Sulphuric Acid (98% Solution)

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

1.1 Product identifier
Product name SULPHURIC ACID (98% SOLUTION)
Synonyms DIPPING ACID ● OIL OF VITRIOL ● SULFURIC ACID ● SULFURIC ACID (98% SOLUTION) ● SULPHURIC
ACID (98% SOLUTION)

1.2 Uses and uses advised against

Uses EXPLOSIVE MANUFACTURE ● FERTILISER ● LABORATORY APPLICATIONS ● LABORATORY
REAGENT ● MANUFACTURE OF CHEMICALS ● PICKLING AND ANODISING METALS ● TEXTILE
CHEMICAL ● WATER TREATMENT

1.3 Details of the supplier of the product

Supplier name CSBP LIMITED
Address Kwinana Beach Road, Kwinana, WA, 6167, AUSTRALIA
Telephone (08) 9411 8777
Fax (08) 9411 8425
Website http://www.csbp.com.au

1.4 Emergency telephone numbers

Emergency 1800 09 3333 (Australia); +61 8 9411 8444

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
Physical Hazards
Not classified as a Physical Hazard

Health Hazards
Skin Corrosion/Irritation: Category 1A

Environmental Hazards
Not classified as an Environmental Hazard

2.2 GHS Label elements

Signal word DANGER
Pictograms

Hazard statements
H314 Causes severe skin burns and eye damage.
Prevention statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

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Response statements
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P321 Specific treatment is advised - see first aid instructions.
P363 Wash contaminated clothing before reuse.
Storage statements
P405 Store locked up.
Disposal statements
P501 Dispose of contents/container in accordance with relevant regulations.

2.3 Other hazards

No information provided.

3. COMPOSITION/ INFORMATION ON INGREDIENTS

3.1 Substances / Mixtures
Ingredient CAS Number EC Number Content
SULPHURIC ACID 7664-93-9 231-639-5 98%
WATER 7732-18-5 231-791-2 Remainder

4. FIRST AID MEASURES

4.1 Description of first aid measures
Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to
stop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Full-face Type B (Inorganic and acid
gas) respirator or an Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If
swallowed, do not induce vomiting.
First aid facilities Eye wash facilities and safety shower should be available.

4.2 Most important symptoms and effects, both acute and delayed
Over exposure may result in severe skin, eye and respiratory burns with permanent lung and tissue damage. Strong inorganic acid
mists containing sulphuric acid is classified as carcinogenic to humans (IARC Group 1).

4.3 Immediate medical attention and special treatment needed

CORROSIVE POISONING TREATMENT: Immediate treatment preferably in a hospital is mandatory. In treating corrosive poisoning,
DO NOT INDUCE VOMITING; DO NOT ATTEMPT GASTRIC LAVAGE; and DO NOT ATTEMPT TO NEUTRALISE THE CORROSIVE
SUBSTANCE. Vomiting will increase the severity of damage to the oesophagus as the corrosive substance will again come in contact
with it. Attempting gastric lavage may result in perforating either the oesophagus or stomach. Immediately dilute the corrosive
substance by having the patient drink milk or water. If the trachea has been damaged tracheostamy may be required. For
oesophageal burns begin broad-spectrum antibiotics and corticosteroid therapy. Intravenous fluids will be required if oesophageal or
gastric damage prevents ingestion of liquids. Long-range therapy will be directed toward preventing or treating oesophageal scars and
strictures.

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
Use an extinguishing agent suitable for the surrounding fire.

5.2 Special hazards arising from the substance or mixture

Non flammable. May evolve toxic gases (sulphur oxides) when heated to decomposition. May evolve flammable hydrogen gas in
contact with some metals.

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5.3 Advice for firefighters

Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those
downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use
waterfog to cool intact containers and nearby storage areas.

5.4 Hazchem code

2P
2 Fine Water Spray.
P Risk of violent reaction or explosion. Wear liquid-tight chemical protective clothing and breathing apparatus. Dilute spill and
run-off.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilate
area where possible. Contact emergency services where appropriate.

6.2 Environmental precautions

Prevent product from entering drains and waterways.

6.3 Methods of cleaning up

Contain spillage, then cover / absorb spill with sodium bicarbonate or 50-50 mixture of sodium carbonate and calcium hydroxide.
Collect for complete neutralisation and appropriate disposal.

6.4 Reference to other sections

See Sections 8 and 13 for exposure controls and disposal.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.
Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.

7.2 Conditions for safe storage, including any incompatibilities

Store in a secured, cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs.
Ensure containers are adequately labelled and protected from physical damage when not in use. Check regularly for leaks or spills.
Large storage areas should have appropriate ventilation and fire protection systems. This product should be stored in mild steel
containers that conform to AS3780 or API-650.

7.3 Specific end uses

No information provided.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters
Exposure standards
TWA STEL
Ingredient Reference
ppm mg/m³ ppm mg/m³
Sulphuric acid SWA [AUS] -- 1 -- 3

Biological limits
No biological limit values have been entered for this product.

8.2 Exposure controls

Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction
ventilation is recommended. Maintain vapour/gas levels below the recommended exposure standard.

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PPE
Eye / Face Wear splash-proof goggles. When using large quantities or where heavy contamination is likely, wear a
faceshield.
Hands Wear PVC or rubber gloves.
Body Wear coveralls. When using large quantities or where heavy contamination is likely, wear rubber boots and
a PVC apron. In a laboratory situation, wear a laboratory coat.
Respiratory Where an inhalation risk exists, wear a Type B-Class P2 (Inorganic gases/vapors and Particulate) respirator.
If spraying, with prolonged use, or if in confined areas, wear an Air-line respirator.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
Appearance VISCOUS CLEAR TO BROWN LIQUID
Odour SLIGHT ODOUR
Flammability NON FLAMMABLE
Flash point NOT RELEVANT
Boiling point 335°C
Melting point 10°C
Evaporation rate NOT AVAILABLE
pH < 1 (10% solution)
Vapour density 3.4 (Air = 1)
Specific gravity 1.84
Solubility (water) SOLUBLE
Vapour pressure 0.011 kPa @ 25°C (Approximately)
Upper explosion limit NOT RELEVANT
Lower explosion limit NOT RELEVANT
Partition coefficient NOT AVAILABLE
Autoignition temperature NOT AVAILABLE
Decomposition temperature NOT AVAILABLE
Viscosity 24 mPa·s @ 20°C
Explosive properties NOT AVAILABLE
Oxidising properties NOT AVAILABLE
Odour threshold NOT AVAILABLE
9.2 Other information
Density 1.84 t/m³ @ 20°C (Bulk)

10. STABILITY AND REACTIVITY

10.1 Reactivity
May be corrosive to metals.

10.2 Chemical stability

Potential for exothermic hazard.

10.3 Possibility of hazardous reactions

Polymerization is not expected to occur.

10.4 Conditions to avoid

Avoid contact with incompatible substances.

10.5 Incompatible materials

Incompatible with oxidising agents (e.g. hypochlorites), alkalis (e.g. sodium hydroxide) and some metals. Incompatible with cyanides,
sulphides and carbides and amines.

10.6 Hazardous decomposition products

May evolve toxic gases (sulphur oxides) when heated to decomposition.

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11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute toxicity An acute oral toxicity study indicates an LD50 for sulphuric acid of 2140 mg/kg (rat). Toxic signs of oral
exposure in human are of irritation/corrosion of the gastrointestinal tract.
Information available for the ingredients:

Oral LD50 Dermal LD50 Inhalation LC50

Ingredient

SULPHURIC ACID 2140 mg/kg (rat) -- 18 mg/m³ (guinea pig);

510 mg/m3/2hrs (rat)
Skin Causes severe burns. Contact may result in irritation, redness, pain, rash, dermatitis and severe burns.
Eye Causes severe burns. Contact may result in irritation, lacrimation, pain, redness and corneal burns with
possible permanent eye damage.
Sensitisation Not classified as causing skin or respiratory sensitisation.
Mutagenicity Insufficient data available to classify as a mutagen.
Carcinogenicity Occupational exposure to strong inorganic acid mists containing sulphuric acid is classified as carcinogenic
to humans (IARC Group 1).
Reproductive Insufficient data available to classify as a reproductive toxin.
STOT - single Over exposure may result in mucous membrane irritation of the respiratory tract, coughing, bronchitis,
exposure ulceration, bloody nose, lung tissue damage and deterioration of pulmonary function.
STOT - repeated Not classified as causing organ damage from repeated exposure. Adverse effects are generally associated
exposure with single exposure.
Aspiration Not expected to present an aspiration hazard.

12. ECOLOGICAL INFORMATION

12.1 Toxicity
Sulphuric acid is harmful to aquatic life in very low concentrations. May cause corrosion and deterioration of many common materials
found in the environment (eg steel, limestone).

12.2 Persistence and degradability

Sulfuric acid is a strong mineral acid that dissociates readily in water to sulfate ions and hydrated protons, and is totally miscible with
water.

12.3 Bioaccumulative potential

Sulphuric acid is not anticipated to accumulate in living tissues.

12.4 Mobility in soil

Sulphuric acid is miscible with water and its dilution will increase the velocity of downward movement in the soil where it may dissolve
the soil material.

12.5 Other adverse effects

Avoid contaminating waterways.

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Waste disposal For small amounts (as determined by risk assessment or similar): Wearing the protective equipment detailed
above, neutralise to pH 6-8 by SLOW addition to a saturated sodium bicarbonate solution or similar basic
solution. Dilute with excess water and flush to drain. Waste disposal should only be undertaken in a well
ventilated area. For larger amounts: Dispose in accordance with local regulations.
Legislation Dispose of in accordance with relevant local legislation.

14. TRANSPORT INFORMATION

CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

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LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)

14.1 UN Number 1830 1830 1830

14.2 Proper SULFURIC ACID with more than SULFURIC ACID with more than SULFURIC ACID with more than
Shipping Name 51% acid 51% acid 51% acid

14.3 Transport 8 8 8
hazard class
14.4 Packing Group II II II
14.5 Environmental hazards
No information provided.
14.6 Special precautions for user
Hazchem code 2P
GTEPG 8A1
EmS F-A, S-B

15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule Classified as a Schedule 6 (S6) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).
Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and
Labelling of Chemicals.
Inventory listings AUSTRALIA: AICS (Australian Inventory of Chemical Substances)
All components are listed on AICS, or are exempt.

16. OTHER INFORMATION

Additional information ACIDS: When mixing acids with water (diluting), caution must be taken as heat will be generated
which causes violent spattering. Always add a small volume of acid to a large volume of water,
NEVER the reverse.

RESPIRATORS: In general the use of respirators should be limited and engineering controls
employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator
selection and training is undertaken. Remember that some respirators may be extremely
uncomfortable when used for long periods. The use of air powered or air supplied respirators should
be considered where prolonged or repeated use is necessary.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:

The recommendation for protective equipment contained within this report is provided as a guide
only. Factors such as form of product, method of application, working environment, quantity used,
product concentration and the availability of engineering controls should be considered before final
selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:

It should be noted that the effects from exposure to this product will depend on several factors
including: form of product; frequency and duration of use; quantity used; effectiveness of control
measures; protective equipment used and method of application. Given that it is impractical to
prepare a report which would encompass all possible scenarios, it is anticipated that users will
assess the risks and apply control methods where appropriate.

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Abbreviations ACGIH American Conference of Governmental Industrial Hygienists

CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds
CNS Central Nervous System
EC No. EC No - European Community Number
EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)
GHS Globally Harmonized System
GTEPG Group Text Emergency Procedure Guide
IARC International Agency for Research on Cancer
LC50 Lethal Concentration, 50% / Median Lethal Concentration
LD50 Lethal Dose, 50% / Median Lethal Dose
mg/m³ Milligrams per Cubic Metre
OEL Occupational Exposure Limit
pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).
ppm Parts Per Million
STEL Short-Term Exposure Limit
STOT-RE Specific target organ toxicity (repeated exposure)
STOT-SE Specific target organ toxicity (single exposure)
SUSMP Standard for the Uniform Scheduling of Medicines and Poisons
SWA Safe Work Australia
TLV Threshold Limit Value
TWA Time Weighted Average

Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the
product and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by the
manufacturer, importer or supplier or obtained from third party sources and is believed to represent
the current state of knowledge as to the appropriate safety and handling precautions for the product
at the time of issue. Further clarification regarding any aspect of the product should be obtained
directly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does
not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts
no liability for any loss, injury or damage (including consequential loss) which may be suffered or
incurred by any person as a consequence of their reliance on the information contained in this SDS.

Prepared by Risk Management Technologies

5 Ventnor Ave, West Perth
Western Australia 6005
Phone: +61 8 9322 1711
Fax: +61 8 9322 1794
Email: [email protected]
Web: www.rmtglobal.com

[ End of SDS ]

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