Formaldehyde, 37% w/w

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 11/15/2013 Revision date: 05/16/2018 Supersedes: 06/09/2015 Version: 2.1

SECTION 1: Identification
1.1. Identification
Product form : Substance
Substance name : Formaldehyde, 37% w/w
CAS-No. : 50-00-0
Product code : LC14650
Formula : CH2O
Synonyms : formic aldehyde, 37% / formol, 37% / methanal, 37% / methyl aldehyde, 37% / methylene
glycol, 37% / methylene oxide, 37% / oxomethane, 37% / oxomethylene, 37% / paraform, 37% /
tetraoxymethylene, 37%
1.2. Recommended use and restrictions on use
Use of the substance/mixture : Chemical intermediate
Disinfectant
Laboratory chemical
Recommended use : Laboratory chemicals
Restrictions on use : Not for food, drug or household use
1.3. Supplier
LabChem Inc
Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
[email protected] - www.labchem.com

1.4. Emergency telephone number

Emergency number : CHEMTREC: 1-800-424-9300 or +1-703-741-5970

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids H226 Flammable liquid and vapour
Category 3
Acute toxicity (oral) H302 Harmful if swallowed
Category 4
Acute toxicity (dermal) H312 Harmful in contact with skin
Category 4
Acute toxicity H330 Fatal if inhaled
(inhalation:vapour)
Category 2
Skin corrosion/irritation H314 Causes severe skin burns and eye damage
Category 1C
Serious eye damage/eye H318 Causes serious eye damage
irritation Category 1
Carcinogenicity Category H350 May cause cancer (Inhalation)
1A
Specific target organ H370 Causes damage to organs (central nervous system, optic nerve, respiratory system)
toxicity (single exposure)
Category 1
Hazardous to the aquatic H401 Toxic to aquatic life
environment - Acute
Hazard Category 2
Full text of H statements : see section 16

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Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

2.2. GHS Label elements, including precautionary statements

GHS-US labeling
Hazard pictograms (GHS-US) :

GHS02 GHS05 GHS06 GHS08

Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 - Flammable liquid and vapour
H302+H312 - Harmful if swallowed or in contact with skin
H314 - Causes severe skin burns and eye damage
H330 - Fatal if inhaled
H350 - May cause cancer (Inhalation)
H370 - Causes damage to organs (central nervous system, optic nerve, respiratory system)
H401 - Toxic to aquatic life
Precautionary statements (GHS-US) : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical, lighting, ventilating equipment
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P260 - Do not breathe mist, vapors, spray.
P264 - Wash exposed skin thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective clothing, protective gloves, eye protection, face protection.
P284 - Wear respiratory protection.
P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a poison center or doctor/physician.
P363 - Wash contaminated clothing before reuse.
P403+P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/container to comply with local, state and federal regulations
If inhaled: Remove person to fresh air and keep comfortable for breathing
2.3. Other hazards which do not result in classification
Other hazards not contributing to the : None under normal conditions.
classification
2.4. Unknown acute toxicity (GHS US)
Not applicable

SECTION 3: Composition/Information on ingredients

3.1. Substances
Substance type : Multi-constituent
Name : Formaldehyde, 37% w/w
CAS-No. : 50-00-0
Name Product identifier % GHS-US classification
Water (CAS-No.) 7732-18-5 48 - 53 Not classified
Formaldehyde (CAS-No.) 50-00-0 37 Acute Tox. 1 (Inhalation:gas),
H330
Carc. 1A, H350
Methanol (CAS-No.) 67-56-1 10 - 15 Flam. Liq. 2, H225
Acute Tox. 3 (Oral), H301
Acute Tox. 3 (Dermal), H311
Acute Tox. 3 (Inhalation), H331
STOT SE 1, H370

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Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Full text of hazard classes and H-statements : see section 16

3.2. Mixtures
Not applicable
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory
arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious
with labored breathing: half-seated. Victim in shock: on his back with legs slightly raised.
Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no
warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid
physical strain. Depending on the victim's condition: doctor/hospital.
First-aid measures after inhalation : Remove the victim into fresh air. Immediately consult a doctor/medical service.
First-aid measures after skin contact : Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing
agents. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover
wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take
victim to hospital.
First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Do not apply neutralizing agents. Take victim to an
ophthalmologist.
First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce
vomiting. Immediately consult a doctor/medical service. Call Poison Information Centre
(www.big.be/antigif.htm). Ingestion of large quantities: immediately to hospital. Take the
container/vomit to the doctor/hospital. Do not give chemical antidote. Doctor: gastric lavage.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects : Not expected to present a significant hazard under anticipated conditions of normal use.
Symptoms/effects after inhalation : Runny nose. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous
membranes. EXPOSURE TO HIGH CONCENTRATIONS: Possible oedema of the upper
respiratory tract. Possible laryngeal spasm/oedema. Respiratory difficulties. Risk of lung
edema.
Symptoms/effects after skin contact : Caustic burns/corrosion of the skin.
Symptoms/effects after eye contact : Corrosion of the eye tissue.
Symptoms/effects after ingestion : Nausea. Vomiting. Diarrhoea. AFTER ABSORPTION OF LARGE QUANTITIES: Central
nervous system depression. Dizziness. Blood in vomit. Blood in stool. Shock. Disturbances of
consciousness. Change in the blood composition. Change in urine composition. Urine
discolouration.
Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Dry skin. Skin
rash/inflammation. Coughing. Possible inflammation of the respiratory tract. Respiratory
difficulties.
4.3. Immediate medical attention and special treatment, if necessary
Obtain medical assistance.

SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Quick-acting ABC powder extinguisher. Quick-acting BC powder extinguisher. Quick-acting
class B foam extinguisher. Quick-acting CO2 extinguisher. Class B foam (alcohol-resistant).
Water spray if puddle cannot expand.
Unsuitable extinguishing media : Water (quick-acting extinguisher, reel); risk of puddle expansion. Water; risk of puddle
expansion.
5.2. Specific hazards arising from the chemical
Fire hazard : DIRECT FIRE HAZARD. Material presenting a fire hazard. INDIRECT FIRE HAZARD.
Temperature above flashpoint: higher fire/explosion hazard. Reactions involving a fire hazard:
see "Reactivity Hazard".
Explosion hazard : INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard".
Reactivity : Reacts violently with many compounds e.g.: with (strong) oxidizers: (increased) risk of
fire/explosion. Reacts with (some) acids: release of (highly) toxic compounds. Unstabilized
product polymerizes.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to
heat. Take account of toxic fire-fighting water. Use water moderately and if possible collect or
contain it.
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Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Gas-tight suit. Corrosion-proof suit.
Emergency procedures : Keep upwind. Mark the danger area. Consider evacuation. Close doors and windows of
adjacent premises. No naked flames. Keep containers closed. Wash contaminated clothes.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection. Do not breathe gas, fumes, vapor or spray.
Emergency procedures : If a major spill occurs, all personnel should be immediately evacuated and the area ventilated.
Ventilate area. Stop leak if safe to do so.
6.2. Environmental precautions
Prevent soil and water pollution. Prevent spreading in sewers.
6.3. Methods and material for containment and cleaning up
For containment : Contain released substance, pump into suitable containers. Plug the leak, cut off the supply.
Dam up the liquid spill. Try to reduce evaporation. Dilute toxic gases/vapours with water spray.
Take account of toxic/corrosive precipitation water.
Methods for cleaning up : Take up liquid spill into absorbent material, e.g.: dry sand/earth/vermiculite. Scoop absorbed
substance into closing containers. Carefully collect the spill/leftovers. Damaged/cooled tanks
must be emptied. Clean contaminated surfaces with an excess of water. Take collected spill to
manufacturer/competent authority. Wash clothing and equipment after handling.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Use earthed equipment. Keep away from naked flames/heat. At temperature > flashpoint: use
spark-/explosionproof appliances. In finely divided state: use spark-/explosionproof appliances.
Finely divided: keep away from ignition sources/sparks. Measure the concentration in the air
regularly. Carry operations in the open/under local exhaust/ventilation or with respiratory
protection. Exhaust gas must be neutralised. Comply with the legal requirements. Remove
contaminated clothing immediately. Clean contaminated clothing. Keep the substance free from
contamination. Thoroughly clean/dry the installation before use. Do not discharge the waste
into the drain.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with
mild soap and water before eating, drinking or smoking and when leaving work. Wash
contaminated clothing before reuse. Contaminated work clothing should not be allowed out of
the workplace.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container
closed when not in use.
Incompatible products : Strong oxidizers. Strong bases. metals. Acid chlorides. Acid anhydrides. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.
Storage temperature : < 55 °C
Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources.
Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: combustible materials. oxidizing agents. strong acids.
(strong) bases.
Storage area : Store in a cool area. Keep container in a well-ventilated place. Keep locked up. Provide for a
tub to collect spills. Unauthorized persons are not admitted. Meet the legal requirements.
Special rules on packaging : SPECIAL REQUIREMENTS: closing. clean. correctly labelled. meet the legal requirements.
Secure fragile packagings in solid containers.
Packaging materials : SUITABLE MATERIAL: stainless steel. aluminium. HDPE. LDPE (Low Density Poly Ethylene).
MATERIAL TO AVOID: steel. iron. copper. zinc. nickel. paper. cardboard. glass.

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Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Formaldehyde, 37% w/w (50-00-0)
ACGIH ACGIH Ceiling (mg/m³) 0.37 mg/m³
OSHA OSHA PEL (TWA) (ppm) 0.75 ppm
OSHA OSHA PEL (STEL) (ppm) 2 ppm
IDLH US IDLH (ppm) 20 ppm
NIOSH NIOSH REL (TWA) (ppm) 0.016 ppm
NIOSH NIOSH REL (ceiling) (ppm) 0.1 ppm 15 min.

Formaldehyde (50-00-0)
ACGIH ACGIH Ceiling (mg/m³) 0.37 mg/m³
ACGIH ACGIH Ceiling (ppm) 0.3 ppm
OSHA OSHA PEL (TWA) (ppm) 0.75 ppm
OSHA OSHA PEL (STEL) (ppm) 2 ppm
IDLH US IDLH (ppm) 20 ppm
NIOSH NIOSH REL (TWA) (ppm) 0.016 ppm
NIOSH NIOSH REL (ceiling) (ppm) 0.1 ppm 15 min.

Methanol (67-56-1)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 250 ppm
OSHA OSHA PEL (TWA) (mg/m³) 260 mg/m³
OSHA OSHA PEL (TWA) (ppm) 200 ppm
IDLH US IDLH (ppm) 6000 ppm
NIOSH NIOSH REL (TWA) (mg/m³) 250 mg/m³
NIOSH NIOSH REL (TWA) (ppm) 200 ppm
NIOSH NIOSH REL (STEL) (mg/m³) 325 mg/m³
NIOSH NIOSH REL (STEL) (ppm) 250 ppm
NIOSH Remark (NIOSH) Skin

Water (7732-18-5)
Not applicable

8.2. Appropriate engineering controls

Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential
exposure. Provide adequate general and local exhaust ventilation. Ensure adequate ventilation.

8.3. Individual protection measures/Personal protective equipment

Personal protective equipment:
Gas mask with filter type A. Protective goggles. Protective clothing. Face shield. Chemical resistant apron.

Materials for protective clothing:

GIVE EXCELLENT RESISTANCE: butyl rubber. nitrile rubber. viton. GIVE GOOD RESISTANCE: tetrafluoroethylene.
polyethylene/ethylenevinylalcohol. GIVE LESS RESISTANCE: neoprene. PVC. GIVE POOR RESISTANCE: natural rubber. polyethylene. PVA

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Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Hand protection:
Gloves

Eye protection:
Safety glasses

Skin and body protection:

Head/neck protection. Corrosion-proof clothing

Respiratory protection:
Full face mask with filter type A at conc. in air >
exposure limit. High vapour/gas concentration:
self-contained respirator

Other information:
Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Liquid.
Color : Colourless
Odor : Irritating/pungent odour
Odor threshold : 1 ppm
1.2 mg/m³
pH : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : > 60 °C
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Non flammable.
Vapor pressure : 14 hPa (20 °C)
Relative vapor density at 20 °C : No data available
Relative density : No data available
Specific gravity / density : 1.08 g/ml
Molecular mass : 30.03 g/mol
Solubility : Soluble in water. Soluble in ethanol. Soluble in methanol. Soluble in ether. Soluble in acetone.
Water: soluble
Ethanol: soluble
Ether: miscible
Acetone: miscible
Log Pow : No data available
Auto-ignition temperature : 395 °C (Aqueous solution, 1013 hPa)
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : 7 - 73 vol % (Pure substance)
LEL: 7 vol % (Pure substance)
UEL: 73 vol % (Pure substance)
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
VOC content : >= 33 %
Other properties : Clear. Physical properties depending on the concentration. Volatile. Substance has acid
reaction.
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Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 10: Stability and reactivity

10.1. Reactivity
Reacts violently with many compounds e.g.: with (strong) oxidizers: (increased) risk of fire/explosion. Reacts with (some) acids: release of (highly) toxic
compounds. Unstabilized product polymerizes.
10.2. Chemical stability
No additional information available
10.3. Possibility of hazardous reactions
None. Not established.
10.4. Conditions to avoid
Incompatible materials. Heat. Sparks. Open flame. Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong bases. Strong oxidizers. Strong acids. metals.
10.6. Hazardous decomposition products
Carbon dioxide. Carbon monoxide. Hydrogen. Formaldehyde. fume.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Likely routes of exposure : Inhalation; Skin and eye contact

Acute toxicity : Not classified
Formaldehyde, 37% w/w (50-00-0)
LD50 oral rat 500 mg/kg
ATE US (oral) 500 mg/kg body weight
ATE US (dermal) 2000 mg/kg body weight
ATE US (vapors) 0.578 mg/l/4h
Formaldehyde (50-00-0)
LD50 oral rat 500 mg/kg
LC50 inhalation rat (ppm) 0.579 ppm/4h
ATE US (oral) 500 mg/kg body weight
ATE US (gases) 0.579 ppmV/4h
Methanol (67-56-1)
LD50 oral rat 1187 - 2769 mg/kg body weight (BASF test, Rat, Male/female, Weight of evidence)
LD50 dermal rabbit 17100 mg/kg (Rabbit, Inconclusive, insufficient data)
LC50 inhalation rat (mg/l) 128.2 mg/l air (BASF test, 4 h, Rat, Male/female, Weight of evidence)
ATE US (oral) 100 mg/kg body weight
ATE US (dermal) 300 mg/kg body weight
ATE US (gases) 700 ppmV/4h
ATE US (vapors) 3 mg/l/4h
ATE US (dust, mist) 0.5 mg/l/4h
Water (7732-18-5)
LD50 oral rat ≥ 90000 mg/kg
ATE US (oral) 90000 mg/kg body weight
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : May cause cancer (Inhalation).

Formaldehyde (50-00-0)
IARC group 1 - Carcinogenic to humans
National Toxicology Program (NTP) Status 2 - Known Human Carcinogens

Reproductive toxicity : Not classified

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Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Specific target organ toxicity – single exposure : Causes damage to organs (central nervous system, optic nerve, respiratory system).

Specific target organ toxicity – repeated : Not classified

exposure

Aspiration hazard : Not classified

Potential Adverse human health effects and : Odour tolerance may develop. Toxic if swallowed. Toxic in contact with skin. Causes severe
symptoms skin burns. Toxic if inhaled. May cause respiratory irritation. Causes serious eye damage.
Symptoms/effects after inhalation : Runny nose. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous
membranes. EXPOSURE TO HIGH CONCENTRATIONS: Possible oedema of the upper
respiratory tract. Possible laryngeal spasm/oedema. Respiratory difficulties. Risk of lung
edema.
Symptoms/effects after skin contact : Caustic burns/corrosion of the skin.
Symptoms/effects after eye contact : Corrosion of the eye tissue.
Symptoms/effects after ingestion : Nausea. Vomiting. Diarrhoea. AFTER ABSORPTION OF LARGE QUANTITIES: Central
nervous system depression. Dizziness. Blood in vomit. Blood in stool. Shock. Disturbances of
consciousness. Change in the blood composition. Change in urine composition. Urine
discolouration.
Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Dry skin. Skin
rash/inflammation. Coughing. Possible inflammation of the respiratory tract. Respiratory
difficulties.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Not classified as dangerous for the environment according to the criteria of Regulation (EC) No
1272/2008.
Ecology - air : None of the known components is included in the list of fluorinated greenhouse gases
(Regulation (EU) No 517/2014). Not classified as dangerous for the ozone layer (Regulation
(EC) No 1005/2009).
Ecology - water : Toxic to crustacea. Toxic to fishes. Toxic to algae. pH shift.
Formaldehyde, 37% w/w (50-00-0)
EC50 Daphnia 2 2 mg/l

Methanol (67-56-1)
LC50 fish 1 15400 mg/l (EPA 660/3 - 75/009, 96 h, Lepomis macrochirus, Flow-through system, Fresh
water, Experimental value)
EC50 Daphnia 1 18260 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 96 h, Daphnia magna, Semi-
static system, Fresh water, Experimental value)
ErC50 (algae) 22000 mg/l (OECD 201: Alga, Growth Inhibition Test, 96 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value)

12.2. Persistence and degradability

Formaldehyde, 37% w/w (50-00-0)
Persistence and degradability Readily biodegradable in water.

Methanol (67-56-1)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Biochemical oxygen demand (BOD) 0.6 - 1.12 g O₂/g substance
Chemical oxygen demand (COD) 1.42 g O₂/g substance
ThOD 1.5 g O₂/g substance
Water (7732-18-5)
Persistence and degradability Not established.

12.3. Bioaccumulative potential

Formaldehyde, 37% w/w (50-00-0)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
Formaldehyde (50-00-0)
Log Pow 0.35

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Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Methanol (67-56-1)
BCF fish 1 1 - 4.5 (72 h, Cyprinus carpio, Static system, Fresh water, Experimental value)
Log Pow -0.77 (Experimental value)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
Water (7732-18-5)
Bioaccumulative potential Not established.

12.4. Mobility in soil

Formaldehyde, 37% w/w (50-00-0)
Ecology - soil Contains component(s) with potential for mobility in the soil. Toxic to flora.

Methanol (67-56-1)
Surface tension 0.023 N/m (20 °C)
Log Koc -0.89 - -0.21 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil.

12.5. Other adverse effects

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Disposal methods
Regional legislation (waste) : LWCA (the Netherlands): KGA category 06.
Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not
be mixed together with other waste. Different types of hazardous waste shall not be mixed
together if this may entail a risk of pollution or create problems for the further management of
the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or
handle hazardous waste shall take the necessary measures to prevent risks of pollution or
damage to people or animals. Remove to an authorized plant for the destruction, neutralization
and elimination of hazardous waste.
Additional information : Hazardous waste according to Directive 2008/98/EC, as amended by Regulation (EU) No
1357/2014 and Regulation (EU) No 2017/997.
Ecology - waste materials : Avoid release to the environment. Hazardous waste due to toxicity.

SECTION 14: Transport information

Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1198 Formaldehyde solutions, flammable, 3, III

UN-No.(DOT) : UN1198
Proper Shipping Name (DOT) : Formaldehyde solutions, flammable
Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : III - Minor Danger
Hazard labels (DOT) : 3 - Flammable liquid
8 - Corrosive

DOT Packaging Non Bulk (49 CFR 173.xxx) : 203

DOT Packaging Bulk (49 CFR 173.xxx) : 242

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Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

DOT Special Provisions (49 CFR 172.102) : B1 - If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then the
bulk packaging requirements of 173.241 of this subchapter are applicable. If the material has a
flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this
subchapter are applicable.
IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids
with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55
C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table
2 for UN2672).
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
DOT Packaging Exceptions (49 CFR 173.xxx) : 4b;150
DOT Quantity Limitations Passenger aircraft/rail : 5 L
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : 60 L
CFR 175.75)
DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel.
DOT Vessel Stowage Other : 40 - Stow ‘‘clear of living quarters’’
Other information : No supplementary information available.

SECTION 15: Regulatory information

15.1. US Federal regulations
Formaldehyde, 37% w/w (50-00-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
RQ (Reportable quantity, section 304 of EPA's List of Lists) 100 lb
SARA Section 311/312 Hazard Classes Physical hazard - Flammable (gases, aerosols, liquids, or solids)
Health hazard - Acute toxicity (any route of exposure)
Health hazard - Skin corrosion or Irritation
Health hazard - Serious eye damage or eye irritation
Health hazard - Carcinogenicity
Health hazard - Specific target organ toxicity (single or repeated exposure)
SARA Section 313 - Emission Reporting 0.1 %
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory

Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of
1986 and 40 CFR Part 372.
Formaldehyde CAS-No. 50-00-0 37%
Methanol CAS-No. 67-56-1 10 - 15%

Formaldehyde (50-00-0)
RQ (Reportable quantity, section 304 of EPA's 100 lb
List of Lists)
SARA Section 302 Threshold Planning 500 lb
Quantity (TPQ)
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Delayed (chronic) health hazard
Methanol (67-56-1)
RQ (Reportable quantity, section 304 of EPA's 5000 lb
List of Lists)
SARA Section 311/312 Hazard Classes Physical hazard - Flammable (gases, aerosols, liquids, or solids)
Health hazard - Acute toxicity (any route of exposure)
Health hazard - Specific target organ toxicity (single or repeated exposure)

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Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

15.2. International regulations

CANADA
Formaldehyde, 37% w/w (50-00-0)
Listed on the Canadian DSL (Domestic Substances List)

Methanol (67-56-1)
Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations
No additional information available

National regulations
Formaldehyde, 37% w/w (50-00-0)
Listed on the Canadian IDL (Ingredient Disclosure List)
Formaldehyde (50-00-0)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)

15.3. US State regulations

Formaldehyde, 37% w/w (50-00-0)
U.S. - California - Proposition 65 - Carcinogens Yes
List
U.S. - California - Proposition 65 - Developmental Yes
Toxicity
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Female
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Male
No significant risk level (NSRL) 40 µg/day

This product can expose you to Formaldehyde, which is known to the State of California to cause cancer, and Methanol,
which is known to the State of California to cause birth defects or other reproductive harm. For more information go to
www.P65Warnings.ca.gov.
Formaldehyde (50-00-0)
U.S. - California - U.S. - California - U.S. - California - U.S. - California - No significant risk
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - level (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity -
Female Male
Yes No No No 40
Methanol (67-56-1)
U.S. - California - U.S. - California - U.S. - California - U.S. - California - No significant risk
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - level (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity -
Female Male
No Yes No No

SECTION 16: Other information

Revision date : 05/16/2018
Other information : None.

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Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Full text of H-phrases: see section 16:

--- H225 Highly flammable liquid and vapour
---
--- H226 Flammable liquid and vapour
---
--- H301 Toxic if swallowed
---
--- H302 Harmful if swallowed
---
--- H311 Toxic in contact with skin
---
--- H312 Harmful in contact with skin
---
--- H314 Causes severe skin burns and eye damage
---
--- H318 Causes serious eye damage
---
--- H330 Fatal if inhaled
---
--- H331 Toxic if inhaled
---
--- H350 May cause cancer
---
--- H370 Causes damage to organs
---
--- H401 Toxic to aquatic life
---
NFPA health hazard : 3 - Materials that, under emergency conditions, can cause
serious or permanent injury.
NFPA fire hazard : 2 - Materials that must be moderately heated or exposed to
relatively high ambient temperatures before ignition can
occur.
NFPA reactivity : 0 - Material that in themselves are normally stable, even
under fire conditions.

Hazard Rating
Health : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is
given
Flammability : 2 Moderate Hazard - Materials which must be moderately heated or exposed to high ambient
temperatures before ignition will occur. Includes liquids having a flash point at or above 100 F
but below 200 F. (Classes II & IIIA)
Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT
react with water, polymerize, decompose, condense, or self-react. Non-Explosives.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator

SDS US LabChem

Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.

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