Pyrolysis-Gasoline-Blend 800001013067 Us en

Download as pdf or txt
Download as pdf or txt
You are on page 1of 27

SAFETY DATA SHEET

According to OSHA Hazard Communication Standard, 29 CFR


1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

SECTION 1. IDENTIFICATION

Product name : Pyrolysis Gasoline Blend

Product code : Q9198

CAS-No. : 68606-10-0

Manufacturer or supplier's details


Company : Shell Chemical LP
PO Box 576
HOUSTON TX 77001
USA
SDS Request : 1-800-240-6737
Customer Service : 1-855-697-4355

Emergency telephone number


Chemtrec Domestic (24 hr) : 1-800-424-9300
Chemtrec International (24 : 1-703-527-3887
hr)

Recommended use of the chemical and restrictions on use


Recommended use : Raw material for use in the chemical industry., Chemical in-
termediate.

Restrictions on use : This product must not be used in applications other than the
above without first seeking the advice of the supplier.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Flammable liquids : Category 1

Skin irritation : Category 2

Eye irritation : Category 2

Germ cell mutagenicity : Category 1B

Carcinogenicity : Category 1A

Reproductive toxicity : Category 2

Specific target organ toxicity : Category 3 (Narcotic effects)


- single exposure

1 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Specific target organ toxicity : Category 1 (Blood, Blood-forming organs, Immune system)
- repeated exposure

Specific target organ toxicity : Category 2 (Central nervous system, Auditory system, Respira-
- repeated exposure tory system, Visual system, Peripheral nervous system)

Aspiration hazard : Category 1

Long-term (chronic) aquatic : Category 2


hazard

GHS label elements


Hazard pictograms :

Signal word : Danger

Hazard statements : PHYSICAL HAZARDS:


H224 Extremely flammable liquid and vapour.
HEALTH HAZARDS:
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H340 May cause genetic defects.
H350 May cause cancer.
H361 Suspected of damaging fertility or the unborn child.
H336 May cause drowsiness or dizziness.
H372 Causes damage to organs through prolonged or repeated
exposure.
H373 May cause damage to organs through prolonged or re-
peated exposure.
H304 May be fatal if swallowed and enters airways.
ENVIRONMENTAL HAZARDS:
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements :
Prevention:
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting equip-
ment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
P264 Wash hands thoroughly after handling.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P270 Do not eat, drink or smoke when using this product.

2 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

P273 Avoid release to the environment.


Response:
P370+P378 In case of fire: Use appropriate media for extinction.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 If skin irritation occurs: Get medical advice/ atten-
tion.
P362 Take off contaminated clothing and wash before reuse.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P304 + P340 IF INHALED: Remove victim to fresh air and keep
at rest in a position comfortable for breathing.
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/ doctor.
P331 Do NOT induce vomiting.
P312 Call a POISON CENTER/ doctor if you feel unwell.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P235 Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents and container to appropriate waste
site or reclaimer in accordance with local and national regula-
tions.

Other hazards which do not result in classification


In use, may form flammable/explosive vapour-air mixture.
This material is a static accumulator.
Even with proper grounding and bonding, this material can still accumulate an electrostatic
charge.
If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air-
vapour mixtures can occur.
Slightly irritating to respiratory system.
The classification of this material is based on OSHA HCS 2012 criteria.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Substance

Hazardous components
Chemical name Synonyms CAS-No. Concentration (% w/w)
Gasoline, pyrolysis, Gasoline, py- 68606-10-0 <= 100
debutanizer bottoms; rolysis, debu-

3 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Low boiling point tanizer bottoms


naphtha -unspecified
Further information
Contains:
Chemical name Identification number Concentration (% w/w)
Benzene 71-43-2 >=30 - <=55
Isoprene 78-79-5 >=10 - <=20
Toluene 108-88-3 >=5 - <=10
Dicyclopentadiene 77-73-6 >=2 - <=8

SECTION 4. FIRST-AID MEASURES

General advice : Not expected to be a health hazard when used under normal
conditions.

If inhaled : Remove to fresh air. If rapid recovery does not occur,


transport to nearest medical facility for additional treatment.

In case of skin contact : Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.

In case of eye contact : Immediately flush eye(s) with plenty of water.


Remove contact lenses, if present and easy to do. Continue
rinsing.
Transport to the nearest medical facility for additional treat-
ment.

If swallowed : In general no treatment is necessary unless large quantities


are swallowed, however, get medical advice.

Most important symptoms : Breathing of high vapour concentrations may cause central
and effects, both acute and nervous system (CNS) depression resulting in dizziness, light-
delayed headedness, headache, nausea and loss of coordination.
Continued inhalation may result in unconsciousness and
death.
Skin irritation signs and symptoms may include a burning sen-
sation, redness, swelling, and/or blisters.
Eye irritation signs and symptoms may include a burning sen-
sation, redness, swelling, and/or blurred vision.
No specific hazards under normal use conditions.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Damage to blood-forming organs may be evidenced by: a)
fatigue and anaemia (RBC), b) decreased resistance to infec-
tion, and/or excessive bruising and bleeding (platelet effect).
Immunotoxicity may be evidenced by decreased resistance to
infection.
Peripheral nerve damage may be evidenced by impairment of
motor function (incoordination, unsteady walk, or muscle

4 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

weakness in the extremities, and/or loss of sensation in the


arms and legs).

Auditory system effects may include temporary hearing loss


and/or ringing in the ears.
Visual system disturbances may be evidenced by decreases
in the ability to discriminate between colours.

Protection of first-aiders : When administering first aid, ensure that you are wearing the
appropriate personal protective equipment according to the
incident, injury and surroundings.

Indication of any immediate : IMMEDIATE TREATMENT IS EXTREMELY IMPORTANT!


medical attention and special Call a doctor or poison control center for guidance.
treatment needed Treat symptomatically.
Potential for cardiac sensitisation, particularly in abuse situa-
tions. Hypoxia or negative inotropes may enhance these ef-
fects. Consider: oxygen therapy.
Consider: oxygen therapy.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon diox-
ide, sand or earth may be used for small fires only.

Unsuitable extinguishing : Do not use water in a jet.


media

Specific hazards during fire- : Clear fire area of all non-emergency personnel.
fighting Hazardous combustion products may include:
A complex mixture of airborne solid and liquid particulates and
gases (smoke).
Carbon monoxide.
Unidentified organic and inorganic compounds.
Flammable vapours may be present even at temperatures
below the flash point.
The vapour is heavier than air, spreads along the ground and
distant ignition is possible.
Will float and can be reignited on surface water.

Specific extinguishing meth- : Standard procedure for chemical fires.


ods

Further information : Keep adjacent containers cool by spraying with water.

Special protective equipment : Proper protective equipment including chemical resistant


for firefighters gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).

SECTION 6. ACCIDENTAL RELEASE MEASURES

5 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Personal precautions, protec- : Observe all relevant local and international regulations.
tive equipment and emer- Notify authorities if any exposure to the general public or the
gency procedures environment occurs or is likely to occur.
Local authorities should be advised if significant spillages
cannot be contained.
Avoid contact with skin, eyes and clothing.
Isolate hazard area and deny entry to unnecessary or unpro-
tected personnel.
Do not breathe fumes, vapour.
Do not operate electrical equipment.

Environmental precautions : Shut off leaks, if possible without personal risks. Remove all
possible sources of ignition in the surrounding area. Use ap-
propriate containment to avoid environmental contamination.
Prevent from spreading or entering drains, ditches or rivers by
using sand, earth, or other appropriate barriers. Attempt to
disperse the vapour or to direct its flow to a safe location for
example by using fog sprays. Take precautionary measures
against static discharge. Ensure electrical continuity by bond-
ing and grounding (earthing) all equipment.
Monitor area with combustible gas indicator.

Methods and materials for : For small liquid spills (< 1 drum), transfer by mechanical
containment and cleaning up means to a labeled, sealable container for product recovery or
safe disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
contaminated soil and dispose of safely.
For large liquid spills (> 1 drum), transfer by mechanical
means such as vacuum truck to a salvage tank for recovery or
safe disposal. Do not flush away residues with water. Retain
as contaminated waste. Allow residues to evaporate or soak
up with an appropriate absorbent material and dispose of
safely. Remove contaminated soil and dispose of safely

Ventilate contaminated area thoroughly.


If contamination of site occurs remediation may require spe-
cialist advice.

Additional advice : For guidance on selection of personal protective equipment


see Section 8 of this Safety Data Sheet.
For guidance on disposal of spilled material see Section 13 of
this Safety Data Sheet.

U.S. regulations may require reporting releases of this materi-


al to the environment which exceed the reportable quantity
(refer to Section 15) to the National Response Center at (800)
424-8802.
Under Section 311 of the Clean Water Act (CWA) this material
is considered an oil. As such, spills into surface waters must
be reported to the National Response Center at (800) 424-
8802.
This material is covered by EPA's Comprehensive Environ-
mental Response, Compensation and Liability Act (CERCLA)

6 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Petroleum Exclusion. Therefore, releases to the environment


may not be reportable under CERCLA.

SECTION 7. HANDLING AND STORAGE

Technical measures : Avoid breathing of or direct contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. For
guidance on selection of personal protective equipment see
Section 8 of this Safety Data Sheet.
Use the information in this data sheet as input to a risk as-
sessment of local circumstances to help determine appropri-
ate controls for safe handling, storage and disposal of this
material.
Ensure that all local regulations regarding handling and stor-
age facilities are followed.

Advice on safe handling : Avoid inhaling vapour and/or mists.


Avoid contact with skin, eyes and clothing.
Extinguish any naked flames. Do not smoke. Remove ignition
sources. Avoid sparks.
Use local exhaust ventilation if there is risk of inhalation of
vapours, mists or aerosols.
Bulk storage tanks should be diked (bunded).
When using do not eat or drink.

The vapour is heavier than air, spreads along the ground and
distant ignition is possible.

Avoidance of contact : Strong oxidising agents.

Product Transfer : Even with proper grounding and bonding, this material can still
accumulate an electrostatic charge. If sufficient charge is al-
lowed to accumulate, electrostatic discharge and ignition of
flammable air-vapour mixtures can occur. Be aware of han-
dling operations that may give rise to additional hazards that
result from the accumulation of static charges. These include
but are not limited to pumping (especially turbulent flow), mix-
ing, filtering, splash filling, cleaning and filling of tanks and
containers, sampling, switch loading, gauging, vacuum truck
operations, and mechanical movements. These activities may
lead to static discharge e.g. spark formation. Restrict line ve-
locity during pumping in order to avoid generation of electro-
static discharge (≤ 1 m/s until fill pipe submerged to twice its
diameter, then ≤ 7 m/s). Avoid splash filling. Do NOT use
compressed air for filling, discharging, or handling operations.

Refer to guidance under Handling section.

Conditions for safe storage : Refer to section 15 for any additional specific legislation cov-
ering the packaging and storage of this product.

Further information on stor- : Storage Temperature:


age stability Ambient.

7 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Bulk storage tanks should be diked (bunded).


Locate tanks away from heat and other sources of ignition.
Cleaning, inspection and maintenance of storage tanks is a
specialist operation, which requires the implementation of
strict procedures and precautions.
Must be stored in a diked (bunded) well- ventilated area, away
from sunlight, ignition sources and other sources of heat.
Keep away from aerosols, flammables, oxidizing agents, cor-
rosives and from other flammable products which are not
harmful or toxic to man or to the environment.
Electrostatic charges will be generated during pumping.
Electrostatic discharge may cause fire. Ensure electrical con-
tinuity by bonding and grounding (earthing) all equipment to
reduce the risk.
The vapours in the head space of the storage vessel may lie
in the flammable/explosive range and hence may be flamma-
ble.

Packaging material : Suitable material: For containers, or container linings use mild
steel, stainless steel., For container paints, use epoxy paint,
zinc silicate paint.
Unsuitable material: Avoid prolonged contact with natural,
butyl or nitrile rubbers.

Container Advice : Do not cut, drill, grind, weld or perform similar operations on or
near containers.

Specific use(s) : Not applicable

See additional references that provide safe handling practices


for liquids that are determined to be static accumulators:
American Petroleum Institute 2003 (Protection Against Igni-
tions Arising out of Static, Lightning and Stray Currents) or
National Fire Protection Agency 77 (Recommended Practices
on Static Electricity).
IEC/TS 60079-32-1: Electrostatic hazards, guidance

SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Components with workplace control parameters


Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
Not Assigned TWA 500 ppm OSHA Z-1
2,000 mg/m3
Benzene 71-43-2 TWA 0.25 ppm Shell Internal
0.8 mg/m3 Standard
(SIS) for 8-12
hour TWA.
Benzene STEL 2.5 ppm Shell Internal
8 mg/m3 Standard

8 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

(SIS) for 15
min (STEL)
Benzene TWA 0.05 ppm ACGIH
Benzene STEL 2.5 ppm ACGIH
Benzene PEL 1 ppm OSHA CARC
Benzene STEL 5 ppm OSHA CARC
Benzene TWA 10 ppm OSHA Z-2
Benzene CEIL 25 ppm OSHA Z-2
Benzene Peak 50 ppm OSHA Z-2
(10 minutes)
Isoprene 78-79-5 TWA 10 ppm Shell Internal
28 mg/m3 Standard
(SIS) for 8-12
hour TWA.
Isoprene STEL 50 ppm Shell Internal
140 mg/m3 Standard
(SIS) for 15
min (STEL)
Toluene 108-88-3 TWA 20 ppm ACGIH
Toluene TWA 200 ppm OSHA Z-2
Toluene CEIL 300 ppm OSHA Z-2
Toluene Peak 500 ppm OSHA Z-2
(10 minutes)
Dicyclopentadiene 77-73-6 TWA 0.5 ppm ACGIH
Dicyclopentadiene STEL 1 ppm ACGIH
Biological occupational exposure limits
Components CAS-No. Control Biological Sam- Permissible Basis
parameters specimen pling concentra-
time tion
Benzene 71-43-2 S- Urine End of 25 µg/g ACGIH
Phenylmer- shift (As creatinine BEI
capturic soon as
acid possible
after
exposure
ceases)
t,t-Muconic Urine End of 500 µg/g ACGIH
acid shift (As creatinine BEI
soon as
possible
after
exposure
ceases)
Toluene 108-88-3 Toluene In blood Prior to 0.02 mg/l ACGIH
last shift BEI
of work-
week
Toluene Urine End of 0.03 mg/l ACGIH
shift (As BEI
soon as
possible
after

9 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

exposure
ceases)
o-Cresol Urine End of 0.3 mg/g ACGIH
shift (As Creatinine BEI
soon as
possible
after
exposure
ceases)

Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general
workplace may be required to confirm compliance with an OEL and adequacy of exposure con-
trols. For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and sam-
ples analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or con-
tact the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Meth-
ods http://www.cdc.gov/niosh/
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
http://www.osha.gov/
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substanc-
es http://www.hse.gov.uk/
Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dguv.de/inhalt/index.jsp
L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil

Engineering measures : Use sealed systems as far as possible.


Adequate explosion-proof ventilation to control airborne con-
centrations below the exposure guidelines/limits.
Local exhaust ventilation is recommended.
Firewater monitors and deluge systems are recommended.
Eye washes and showers for emergency use.
Where material is heated, sprayed or mist formed, there is
greater potential for airborne concentrations to be generated.
The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:

General Information:
Consider technical advances and process upgrades (includ-
ing automation) for the elimination of releases. Minimise ex-
posure using measures such as closed systems, dedicated
facilities and suitable general/local exhaust ventilation. Drain
down systems and clear transfer lines prior to breaking con-
tainment. Clean/flush equipment, where possible, prior to
maintenance. Where there is potential for exposure: restrict
access to authorised persons; provide specific activity train-
ing to operators to minimise exposures; wear suitable gloves
and coveralls to prevent skin contamination; wear respiratory
protection when there is potential for inhalation; clear up

10 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

spills immediately and dispose of wastes safely.Ensure safe


systems of work or equivalent arrangements are in place to
manage risks. Regularly inspect, test and maintain all control
measures. Consider the need for risk based health surveil-
lance.

Personal protective equipment


Respiratory protection : If engineering controls do not maintain airborne concentra-
tions to a level which is adequate to protect worker health,
select respiratory protection equipment suitable for the spe-
cific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air-filtering respirators are unsuitable (e.g. airborne
concentrations are high, risk of oxygen deficiency, confined
space) use appropriate positive pressure breathing appa-
ratus.
Where air-filtering respirators are suitable, select an appro-
priate combination of mask and filter.
If air-filtering respirators are suitable for conditions of use:
Select a filter suitable for organic gases and vapours [Type A
boiling point >65°C (149°F)].

Respirator selection, use and maintenance should be in ac-


cordance with the requirements of the OSHA Respiratory
Protection Standard, 29 CFR 1910.134.

Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. Longer term protection: Viton.
Incidental contact/Splash protection: Nitrile rubber.
For continuous contact we recommend gloves with break-
through time of more than 240 minutes with preference for >
480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same but
recognize that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Glove thickness should be typically greater than 0.35 mm
depending on the glove make and model. Suitability and du-
rability of a glove is dependent on usage, e.g. frequency and
duration of contact, chemical resistance of glove material,
dexterity. Always seek advice from glove suppliers. Contami-
nated gloves should be replaced. Personal hygiene is a key
element of effective hand care. Gloves must only be worn on
clean hands. After using gloves, hands should be washed
and dried thoroughly. Application of a non-perfumed moistur-
izer is recommended.

11 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Eye protection : Wear goggles for use against liquids and gas.
Wear full face shield if splashes are likely to occur.

Skin and body protection : Wear chemical resistant gloves/gauntlets and boots. Where
risk of splashing, also wear an apron.
Wear antistatic and flame-retardant clothing, if a local risk
assessment deems it so.

Protective measures : Personal protective equipment (PPE) should meet recom-


mended national standards. Check with PPE suppliers.

Hygiene measures : Wash hands before eating, drinking, smoking and using the
toilet.
Launder contaminated clothing before re-use.
Do not ingest. If swallowed, then seek immediate medical
assistance.

Environmental exposure controls


General advice : Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.
Minimise release to the environment. An environmental as-
sessment must be made to ensure compliance with local envi-
ronmental legislation.
Information on accidental release measures are to be found in
section 6.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid.

Colour : Yellowish tinted

Odour : aromatic

Odour Threshold : Data not available

pH : Data not available

Melting point/freezing point : Data not available

Boiling point/boiling range : 26 - 179 °C / 79 - 354 °F

Flash point : < -7 °C / < 19 °F

Evaporation rate : Data not available

Flammability
Flammability (liquids) : Static-accumulating flammable liquid.

Lower explosion limit and upper explosion limit / flammability limit


Upper explosion limit / up- : 12.0 %(V)
per flammability limit

12 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Lower explosion limit / : 5.0 %(V)


Lower flammability limit

Vapour pressure : 0.64 bar

Relative vapour density : 2.7

Relative density : 0.76 - 0.77


Method: ASTM D4052

Density : Data not available

Solubility(ies)
Water solubility : 0.05 g/l negligible

Partition coefficient: n- : Data not available


octanol/water

Auto-ignition temperature : Data not available

Decomposition temperature : no data available

Viscosity
Viscosity, dynamic : Data not available

Viscosity, kinematic : Data not available

Explosive properties : Not applicable

Oxidizing properties : no data available

Surface tension : Data not available

Conductivity : Low conductivity: < 100 pS/m, The conductivity of this material
makes it a static accumulator., A liquid is typically considered
nonconductive if its conductivity is below 100 pS/m and is
considered semi-conductive if its conductivity is below 10,000
pS/m., Whether a liquid is nonconductive or semiconductive,
the precautions are the same., A number of factors, for exam-
ple liquid temperature, presence of contaminants, and anti-
static additives can greatly influence the conductivity of a liq-
uid
Molecular weight : Data not available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : The product does not pose any further reactivity hazards in
addition to those listed in the following sub-paragraph.

Chemical stability : No hazardous reaction is expected when handled and stored


according to provisions
Stable under normal conditions of use.

13 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Possibility of hazardous reac- : Reacts with strong oxidising agents.


tions

Conditions to avoid : Avoid heat, sparks, open flames and other ignition sources.

In certain circumstances product can ignite due to static elec-


tricity.

Incompatible materials : Strong oxidising agents.

Hazardous decomposition : Hazardous decomposition products are not expected to form


products during normal storage.
Thermal decomposition is highly dependent on conditions. A
complex mixture of airborne solids, liquids and gases includ-
ing carbon monoxide, carbon dioxide, sulphur oxides and
unidentified organic compounds will be evolved when this
material undergoes combustion or thermal or oxidative degra-
dation.

SECTION 11. TOXICOLOGICAL INFORMATION

Basis for assessment : Information given is based on data from components.

Information on likely routes of exposure


Exposure may occur via inhalation, ingestion, skin absorption, skin or eye contact, and accidental
ingestion.
Acute toxicity

Product:
Acute oral toxicity : LD50 : > 5,000 mg/kg
Remarks: Low toxicity:
Based on available data, the classification criteria are not met.

Acute inhalation toxicity : Remarks: Low toxicity if inhaled.


Based on available data, the classification criteria are not met.

Acute dermal toxicity : LD50 : > 5,000 mg/kg


Remarks: Low toxicity:
Based on available data, the classification criteria are not met.

Components:
Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:
Acute oral toxicity : LD 50 (Rat, male and female): > 5,000 mg/kg
Method: Other guideline method.
Remarks: Based on available data, the classification criteria
are not met.

Acute inhalation toxicity : LC 50 (Rat, male and female): > 20 mg/l


Exposure time: 4 h
Test atmosphere: vapour
Method: Test(s) equivalent or similar to OECD Test Guideline
403

14 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Remarks: Based on available data, the classification criteria


are not met.

Acute dermal toxicity : LD 50 (Rabbit, male and female): > 2,000 mg/kg
Method: Other guideline method.
Remarks: Based on available data, the classification criteria
are not met.

Skin corrosion/irritation

Product:
Remarks: Causes skin irritation.

Components:
Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:
Species: Rabbit
Method: OECD Test Guideline 404
Remarks: Causes skin irritation.

Serious eye damage/eye irritation

Product:
Remarks: Causes serious eye irritation.

Components:
Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:
Species: Rabbit
Method: Other guideline method.
Remarks: Causes serious eye irritation.

Respiratory or skin sensitisation

Product:
Remarks: Not a skin sensitiser.
Based on available data, the classification criteria are not met.

Components:
Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:
Species: Guinea pig
Method: Other guideline method.
Remarks: Based on available data, the classification criteria are not met.

Germ cell mutagenicity

Product:
: Remarks: Contains Benzene, CAS # 71-43-2., May cause
heritable genetic damage

Components:

15 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:


: Method: Test(s) equivalent or similar to OECD Guideline 471
Remarks: Based on available data, the classification criteria
are not met.

: Method: Test(s) equivalent or similar to OECD Test Guideline


473
Remarks: Based on available data, the classification criteria
are not met.

: Test species: Mouse


Method: OECD Test Guideline 474
Remarks: May cause heritable genetic damage, Contains
benzene.

Germ cell mutagenicity- As- : May cause genetic defects.


sessment

Carcinogenicity

Product:
Remarks: Contains Benzene, CAS # 71-43-2., Known human carcinogen., May cause leukaemia
(AML - acute myelogenous leukaemia).

Components:
Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:
Species: Rat, (male and female)
Application Route: Oral
Method: Other guideline method.
Remarks: Known human carcinogen., May cause leukaemia (AML - acute myelogenous leu-
kaemia)., Causes cancer in laboratory animals., Contains benzene.

Species: Rat, (male and female)


Application Route: Inhalation
Method: Test(s) equivalent or similar to OECD Test Guideline 453
Remarks: Known human carcinogen., May cause leukaemia (AML - acute myelogenous leu-
kaemia)., Causes cancer in laboratory animals., Contains benzene.

Carcinogenicity - Assess- : May cause cancer.


ment

IARC Group 1: Carcinogenic to humans

Benzene 71-43-2

Group 2B: Possibly carcinogenic to humans

Gasoline, Pyrolysis, Debu- 68606-10-0


tanizer Bottoms

16 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Isoprene 78-79-5

OSHA OSHA specifically regulated carcinogen

Benzene 71-43-2

NTP Known to be human carcinogen

Benzene 71-43-2

Reasonably anticipated to be a human carcinogen

Isoprene 78-79-5

Reproductive toxicity

Product:
:
Remarks: Suspected of damaging fertility or the unborn child.,
Contains n-Hexane, CAS # 110-54-3., Affects reproductive
system in animals at doses which produce other toxic effects.,
Contains Toluene, CAS # 108-88-3., Causes foetotoxicity in
animals at doses which are maternally toxic.

Components:
Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:
:

Remarks: Suspected of damaging fertility or the unborn child.,


Affects reproductive system in animals at doses which pro-
duce other toxic effects., Contains n-Hexane, CAS # 110-54-
3., Causes foetotoxicity in animals at doses which are mater-
nally toxic., Contains Toluene, CAS # 108-88-3.

Effects on foetal develop- : Species: Rat, female


ment Application Route: Inhalation
Remarks: Suspected of damaging fertility or the unborn child.,
Affects reproductive system in animals at doses which pro-
duce other toxic effects., Contains n-Hexane, CAS # 110-54-
3., Causes foetotoxicity in animals at doses which are mater-
nally toxic., Contains Toluene, CAS # 108-88-3.

Reproductive toxicity - As- : This product does not meet the criteria for classification in
sessment categories 1A/1B.

STOT - single exposure

Product:
Exposure routes: Inhalation
Target Organs: Narcotic effects.
Remarks: May cause drowsiness and dizziness., Inhalation of vapours or mists may cause irrita-
tion to the respiratory system.

17 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Components:
Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:
Exposure routes: Inhalation
Target Organs: Central nervous system
Remarks: May cause drowsiness and dizziness., Inhalation of vapours or mists may cause irrita-
tion to the respiratory system.

STOT - repeated exposure

Product:
Target Organs: Blood, Blood-forming organs, Immune system
Assessment: Causes damage to organs through prolonged or repeated exposure.
Remarks: Contains Benzene, CAS # 71-43-2., Blood: may cause haemolysis of red blood cells
and/or anaemia., Blood-forming organs: repeated exposure affects the bone marrow., Immune
System: animal studies on this material or its components have demonstrated immunotoxicity.

Target Organs: Central nervous system, Peripheral nervous system, Respiratory system, Visual
system, Auditory system
Assessment: May cause damage to organs through prolonged or repeated exposure.
Remarks: Contains Toluene, CAS # 108-88-3., Central nervous system: repeated exposure af-
fects the nervous system., Effects were seen at high doses only., Auditory system: prolonged
and repeated exposures to high concentrations have resulted in hearing loss in rats. Solvent
abuse and noise interaction in the work environment may cause hearing loss., Not applicable,
Respiratory system: repeated exposure affects the respiratory system. Effects were seen at high
doses only., Contains n-Hexane, CAS # 110-54-3., Peripheral nervous system: repeated expo-
sure causes peripheral neuropathy in animals., Visual system: may cause decreased color per-
ception. , These subtle changes have not been found to lead to functional colour vision deficits.

Components:
Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:
Exposure routes: Oral
Target Organs: Blood-forming organs, Immune system, Central nervous system, Auditory sys-
tem, Respiratory system, Visual system, Peripheral nervous system
Remarks: Causes damage to blood, blood-forming organs and immune system., Blood: may
cause haemolysis of red blood cells and/or anaemia., Blood-forming organs: repeated exposure
affects the bone marrow., Immune System: animal studies on this material or its components
have demonstrated immunotoxicity., Contains benzene., May cause damage to central nervous
system, respiratory system, visual system, and auditory system through prolonged or repeated
exposure., Central nervous system: repeated exposure affects the nervous system., Effects were
seen at high doses only., Auditory system: prolonged and repeated exposures to high concentra-
tions have resulted in hearing loss in rats. , Visual system: may cause decreased color percep-
tion. , These subtle changes have not been found to lead to functional colour vision deficits.,
Respiratory system: repeated exposure affects the respiratory system. Effects were seen at high
doses only., Contains Toluene, CAS # 108-88-3., Peripheral nervous system: repeated exposure
causes peripheral neuropathy in animals., Contains n-Hexane, CAS # 110-54-3.

Repeated dose toxicity

Components:
Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:
Species: Rat, male and female

18 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Application Route: Oral


Method: Test(s) equivalent or similar to OECD Test Guideline 408
Target Organs: hematopoietic system

Species: Rat, male and female


Application Route: Inhalation
Test atmosphere: vapour
Method: Test(s) equivalent or similar to OECD Test Guideline 413
Target Organs: No specific target organs noted

Species: Rabbit, female


Application Route: Dermal
Method: Test(s) equivalent or similar to OECD Test Guideline 410
Target Organs: No specific target organs noted

Aspiration toxicity

Product:
Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which
can be fatal.

Components:
Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:
Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which
can be fatal.

Further information

Product:
Remarks: Exposure to very high concentrations of similar materials has been associated with
irregular heart rhythms and cardiac arrest.

Remarks: Myelodysplastic syndrome (MDS) was observed in individuals exposed to very high
levels (50 ppm to 300 ppm range) of benzene over a long period of time in the workplace. The
relevance of these results to lower levels of exposure is not known.

Remarks: Classifications by other authorities under varying regulatory frameworks may exist.

Components:
Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:
Remarks: Classifications by other authorities under varying regulatory frameworks may exist.

SECTION 12. ECOLOGICAL INFORMATION

Basis for assessment : Incomplete ecotoxicological data are available for this product.
The information given below is based partly on a knowledge of
the components and the ecotoxicology of similar products.

19 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Ecotoxicity

Product:
Toxicity to fish (Acute toxici- : LL50: > 1 - 10 mg/l
ty) Remarks: Toxic

Toxicity to daphnia and other : EL50: > 1 - 10 mg/l


aquatic invertebrates (Acute Remarks: Toxic
toxicity)

Toxicity to algae (Acute tox- : EL50: > 1 - 10 mg/l


icity) Remarks: Toxic

Toxicity to fish (Chronic tox- : Remarks: Data not available


icity)

Toxicity to daphnia and other : Remarks: Data not available


aquatic invertebrates (Chron-
ic toxicity)

Toxicity to microorganisms : Remarks: LL/EL/IL50 >10 <= 100 mg/l


(Acute toxicity) Harmful

Components:

Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:


Toxicity to fish (Acute toxici- : LC50 (Oncorhynchus mykiss (rainbow trout)): 1 mg/l
ty) Exposure time: 96 h
Method: OECD Test Guideline 203
Remarks: Toxic
LL/EL/IL50 > 1 <= 10 mg/l

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 1.2 mg/l
aquatic invertebrates (Acute Exposure time: 48 h
toxicity) Method: OECD Test Guideline 202
Remarks: Toxic
LL/EL/IL50 > 1 <= 10 mg/l

Toxicity to algae (Acute tox- : EC50 (Pseudokirchneriella subcapitata (algae)): 1.3 mg/l
icity) Exposure time: 96 h
Method: OECD Test Guideline 201
Remarks: Toxic
LL/EL/IL50 > 1 <= 10 mg/l

Toxicity to fish (Chronic tox- : Remarks: Data not available


icity)

Toxicity to daphnia and other : Remarks: Data not available


aquatic invertebrates (Chron-
ic toxicity)

Toxicity to microorganisms : (Tetrahymena pyriformis): 76.7 mg/l


(Acute toxicity) Exposure time: 72 h
Method: Based on quantitative structure-activity relationship

20 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

(QSAR) modelling
Remarks: Harmful
LL/EL/IL50 >10 <= 100 mg/l

Persistence and degradability

Product:
Biodegradability : Remarks: Not readily biodegradable.

Remarks: Oxidises rapidly by photo-chemical reactions in air.

Components:

Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:


Biodegradability : Biodegradation: 7.3 %
Exposure time: 28 d
Method: OECD Test Guideline 301F
Remarks: Not readily biodegradable.

Bioaccumulative potential

Product:
Bioaccumulation : Remarks: Contains components with the potential to bioac-
cumulate.

Components:

Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:


Bioaccumulation : Species: Pimephales promelas (fathead minnow)
Bioconcentration factor (BCF): 0.73 - 4.15
Method: Based on quantitative structure-activity relationship
(QSAR) modelling
Remarks: Contains components with the potential to bioac-
cumulate.

Mobility in soil

Product:
Mobility : Remarks: Floats on water.

Remarks: If product enters soil, one or more constituents will


be mobile and may contaminate groundwater.

Components:

Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:


Mobility : Remarks: Floats on water.
If the product enters soil, one or more constituents will or may
be mobile and may contaminate groundwater.

21 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Other adverse effects

Product:
Additional ecological infor- : In view of the high rate of loss from solution, the product is
mation unlikely to pose a significant hazard to aquatic life.

Components:

Gasoline, pyrolysis, debutanizer bottoms; Low boiling point naphtha -unspecified:


Results of PBT and vPvB : The substance does not fulfill all screening criteria for persis-
assessment tence, bioaccumulation and toxicity and hence is not consid-
ered to be PBT or vPvB.

Additional ecological infor- : In view of the high rate of loss from solution, the product is
mation unlikely to pose a significant hazard to aquatic life.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Recover or recycle if possible.
It is the responsibility of the waste generator to determine the
toxicity and physical properties of the material generated to
determine the proper waste classification and disposal meth-
ods in compliance with applicable regulations.
Waste product should not be allowed to contaminate soil or
ground water, or be disposed of into the environment.
Do not dispose into the environment, in drains or in water
courses
Do not dispose of tank water bottoms by allowing them to
drain into the ground. This will result in soil and groundwater
contamination.
Waste arising from a spillage or tank cleaning should be dis-
posed of in accordance with prevailing regulations, preferably
to a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.

Waste, spills or used product is dangerous waste.

Disposal should be in accordance with applicable regional,


national, and local laws and regulations.
Local regulations may be more stringent than regional or na-
tional requirements and must be complied with.

MARPOL - see International Convention for the Prevention of


Pollution from Ships (MARPOL 73/78) which provides tech-
nical aspects at controlling pollutions from ships.

Contaminated packaging : Drain container thoroughly.


After draining, vent in a safe place away from sparks and fire.
Residues may cause an explosion hazard. Do not puncture,
cut or weld uncleaned drums.
Send to drum recoverer or metal reclaimer.

22 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Comply with any local recovery or waste disposal regulations.

SECTION 14. TRANSPORT INFORMATION

National Regulations
US Department of Transportation Classification (49 CFR Parts 171-180)
UN/ID/NA number : UN 3295
Proper shipping name : HYDROCARBONS, LIQUID, N.O.S.
Class : 3
Packing group : I
Labels : 3
ERG Code : 128
Marine pollutant : no
International Regulations

IATA-DGR
UN/ID No. : UN 3295
Proper shipping name : HYDROCARBONS, LIQUID, N.O.S.
Class : 3
Packing group : I
Labels : 3
IMDG-Code
UN number : UN 3295
Proper shipping name : HYDROCARBONS, LIQUID, N.O.S.
(n-Hexane)
Class : 3
Packing group : I
Labels : 3
Marine pollutant : yes
Maritime transport in bulk according to IMO instruments
MARPOL Annex 1 rules apply for bulk shipments by sea.

Special precautions for user


Remarks : Special Precautions: Refer to Section 7, Handling & Storage,
for special precautions which a user needs to be aware of or
needs to comply with in connection with transport.

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity


Components CAS-No. Component RQ Calculated product RQ
(lbs) (lbs)
Benzene 71-43-2 10 18

23 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

Benzene 71-43-2 10 10 (D018)


Toluene 108-88-3 100 100 (F005)
*: The components with RQs are given for information., Shell classifies this material as an "oil"
under the CERCLA Petroleum Exclusion, therefore releases to the environment are not reporta-
ble under CERCLA.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity

This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Skin corrosion or irritation
Serious eye damage or eye irritation
Aspiration hazard
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
Specific target organ toxicity (single or repeated exposure)

SARA 313 : The following components are subject to reporting levels es-
tablished by SARA Title III, Section 313:

Benzene 71-43-2 >= 50 - < 70 %

Isoprene 78-79-5 >= 20 - < 30 %

Toluene 108-88-3 >= 10 - < 20 %

Dicyclopentadiene 77-73-6 >= 5 - < 10 %

Clean Water Act


The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table
117.3:
Benzene 71-43-2 55 %
Isoprene 78-79-5 20 %
Toluene 108-88-3 10 %
US State Regulations

Pennsylvania Right To Know


Gasoline, Pyrolysis, Debutanizer Bottoms 68606-10-0
Benzene 71-43-2
Isoprene 78-79-5
Toluene 108-88-3
Dicyclopentadiene 77-73-6
California Prop. 65
WARNING: This product can expose you to chemicals including Benzene, Isoprene, which is/are
known to the State of California to cause cancer, and Benzene, Toluene, which is/are known to
the State of California to cause birth defects or other reproductive harm. For more information go
to www.P65Warnings.ca.gov.

24 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

California List of Hazardous Substances


Benzene 71-43-2
Isoprene 78-79-5
Toluene 108-88-3
Dicyclopentadiene 77-73-6
California Regulated Carcinogens
Benzene 71-43-2
Other regulations:
The regulatory information is not intended to be comprehensive. Other regulations may apply
to this material.

The components of this product are reported in the following inventories:


TSCA : Listed

SECTION 16. OTHER INFORMATION

Further information

NFPA Rating (Health, Fire, Reac- 2, 4, 1


tivity)

Full text of other abbreviations


ACGIH : USA. ACGIH Threshold Limit Values (TLV)
ACGIH BEI : ACGIH - Biological Exposure Indices (BEI)
OSHA CARC : OSHA Specifically Regulated Chemicals/Carcinogens
OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-
its for Air Contaminants
OSHA Z-2 : USA. Occupational Exposure Limits (OSHA) - Table Z-2
ACGIH / TWA : 8-hour, time-weighted average
ACGIH / STEL : Short-term exposure limit
OSHA CARC / PEL : Permissible exposure limit (PEL)
OSHA CARC / STEL : Excursion limit
OSHA Z-1 / TWA : 8-hour time weighted average
OSHA Z-2 / TWA : 8-hour time weighted average
OSHA Z-2 / CEIL : Acceptable ceiling concentration
OSHA Z-2 / Peak : Acceptable maximum peak above the acceptable ceiling con-
centration for an 8-hr shift
Abbreviations and Acronyms : The standard abbreviations and acronyms used in this docu-
ment can be looked up in reference literature (e.g. scientific
dictionaries) and/or websites.

ACGIH = American Conference of Governmental Industrial


Hygienists
ADR = European Agreement concerning the International
Carriage of Dangerous Goods by Road
AICS = Australian Inventory of Chemical Substances
ASTM = American Society for Testing and Materials
BEL = Biological exposure limits

25 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

BTEX = Benzene, Toluene, Ethylbenzene, Xylenes


CAS = Chemical Abstracts Service
CEFIC = European Chemical Industry Council
CLP = Classification Packaging and Labelling
COC = Cleveland Open-Cup
DIN = Deutsches Institut fur Normung
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
DSL = Canada Domestic Substance List
EC = European Commission
EC50 = Effective Concentration fifty
ECETOC = European Center on Ecotoxicology and Toxicolo-
gy Of Chemicals
ECHA = European Chemicals Agency
EINECS = The European Inventory of Existing Commercial
Chemical Substances
EL50 = Effective Loading fifty
ENCS = Japanese Existing and New Chemical Substances
Inventory
EWC = European Waste Code
GHS = Globally Harmonised System of Classification and
Labelling of Chemicals
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IC50 = Inhibitory Concentration fifty
IL50 = Inhibitory Level fifty
IMDG = International Maritime Dangerous Goods
INV = Chinese Chemicals Inventory
IP346 = Institute of Petroleum test method N° 346 for the
determination of polycyclic aromatics DMSO-extractables
KECI = Korea Existing Chemicals Inventory
LC50 = Lethal Concentration fifty
LD50 = Lethal Dose fifty per cent.
LL/EL/IL = Lethal Loading/Effective Loading/Inhibitory loading
LL50 = Lethal Loading fifty
MARPOL = International Convention for the Prevention of
Pollution From Ships
NOEC/NOEL = No Observed Effect Concentration / No Ob-
served Effect Level
OE_HPV = Occupational Exposure - High Production Volume
PBT = Persistent, Bioaccumulative and Toxic
PICCS = Philippine Inventory of Chemicals and Chemical
Substances
PNEC = Predicted No Effect Concentration
REACH = Registration Evaluation And Authorisation Of
Chemicals
RID = Regulations Relating to International Carriage of Dan-
gerous Goods by Rail
SKIN_DES = Skin Designation
STEL = Short term exposure limit
TRA = Targeted Risk Assessment
TSCA = US Toxic Substances Control Act
TWA = Time-Weighted Average
vPvB = very Persistent and very Bioaccumulative

26 / 27
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Pyrolysis Gasoline Blend
Version Revision Date: SDS Number: Print Date: 05/06/2023
23.0 08/05/2022 800001013067 Date of last issue: 04/06/2020

A vertical bar (|) in the left margin indicates an amendment from the previous version.

Sources of key data used to : The quoted data are from, but not limited to, one or more
compile the Safety Data sources of information (e.g. toxicological data from Shell
Sheet Health Services, material suppliers’ data, CONCAWE, EU
IUCLID date base, EC 1272 regulation, etc).

Revision Date : 08/05/2022

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

US / EN

27 / 27

You might also like