Name: ………………………………………………………………..

Date Due: ………………………………………………………………..

Year 12 80% A

70% B

AS Level Chemistry 60% C

2008 - 2009 50% D

40% E

Below U

1.2
Assessed Homework %
Amount of Substance

59
10.2 Assessed Homework
.

1. (a) Define the term relative atomic mass.

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(2)

(b) How would you calculate the mass of one mole of atoms from the mass of a single

atom?

……………………………………………………………………………………. (1)

(c) Sodium hydride reacts with water according to the following equation.

NaH (s) + H2O (l) → NaOH (aq) + H2 (g)

A 1.00 g sample of sodium hydride was added to water and the resulting solution

was diluted to a volume of exactly 250 cm3

(i) Calculate the concentration in moldm-3, of sodium hydroxide solution formed.

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(ii) Calculate the volume of hydrogen gas evolved, measured at 293 K and 100

kPa.

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(iii) Calculate the volume of 0.112 M hydrochloric acid which would react exactly

with a 25.0 cm3 sample of sodium hydroxide solution.

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(8)

[TOTAL 11 marks]

1
10.2 Assessed Homework

2. (a) Sodium carbonate forms a number of hydrates of general formula Na2CO3.xH2O

A 3.01 g sample of one of these hydrates was dissolved in water and the solution
3
made up to 250 cm .
3 3 –
In a titration, a 25.0 cm portion of this solution required 24.3 cm of 0.200 mol
1 –3
 dm hydrochloric acid for complete reaction.

The equation for this reaction is shown below.

Na2CO3 + 2HCl  2NaCl + H2O + CO2

3 –3
(i) Calculate the number of moles of HCl in 24.3 cm of 0.200 mol dm
hydrochloric acid.

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3
(ii) Deduce the number of moles of Na2CO3 in 25.0 cm of the Na2CO3
solution.

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3
(iii) Hence deduce the number of moles of Na2CO3 in the original 250 cm of
solution.

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(iv) Calculate the Mr of the hydrated sodium carbonate.

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(5)

(b) In an experiment, the Mr of a different hydrated sodium carbonate was found to

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(3)

–3 3
(c) A gas cylinder, of volume 5.00 × 10 m , contains 325 g of argon gas.

(i) Give the ideal gas equation.

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2
10.2 Assessed Homework

(ii) Use the ideal gas equation to calculate the pressure of the argon gas in the
cylinder at a temperature of 298 K.
–1 –1
(The gas constant R = 8.31 J K mol )

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(4)

[Total 12 marks]

3. (a) A sample of ethanol vapour, C2H5OH (Mr = 46.0), was maintained at a pressure
of
100 kPa and at a temperature of 366K.

(i) State the ideal gas equation.

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3
(ii) Use the ideal gas equation to calculate the volume, in cm , that 1.36 g of
ethanol vapour would occupy under these conditions.
–1 –1
(The gas constant R = 8.31 J K mol )

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(5)

(b) Magnesium nitride reacts with water to form magnesium hydroxide and ammonia.

(i) Balance the equation, given below, for the reaction between magnesium
nitride and water.

Mg3N2 + H2O  Mg(OH)2 + NH3

3
10.2 Assessed Homework

(ii) Calculate the number of moles, and hence the number of molecules, of
NH3 in 0.263 g of ammonia gas.
23 –1
(The Avogadro constant L = 6.02 × 10 mol )

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(4)

(c) Sodium carbonate is manufactured in a two-stage process as shown by the

NaCl + NH3 + CO2 + H2O  NaHCO3 + NH4Cl

2NaHCO3  Na2CO3 + H2O + CO

Calculate the maximum mass of sodium carbonate which could be obtained from
800 g of sodium chloride.

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(4)
[Total 13 marks]

4. (a) The equation for the reaction between magnesium carbonate and hydrochloric
acid is given below.

MgCO3 + 2HCl  MgCl2 + H2O + CO2

3 –3
When 75.0 cm of 0.500 mol dm hydrochloric acid were added to 1.25 g of
impure MgCO3 some acid was left unreacted. This unreacted acid required 21.6
3
cm of a
–3
0.500 mol dm solution of sodium hydroxide for complete reaction.

3 –3
(i) Calculate the number of moles of HCl in 75.0 cm of 0.500 mol dm
hydrochloric acid.
4
10.2 Assessed Homework
........................................................................................................................

(ii) Calculate the number of moles of NaOH used to neutralise the unreacted
HCl.

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(iii) Show that the number of moles of HCl which reacted with the MgCO3 in
the sample was 0.0267

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(iv) Calculate the number of moles and the mass of MgCO3 in the sample, and
hence deduce the percentage by mass of MgCO3 in the sample.

Moles of MgCO3 ............................................................................................

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Mass of MgCO3 .............................................................................................

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Percentage of MgCO3 ...................................................................................

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(8)

(b) A compound contains 36.5% of sodium and 25.5% of sulphur by mass, the rest
being oxygen.

(i) Use this information to show that the empirical formula of the compound is
Na2SO3

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(ii) When Na2SO3 is treated with an excess of hydrochloric acid, aqueous

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5
10.2 Assessed Homework
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(4)

[Total 12 marks]

5. (a) Give the meaning of the term empirical formula

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……………………………………………………………………………………. …….. (1)

(b) Analysis of 3.150 g of compound X showed that it contained 0.769 g of calcium and
0.539 g of nitrogen; the remainder was oxygen. Calculate the empirical formula of
X.

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(3)
(c) What additional information is required in order to deduce the molecular formula of
X.
…………………………………………………………………………………………….. (1)

(d) A sample of X when heated in alkaline solution with an aluminium-zinc alloy

produced ammonia gas. After cooling to 293 K, the ammonia occupied a volume of

1.53 x 10-3 m3 at a pressure of 95.0 kPa. The ammonia was dissolved in water and

made up to 250 cm 3 of aqueous solution. A 25.0 cm 3 sample of this was then

titrated with a 0.150 M hydrochloric acid.

(i) Calculate the number of moles of ammonia gas in 1.53x 10 -3 m3 , at a

pressure of 95.0 kPa and a temperature of 293K.

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(ii) Calculate the concentration in moldm-3 of ammonia in aqueous solution.

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(iii) Calculate the volume of 0.150 M hydrochloric acid required to neutralise the

25.0 cm3 sample of ammonia solution.

6
10.2 Assessed Homework
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(6)
[Total 11 marks]