Sist Iso 9297 1996
Sist Iso 9297 1996
Sist Iso 9297 1996
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Water quality -- Determination of chloride -- Silver nitrate titration with chromate indicator
(Mohr's method)
ICS:
13.060.50 3UHLVNDYDYRGHQDNHPLþQH Examination of water for
VQRYL chemical substances
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
iTeh STANDARD PREVIEW
(standards.iteh.ai)
SIST ISO 9297:1996
https://standards.iteh.ai/catalog/standards/sist/683f2a0e-313c-42ae-80e2-
d5c9f671665a/sist-iso-9297-1996
INTERNATIONAL
STANDARD
First edition
1989-l l-1 5
Reference number
IS0 9297: 1989(E)
IS0 9297:1989(E)
Foreword
0 IS0 1989
All rights reserved. No part of this publication may be reproduced or utilized in any form
or by any means, electronic or mechanical, including photocopying and microfilm, without
permission in writing from the publisher.
International Organization for Standard ization
Case Postale 56 l CH-1211 Gerkve 20 l Switzerl and
Printed in Switzerland
ii
IS0 9297:1989(E)
Introduction
Nearly all natural waters, as well as rain water and many waste waters,
contain chloride ions. Concentrations can vary widely from a few milli-
grams per litre in some natural waters to very high concentrations in
polluted waste water, marine water and saline ground water.
1 scope
Table 1 - Interferences
Amount interfering
Substance
1 .l Application range mg/l
IS0 385,1:1984, Laboratory glassware - Burettes - 4.4 Nitric acid, c(HN0,) z 0,l mol/l.
Part 1: General requirements.
Stored in a glass bottle, the solution is stable indef-
IS0 5667-l :1980, Water quality - Sampling - initely.
Part 1: Guidance on the design of sampling pro-
grammes. 4.5 Sodium hydroxide, solution, c(NaOH) 3
0,l mol/l.
IS0 5667.211982, Water quality - Sampling -
Part 2: Guidance on sampling techniques.
4.6 Reagent, for improvement of the buffer capac-
IS0 5667-3:1985, Water quality - Sampling - ity.
Part 3: Guidance on the preservation and handling
of samples. Calcium carbonate (CaCO,) or sodium hydrogen
carbonate (NaHCO,) in powder form.
IS0 572511986, Precision of test methods - Determi-
nation of repeatability and reproducibility for a
standard test method by inter-laboratory tests. 5 Apparatus
Reaction of chloride with added silver ions to form 5.1 Burette, of capacity 25 ml, complying with
insoluble silver chloride which precipitates IS0 385-l.
quantitatively. Addition of a small excess of silver
ions to form a red brown silver chromate with
chromate ions that have been added as an indicator. 6 Procedure
This reaction
The pH is maintained
is used for indicating iTeh STANDARD
in the range of 5 to 9,5
PREVIEW
the end-point.
For sampling and preservation of samples refer to
throughout
tation.
the titration (standards.iteh.ai) 5667-2 and IS0
in order to allow precipi-
IS0 5667-1, IS0 5667-3.
If stored in the dark in a brown glass bottle with Adjust the pH in one aliquot, then take another and,
this time without measuring the pH, add the same
glass stoppers, the solution is stable for several
amounts of acid/hydroxide solution.
months. The solution is standardized against 10 ml
sodium chloride standard reference solution (diluted
NOTE 2 If the pH is less than 5, pH-adjustment with
to 100 ml) using the procedure given in 6.1, however, calcium carbonate or sodium hydrogen carbonate (4.6) is
there is no need for pH adjustment. preferable. This will also improve the buffer capacity. The
amount added should be chosen so that a carbonate res-
idue is left in the sample even after titration.
4.2 Potassium chromate, indicator, 100 g/l solution.
Dissolve 10 g of potassium chromate (K,CrO,) in
water and dilute to 100 ml. Add 1 ml of potassium chromate indicator solution
(4.2). Titrate the solution by dropwise addition of sil-
ver nitrate solution until the colour of the solution
4.3 Sodium chloride, standard reference solution, just changes to a reddish brown (volume VJ.
c(NaCI) = 0,02 mol/l. Dissolve I,1688 g of sodium
chloride (NaCI), previously dried at 105 OC, in water After addition of one drop of sodium chloride sol-
and dilute to 1000 ml in a one-mark volumetric flask. ution (4.3), the colour should disappear.
2
IS0 9297:1989(E)
Use the titrated sample treated with sodium chloride VS is the volume, in millilitres, of the silver
solution for comparison with the next titrations. nitrate solution (4.1) used for the titration
of the sample;
Where the titrant volume exceeds 25 ml, repeat the
determination using a larger capacity burette or a c is the actual concentration, expressed in
smaller test portion volume. moles of AgNO, per litre, of the silver
nitrate solution;
6.2 Blank test
s is the conversion factor,
Titrate a blank solution as described in 6.1, using
f = 35453mg/mol.
100 ml of water instead of the test sample. Report the result to the nearest 1 mg/l, giving three
significant figures only.
The blank value should not exceed 0,2 ml of 4.1.
Otherwise check the purity of the water.
7.2 Precision
7 Expression of results
The precision of the method is given in table 2.*)
7.1 Calculation
PCI
iTehin milligrams
is the concentration,
STANDARD per li-
PREVIEW
b) all information neces sary for a complete identifi-
tre, of chloride;
(standards.iteh.ai) cation of the sample;
va is the volume, in millilitres, of the test
sample (maximum 100 ml; dilutions SISTmust c) the results and the method of expression used;
ISO 9297:1996
be taken into https://standards.iteh.ai/catalog/standards/sist/683f2a0e-313c-42ae-80e2-
account);
d) details of any operations not included in this
T/ b is the volume, in millilitres, d5c9f671665a/sist-iso-9297-1996
of the silver International Standard or regarded as optional,
nitrate solution used for the titration of together with any circumstances that may have
the blank; affected the results.
*) Values taken from an interlaboratory trial carried out in Germany, F.R., in 1983 in accordance with IS0 5725, except that
the method to reject outliers was different.