Safety Data Sheet

30% OPP SMOKE GENERATOR

SECTION 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND COMPANY OR

UNDERTAKING
Product Identifier
1.1. Tradename: FUMITE OPP SMOKE GENERATOR

Contains 2-phenylphenol and Potassium chlorate

UFI: 4M60-U0UE-W00R-A223

1.2. Relevant identified uses of Disinfectant Smoke Generator (FU)

the substance or mixture and
uses advised against

1.3. Details of the supplier of the safety data sheet

Company Octavius Hunt Ltd
Redfield, BRISTOL, BS5 9NQ, UK
Phone +44 (0) 117 955 5305
Fax +44 (0) 117 955 7875
Website www.octaviushunt.co.uk
Email [email protected]

1.4. Emergency + 44 (0) 7720 051020 (24h)

telephone
number

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

- Classification (Regulation (EC) No 1272/2008) [CLP/GHS]: Skin Irrit.. 2. H315; Eye Irrit..
2A H319, STOT Resp. 3. H335; Aquatic Chronic 1, H410
- Additional Information: For full text of Hazard and EU Hazard-statements: see section 16
2.2 Label elements

Signal word: Warning

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 SECTION 2: HAZARDS IDENTIFICATION (....)

Hazard statements

H315 Causes skin irritation.

H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H410 Very Toxic to aquatic life with long lasting effects.

Precautionary statements

P261 Avoid breathing dust / smoke

P264 Wash skin thoroughly after handling
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P501 Dispose of contents/container to a licensed hazardous-waste disposal contractor
or collection site except for empty clean containers which can be disposed of as
nonhazardous waste.

Supplemental Hazard Information (EU)

- None

2.3 Other hazards

- Ignites readily. Product burns without a flame to give a dense white smoke.
- This product contains <1% respirable silica
- Not a PBT according to Reach Annex XIII
- Not a vPvB according to Reach Annex XIII

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1. Substances: N.A.

3.2. Mixture

Contains the following hazardous ingredients or ingredients with a workplace

exposure limit
Chemical Conc. CAS No. EC No. Classification REACH WEL/O
Name according to Registration EL
Regulation (EC) No Number
1278/2008 (CLP).
2- 30.0% 90-43-7 201-993-5 Skin Irrit.. 2. H315 01- No
phenylphenol w/w Eye Irrit.. 2A H319 2119511183-
(ISO) STOT Resp. 3. H335 53-0000
Aquatic Acute 1. H400
Aquatic Chronic 1,
H410
Potassium 10 -20% 3811-04-9 223-289-7 Ox. Liq. H271; 01- No
chlorate w/w Acute Tox. H302; 2119494917-
Acute Tox 4 H332; 18-xxxx
Aquatic Chronic 2,
H411

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SECTION 4: FIRST AID MEASURES

Rescuers should take suitable precautions to avoid becoming casualties themselves

4.1 Description of First Aid Measures General Advice:
Show this safety data sheet to the doctor in attendance
Contact with eyes:
If substance has got into eyes, immediately wash out with plenty of water for several
minutes. Irrigate eyes thoroughly whilst lifting eyelids.
Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention
Contact with skin:
Take off contaminated clothing and wash it before reuse.
Wash affected area with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention
Inhalation:
If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable
for breathing.
If unconscious, place person in recovery position
Apply artificial respiration only if patient is not breathing but do not use mouth to mouth
resuscitation. Get immediate medical advice/attention.
Ingestion:
Rinse mouth with water (do not swallow).
Give 200-300mls (half pint) water to drink.
Do NOT induce vomiting. Get medical advice/attention.
4.2. Most important symptoms and effects, both acute and delayed
Contact with eyes
- May cause skin irritation.
Contact with skin
- May cause redness and irritation.
Ingestion
- May cause stomach pain.
- May cause nausea/vomiting.
Inhalation
- May cause shortness of breath.
- May cause coughing and tightness of chest.
- Prolonged and/or massive inhalation of respirable crystalline silica dust may cause lung
fibrosis, commonly referred to as silicosis. Principal symptoms of silicosis are cough and
breathlessness
4.3. Immediate Medical Attention
Risk of methemoglobinemia. Not to be treated with methylthionine. - Treat symptomatically.

SECTION 5: FIRE FIGHTING MEASURES

5.1. Extinguishing media:

Suitable extinguishing media:
Sand/earth; foam; water spray; carbon dioxide.
- Unsuitable extinguishing media:
Do not use water jets; Dry agent extinguishers are unsuitable and should not be used.
5.2. Special Hazards arising from the mixture:
- Ignites readily.
- Contains an oxidising agent; may assist combustion.
- May form explosive dust/air mixtures.
- Gives off irritating fumes (or gases) in a fire.
- Decomposition products may include oxygen, carbon oxides, nitrogen oxides.
5.3. Advice for fire-fighters:
- Collect contaminated fire extinguishing water separately. This MUST not be discharged into
drains. Prevent fire extinguishing water from contaminating surface or ground water.
- Special protective equipment: Wear self-contained breathing apparatus (SCBA). Wear full
protective clothing including chemical protection suit.

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SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures:

- No action shall be taken involving any personal risk or without suitable training.
- Only trained and authorised personnel should carry out emergency response.
- Avoid formation of dust.
- Shut off all ignition sources
- Personal precautions for non-emergency personnel: Avoid breathing dust/fume/gas/mist/
vapours/spray;
Avoid contact with skin and eyes;
Wear protective clothing as per section 8; Wash thoroughly after handling; Eyewash bottles should
be available.
- Personal precautions for emergency responders: Evacuate the area and keep personnel upwind;
Wear chemical protection suit; Wear self-contained breathing apparatus (SCBA).
6.2. Environmental precautions:
- Avoid release to the environment.
- Do not allow to enter public sewers and watercourses.
- If contamination of drainage systems or water courses is unavoidable, immediately inform
appropriate authorities.
6.3. Methods and material for containment and cleaning up:
- Do not absorb spillage in sawdust or other combustible material.
- Avoid formation of dust.
- Shut off all ignition sources.
- Take action to prevent static discharges.
- Do not allow to enter public sewers and watercourses.
- Small spills Wipe up spillage with damp absorbent cloth or towel.
Wash spill site with water and detergent.
- Large spills Evacuate the area and keep personnel upwind.
Damp down to avoid dust generation.
Absorb spillage in earth or sand.
Sweep or shovel-up spillage and remove to a safe place.
Place in appropriate container.
Seal containers and label them.
Remove contaminated material to safe location for subsequent disposal.
Ventilate the area and wash spill site after material pick-up is complete.

6.4. Reference to other sections:

- See section(s): 7, 8 & 13

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SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

- Read the label before use.
- Prevent formation of dust.
- Take precautionary measures against static discharges.
- Ensure adequate ventilation.
- In case of inadequate ventilation wear respiratory protection.
- Avoid contact with skin and eyes.
- Do not eat, drink or smoke when using this product.
- Keep away from heat and sources of ignition.
- Avoid contact with acids and alkalis.
- Avoid release to the environment.
- Take off contaminated clothing.
- Contaminated work clothing should not be allowed out of the workplace.
- Contaminated clothing should be laundered before reuse.
– Eyewash bottles should be available.
7.2. Conditions for storage, including any incompatibilities
- Shelf life: 2 years when stored in the original unopened sales container at ambient temperatures.
- Store in a cool, dry well-ventilated place. Keep container tightly closed.
- Keep away from combustible material.
- Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
- Keep out of reach of children.
7.3. Specific end use
A Disinfectant Smoke Generator.

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SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. Control parameters

- For currently recommended monitoring procedures, see HSE series ‘Methods for the
Determination of Hazardous Substances’ (MDHS).
- Occupational exposure to respirable crystalline silica dust should be monitored and controlled.

- 2-phenylphenol (ISO)
No information available

- Potassium chlorate
DNEL (inhalational) 5.76 mg/m3 Industry, Long Term, Systemic Effects
DNEL (dermal) 3.5 mg/kg (bw/day) Industry, Long Term, Systemic Effects
DNEL (inhalational) 300 ug/m3 Consumer, Long Term, Systemic Effects
DNEL (dermal) 130 ug/kg (bw/day) Consumer, Long Term, Systemic Effects
DNEL (oral) 60 ug/kg (bw/day) Consumer, Long Term, Systemic Effects PNEC aqua (freshwater)
1.15 mg/l PNEC aqua (marine water) 1.15 mg/l PNEC (STP) 115 mg/l PNEC terrestrial (soil) 3.83
mg/kg

8.2. Exposure controls

- Selection and use of personal protective equipment should be based on a risk assessment of
exposure potential.
- Respiratory protection
In case of insufficient ventilation, wear suitable respiratory equipment.
Where a reusable half mask respirator is required, use EN 140, with gas/vapour filter EN 14387
type ABEK, or EN 405; EN 1827 and EN 143 particle filter.
Where a full face mask respirator is required, use EN 136, with gas/vapour filter EN 14387 type
ABEK and particle filter EN 143.
- Skin protection
Wear suitable protective clothing.
Wear protective gloves. The selected protective gloves have to satisfy the specifications of EU
Directive 89/686/EEC and standard EN 374. The selection of a suitable glove depends on work
conditions and whether the product is present on its own or in combination with other substances.
Breakthrough time is dependent on the characteristics of the brand of glove used and the supplier
should be consulted. PVC or rubber gloves are recommended.
- Eye/face protection
Wear goggles giving complete eye protection approved to standard EN 166.
- Hygiene measures
Contaminated clothing should be laundered before reuse.
Do not eat, drink or smoke when using this product.
Eyewash bottles should be available.
- Environmental exposure controls
Avoid release to the environment.
Do not empty into drains
A self-contained product unlikely to be released unless packaging significantly damaged.

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Colour: Off-white.
Physical State: Powder in a metallic tin.
Odour: Phenolic.
Melting Point: Not applicable.
Boiling point: Not applicable.
Flash-Point: Does not flash.
Autoignition temperature 335oC
Minimum Ignition temp. Not available.
Minimum Ignition: Not available
Oxidizing properties: Contains an oxidising agent; may assist
combustion.
Energy Explosive properties Not applicable
Vapour pressure: Not available.
Solubility: Partly soluble in/with water.
pH-value (quant.): Not available.
Partition coeff. (n-octanol/water): Not available.
Density: Not available.

9.2 Other Information:

- No information available

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity
- No hazardous reactions known if used for its intended purpose
10.2 Chemical stability
- Considered stable under normal conditions.
10.3 Possibility of hazardous reactions
- Reacts with combustible material.
- Reacts with acids liberating toxic gas (chlorine).
10.4 Conditions to avoid
- Avoid formation of dust.
- Keep away from heat and sources of ignition.
- Keep away from static electricity.
10.5 Incompatible materials
- Incompatible with strong acids.
- Incompatible with alkalis (strong bases).
- Incompatible with halogenated substances.
10.6 Hazardous decomposition products
- Decomposition products may include oxygen, carbon oxides, nitrogen oxides.

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SECTION 11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects

Chemical name LD50 (oral, rat) LC50 (inhalation, rat) LD50 (dermal, rabbit)
- 2-phenylphenol 2733 mg/kg >0.036 mg/l >5000 mg/kg
Potassium chlorate 500 mg/kg 5 mg/l (4 hr) NS

- Skin corrosion/irritation
Causes skin irritation.
Classification based on calculation and concentration thresholds.

- Serious eye damage/irritation

Causes serious eye irritation.
Classification based on calculation and concentration thresholds.

- Respiratory or skin sensitisation

Based on available data, the classification criteria are not met.

- Germ cell mutagenicity Based on available data, the classification criteria are not met.

- Carcinogenicity Based on available data, the classification criteria are not met.

- Reproductive toxicity
Based on available data, the classification criteria are not met.

- Specific target organ toxicity (STOT) - single exposure

May cause respiratory irritation
Classification based on calculation and concentration thresholds.

- Specific target organ toxicity (STOT) - repeated exposure

Based on available data, the classification criteria are not met.

- Aspiration hazard
Based on available data, the classification criteria are not met.

- Contact with eyes

May cause severe eye irritation.

- Contact with skin

May cause redness and irritation.

- Ingestion Can form methaemoglobin in the blood, causing cyanosis

May cause stomach pain.
May cause nausea/vomiting.

- Inhalation Causes shortness of breath.

May cause coughing and tightness of chest.
Prolonged and/or massive inhalation of respirable crystalline silica dust may cause lung fibrosis,
commonly referred to as silicosis. Principal symptoms of silicosis are cough and breathlessness.

SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bio accumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
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 No data available
12.6 Other adverse effects
Toxic to aquatic life with long lasting effects.
No further data available

SECTION 13. DISPOSAL CONSIDERATIONS

13.1. WASTE TREATMENT METHODS

- Do not discharge into drains or the environment, dispose to an authorised waste collection point
- Dispose of product and packaging in accordance with national waste regulations.
- This material and/or its container must be disposed of as hazardous waste.
13.2 Classification
- The waste must be identified according to the List of Wastes (2000/532/EC).
- Hazardous Property Code(s): HP 4 Irritant; HP 5 Harmful; HP 14 Ecotoxic

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SECTION 14. TRANSPORT INFORMATION
Not classified as hazardous for transport
14.1 UN number
- UN No.: 3077
14.2 UN proper shipping name
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., (2-PHENYLPHENOL
MIXTURE).
14.3 Transport hazard class(es)
- Class 9
14.4 Packing group
- III
14.5 Environmental hazards
- H411
14.6 Special precautions for user
- Not Classified
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
- Not applicable
14.8 Road/Rail (ADR/RID)
- Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., (2-
PHENYLPHENOL MIXTURE).
- ADR UN No.: 3077
- ADR Hazard Class: 9
- ADR Packing Group: III
- Tunnel Code: Not applicable
14.9 Sea (IMDG)
- Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., (2-
PHENYLPHENOL MIXTURE).
- IMDG UN No.: 3077
- IMDG Hazard Class: 9
- IMDG Pack Group.: III
14.10 Air (ICAO/IATA)
- Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., (2-
PHENYLPHENOL MIXTURE).
- ICAO UN No.: 3077
- ICAO Hazard Class: 9
– ICAO Packing Group: III

SECTION 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
- This safety data sheet is provided in compliance with REACH Regulation (EC) No 1907/2006 as
amended by Regulation (EU) 2015/830.
- Regulation (EC) No. 1272/2008 on the classification, labelling and packaging of substances and
mixtures (CLP Regulation) applies in Europe.
- The COSHH Regulations apply in the UK.
15.2 Chemical safety assessment
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

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SECTION 16. OTHER INFORMATION

Information contained in this data sheet is accurate to the best of our knowledge and belief and is
given in good faith. It is intended to describe our product from the point of view of safety
requirements and is not intended to guarantee any particular properties.
Sources of data: Information from published literature and supplier safety data sheets

Revision No. 6.1. Revised March 2020.

Changes made: Revised to add in H332 to potassium chlorate in table 3.2

Classification and procedure used to derive the classification for mixtures according to Regulation
(EC) 1272/2008 [CLP]:
Skin Irrit.. 2. H315 Classification based on calculation and concentration thresholds
Eye Irrit.. 2A H319 Classification based on calculation and concentration thresholds
STOT Resp. 3. H335 Classification based on calculation and concentration thresholds
Aquatic Chronic 1, H410 Classification based on calculation and concentration thresholds

Text not given with phrase codes where they are used elsewhere in this safety data sheet:
- H271: May cause fire or explosion; strong oxidiser
- H302: Harmful if swallowed
- H372: Causes damage to organs through prolonged or repeated exposure
- H332: Harmful if inhaled
- H400: Very toxic to aquatic life
- H411: Toxic to aquatic life with long lasting effects

Acronyms
- CAS: Chemical Abstracts Service
- DNEL: Derived No-Effect Level
- EC: European Community
- EC50: Effective Concentration, 50%
- GHS: Globally Harmonised System
- IARC: International Agency for Research on Cancer
- IC50: Half-maximal inhibitory concentration
- LC50: Lethal Concentration, 50%
- LD50: Lethal Dose, 50%
- NOAEC: No observed adverse effect concentration
- NOAEL: No observed adverse effect level
- NOEC: No observed effect concentration
- OEL: Occupational Exposure Limit
- PBT: Persistent, Bioaccumulative and Toxic
- PNEC: Predicted No-Effect Concentration
- REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals
- vPvB: very Persistent and very Bioaccumulative
- WEL: Workplace Exposure Limit

Previous revisions should be destroyed.

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