This document describes a 1D simulation of a lithium ion battery in COMSOL. It includes definitions of parameters like electrode radii and concentrations. It defines the geometry as 1D cylindrical domains for the negative electrode, separator, and positive electrode. It specifies the materials as a polymer electrolyte and LMO electrode. The study will initialize current distribution and perform a time dependent simulation. Results will include data sets and plot groups.
This document describes a 1D simulation of a lithium ion battery in COMSOL. It includes definitions of parameters like electrode radii and concentrations. It defines the geometry as 1D cylindrical domains for the negative electrode, separator, and positive electrode. It specifies the materials as a polymer electrolyte and LMO electrode. The study will initialize current distribution and perform a time dependent simulation. Results will include data sets and plot groups.
This document describes a 1D simulation of a lithium ion battery in COMSOL. It includes definitions of parameters like electrode radii and concentrations. It defines the geometry as 1D cylindrical domains for the negative electrode, separator, and positive electrode. It specifies the materials as a polymer electrolyte and LMO electrode. The study will initialize current distribution and perform a time dependent simulation. Results will include data sets and plot groups.
This document describes a 1D simulation of a lithium ion battery in COMSOL. It includes definitions of parameters like electrode radii and concentrations. It defines the geometry as 1D cylindrical domains for the negative electrode, separator, and positive electrode. It specifies the materials as a polymer electrolyte and LMO electrode. The study will initialize current distribution and perform a time dependent simulation. Results will include data sets and plot groups.
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Lithium ion 1D simulation in Comsol
Produced by ; Mohammad Kooshki
Report date Dec 20, 2021 12:23:19 AM
1 Contents 1. Global Definitions................................................................................................................................ 1.1. Parameters 1............................................................................................................................................................... 1.2. Variables....................................................................................................................................................................... 2. Component 1........................................................................................................................................ 2.1. Geometry 1.................................................................................................................................................................. 2.2. Materials....................................................................................................................................................................... 2.3. Lithium-Ion Battery................................................................................................................................................... 2.4. Mesh 1........................................................................................................................................................................... 3. Study 1.................................................................................................................................................. 3.1. Current Distribution Initialization........................................................................................................................ 3.2. Time Dependent........................................................................................................................................................ 4. Results................................................................................................................................................... 4.1. Data Sets....................................................................................................................................................................... 4.2. Plot Groups..................................................................................................................................................................
2 1 Global Definitions Dat Dec 20, 2021 12:21:37 AM e
GLOBAL SETTINGS Name Simulation of Lithiom ion 1D in Comsol.mph C:\Users\Mohammad\Desktop\Battery simulation\Simulation of Lithiom ion 1D in Path Comsol.mph COMSOL version COMSOL 5.3 (Build: 223)
USED PRODUCTS COMSOL Multiphysics Batteries & Fuel Cells Module
1.1 PARAMETERS 1 PARAMETERS Name Expression Value Description Negative rp_neg 12.5e-6[m] 1.25E−5 m electrode radius Positive rp_pos 8e-6[m] 8E−6 m electrode radius T 25[degC] 298.15 K Temperature Volume fraction epss_pos 1 - epsl_pos -0.073 0.297 of positive electrode Volume fraction of positive epsl_pos 0.444 + 0.186 0.63 electolyte for kathode Volume fraction epss_neg 1 - epsl_neg - 0.026 0.471 of negative electrode Volume fraction of negative epsl_neg 0.357 + 0.146 0.503 electolyte for anode initial cl_0 2000[mol/m^3] 2000 mol/m³ concentration initial concentration for cs0_neg 0.56*31507[mol/m^3] 17644 mol/m³ negative electrode cs0_pos 0.17*22860[mol/m^3] 3886.2 mol/m³ initial
3 Name Expression Value Description concentration for positive electrode rate constande k_neg 4.4e-10[m/s] 4.4E−10 m/s of anode reaction rate constant of k_pos 4.8e-10[m/s] 4.8E−10 m/s kathode reaction lenght of L_neg 100[um] 1E−4 m negative electrode lenght of L_sep 52[um] 5.2E−5 m separator length of L_pos 183[um] 1.83E−4 m positive electrode i_1C 0.5[A/m^2] 0.5 A/m² initial current rate of current with C_rate 1 1 concntration corrolation current density i_app -i_1C*C_rate −0.5 A/m² of application
1.2 VARIABLES
1.2.1 Variables 1 SELECTION Geometric entity Entire model level
Name Expression Unit Description
deltai (i_app - 10) A/m²
4 2 Component 1
2.1 GEOMETRY 1
Geometry 1
UNITS Length unit m Angular deg unit
2.2 MATERIALS
2.2.1 LiPF6 in 1:2 EC:DMC and p(VdF-HFP) (Polymer electrolyte, Li-ion
Battery) T=25 C
1:2 EC/DMC by volume
Reference
M. Doyle, J. Newman, A.S. Gozdz, C.N. Schmutz, and J.M. Tarascon, “Comparison of Modeling Predictions with Experimental Data from Plastic Lithium Ion Cells,” J. Electrochem. Soc., vol. 143, p. 1890, 1996.
5 LiPF6 in 1:2 EC:DMC and p(VdF-HFP) (Polymer electrolyte, Li-ion Battery)
M. Doyle, J. Newman, A.S. Gozdz, C.N. Schmutz, and J.M. Tarascon, “Comparison of Modeling Predictions with Experimental Data from Plastic Lithium Ion Cells,” J. Electrochem. Soc., vol. 143, p. 1890, 1996
V. Srinivasan and C.Y. Wang, "Analysis of Electrochemical and Thermal Behavior of Li-Ion Cells," J. Electrochem. Soc., vol. 150, p. A98, 2003
V. Srinivasan, and J. Newman, “Design and Optimization of a Natural Graphite/Iron Phosphate Lithium Ion Cell,” J. Electrochem. Soc., vol. 151, p. 1530, 2004.
K. Kumaresan, G. Sikha, and R. E. White, “Thermal Model for a Li-Ion Cell,” J. Electrochem. Soc., vol. 155, p. A164, 2008.
R. E. Gerver and J. P. Meyers, "Three-Dimensional Modeling of Electrochemical Performance and Heat
Generation of Lithium-Ion Betteries in Tabbed Planar Configurations", J. Electrochemical Soc., vol. 158, p. A835, 2011
K. E. Thomas, and J. Newman, “Heats of mixing and of entropy in porous insertion electrodes,” J. Power Sources., vol. 119-121, p. 844, 2003.
SELECTION Geometric entity Domain level Selection No domains
2.3 LITHIUM-ION BATTERY
Lithium-Ion Battery
EQUATIONS
8 FEATURES Electrolyte 1 No Flux 1 Insulation 1 Initial Values 1 Porous Electrode (Positive) Porous Electrode (Negative) Electric Ground 1 Electrode Current Density 1
2.3.1 Electrolyte 1 EQUATIONS
2.3.2 No Flux 1 EQUATIONS
2.3.3 Insulation 1 EQUATIONS
2.3.4 Porous Electrode (Positive)
EQUATIONS
9 Porous Electrode Reaction 1
EQUATIONS
2.3.5 Porous Electrode (Negative)
EQUATIONS
Porous Electrode Reaction 1
EQUATIONS
2.3.6 Electric Ground 1
EQUATIONS
2.3.7 Electrode Current Density 1
EQUATIONS
10 2.4 MESH 1
Mesh 1
11 3 Study 1 COMPUTATION INFORMATION Computation 12 s time CPU Intel(R) Pentium(R) CPU G2020 @ 2.90GHz, 2 cores Operating system Windows 7
3.1 CURRENT DISTRIBUTION INITIALIZATION
STUDY SETTINGS Description Value Include geometric Off nonlinearity
