441 J K_1 mol_1
    R1 Rydberg’s constant 1.097373177_107 m_1
    Tø, θø Standard temperature (IUPAC) 273.15 K, 0 _C
    Tnormal, θnormal Normal temperature 298.15 K, 25 _C
    u Atomic mass unit 1.6605402_10_27 kg
    Vm
    ø ¼ R_Tø/pø Molar volume of an ideal gas 22.41383 l mol _1
    Table 1.7 Conversion
    factors for energy
    J cal eV
    1 J 1 0.2390 6.24150974_1018
    1 cal 4.184 1 2.612_1019
    1 eV 1.60217646_10_19 3.829_10_20 1
    substances at normal conditions (Tnormal ¼ 298 K, pnormal ¼ 1.013 bar)
    Table 1.9 Enthalpy of formation, Gibbs free energy of formation and molar heat capacity of select
    1.3.7 Thermodynamic Properties of Select Substances
    1.4 Summary of Important Formulae and Equations
    Table 1.8 Conversion factors for pressure
    Pa bar atm mm Hg (Torr) psi
    1 Pa 1 10_5 9.869_10_6 7.501_10_3 1.450_10_4
    1 bar 105 1 0.9869 750.1 14.50
    1 atm 1.013_105 1.013 1 760.0 14.69
    1 mm Hg (Torr) 133.3 1.333_10_3 1.316_10_3 1 1.933_10_2
    1 psi 6.895_104 6.897 10_2 6.807 10_2 51.72 1
    Species ΔHf in kJ mol_1 ΔGf in kJ mol_1 Cp,m in J K_1 mol_1
    C(graphite) 0 0 8.53
    HCO3
    _
    (aq) _689.9 _586.8
    H2(g) 0 0 28.82
    H+
    (aq) 0
    H2O(l) _285.83 _237.14 75.4
    H2O(g) _241.83 _228.61 33.58
    Ni(OH)2(s) _444
    O2(g) 0 0 29.35
    O3(g) 142.67 163.19 39.22
    OH_
    (aq) _230.02 _157.22
    Table 1.10 Important formulae and equations
    Thermodynamics
    p_1
    V
    Boyle’s law
    The pressure exerted by an ideal gas is inversely
    proportional to the volume it occupies if the
    temperature and amount of gas remain unchanged
    within a closed system.
    V _ T Charles’ law
    Gases tend to expand when heated; at constant
    pressure, the volume is directly proportional to the
    temperature.
    p _ T Gay-Lussac’s law
    If mass and volume of a gas are held constant, the
    pressure exerted by the gas increases directly
    proportional to the temperature.

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