Electrochemistry

(1+2+5=8)
For: PU Boards

(1 MARK)
1. What is a secondary cell? (2014,2020)
2. Write the S.I. unit of molar conductivity. (2014s)
3. What happens to molar conductivity when one mole of KCL dissolved in one liter is diluted
to five liters? (2015)
3+
4. How many Coulombs of electricity required to oxidize one mole of Al to Al ? (2015s)
5. Which gas is evolved at cathode during the electrolysis of an aqueous solution of NaCl?
(2016)
6. Write the Nernst equation for Daniel cell. (2016s)
7. Write the mathematical expression for limiting molar conductivity of sodium chloride
[NaCl]. (2017)
8. Write the anodic reaction taking place at H2 – O2 fuel cell. (2017s)
9. How many Faraday of electricity is required to reduce 1 mole of [MnO4] ions to
Mn2+ ions? (2018)
10. Why does the conductivity of a solution decrease with dilution? (2018s)
11. State Faradays first law of electrolysis. (2019s)
12. The resistance of a conductivity cell containing 0.001M KCl solution at 298K is 1500Ω.
What is the cell constant if conductivity of 0.001M KCl solution at 298K
is 0.146 x 10-3 Scm-1?. (2021m)
13. Define molar conductivity. (2021m)
(2 MARKS)
1. What is molar conductivity? How is it related to the conductivity of a solution whose
concentration is Cmolm-3? (2014)
2. What is Corrosion? Name one method to prevent it. (2014s)
3. State Faradays first law of electrolysis. For the electrode reaction Zn2++2e- Zn(s), What
quantity of electricity in coulombs required to deposit one mole of zinc. (2015)
4. State :
i) Kohlrausch’s law
ii) Faraday first law of electrolysis (2015s)
5. What is a secondary cell? Write the equation for the cathodic reaction of lead storage battery.
(2016s)
6. Write the cathodic and anodic cell reactors of Hydrogen-Oxygen fuel cell. (2017)
7. Draw a neat diagram of H2 – O2 fuel cell.
Write the reaction occurs at cathode of the cell. (2018,2018s)
0 2
8. 𝜆 m for Nacl, HCl and CH3COONa are 126.4, 425.9 and 91.0 S cm /mol respectively.
Calculate 𝜆0m for CH3COOH. (2017s)
9. State Faraday’s second law of electrolysis (2019)
10. Draw a neat labelled diagram of Standard Hydrogen Electrode (SHE).
Write its Half-Cell reaction. (2019s)
11. A solution of Ni(NO3)2 is electrolyzed between platinum electrodes using a current of 5
amperes for 20 minutes. What mass of nickel is deposited at the cathode? [molar mass of Ni =
58.7 gram mol-1] (2020)
12. Write the overall cell reaction during the working of Daniel cell. (2021m)
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 Electrochemistry
(1+2+5=8)
For: PU Boards

13. Mention any two factors that determines the products of electrolysis (2021m)
(5 MARKS)

1. a) Draw labelled diagram of Standard Hydrogen Electrode (SHE). Write its half-cell reaction
and E0 value.
b) Calculate ∆rG- for the following reaction:
Fe+2(aq) + Ag+(aq) Fe+3(aq)+Ag(s)
0
(Given: E cell=+0.03 V, F=96500C). (2014)
2. a) Describe the construction and working of standard hydrogen electrode.
b) State Faraday’s Second Law of Electrolysis. (2014s)
3. a) Calculate the EMF of the cell for the reaction
Mg(s)+2Ag+(aq) → Mg 2+(aq)+2Ag(s)
Given: E0(Mg2+/Mg)= -2.37V & E0(Ag+/Ag = 0.80V)
[Mg2+]= 0.001M; [Ag+] = 0.0001M
Log 105=5, F = 96487 C mol-1
b) What are fuel cells? (2015)
4. a) Draw the neat labelled diagram of Standard Hydrogen Electrode (SHE) and write its
symbolic representation.
b) Calculate the emf of the cell in which the following reaction takes place
Ni(s) + 2Ag+ (0.002m) → Ni2+(0.160M)+2Ag(s)
[Given E0cell= 1.05V] (2015s)
5. a) State faraday’s first law of electrolysis write its mathematical from using usual notations.
b) State Kohlrausch law
c) Write the overall cell reaction taking place in Daniel cell (2016)
6. a) Find the value of ∆G0 at 250C for the following electrochemical cell.
Cu|Cu2+ (1 M)||Ag+(1M)|Ag
[E0Cu=+0.34V, E0Ag=+0.8V]
F=96487 C (2016s)
b) Write the equations of anodic and cathodic reaction occur during rusting of iron.
7. a) The electrode potential for the Daniel cell given below is 1.1V.
Zn(s)|Zn2+(aq) || Cu 2+(aq)|Cu(s)
Write overall cell reaction and calculate the standard Gibb’s energy for the reaction.
[F = 96487 c/mol]
b) Mention any two factors which affects the conductivity of electrolytic solution. (2017)
8. a) Calculate the equilibrium constant for the reaction
Cu(s) + 2Ag+(aq) → Cu+2(aq) + 2Ag(s); E+cell = 0.46 V
b) Write half-cell reaction and E+ value of (SHE) standard hydrogen electrode. (2017s)
9. a) Calculate the EMF of the cell for the reaction
Mg(s) + Cu2+(0.0001M) → Mg 2+(0.001M)+Cu(s)
Given that: E0 (Mg2+/Mg)= -2.37V
E0 (Cu2+/Cu) = +0.34V
b) i) State Kohlrausch law.
ii) What is meant by limiting molar conductance (2018)

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 Electrochemistry
(1+2+5=8)
For: PU Boards

10. a) Calculate emf of the cell in which the following reaction takes place:
Ni(s) + 2Ag+(aq) → Ni2+(aq) + 2Ag(s)
(0.002 M) (0.160 M)

Given : Ecell = 1.05 V

b) State the Faraday’s first law of electrolysis. How many Faraday of electricity is required
for the reduction of 1 mole of Mg2+ ions? (2018s)
11. a) Write the equations for the reactions taking place at anode and cathode in the Lead-storage
battery.
b) Calculate the value of ∆rG0 at 298 K for the cell reaction.
Mg(s)+2Ag+(aq) → Mg 2+(aq)+2Ag(s)
0 0
[Given : 𝐸𝑀𝑔 = -2.36 V, 𝐸𝐴𝑙 = -1.66 V and F = 96487 C]. (2019)
0 0
12. a) For a given data: 𝐸𝑀𝑔2+ /𝑀𝑔 = −2.37𝑉, 𝐸𝐶𝑢2+/𝐶𝑢 = +0.34 V
calculate the emf of the cell in which the following reaction takes place.
Mg(s) + Cu2+(0.0001M) → Mg 2+(0.001M)+Cu(s)
b) State Kohlrausch law of independent migration of ions.
c) Write the overall cell reaction in mercury cell. (2019s)
13. a) Calculate the e.m.f of the coil in which the following reaction takes place. [3]
+ 2+
Ni + 2A𝑔0.002𝑀 → N𝑖0.160𝑀 + 2Ag(s) Given E0cell = 1.05 V
b) i) State Kohlrausch’s law of independence migration of ions [1]
ii) What is meant by limiting molar conductivity? [1] (2020)
14. a) The standard electrode potential for Daniel cell is 1.1V. Calculate the standard Gibbs
energy change for the reaction;
Zn(s)+2Cu+2(aq) → Zn 2+(aq)+Cu(s)
b) Write any two factors affecting ionic conductance. (2021m)
15. a) Calculate the EMF of the cell for the reaction
Mg(s)+2Ag+(aq) → Mg 2+(aq)+2Ag(s)
Given: E0(Mg2+/Mg)= -2.37V & E0(Ag+/Ag = 0.80V)
[Mg2+]= 0.001M; [Ag+] = 0.0001M
Log 105=5, F = 96487 C mol-1
b) What is limiting molar conductivity? Represent graphically the variation of molar
conductivity with concentration of acetic acid. (2021m)

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