HS Evap Klean Ace-CCC

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SAFETY DATA SHEET

Issue Date 01-Jun-2012 Revision Date 26-Feb-2015 Version 1

1. IDENTIFICATION

Product Identifier
Product Name ACE EVAP-KLEEN

Other means of identification


SDS # CCL

UN/ID No Not Regulated


Other Information Package type: 32oz., 1, 2.5, 5, 55 gal.

Recommended use of the chemical and restrictions on use


Recommended Use Cleaning aluminum finned cooling and heating coils.
Restrictions on Use For professional use only. Product is a concentrate and should be diluted prior to use.

Details of the supplier of the safety data sheet


Manufacturer Address
Atlantic Chemical & Equipment Company
3471 Atlanta Industrial Parkway
Suite 200
Atlanta, GA 30331

Emergency telephone number


Company Phone Number 404-505-6626
1-800-929-2436
Emergency Telephone Chemtrec 1-800-424-9300

2. HAZARDS IDENTIFICATION

Classification

Skin corrosion/irritation Category 1 Sub-category B


Serious eye damage/eye irritation Category 1

Signal word
Danger

Hazard statements
Causes skin burns and eye damage

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CCL - ACE EVAP-KLEEN Revision Date 26-Feb-2015

Appearance Clear green Physical state Liquid Odor Bland

Precautionary Statements - Prevention


Do not breathe dust/fume/gas/mist/vapors/spray
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection

Precautionary Statements - Response


Immediately call a POISON CENTER or doctor/physician
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor/physician
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Immediately call a POISON CENTER or doctor/physician
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting

Precautionary Statements - Storage


Store locked up
Keep containers tightly closed in a dry, cool and well-ventilated place

Precautionary Statements - Disposal


Dispose of in accordance with federal, state and local regulations

Hazards not otherwise classified (HNOC)


Not Applicable
Other Information
Not Applicable

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight


Sodium metasilicate pentahydrate 10213-79-3 <13
2-Butoxyenthanol 111-76-2 <18
Monoethanolamine 141-43-5 <12
EDTA 143-19-1 <9
Sodium hydroxide 1310-73-2 <7

4. FIRST AID MEASURES

First aid measures

General advice Provide this SDS to medical personnel for treatment.

Inhalation Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical
attention immediately.

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CCL - ACE EVAP-KLEEN Revision Date 26-Feb-2015

Eye contact Immediately flush with plenty of water for up to 15 minutes. Immediate medical attention is
required.

Ingestion Drink plenty of water. Do NOT induce vomiting. If vomiting occurs naturally, have victim
lean forward to reduce risk of aspiration. Seek medical attention immediately.

Skin Contact Neutralize with very diluted vinegar solution, wash with soap and water, apply skin cream.
For large burns - GET IMMEDIATE MEDICAL ATTENTION.

Most important symptoms and effects, both acute and delayed

Symptoms Inhalation may cause irritation to nasal passages. Severe burns to exposed skin. Inhalation of
fumes or acid mist can cause irritation or corrosive burns to the upper respiratory system,
including nose, mouth and throat.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media


Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media Not determined.

Specific hazards arising from the chemical


Avoid mixing with acids and soft metals.

Protective equipment and precautions for firefighters


As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Wear impervious to strong alkaline protective clothing.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Use personal protective equipment as required. Wash thoroughly after handling.

Environmental precautions See Section 12 for additional ecological information.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so. Neutralize with water and vinegar.

Methods for cleaning up For small spills: wash to drain after product is neutralized. Contain and collect spillage with
non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and place in container for disposal according to local / national regulations (see Section 13).

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Do not breathe
dust/fume/gas/mist/vapors/spray. Avoid contact with skin, eyes or clothing. Wash face,
hands and any exposed skin thoroughly after handling. Avoid mixing with acids and soft
metals. Use personal protection recommended in Section 8.

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CCL - ACE EVAP-KLEEN Revision Date 26-Feb-2015

Conditions for safe storage, including any incompatibilities

Storage Conditions Store locked up. Keep container tightly closed in a dry and well-ventilated place.

Incompatible materials Acids.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Sodium metasilicate - - -
pentahydrate 10213-79-3
2-Butoxyethanol TWA: 20 ppm TWA: 50 ppm TWA: 240 mg/m3 IDLH: 700 ppm
111-76-2 (vacated) TWA: 25 ppm (vacated) TWA: 5 ppm TWA: 24 mg/m3
TWA: 120 mg/m3
(vacated) S*
S*
Monoethanolamine STEL: 6 ppm TWA: 3 ppm TWA: 6 IDLH: 30 ppm
141-43-5 TWA: 3 ppm mg/m3 (vacated) TWA: TWA: 3 ppm
3 ppm TWA: 8 mg/m3
(vacated) TWA: 8 mg/m3 STEL: 6 ppm
(vacated) STEL: 6 ppm STEL: 15 mg/m3
(vacated) STEL: 15 mg/m3
Sodium hydroxide Ceiling: 2 mg/m3 TWA: 2 mg/m3 IDLH: 10 mg/m3
1310-73-2 (vacated) Ceiling: 2 mg/m3 Ceiling: 2 mg/m3
Appropriate engineering controls

Engineering Controls If vapors are detected, ventilate work area by opening windows and using exhaust fans.
Always work with wind from behind.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear goggles or chemical safety glasses.

Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls,
as appropriate, to prevent skin contact. Wear protective Neoprene™ gloves.

Respiratory protection Ensure adequate ventilation, especially in confined areas.

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state Liquid


Appearance Clear green Odor Herbal

Color Clear green Odor threshold Not determined

Property Values Remarks • Method


pH 13.0
Melting point/freezing point Not determined
Boiling point/boiling range Not determined
Flash point Not determined
Evaporation rate Not determined
Flammability (solid, gas) Not determined
Flammability Limits in Air
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CCL - ACE EVAP-KLEEN Revision Date 26-Feb-2015

Upper flammability limits Not determined


Lower flammability limit Not determined

Vapor pressure Not determined


Vapor density Not determined
Specific Gravity 1.062
Water solubility Not determined

Solubility in other solvents Not determined


Partition coefficient Not determined
Autoignition temperature Not determined
Decomposition temperature Not determined
Kinematic viscosity Not determined
Dynamic viscosity Not determined
Explosive properties Not determined

Oxidizing properties Not determined

Other Information

10. STABILITY AND REACTIVITY

Reactivity
Not reactive under normal conditions

Chemical stability
Stable under recommended storage conditions.

Possibility of Hazardous Reactions


None under normal processing.

Hazardous polymerization Hazardous polymerization does not occur.

Conditions to avoid
Incompatible materials. Keep out of reach of children.

Incompatible materials
Acids.

Hazardous Decomposition Products


Thermal decomposition can lead to release of irritating and toxic gases and vapors.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Inhalation May cause irritation to the mucous membranes and upper respiratory tract.

Eye contact Causes severe eye damage.

Skin Contact Causes severe skin burns.

Ingestion May cause gastrointestinal irritation, nausea, diarrhea, and vomiting.

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CCL - ACE EVAP-KLEEN Revision Date 26-Feb-2015

Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

Water > 90 mL/kg ( Rat ) - -


7732-18-5
Sodium metasilicate pentahydrate = 847 mg/kg ( Rat ) - -
10213-79-3
2-Butoxyethanol = 470 mg/kg ( Rat ) = 220 mg/kg ( Rabbit ) 2270 mg/kg = 2.21 mg/L ( Rat ) 4 h 450 ppm
111-76-2 ( Rat ) ( Rat ) 4 h
Monoethanolamine = 1720 mg/kg ( Rat ) = 1 mL/kg ( Rabbit ) = 1025 mg/kg -
141-43-5 ( Rabbit )
Sodium hydroxide - = 1350 mg/kg ( Rabbit ) -
1310-73-2
Information on physical, chemical and toxicological effects

Symptoms Please see section 4 of this SDS for symptoms.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA,
IARC or NTP.

Chemical Name ACGIH IARC NTP OSHA


2-Butoxyethanol A3 Group 3
111-76-2

Numerical measures of toxicity- Product


Not determined

The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 5498 mg/kg
ATEmix (dermal) 5099 mg/kg
ATEmix (inhalation-gas) 663769 mg/l
ATEmix (inhalation-dust/mist) 26.1 mg/l

12. ECOLOGICAL INFORMATION

Ecotoxicity

Harmful to aquatic life Harmful to aquatic life with long lasting effects

Chemical Name Algae/aquatic plants Fish Toxicity to Crustacea


microorganisms
2-Butoxyethanol 1490: 96 h Lepomis 1698 - 1940: 24 h Daphnia
111-76-2 macrochirus mg/L LC50 magna mg/L EC50 >1000:
static 2950: 96 h Lepomis 48 h Daphnia magna mg/L
macrochirus mg/L LC50 EC50
Monoethanolamine 15: 72 h Desmodesmus 227: 96 h Pimephales 65: 48 h Daphnia magna
141-43-5 subspicatus mg/L EC50 promelas mg/L LC50 mg/L EC50
flow-through 3684: 96 h
Brachydanio rerio mg/L
LC50 static 300 - 1000: 96 h
Lepomis macrochirus mg/L
LC50 static 114 - 196: 96 h
Oncorhynchus mykiss mg/L
LC50 static 200: 96 h
Oncorhynchus mykiss mg/L
LC50 flow-through
Sodium hydroxide 45.4: 96 h Oncorhynchus
1310-73-2 mykiss mg/L LC50 static

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CCL - ACE EVAP-KLEEN Revision Date 26-Feb-2015

Persistence and degradability


Not determined.

Bioaccumulation
Not determined.

Mobility
Not determined.

Chemical Name Partition coefficient


2-Butoxyethanol 0.81
111-76-2
Monoethanolamine -1.91
141-43-5

Other adverse effects Not determined

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.

Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and
regulations.

14. TRANSPORT INFORMATION

DOT
UN/ID No Not Regulated
Proper shipping name

Hazard Class
Packing Group

IATA
UN/ID No Not Regulated
Proper shipping name
Hazard Class
Packing Group

IMDG
UN/ID No Not Regulated
Proper shipping name
Hazard Class
Packing Group

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CCL - ACE EVAP-KLEEN Revision Date 26-Feb-2015

15. REGULATORY
International Inventories
Legend:
TSCA- United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances IECSC
- China Inventory of Existing Chemical Substances KECL -
Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances

US Federal Regulations

Chemical Name CAS No Weight-% SARA 313 - Threshold


Values %
2-Butoxyethanol - 111-76-2 111-76-2 <18 1.0

SARA 311/312 Hazard Categories


Acute health hazard Yes
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No

US State Regulations

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania


2-Butoxyethanol X X X
111-76-2
Monoethanolamine X X X
141-43-5
Sodium hydroxide X X X
1310-73-2

U.S. EPA Label Information

16. OTHER INFORMATION

NFPA Health hazards Flammability Instability Special Hazards Not


Not determined Not determined Not determined determined
HMIS Health hazards Flammability Physical hazards Personal protection
3 0 1 X

Issue Date 01-Jun-2012


Revision Date 26-Feb-2015
Revision Note
new format
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

End of Safety Data Sheet

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