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    10 ExoSuppl

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    Eduardo Calderon
    APPLIED THERMODYNAMICS

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    10 ExoSuppl

    Uploaded by

    Eduardo Calderon
    24 views6 pages
    APPLIED THERMODYNAMICS

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    APPLIED THERMODYNAMICS

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    24 views6 pages

    10 ExoSuppl

    Uploaded by

    Eduardo Calderon
    APPLIED THERMODYNAMICS

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 6

    Refining-Petrochemicals-Chemicals-Engineering

    ———

    APPLIED THERMODYNAMICS

    — Additional exercises —

    EXERCISE 1

    Thermodynamic diagrams
    Law of perfect gases
    Law of corresponding states

    EXERCISE 2
    Law of corresponding states
    Equation of state

    EXERCISE 3
    Bubble point temperature calculation

    EXERCISE 4

    Equilibrium diagram of the iC4 -nC 4 mixture at 5 abs atm.

    EXERCISE 5
    Equilibrium diagram of a n-hexane-water mixture at 1 abs atm.

    BA ELV - 00185_A_A - Rev. 1 09/07/2007

    „ 2007 ENSPM Formation Industrie - IFP Training


    1

    Exercise 1
    1 - A boiler produces saturated steam at 280°C..

    a - What is the steam pressure?

    b - What is its enthalpy?

    2 - The steam is superheated up to 430°C. The pressure at the boiler outlet is 4 atm less than in the
    drum.

    a - What is the superheated steam enthalpy?

    b - What is the average specific heat of steam between 280°C and 430°C?

    c - What is the density of the steam in the outlet conditions:

    • by the law of perfect gas


    • by plate C 6
    • by the law of corresponding states

    Exercise 2

    What is the compressibility factor of the gas whose composition is given below, at 19 abs atm. and
    42°C?

    1 - By the law corresponding states

    2 - By Redlich Kwong equation of state

    H2 C1 C2 C3 nC4 nC5

    % mol 72 12 6 5 3 2 100

    00185_A_A © 2007 ENSPM Formation Industrie - IFP Training


    2

    Exercise 3
    Calculate the bubble point temperature of the following mixture at 17 abs atm.

    C2 C3 iC4 nC4 nC5

    % mol 4 25 30 40 1 100

    Exercise 4

    – Calculate and draw the isobaric equilibrium diagram for the isobutane–n-butane binary mixture at 5
    abs atm (use the Scheibel and Jenny K values).

    – Conclusion about the iC4 -nC 4 separation ?

    (See on page 3)

    Exercise 5

    Draw the isobaric equilibrium diagram for the n-hexane-water binary mixture under atmospheric
    pressure.

    (See on pages 4 and 5).

    00185_A_A © 2007 ENSPM Formation Industrie - IFP Training


    3

    D TH 1167 C

    00185_A_A © 2007 ENSPM Formation Industrie - IFP Training


    4

    Vapor pressure curves


    — WATER and n-HEXANE —

    2.8 2.8
    Vapor pressure (atm.abs.)

    Vapor pressure (atm.abs.)


    2.6 2.6

    2.4 2.4

    2.2 2.2

    2.0 2.0

    1.8 1.8

    1.6 1.6

    1.4 1.4

    1.2 1.2

    1.0 1.0

    0.8 0.8
    e
    an
    ex
    n-h

    0.6 0.6

    0.4 ter 0.4


    Wa

    0.2 0.2
    D TH 1167 B

    Temperature (°C)
    0 0
    0 10 20 30 40 50 60 70 80 90 100

    00185_A_A © 2007 ENSPM Formation Industrie - IFP Training


    5

    D TH 1167 C

    00185_A_A © 2007 ENSPM Formation Industrie - IFP Training

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