Revision date: 26/06/2015 Revision: 16 Supersedes date: 11/06/2015

SAFETY DATA SHEET

Ultimeg 2020 hardener
According to Regulation (EC) No 1907/2006, Annex II, as amended by Regulation (EU) No 453/2010

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name Ultimeg 2020 hardener

Product number u2020.h

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Hardener.

1.3. Details of the supplier of the safety data sheet

Supplier AEV LIMITED
MARION STREET
BIRKENHEAD
MERSEYSIDE
CH41 6LT

Tel. +44(0)151 647 3322

Fax. +44(0)151 647 3377

1.4. Emergency telephone number

Emergency telephone +44 (0) 151 647 3322 (Monday to Friday 09.00 - 17.00)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification
Physical hazards Not Classified

Health hazards Acute Tox. 4 - H302 Acute Tox. 3 - H331 Skin Corr. 1B - H314 Eye Dam. 1 - H318 Skin Sens.
1 - H317 Repr. 2 - H361f

Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

Classification (67/548/EEC or Xn;R21/22. Repr. Cat. 3;R62. C;R34. R43. N;R50/53.

1999/45/EC)

2.2. Label elements

Pictogram

Signal word Danger

Hazard statements H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H361f Suspected of damaging fertility.
H410 Very toxic to aquatic life with long lasting effects.

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Precautionary statements P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe vapour/spray.
P261 Avoid breathing vapour/spray.
P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of water.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P311 Call a POISON CENTER/doctor.
P321 Specific treatment (see medical advice on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container in accordance with national regulations.

Contains 3,6,9,12-TETRA-AZATETRADECAMETHLYENEDIAMINE, ISOPHORONEDIAMINE,

DIETHYLENETRIAMINE, POLY(OXY(METHYL-1,2-ETHANEDIYL), 4,4'-
ISOPROPYLIDENEDIPHENOL

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures

3,6,9,12-TETRA-AZATETRADECAMETHLYENEDIAMINE 30-60%
CAS number: 4067-16-7 EC number: 223-775-9
M factor (Acute) = 1 M factor (Chronic) = 1

Classification Classification (67/548/EEC or 1999/45/EC)

Skin Corr. 1B - H314 C;R34. N;R50/53. R43.
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

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ISOPHORONEDIAMINE 30-60%
CAS number: 2855-13-2 EC number: 220-666-8

Classification Classification (67/548/EEC or 1999/45/EC)

Acute Tox. 4 - H302 C;R34 Xn;R21/22 R43 R52/53
Acute Tox. 4 - H312
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Aquatic Chronic 3 - H412

DIETHYLENETRIAMINE 10-30%
CAS number: 111-40-0 EC number: 203-865-4

Classification Classification (67/548/EEC or 1999/45/EC)

Acute Tox. 4 - H302 C;R34 Xn;R21/22 R43
Acute Tox. 4 - H312
Acute Tox. 1 - H330
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317

POLY(OXY(METHYL-1,2-ETHANEDIYL) 5-10%
CAS number: 9046-10-0

Classification Classification (67/548/EEC or 1999/45/EC)

Skin Corr. 1B - H314 C;R34.
Eye Dam. 1 - H318

4,4'-ISOPROPYLIDENEDIPHENOL 1-5%
CAS number: 80-05-7 EC number: 201-245-8

Classification Classification (67/548/EEC or 1999/45/EC)

Eye Dam. 1 - H318 Repr. Cat. 3;R62 Xi;R37,R41 R43 R52
Skin Sens. 1 - H317
Repr. 2 - H361f
STOT SE 3 - H335

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Get medical attention if any discomfort continues.

Inhalation Place unconscious person on their side in the recovery position and ensure breathing can
take place. Move affected person to fresh air at once. Get medical attention.

Ingestion Give plenty of water to drink. DO NOT induce vomiting. Get medical attention immediately.

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Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water. Continue to rinse
for at least 15 minutes. Get medical attention. Get medical attention if irritation persists after
washing.

Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15
minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Small fires: Foam, carbon dioxide or dry powder. Larger fires: Water spray. Foam.

5.2. Special hazards arising from the substance or mixture

Specific hazards Thermal decomposition or combustion products may include the following substances:
Corrosive gases or vapours. Ammonia or amines. Toxic gases/vapours/fumes of: Carbon.
Carbon dioxide (CO2). Carbon monoxide (CO). Hydrocarbons. Nitrous gases (NOx).

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Absorb spillage
with non-combustible, absorbent material. Collect and place in suitable waste disposal
containers and seal securely. For waste disposal, see Section 13.

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid spilling. Avoid contact with skin and eyes. Do not use in confined spaces without
adequate ventilation and/or respirator. Mechanical ventilation or local exhaust ventilation may
be required.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Keep only in the original container. Store cool. Keep away from oxidising materials, heat and
flames.

7.3. Specific end use(s)

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

Occupational exposure limits
DIETHYLENETRIAMINE
Long-term exposure limit (8-hour TWA): WEL 1 ppm 4.3 mg/m³
Sk
WEL = Workplace Exposure Limit
Sk = Can be absorbed through the skin.

8.2. Exposure controls

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Protective equipment

Appropriate engineering Provide adequate ventilation. Avoid inhalation of vapours.

controls

Eye/face protection The following protection should be worn: Chemical splash goggles.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. Nitrile rubber.

Other skin and body Wear appropriate clothing to prevent reasonably probable skin contact.
protection

Hygiene measures Do not smoke in work area. Contaminated clothing should be placed in a closed container for
disposal or decontamination. When using do not eat, drink or smoke.

Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn. Wear a respirator
fitted with the following cartridge: Gas filter, type K.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Clear, yellowish liquid.

Odour Fishy.

Initial boiling point and range > 200 C°C @

Flash point > 95°C CC (Closed cup).

Vapour pressure < 4 hPa @ °C

Relative density 0.98 @ 25°C

Solubility(ies) Slightly soluble in water.

Viscosity 0.5 @ °C

9.2. Other information

SECTION 10: Stability and reactivity

10.1. Reactivity
10.2. Chemical stability
Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid
Conditions to avoid Avoid contact with the following materials: Acids. Oxidising agents.

10.5. Incompatible materials

10.6. Hazardous decomposition products
SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 1,172.1

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Acute toxicity - dermal

ATE dermal (mg/kg) 2,267.66

Acute toxicity - inhalation

ATE inhalation (vapours mg/l) 2.8

Inhalation May cause respiratory system irritation.

Ingestion May cause stomach pain or vomiting. May cause internal injury. Diarrhoea. Gastrointestinal
symptoms, including upset stomach. May cause burns in mucous membranes, throat,
oesophagus and stomach.

Skin contact Causes burns. Product has a defatting effect on skin. Irritating to skin. May cause
sensitisation by skin contact.

Eye contact Vapour exposure may cause delayed corneal epithelial oedema and visual disturbances
(haloes around lights). Conjunctivitis and lacrimation. May cause chemical eye burns. Risk of
serious damage to eyes.

Acute and chronic health This product is corrosive. Possible risk of adverse reproductive effects.
hazards

SECTION 12: Ecological Information

Ecotoxicity Dangerous for the environment. May cause long-term adverse effects in the aquatic
environment.

12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 2735

UN No. (IMDG) 2735

UN No. (ICAO) 2735

14.2. UN proper shipping name

Proper shipping name POLYAMINE LIQUID CORROSIVE NO'S
(ADR/RID)

Proper shipping name POLYAMINE LIQUID CORROSIVE NO'S

(IMDG)

Proper shipping name (ICAO) POLYAMINE LIQUID CORROSIVE NO'S

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Proper shipping name (ADN) POLYAMINE LIQUID CORROSIVE NO'S

14.3. Transport hazard class(es)

ADR/RID class 8

IMDG class 8

ICAO class/division 8

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

ICAO packing group III

14.5. Environmental hazards

14.6. Special precautions for user
IMDG Code segregation 18. Alkalis
group

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Health and Safety at Work etc. Act 1974 (as amended).
The Control of Substances Hazardous to Health Regulations 2002 (SI 2002 No. 2677) (as
amended).
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009
No. 716).

EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).

Guidance Workplace Exposure Limits EH40.

CHIP for everyone HSG228.
Safety Data Sheets for Substances and Preparations.

15.2. Chemical safety assessment

SECTION 16: Other information

Revision date 26/06/2015

Revision 16

Supersedes date 11/06/2015

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Risk phrases in full R21/22 Harmful in contact with skin and if swallowed.
R34 Causes burns.
R37 Irritating to respiratory system.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R52 Harmful to aquatic organisms.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R62 Possible risk of impaired fertility.

Hazard statements in full H302 Harmful if swallowed.

H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H361f Suspected of damaging fertility.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

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