Syllabus Upto: Atomic
Syllabus Upto: Atomic
Syllabus Upto: Atomic
: PC
1/8/20247
upto Thd -2
Atomic Str -
XI
H I U = 0
+ W 0
v9 ,
9 ,
+ 92 =
* -
-
iÉ Far?→w
←
.
• a-
ñ="÷¥:
IW1
92 TREE =
1-
IT ,
I
g.
=
CE
"
¥ =
1¥
?? I -_ ok ??
*
7=1
-1 ?? Ty - ok ? ?
n'
-
*
Kelvin-Planck Statement "
Motion
Perpetual
=tÑPMM-2y)
machine
kind is
↳ or , of second
impossible
t-MPOSSIBLE.MY
.
→ I w=
- too
e ←
It
92--0
stony
is
FIOT :
PMm impossible .
→
I
cyclic → W
p
←
I
Networked
pram -
I
KP -
SLOT
Y1W it 1W
II. F-
die
} ,
cyclic
HE
1W
I / to
92=0
KP ✓ ✗
2=1 ?? torn .E .
is Impossible
can't achieve this
Best Carnot
Imax
= I -
In > 2
Actual
HE .
Mine .
This .
0 1.0
- -
f.
-
-
.
-
- - - - .
- -
- - -
slope ¥H
-
:
Slope -_
¥12
> '
0K In % TH
Th
Tn fix [ fix
¥ ¥)÷+÷
I -
n=
.
, .
(8%-1)-1; -
kn
ÉIÉ)-②
⇐"
(A) =
1%1-21 )
TH
Two Adiabats can never intersect
փ:;;:
- I
n
-
to
1W / =
>
Adiabat
Sf .
☐Ñ=+r+E
'
p A- .
{ sf
too
ii¥É;;
9--0
B
Intersected
'
-
%
.
.
'
""
2 ?
±
÷
-
I 7
-
- -
•
↳
?⃝
÷
PV
Anticlockwise
>
.it#.uni-wmi:-
(;É
Clausius Statement
¥0
Coppet ¥6
'
copy p =
1W IN
30 30
70
TO
KPICLausiusmf.li?s20--gof
too
*
3°
no
C¥
1-
30
30
go µ 70
70
try
comp
.
-4¥
É A 70
*
*
"
÷ ) :: :
-
v. w
gas
.
Fluid
:
Thermodynamic Temperature Scale
÷
I
n=
-
Reversible vs Irreversible Cycle Efficiency
I Rev
>
2 In
H1E HE .
= Cannot HE
.
Proof . . -
oOh•-eEoSoozegeeeE
eEeosegpnfIEpRpogoaeeooE-*
sgeeooeoq
*
All Carnot engines
v60
µ 1W
§ :3 1¥ efficiency
same .
440
¥:*:* ⑤ ✗
Tin
The Clausius Inequality
E-
+ ' 50
4C 1491 +5112 + Shh,s) → C2H , - S -
GH5
is )
L t for
4lCG)l0Hls)S ✓
GH5 -5-5-4115
+ Zoo
44s ,
t 51121s) +2544s)→
11
4ccs)I0HisI2
{ 1 12×45 150 1- Es
-
s
-225
?
"
±
I t )
¥
fear H =
Eabs -
Eve
= C- ⇐c- 2 C-
c- c
=
(590 -
2×331) K5
If
Introducing Entropy Function
Boom
I
- :-c:-&
c .
Art '
?
↳ Hq + 502 → 3h02 + 4112011 )
ZECC
8-4-1, ↳ /
✓
5<-0--0
tiny f- (4×41)
[ 64=0+81-0-1 ]
a b mole
Eg= ?
HRel .
= Habs
/
.
(10×2) ✗ b = 130 a
Ing = 4- I = -
I
✓ 5 4
-
St -
try w =
=
-
-
Ing
C- 1)
RT
RT
=
RT (for 3 mole
A)
ARE
IF
Han +
50mmol
Bacon ),
"
¥É÷° -5%10-115
40mmol
ARE
SB20
mm
WA 10mmol
]
(Remaining)
45×1%45 to "'
i -57×40%0 KJ
40mmol
÷"
-
✗→
¥