Ques 2
Ques 2
Ques 2
(may
be one can think of doing this by keeping the what will be
the final pressure? Given the volumetric expansion coefficient of cooper as 4.95x
10- 5
K
-
1
and isothermal compressibility is 7x10- 12 Pa-1
.
2) Calculate the work in compressing quasi-statically, isothermally 32 gms of
oxygen at
298K from 1 atm to 1000 atms. Assume ideal gas behaviour.
Suppose the pressure on 32 g of copper is increased quasi-statically and
isothermally at
298K from 1 to 1000 atm, estimate the work done. Given the density of copper is
8960
kgm-
³ and isothermal compressibility of copper is 7.0x10-12 Pa-1
.
3) A constant volume gas thermometer of volume 1x10- 3 m
3
contains 0.05 mol of a gas. It
is assumed that the gas obeys the perfect gas law, pVm = RT ; where Vm is the
volume
per 1 mol of gas ; but, in fact, its behavior is better described by the equation
2
)(Vm - b) = RT
wher
¹ is called the gas
constant. The thermometer is calibrated at the triple point of water. By how much
will
1) If a block of copper at 1 atm and temperature 298K is heated at constant volume
(may
be one can think of doing this by keeping the copper block tightly in a container
made
from a material which has very low thermal expansion coefficient) to 308K, what
will be
the final pressure? Given the volumetric expansion coefficient of cooper as 4.95x
10- 5
K
-
1
and isothermal compressibility is 7x10- 12 Pa-1
.
2) Calculate the work in compressing quasi-statically, isothermally 32 gms of
oxygen at
298K from 1 atm to 1000 atms. Assume ideal gas behaviour.
Suppose the pressure on 32 g of copper is increased quasi-statically and
isothermally at
298K from 1 to 1000 atm, estimate the work done. Given the density of copper is
8960
kgm-
³ and isothermal compressibility of copper is 7.0x10-12 Pa-1
.
3) A constant volume gas thermometer of volume 1) If a block of copper at 1 atm and
temperature 298K is heated at constant volume (may
be one can think of doing this by keeping the copper block tightly in a container
made
from a material which has very low thermal expansion coefficient) to 308K, what
will be
the final pressure? Given the volumetric expansion coefficient of cooper as 4.95x
10- 5
K
-
1
and isothermal compressibility is 7x10- 12 Pa-1
.
2) Calculate the work in compressing quasi-statically, isothermally 32 gms of
oxygen at
298K from 1 atm to 1000 atms. Assume ideal gas behaviour.
Suppose the pressure on 32 g of copper is increased quasi-statically and
isothermally at
298K from 1 to 1000 atm, estimate the work done. Given the density of copper is
8960
kgm-
³ and isothermal compressibility of copper is 7.0x10-12 Pa-1
.
3) A constant volume gas thermometer of volume 1x10- 3 m
3
contains 0.05 mol of a gas. It
is assumed that the gas obeys the perfect gas law, pVm = RT ; where Vm is the
volume
per 1 mol of gas ; but, in fact, its behavior is better described by the equation
(p + a / Vm
2
)(Vm - b) = RT
where a = 8 N m4 mol-2
and b = 3 x 10-5 m³ mol-
¹. R≈ 8.31 m³ Pa K-
¹ mol-
¹ is called the gas
constant. The thermometer is calibrated at the triple point of water. By how much
will
temperature measurements be in error at 100 °C1) If a block of copper at 1 atm and
temperature 298K is heated at constant volume (may
be one can think of doing this by keeping the copper block tightly in a container
made
from a material which has very low thermal expansion coefficient) to 308K, what
will be
the final pressure? Given the volumetric expansion coefficient of cooper as 4.95x
10- 5
K
-
1
and isothermal compressibility is 7x10- 12 Pa-1
.
2) Calculate the work in compressing quasi-statically, isothermally 32 gms of
oxygen at
298K from 1 atm to 1000 atms. Assume ideal gas behaviour.
Suppose the pressure on 32 g of copper is increased quasi-statically and
isothermally at
298K from 1 to 1000 atm, estimate the work done. Given the density of copper is
8960
kgm-
³ and isothermal compressibility of copper is 7.0x10-12 Pa-1
.
3) A constant volume gas thermometer of volume 1x10- 3 m
3
contains 0.05 mol of a gas. It
is assumed that the gas obeys the perfect gas law, pVm = RT ; where Vm is the
volume
per 1 mol of gas ; but, in fact, its behavior is better described by the equation
(p + a / Vm
2
)(Vm - b) = RT
where a = 8 N m4 mol-2
and b = 3 x 10-5 m³ mol-
¹. R≈ 8.31 m³ Pa K-
¹ mol-
¹ is called the gas
constant. The thermometer is calibrated at the triple point of water. By how much
will
temperature measurements be in error at 100 °C1x10- 3 m
3
contains 0.05 mol of a gas. It
is assumed that the gas obeys the perfect gas law, pVm = RT ; where Vm is the
volume
per 1 mol of gas ; but, in fact, its behavior is better described by the equation
(p + a / Vm
2
)(Vm - b) = RT
where a = 8 N m4 mol-2
and b = 3 x 10-5 m³ mol-
¹. R≈ 8.31 m³ Pa K-
¹ mol-
¹ is called the gas
constant. The thermometer is calibrated at the triple point of water. By how much
will
temperature measurements be in error at 100 °C
temperature measurements be in error at 100 °C