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    Lampiran Vle

    Uploaded by

    Jiho

    Copyright:

    © All Rights Reserved
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    Lampiran Vle

    Uploaded by

    Jiho
    38 views6 pages

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    38 views6 pages

    Lampiran Vle

    Uploaded by

    Jiho

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 6

    LAMPIRAN

    I. Data Percobaan
    Komponen
    No. Formula Molar Mass Name
    1. CHCl3 119,377 Chloroform
    2. C6H14 86,177 Hexane
    I.1 Isotermik
    Constant Value
    Temperature 328,15 K
    55 C

    x1 x2
    P (kPa)
    (mol/mol) (mol/mol)
    64,395 0 1
    69,248 0,1035 0,8965
    73,607 0,2035 0,7965
    76,674 0,2905 0,7095
    79,407 0,3964 0,6036
    82,3 0,4992 0,5008
    83,673 0,5965 0,4035
    84,673 0,6991 0,3009
    84,913 0,8 0,2
    84,153 0,9003 0,0997
    82,393 1 0
    II. Perhitungan
    1. Psat sat
    1 dan P2

    a. Psat
    1

    Psat
    1 =exp A− ( T B+C )
    2548,74
    =exp ( 13,7324−
    55+218,552 )
    Psat
    1

    Psat
    1 =82,69798 kPa

    b. Psat
    2

    Psat
    2 =exp A− ( T B+C )
    2696,04
    =exp ( 13,8193−
    25+ 224,314 )
    Psat
    2

    Psat
    2 =64,52425 kPa

    2. γ 1 dan γ 2 eksperimen
    y1 P
    a. γ 1=
    x 1 Psat
    1

    0,161 x 69,248
    γ 1=
    0,1035 x 82,69798
    γ 1=1,30256
    y2 P
    b. γ 2=
    x 2 Psat
    2

    1,00438 x 69,248
    γ 2=
    0,8965 x 64,52425
    γ 2=1,00438
    3. ln γ 1 dan γ 2 eksperimen
    a. ln γ 1
    ln γ 1 = ln 1,30256
    ln γ 1 = 0,26433
    b. ln γ 2
    ln γ 2 = ln 1,00438
    ln γ 2 = 0,0044
    4. G E / RT eksperimen
    GE
    =( x 1 ln γ 1 ) + ( x 2 ln γ 2)
    RT
    GE (
    = 0,1035 x 0,2643 ) + ( 0,8965 x 0,0044 )
    RT
    GE
    =0,0313
    RT
    5. G E / x1 x 2 RT eksperimen
    GE
    RT
    G E / x1 x 2 RT =
    x1 x2
    0,0313
    G E / x1 x 2 RT =
    0,1035 x 0,8965
    G E / x1 x 2 RT =0,3370
    6. A12 dan A21 persamaan Margules
    a. A12=intercept
    A12=0,352
    b. A21=intercept + slope
    A21=0,352+ 0,1655
    A21=0,5175
    7. A12 dan A21 persamaan Van Laar
    1
    a. A12=
    intercept
    1
    A12=
    2,8248
    A12=0,35401
    1
    b. A21=
    interce pt +slope
    1
    A21=
    (2,8248+(−1,0086))
    A21=0,5506
    8. ln γ 1 dan γ 2 persamaan Margules
    a. ln γ 1
    2
    ln γ 1 = x 2 [ A12 +2( A12 + A21 ) x 1 ]

    ln γ 1 = 0,89652 [ 0,352+ 2(0,352+0,5175)0,1035 ]


    ln γ 1 = 0,31044
    b. ln γ 2
    2
    ln γ 2 = x 1 [ A21 +2( A21 + A12) x 2 ]
    ln γ 2 = 0,10352 [ 0,5175+2 ( 0,5175+ 0,352 ) 0,8965 ]
    ln γ 2 = 0,00236
    9. γ 1 dan γ 2 persamaan Margules
    a. γ 1
    γ 1=exp (ln γ 1)
    γ 1 = 1,364
    b. γ 2
    γ 2=exp (ln γ 2)
    γ 2 = 1,0024
    10. G E / RT persamaan Margules
    GE
    =( A21 x 1 + A12 x 2 ) x 1 x 2
    RT
    GE (
    = 0,5175 x 0,1035+0,352 x 0,8965 ) 0,1035 x 0,8965
    RT
    GE
    =0 , 0343
    RT
    11. G E / x1 x 2 RT persamaan Margules
    GE
    RT
    G E / x1 x 2 RT =
    x1 x2
    0,0343
    G E / x1 x 2 RT =
    0,1035 x 0,8965
    G E / x1 x 2 RT =0,36913
    12. ln γ 1 dan γ 2 persamaan Van Laar
    a. ln γ 1
    −2
    A x
    ln γ 1 = A12 ( 1+ 12 1
    A 21 x 2 )
    −2
    0,35401 x 0 , 1035
    ln γ 1 = 0,35401 1+ ( 0,5506 x 0,8965 )
    ln γ 1 = 0,30677
    b. ln γ 2
    −2
    A x
    ln γ 2 = A21 ( 1+ 21 2
    A 12 x 1 )
    −2
    0,5506 x 0,8965
    ln γ 2 = 0,5506 1+ ( 0,35401 x 0,1035 )
    ln γ 2 = 0,00263
    13. γ 1 dan γ 2 persamaan Van Laar
    a. γ 1
    γ 1=exp (ln γ 1 )
    γ 1 = 1,35903
    b. γ 2
    γ 2=exp (ln γ 2)
    γ 2 = 1,00263

    14. G E / x1 x 2 RT persamaan Van Laar


    GE A 12 A21
    =
    x1 x 2 RT A 12 x 1 + A 21 x 2
    GE 0,35401 x 0,5506
    =
    x1 x 2 RT 0,35401 x 0,1035+0,5506 x 0,8965
    GE
    =0,36759
    x1 x 2 RT
    15. G E / RT persamaan Van Laar
    G E / RT=G E / RT X x 1 x 2
    G E / RT=0,36759 x 0,1035 x 0,8965
    G E / RT=0,03411
    16. Error
    GE /RT percobaan−G E / RT Vanlaar
    Error= | E
    G /RT Van laar |
    0,03127−0,03411
    Error= | 0,03411 |
    Error=0,08315

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