Safety Data Sheet: According To Regulation (EC) No. 1907/2006 (REACH)

Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

according to Regulation (EU) 2015/830
Article No.: RSM006 grotanol 3025

Print date: 28.07.2021 Revision date: 28.07.2021 EN
Version: 4.0 Issue date: 28.07.2021 Page 1 / 9
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Article No. (manufacturer/supplier): RSM006
Trade name/designation grotanol 3025
UFI: DN10-S0VX-900V-DFVK
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Preservative
Industrial use
1.3. Details of the supplier of the safety data sheet
Manufacturer
Vink Chemicals GmbH & Co. KG
Eichenhöhe 29 Telephone: +49 (0) 4186 - 88797 0
D-21255 Kakenstorf
Germany
Department responsible for information:
Mr. Branko Ulaga +49 (0) 4186 - 88797 0
E-mail (competent person) [email protected]
importer
Vink Chemicals UK Ltd.
25 Clinton Place, Seaford
BN25 1NP
United Kingdom
Department responsible for information:
Mr. Branko Ulaga +49 (0) 4186 - 88797 0
E-mail (competent person): [email protected]
1.4. Emergency telephone number
National Poisons Information Service: 0844 892 0111
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [CLP]
The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP].
Acute Tox. 4 / H332 Acute toxicity (inhalative) Harmful if inhaled.
Skin Corr. 1B / H314 Skin corrosion/irritation Causes severe skin burns and eye damage.
Eye Dam. 1 / H318 Serious eye damage/eye irritation Causes serious eye damage.
Resp. Sens. 1 / H334 Respiratory or skin sensitisation May cause allergy or asthma symptoms or
breathing difficulties if inhaled.
Skin Sens. 1 / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
STOT SE 3 / H335 STOT-single exposure May cause respiratory irritation.
Aquatic Acute 1 / H400 Hazardous to the aquatic environment Very toxic to aquatic organisms.
Aquatic Chronic 1 / H410 Hazardous to the aquatic environment Very toxic to aquatic life with long lasting
effects.
2.2. Label elements
The product is classified and labelled according to EC directives or corresponding national laws.
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms
Danger
Hazard statements
H332 Harmful if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
Safety Data Sheet

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
P260 Do not breathe vapour.
P261 Avoid breathing vapours.
P273 Avoid release to the environment.
P280 Wear protective gloves and eye/face protection.
P284 In case of inadequate ventilation wear respiratory protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physician.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
Hazard components for labelling
glutaral
reaction mass of 5-chloro-2- methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3- one (3:1)
Supplemental hazard information
EUH071 Corrosive to the respiratory tract.
2.3. Other hazards
No information available.
SECTION 3: Composition / information on ingredients
3.2. Mixtures
Description Biocide
Hazardous ingredients
EC No. REACH No.
CAS No. Designation weight-%
Index No. classification: // Remark
68603-25-8 Alcohols, C8-C10, ethoxylated propoxylated 8,5 - 11,5

Acute Tox. 4 H302 / Eye Dam. 1 H318
203-856-5
111-30-8 glutaral 8,5 - 11,5
605-022-00-X Acute Tox. 3 H301 / Acute Tox. 2 H330 / Skin Corr. 1B H314 / Resp.
Sens. 1 H334 / Skin Sens. 1A H317 / STOT SE 3 H335 / Aquatic Acute 1
H400 / Aquatic Chronic 2 H411
Specific concentration limit (SCL): Skin Corr. 1B H314 >= 10 / Skin Irrit. 2
H315 >= 0,5 / Eye Dam. 1 H318 >= 2 / Eye Irrit. 2 H319 >= 0,5 /
STOT SE 3 H335 >= 0,5 / Skin Sens. 1 H317 >= 0,5 / Acute Tox. 2
H330 >= 27,7 / Acute Tox. 3 H331 >= 14 / Acute Tox. 4 H332 >=
13,99
This substance has been listed as SVHC (substance of very high concern) in
the Candidate List according to Article 59 of REACH.
55965-84-9 reaction mass of 5-chloro-2- methyl-2H-isothiazol-3-one and < 1,5

613-167-00-5 2-methyl-2H-isothiazol-3- one (3:1)
Acute Tox. 3 H301 / Acute Tox. 2 H310 / Acute Tox. 2 H330 / Skin Corr.
1C H314 / Eye Dam. 1 H318 / Skin Sens. 1A H317 / Aquatic Acute 1 H400
(M = 100) / Aquatic Chronic 1 H410 (M = 100)
Specific concentration limit (SCL): Skin Corr. 1C H314 >= 0,6 / Skin Irrit. 2
H315 >= 0,06 / Eye Dam. 1 H318 >= 0,6 / Eye Irrit. 2 H319 >= 0,06
/ Skin Sens. 1A H317 >= 0,0015
Additional information
Safety Data Sheet

Full text of classification: see section 16

SECTION 4: First aid measures
4.1. Description of first aid measures
General information
In case of unconsciousness give nothing by mouth, place in recovery position and seek medical advice.
In case of inhalation
Remove casualty to fresh air and keep warm and at rest. In all cases of doubt, or when symptoms persist, seek medical
advice.
Following skin contact
Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do
not use solvents or thinners. Consult a physician.
After eye contact
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and
consult an ophthalmologist. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a doctor.
Following ingestion
If swallowed, rinse mouth with water (only if the person is conscious). Rinse mouth immediately and drink plenty of water. Do
NOT induce vomiting.Seek medical advice immediately.
4.2. Most important symptoms and effects, both acute and delayed
In all cases of doubt, or when symptoms persist, seek medical advice.
4.3. Indication of any immediate medical attention and special treatment needed
First Aid, decontamination, treatment of symptoms.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
alcohol resistant foam, carbon dioxide, Powder, spray mist, (water)
Unsuitable extinguishing media
strong water jet
5.2. Special hazards arising from the substance or mixture
Do not breathe gas/fumes/vapour/spray.
5.3. Advice for firefighters
Provide a conveniently located respiratory protective device.
Cool closed containers that are near the source of the fire. Do not allow water used to extinguish fire to enter drains, ground
or waterways.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate affected area. Do not breathe vapours.
6.2. Environmental precautions
Do not allow to enter into surface water or drains. If the product contaminates lakes, rivers or sewages, inform competent
authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it
for disposal in appropriate containers in accordance with the local regulations (see section 13).
6.4. Reference to other sections
Observe protective provisions (see section 7 and 8).
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advices on safe handling
Use only with sufficient ventilation.Refer to chapter 8. : Exposure controls / Personal protection
Safety Data Sheet

Further information
Respiratory protection necessary at: aerosol or mist formation
7.2. Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep/Store only in original container.
Requirements for storage rooms and vessels
Storage in accordance with the Ordinance on Industrial Safety and Health (BetrSiVO).
Further information on storage conditions
Take care of instructions on label. Protect from heat and direct sunlight. Protect from frost.
7.3. Specific end use(s)
No measures required.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limit values
glutaral
Index No. 605-022-00-X / EC No. 203-856-5 / CAS No. 111-30-8
TWA: 0,2 mg/m3; 0,05 ppm
STEL: 0,2 mg/m3; 0,05 ppm
TWA : Long-term occupational exposure limit value
STEL : short-term occupational exposure limit value
Ceiling : peak limitation
8.2. Exposure controls
Personal protection equipment
Respiratory protection
Respiratory protection necessary at: exceeding exposure limit values. Use only respiratory protection equipment with
CE-symbol including four digit test number. Combination filtering device Filter type: ABEK
Hand protection
Wear protective gloves. Recommended glove articles according EN ISO 374. Recommendation for protection against the
commonly occurring ingredients in the products: For short-term contact (e.g. splash guard): Suitable material: Nitriles, Butyl
caoutchouc (butyl rubber), material thickness: >= 0,4 mm, Penetration time of glove material depending on intensity and
duration of exposure to skin: >= 480 min. The exact break through time can be found out by the manufacturer of the protective
gloves and has to be observed. The protective gloves should always be checked for their suitability for specific workplaces
(e.g. mechanical resistance, product compatibility). Follow the glove manufacturer's instructions and information on how to
use, store, care for and replace gloves. The protective gloves should be replaced immediately if they are damaged or the first
signs of wear and tear.
Eye/face protection
Wear eye glasses with side protection according to EN 166.
Body protection
Suitable protective clothing: Protective clothing. Type 6 DIN EN 13034
Protective measures
Avoid contact with eyes and skin.
Environmental exposure controls
Do not allow to enter into surface water or drains. See section 7. No additional measures necessary.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance:
Physical state: Liquid
Appearance: aqueous solution
Colour: light yellow
Odour: characteristic
Odour threshold: not applicable
Safety Data Sheet

pH at 20 °C: 3 / 100,0 weight-%

Melting point/freezing point < 5 °C
Initial boiling point and boiling range: 100 °C
Flash point: > 100 °C
Evaporation rate: not determined
flammability
Burning time: not determined
Upper/lower flammability or explosive limits:
Lower explosion limit: not applicable
Upper explosion limit: not applicable
Vapour pressure at 20 °C: not determined
Vapour density: not determined
Relative density:
Density at 20 °C: 1,031 g/cm³
Solubility(ies):
Water solubility at 20 °C: 999
Partition coefficient: n-octanol/water: see section 12
Auto-ignition temperature: not applicable
Decomposition temperature: not applicable
Viscosity at 20 °C: 3,4 mPa*s
Explosive properties: not applicable
Oxidising properties: not applicable
9.2. Other information
No further relevant information available.
SECTION 10: Stability and reactivity
10.1. Reactivity
10.2. Chemical stability
Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to
section 7.
10.3. Possibility of hazardous reactions
No known hazardous reactions.
10.4. Conditions to avoid
Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to
section 7. Hazardous decomposition byproducts may form with exposure to high temperatures.
10.5. Incompatible materials
Alkalis (lyes), reducing agents, strong oxidizing agents, nucleophiles
10.6. Hazardous decomposition products
None if stored and used properly.
In the event of a fire, hazardous decomposition products can arise, e.g .: Nitrogen oxides (NOx), carbon monoxide (CO),
sulfur dioxide, hydrogen chloride (HCl)
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity
Harmful if inhaled.
Alcohols, C8-C10, ethoxylated propoxylated
oral, LD50, Rat: 616 mg/kg
dermal, LD50, Rabbit: > 3000 mg/kg
inhalative (vapours), LC50, Rat: > 8 mg/L (4 h)
Safety Data Sheet


oral, LD50, Rat 64 - 66 mg/kg
dermal, LD50, Rat: 141 mg/kg
dermal, LD50, Rabbit: 92,4 mg/kg
glutaral
oral, LD50, Rat: 77 mg/kg
inhalative (vapours), LC50, Rat: 0,28 mg/L (4 h)
inhalative (dust and mist), LC50, Rat (4 h)
Skin corrosion/irritation; Serious eye damage/eye irritation
Corrosive
Causes severe skin burns and eye damage.
Skin (4 h)
eyes
Respiratory or skin sensitisation
sensitising
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Skin:
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
Based on available data, the classification criteria are not met.
STOT-single exposure; STOT-repeated exposure
May cause respiratory irritation.
Aspiration hazard
Based on available data, the classification criteria are not met.
Practical experience/human evidence
Overall Assessment on CMR properties
The ingredients in this mixture do not meet the criteria for classification as CMR category 1A or 1B according to CLP.
SECTION 12: Ecological information
Do not allow to enter into surface water or drains.
12.1. Toxicity
Very toxic to aquatic organisms.
Fish toxicity, LC50, Pimephales promelas (fathead minnow): 13,3 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna: 12,3 mg/L (48 h)
Fish toxicity, LC50, Oncorhynchus mykiss (Rainbow trout): 0,19 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna (Big water flea): 0,16 mg/L (48 h)
Algae toxicity, ErC50, Skeletonema costatum: 0,0049 mg/L (120 h)
Long-term Ecotoxicity
Very toxic to aquatic life with long lasting effects.
12.2. Persistence and degradability
, OECD 301 F: 70 (28 day(s))
12.3. Bioaccumulative potential
Toxicological data are not available.
Bioconcentration factor (BCF)
Safety Data Sheet

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Appropriate disposal / Product
Recommendation
Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way.
List of proposed waste codes/waste designations in accordance with EWC
140603* other solvents and solvent mixtures
*Hazardous waste according to Directive 2008/98/EC (waste framework directive).
Appropriate disposal / Package
Non-contaminated packages may be recycled. Vessels not properly emptied are special waste.
SECTION 14: Transport information
14.1. UN number
UN 3265
14.2. UN proper shipping name
Land transport (ADR/RID): Corrosive liquid, acidic, organic, n.o.s.
(Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and
2-Methyl-2H-isothiazol-3-one (3:1), glutaraldehyd solution)
Sea transport (IMDG): CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Air transport (ICAO-TI / IATA-DGR): Corrosive liquid, acidic, organic, n.o.s.
14.3. Transport hazard class(es)
8
14.4. Packing group
II
14.5. Environmental hazards
Land transport (ADR/RID) ENVIRONMENTALLY HAZARDOUS
Marine pollutant p / Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one
and2-Methyl-2H-isothiazol-3-one (3:1)
14.6. Special precautions for user
Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in
case of an accident or leakage.
Advices on safe handling: see parts 6 - 8
Further information
Land transport (ADR/RID)

tunnel restriction code E
Sea transport (IMDG)

EmS-No. F-A, S-B
in packages <= 5 litres not restricted 2.10.2.7
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not applicable
Safety Data Sheet

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation
Restrictions of occupation:
Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC).
Regulation (EU) No. 528/2012 on biocides
biocidal product
biocide, active substance
reaction mass of 5-chloro-2- methyl-2H-isothiazol-3-one and 2,8 g/kg
2-methyl-2H-isothiazol-3- one (3:1)
glutaral 100 g/kg
Input 5-20 g/kg
Authorization number for biocidal products:
PT2
Directive 2010/75/EU on industrial emissions [Industrial Emissions Directive]
VOC-value (in g/L): 207,8
National regulations
15.2. Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information
Full text of classification in section 3:
Acute Tox. 4 / H302 Acute toxicity (oral) Harmful if swallowed.
Eye Dam. 1 / H318 Serious eye damage/eye irritation Causes serious eye damage.
Acute Tox. 3 / H301 Acute toxicity (oral) Toxic if swallowed.
Acute Tox. 2 / H330 Acute toxicity (inhalative) Fatal if inhaled.
Skin Corr. 1B / H314 Skin corrosion/irritation Causes severe skin burns and eye damage.
Resp. Sens. 1 / H334 Respiratory or skin sensitisation May cause allergy or asthma symptoms or
breathing difficulties if inhaled.
Skin Sens. 1A / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
STOT SE 3 / H335 STOT-single exposure May cause respiratory irritation.
Aquatic Acute 1 / H400 Hazardous to the aquatic environment Very toxic to aquatic organisms.
Aquatic Chronic 2 / H411 Hazardous to the aquatic environment Toxic to aquatic life with long lasting effects.
Acute Tox. 2 / H310 Acute toxicity (dermal) Fatal in contact with skin.
Skin Corr. 1C / H314 Skin corrosion/irritation Causes severe skin burns and eye damage.
Aquatic Chronic 1 / H410 Hazardous to the aquatic environment Very toxic to aquatic life with long lasting
effects.
Classification procedure
Classification for mixtures and used evaluation method according to regulation (EC) No 1272/2008 [CLP]
Acute Tox. 4 Acute toxicity (inhalative) Calculation method.
Skin Corr. 1B Skin corrosion/irritation Calculation method.
Eye Dam. 1 Serious eye damage/eye irritation Calculation method.
Resp. Sens. 1 Respiratory or skin sensitisation Calculation method.
Skin Sens. 1 Respiratory or skin sensitisation Calculation method.
STOT SE 3 STOT-single exposure Calculation method.
Aquatic Acute 1 Hazardous to the aquatic environment Calculation method.
Aquatic Chronic 1 Hazardous to the aquatic environment Calculation method.
Abbreviations and acronyms
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
OEL Occupational Exposure Limit Value
BLV Biological Limit Value
CAS Chemical Abstracts Service
CLP Classification, Labelling and Packaging
CMR Carcinogenic, Mutagenic and Reprotoxic
DIN German Institute for Standardization / German industrial standard
DNEL Derived No-Effect Level
Safety Data Sheet

EAKV European Waste Catalogue Directive

EC Effective Concentration
EC European Community
EN European Standard
IATA-DGR International Air Transport Association – Dangerous Goods Regulations
IBC Code International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk
ICAO-TI International Civil Aviation Organization Technical Instructions for the Safe Transport of Dangerous
Goods by Air
IMDG Code International Maritime Code for Dangerous Goods
ISO International Organization for Standardization
LC Lethal Concentration
LD Lethal Dose
MARPOL Maritime Pollution: The International Convention for the Prevention of Pollution from Ships
OECD Organisation for Economic Cooperation and Development
PBT persistent, bioaccumulative, toxic
PNEC Predicted No Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
UN United Nations
VOC Volatile Organic Compounds
vPvB very persistent and very bioaccumulative
Further information
The information supplied on this safety data sheet complies with our current level of knowledge as well as with national and
EU regulations.Without written approval, the product must not be used for purposes different from those mentioned in section
1.It is always the user's duty to take any necessary measures for meeting the requirements laid down by local rules and
regulations.The details in this safety data sheet describe the safety requirements of our product and are not to be regarded
as guaranteed attributes of the product.

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Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Article No.: RSM006 grotanol 3025

SECTION 1: Identification of the substance/mixture and of the company/undertaking

SECTION 2: Hazards identification

Article No.: RSM006 grotanol 3025

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

68603-25-8 Alcohols, C8-C10, ethoxylated propoxylated 8,5 - 11,5

55965-84-9 reaction mass of 5-chloro-2- methyl-2H-isothiazol-3-one and < 1,5

Article No.: RSM006 grotanol 3025

Full text of classification: see section 16

Article No.: RSM006 grotanol 3025

Article No.: RSM006 grotanol 3025

pH at 20 °C: 3 / 100,0 weight-%

Article No.: RSM006 grotanol 3025

reaction mass of 5-chloro-2- methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3- one (3:1)

Article No.: RSM006 grotanol 3025

12.4. Mobility in soil

Land transport (ADR/RID)

Sea transport (IMDG)

Article No.: RSM006 grotanol 3025

SECTION 15: Regulatory information

Article No.: RSM006 grotanol 3025

EAKV European Waste Catalogue Directive

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