Jeyes Safety Data Sheet

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Revision Date 04/03/2014 Revision 2 - 27/11/2013

Revision 2 - 27/11/2013

SAFETY DATA SHEET


Jeyes Fluid

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier


Product name Jeyes Fluid
Product No. 2004907
Internal Id 00018449 (11 - 30/10/2013)
Container size 300 ml

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Outdoor Cleaner

1.3. Details of the supplier of the safety data sheet


Supplier Jeyes Ltd
Brunel Way
Thetford
Norfolk
IP24 1HF
UK
+44 1842 757575
Contact: Rowland Furse / Simon Burt
Email: [email protected]

1.4. Emergency telephone number


+44 1842 757575

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture


Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Acute Tox. 4 - H302;Acute Tox. 4 - H312;Eye Dam. 1 - H318;Skin Sens. 1 -
H317
Environment Not classified.
Classification (1999/45/EEC) Xn;R21/22. Xi;R38, R41. R43.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Human health
Harmful if swallowed. Harmful in contact with skin. May cause an allergic skin reaction. Causes serious eye damage.

2.2. Label elements


Contains 4-CHLORO-M-CRESOL
CRESOL -meta
CRESOL -para

Label In Accordance With (EC) No. 1272/2008

Signal Word Danger


Hazard Statements
H302 Harmful if swallowed.

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H312 Harmful in contact with skin.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
Precautionary Statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P280 Wear protective gloves.
Wear eye protection.
P332 If skin irritation occurs:
P313 Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.
Supplementary Precautionary Statements
P301+312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel
unwell.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.

2.3. Other hazards


Not applicable.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

Fatty acids, Castor oil, Sodium salts 10-30%

CAS-No.: 8013-05-6 EC No.: 232-388-4

Classification (EC 1272/2008) Classification (67/548/EEC)


Skin Irrit. 2 - H315 Xi;R36/38.
Eye Irrit. 2 - H319

4-CHLORO-M-CRESOL 5-10%

CAS-No.: 59-50-7 EC No.: 200-431-6

Classification (EC 1272/2008) Classification (67/548/EEC)


Acute Tox. 4 - H302 Xn;R21/22
Acute Tox. 4 - H312 R43
Eye Dam. 1 - H318 Xi;R41
Skin Sens. 1 - H317 N;R50
Aquatic Acute 1 - H400

Terpineol 1-5%

CAS-No.: 8000-41-7 EC No.: 232-268-1

Classification (EC 1272/2008) Classification (67/548/EEC)


Flam. Liq. 4 - H227 Xi;R36/38.
Acute Tox. 5 - H303
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Aquatic Acute 3 - H402

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CRESOL -meta 1-5%

CAS-No.: 108-39-4 EC No.: 203-577-9

Classification (EC 1272/2008) Classification (67/548/EEC)


Acute Tox. 3 - H301 T;R24/25
Acute Tox. 3 - H311 C;R34
Skin Corr. 1B - H314

CRESOL -para 1-5%

CAS-No.: 106-44-5 EC No.: 203-398-6

Classification (EC 1272/2008) Classification (67/548/EEC)


Acute Tox. 3 - H301 T;R24/25
Acute Tox. 3 - H311 C;R34
Skin Corr. 1B - H314

3,4-XYLENOL < 1%

CAS-No.: 95-65-8 EC No.: 202-439-5

Classification (EC 1272/2008) Classification (67/548/EEC)


Acute Tox. 3 - H301 T;R24/25
Acute Tox. 3 - H311 C;R34
Skin Corr. 1B - H314 N;R51/53
Aquatic Chronic 2 - H411

3,5-XYLENOL < 1%

CAS-No.: 108-68-9 EC No.: 203-606-5

Classification (EC 1272/2008) Classification (67/548/EEC)


Acute Tox. 3 - H301 T;R24/25
Acute Tox. 3 - H311 C;R34
Skin Corr. 1B - H314

2,5-XYLENOL < 1%

CAS-No.: 95-87-4 EC No.: 202-461-5

Classification (EC 1272/2008) Classification (67/548/EEC)


Acute Tox. 3 - H301 T;R24/25
Acute Tox. 3 - H311 C;R34
Skin Corr. 1B - H314 N;R51/53
Aquatic Chronic 2 - H411

2,4-XYLENOL < 1%

CAS-No.: 105-67-9 EC No.: 203-321-6

Classification (EC 1272/2008) Classification (67/548/EEC)


Acute Tox. 3 - H301 T;R24/25
Acute Tox. 3 - H311 C;R34
Skin Corr. 1B - H314 N;R51/53
Aquatic Chronic 2 - H411

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2,6-XYLENOL < 1%

CAS-No.: 576-26-1 EC No.: 209-400-1

Classification (EC 1272/2008) Classification (67/548/EEC)


Acute Tox. 3 - H301 T;R24/25
Acute Tox. 3 - H311 C;R34
Skin Corr. 1B - H314 N;R51/53
Aquatic Chronic 2 - H411

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures


Inhalation
General first aid, rest, warmth and fresh air.
Ingestion
Immediately rinse mouth and provide fresh air. Do not induce vomiting. NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK
FLUIDS! Consult a physician for specific advice.
Skin contact
Remove contaminated clothing. Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing.
Eye contact
Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any
discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation
No specific symptoms noted.
Ingestion
Harmful if swallowed.
Skin contact
Harmful in contact with skin. Skin irritation. May cause an allergic skin reaction.
Eye contact
Causes serious eye damage.

4.3. Indication of any immediate medical attention and special treatment needed
No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in
doubt, GET MEDICAL ATTENTION PROMPTLY!

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media


Extinguishing media
Extinguish with foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media appropriate for surrounding materials.

5.2. Special hazards arising from the substance or mixture


Hazardous combustion products
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
Unusual Fire & Explosion Hazards
None known.
Specific hazards
The product is non-combustible. If heated, toxic vapours may be formed.

5.3. Advice for firefighters


Special Fire Fighting Procedures
Use protective equipment appropriate for surrounding materials.

SECTION 6: ACCIDENTAL RELEASE MEASURES

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6.1. Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes. For personal protection, see section 8.

6.2. Environmental precautions


Collect and dispose of spillage as indicated in section 13.

6.3. Methods and material for containment and cleaning up


Wear necessary protective equipment. Absorb with sand or other inert absorbent. For waste disposal, see section 13.

6.4. Reference to other sections


For personal protection, see section 8. For waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling


Read label before use.

7.2. Conditions for safe storage, including any incompatibilities


Keep away from food, drink and animal feeding stuffs. Store in closed original container at temperatures between 5°C and 25°C.
Storage Class
Lagerklasse 12

7.3. Specific end use(s)


The identified uses for this product are detailed in Section 1.2.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Ingredient Comments
No exposure limits noted for ingredient(s).

8.2. Exposure controls


Respiratory equipment
Use only outdoors or in a well-ventilated area.
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Rubber gloves are recommended.
Eye protection
Wear approved, tight fitting safety glasses where splashing is probable.
Hygiene measures
Wash hands after handling.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties


Appearance Liquid
Colour Dark. Brown.
Odour Tar acid.
Solubility Forms an emulsion with water.
Initial boiling point and boiling range ca. 100°C 760 mm Hg
(°C)
Melting point (°C) ca. 0°C
Relative density ca. 1.042 @ 20°C
Vapour density (air=1)
Not applicable.
Vapour pressure
Not applicable.
Evaporation rate
Not applicable.
pH-Value, Conc. Solution 8.0 - 10.0

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Viscosity 40 - 60 cP @ 20°C
Decomposition temperature (°C)
Not applicable.
Odour Threshold, Lower
Not applicable.
Odour Threshold, Upper
Not applicable.
Flash point (°C) > 61°C CC (Closed cup).
Auto Ignition Temperature (°C)
Not applicable.
Flammability Limit - Lower(%)
Not applicable.
Flammability Limit - Upper(%)
Not applicable.
Partition Coefficient
(N-Octanol/Water)
Not determined.
Explosive properties
Not applicable.
Other Flammability
Not applicable.
Oxidising properties
Not applicable.

9.2. Other information


Not available.

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity
There are no known reactivity hazards associated with this product.

10.2. Chemical stability


Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions


There are no known reactivity hazards associated with this product.

10.4. Conditions to avoid


Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials


Materials To Avoid
No specific, or groups of materials are likely to react to produce a hazardous situation.

10.6. Hazardous decomposition products


None under normal conditions.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Inhalation
No specific health warnings noted.

Ingestion
Harmful if swallowed.

Skin contact
Harmful in contact with skin. Irritating to skin. May cause sensitisation by skin contact.

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Eye contact
Causes serious eye damage.
Route of entry
Skin and/or eye contact.

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity
The product is not expected to be toxic to aquatic organisms.

12.1. Toxicity
Acute Fish Toxicity
Not considered toxic to fish.

12.2. Persistence and degradability


Degradability
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and
will be made available to them, at their direct request or at the request of a detergent manufacturer.

12.3. Bioaccumulative potential


Bioaccumulative potential
No data available on bioaccumulation.
Partition coefficient
Not determined.

12.4. Mobility in soil


Mobility:
Forms an emulsion with water.

12.5. Results of PBT and vPvB assessment


This product does not contain any PBT or vPvB substances.

12.6. Other adverse effects


None known.

SECTION 13: DISPOSAL CONSIDERATIONS

General information
When handling waste, consideration should be made to the safety precautions applying to handling of the product.

13.1. Waste treatment methods


Dispose of waste and residues in accordance with local authority requirements.

SECTION 14: TRANSPORT INFORMATION

General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

Not applicable.

14.4. Packing group

Not applicable.

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14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant


No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC)
No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of
substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
with amendments.
Authorisations (Title VII Regulation 1907/2006)
No specific authorisations are noted for this product.
Restrictions (Title VIII Regulation 1907/2006)
No specific restrictions of use are noted for this product.

15.2. Chemical Safety Assessment


No chemical safety assessment has been carried out.

SECTION 16: OTHER INFORMATION

Revision Comments
Change to CLP classification
Issued By Rowland Furse / Simon Burt
Revision Date 04/03/2014
Revision 2 - 27/11/2013
Risk Phrases In Full
R21/22 Harmful in contact with skin and if swallowed. , R24/25 Toxic in contact with skin and if
swallowed. , R34 Causes burns. , R36/38 Irritating to eyes and skin. , R38 Irritating to skin. , R41 Risk
of serious damage to eyes. , R43 May cause sensitisation by skin contact. , R50 Very toxic to aquatic
organisms. , R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Hazard Statements In Full
H227 Combustible liquid. , H301 Toxic if swallowed. , H302 Harmful if swallowed. , H303 May be
harmful if swallowed. , H311 Toxic in contact with skin. , H312 Harmful in contact with skin. , H314
Causes severe skin burns and eye damage. , H315 Causes skin irritation. , H317 May cause an allergic
skin reaction. , H318 Causes serious eye damage. , H319 Causes serious eye irritation. , H400 Very
toxic to aquatic life. , H402 Harmful to aquatic life. , H411 Toxic to aquatic life with long lasting effects.

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