Assignment 1: ME 760: Name: Anuj Agrawal Roll: 180110012
Assignment 1: ME 760: Name: Anuj Agrawal Roll: 180110012
Assignment 1: ME 760: Name: Anuj Agrawal Roll: 180110012
Q1.
We know,
Q2.
At 298K We have,
ΔH
C2 H4 (g) + 3(O2 + 3.76N2 ) 2CO2 (g) + 2H2 O + 11.28N2
Δf HO 2 = Δf HO 2 = 0
Δf HCO 2 = −393.5 kJ/mol
Δf HH 2 O = −241.8 kJ/mol
ΔH = 47161 kJ/kg = 1320.5 kJ/mol
Δf HC2 H 2 = 2 ∗ Δf HCO 2 + 2 ∗ Δf HH 2 O + ΔH
Δf HC2 H 2 = 49.9 kJ/mol = 49900 kJ/kmol
Q3.
The standard equation of reaction:
ΔH
C2 H6 + 3.5O2 2CO2 (g) + 3H2 O(g)
35 ΔH 7
C2 H6 + O2 2CO2 (g) + 3H2 O(g) + O2 (g)
9 18
By conservation of energy, we have:
ΔH = Δf HC2 H 6 − 2 ∗ Δf HCO 2 − 2 ∗ Δf HH 2 O
ΔH = −83.75 kJ/mol + 2 ∗ 393.5 kJ/mol + 2 ∗ 241.8 kJ/mol
ΔH = 1186.85 kJ/mol
Assignment 1: ME 760 1
P = 1186.85 kJ/mol ∗ 30000 mol/hr
P = 3.558 ∗ 107 kJ/hr = 9882 kW = 33718499 BTU/hr
for every mole of ethane, we have 35/9 moles of O2 flowing into the system. Therefore:
35
ṁo2 = 30 ∗ = 116.67 kmol/hr = 1.037 kg/s
9
Q4.
The standard equation:
Equation of reaction, taking 6:1 molar (volume) ratio of CO2 and CO:
8∗6 8
C8 H18 + x(O2 + 3.76N2 ) → CO2 + CO + 9H2 O + (x − 11.93)O2 + 3.76xN2
7 7
Which gives us, equivalence ratio:
Now, to solve for x, molar ratio of CO2 is 6 percent (equivalent to volume ratio in ideal gas assumption), which gives:
48
= 0.06(8 + 9 + x − 11.93 + 3.76x)
7
⟹ x = 22.94
12.5
⟹ r= = 0.54
x
Finally, molar ratio of O2 in exhaust:
(x − 11.93) ∗ 0.06
48
= 0.096 = 9.6%
7
Q5.
The standard chemical equation:
ΔH
C3 H8 (298K) + 5(O2 + 3.76N2 )(298K) 3CO2 (T ) + 4H2 O(T ) + 18.8N2 (T )
We have:
ΔH = Δf HC3 H 8 − 3 ∗ Δf HCO2 − 4 ∗ Δf HH 2 O
ΔH = −104.63 kJ/mol + 3 ∗ 393.5 kJ/mol + 4 ∗ 241.8 kJ/mol
ΔH = 2043.07 kJ/mol
Now this energy goes into raising the temperature of the products. We have at 298K:
CO
Assignment 1: ME 760 2
cCO
v
2
≈ 42 J/mol-K
H2 O
cv ≈ 26 J/mol-K
cN
v
2
≈ 21 J/mol-K
⟹ cmix
v = (3 ∗ 42 + 4 ∗ 26 + 18.8 ∗ 21) J/mol-K (per mole of fuel)
⟹ cmix v = 624.8 J/mol-K
2043070
⟹ T = 298K + K = 3567.96K
624.8
Q6.
Empirical chemical equation - fuel(450K) + air(750K) = products(T )
Using conservation of energy, we have:
Q7.
The standard chemical equation:
ΔH
C3 H8 (298K) + CH4 (298K) + 7(O2 + 3.76N2 )(298K) 4CO2 (T ) + 6H2 O(T ) + 26.32N2 (T )
ΔH
C3 H8 (298K) + CH4 (298K) + 8.75(O2 + 3.76N2 )(298K) 4CO2 (T ) + 6H2 O(T ) + 32.9N2 (T ) + 1.75O2
8.75
Which gives us an A/Fmolar = 2 = 4.375
We have:
Now this energy goes into raising the temperature of the products. We have at 1200K:
cCO
p
2
≈ 56.3 J/mol-K
H2 O
cp ≈ 43.6 J/mol-K
cNp
2
≈ 33.7 J/mol-K
O2
cp ≈ 35.7 J/mol-K
4 ∗ 56.3 + 6 ∗ 43.6 + 32.9 ∗ 33.7 + 1.75 ∗ 35.7
⟹ cmix
p = J/mol-K
mix
2
⟹ cp = 829 J/mol-K
1422825
⟹ T = 298K + K = 2014.31K
829
Q8.
Input:
Assignment 1: ME 760 3
Output:
Assignment 1: ME 760 4
Q9.
Na ho payega
Q10.
Standard chemical equation:
1
H2 + O2 = H2 O
2
With equivalence ratio of 0.25, we have:
3
H2 (300K) + 2O2 (800K) = H2 O(T ) + O2 (T )
2
Using conservation of energy:
Assignment 1: ME 760 5
Solving for T, we get:
T = 3008K
References:
https://www.ohio.edu/mechanical/thermo/property_tables/combustion/CO2_enth.html
https://www.ohio.edu/mechanical/thermo/property_tables/combustion/oxygen_enth.html
https://www.ohio.edu/mechanical/thermo/property_tables/combustion/H2O_enth.html
https://www.engineeringtoolbox.com/nitrogen-d_977.html
https://www.engineeringtoolbox.com/oxygen-d_978.html
https://www.engineeringtoolbox.com/carbon-dioxide-d_974.html
https://www.engineeringtoolbox.com/water-vapor-d_979.html
Assignment 1: ME 760 6