MATERIAL SAFETY DATA SHEET

(USA)

(Complies with USA OSHA 29 CFR 1910.1200 and ANSI Z 400.1)

Version: 2 Revision date: 06 June 2006

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Product code: A283

Product name: Corrosion Inhibitor A283
Company identification: Schlumberger Technology Corporation
110 Schlumberger Drive
Sugar Land, Texas 77478, USA
Telephone: 1-281-285-7873

Emergency telephone number: USA: 1-281-595-3518

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

DANGER

Main physical hazards: Flammable liquid.

Main health hazards: May be mildly irritating to eyes. May cause skin irritation. Inhalation of
high vapor concentrations can cause CNS-depression and narcosis.
Components of this product are listed by IARC in Group 2B as possibly
carcinogenic to humans. See also MSDS Section 11.
Other hazards: Vapors may cause flash fire or explosion.
Precautions: Keep away from heat, sparks, and flame. To avoid ignition of vapors by
static electricity discharge, all metal parts of the equipment must be
grounded. Avoid contact with eyes. Do not get on skin or clothing. Wash
thoroughly after handling. Do not breathe vapors or spray mist.
HMIS classification: Health: 2 Flammability: 3 Physical hazard: 0

Form: Liquid Color: Dark / Amber Odor: Hydrocarbons

Principle routes of exposure:

Eye contact. Skin contact. Respiratory system.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Components classified as hazardous:

Component CAS-No Weight % - Range

Naphtha (petroleum), hydrotreated heavy 64742-48-9 30 - 60
Propan-2-ol 67-63-0 3-7
Ethylbenzene 100-41-4 3-7
Heavy aromatic naphtha 64742-94-5 1-5
Xylene 1330-20-7 1-5
Naphthalene 91-20-3 0.5 - 1.5

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4. FIRST AID MEASURES

Eye contact: Immediately flush eyes with water for 15 minutes while holding eyelids
open. Seek medical attention.
Skin contact: Take off contaminated clothing and shoes immediately. After contact with
skin, wash immediately with plenty of soap and water for at least 15
minutes. Obtain medical attention.
Ingestion: DO NOT induce vomiting. Call a physician or Poison Control Center
immediately. If delayed, consider giving activated charcoal in water, or 2
glasses of milk or water. Never give anything by mouth to an unconscious
person.
Inhalation: Move to fresh air in case of accidental inhalation of vapors. Obtain
medical attention.

5. FIRE-FIGHTING MEASURES

Fire hazard: Flammable liquid.

OSHA Flammability Class: IC
Flash point: 27 °C / 80 °F
Method: Pensky-Martens CC
Autoignition temperature: No data available.
Flammability limits in air:
Lower: No information available.
Upper: No information available.
Oxidizing properties: None.

Suitable extinguishing media:

Water Fog, Alcohol Foam, CO2, Dry Chemical.

Extinguishing media which must not be used for safety reasons:

Do not use water unless flooding amounts are available.

Special exposure hazards arising from the substance or preparation itself, its combustion
products, or released gases:
Vapors may travel along the ground and ignite when an ignition source is contacted. When heated
strongly or burned, oxides of carbon, nitrogen oxides, ammonia and harmful organic chemical fumes are
released.

Other information:
Vapors may cause flash fire or explosion.

Specific methods:
In the event of fire, cool tanks with water spray

Special protective equipment for firefighters:

Wear protective fire fighting clothing and avoid breathing vapors. Wear self-contained breathing
apparatus and protective suit.

NFPA rating:
Health: 2
Flammability: 3
Instability: 0
Special: None

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6. ACCIDENTAL RELEASE MEASURES

Main physical hazards: Flammable liquid.

Other hazards: Vapors may cause flash fire or explosion.
Personal precautions: Avoid contact with eyes. Do not breathe vapors or spray mist. Do not get
on skin or clothing. Wash thoroughly after handling. Keep away from
sources of ignition - No smoking. See also Section 8.
Methods for cleaning up: Contain with dikes. Use explosion proof equipment to recover. Remove
all sources of ignition. Soak up residual on inert absorbant (sand). Put in
steel or plastic drum approved for flammables.
Environmental precautions: Keep out of waterways. Do not allow material to contaminate ground
water system. Prevent product from entering drains.

7. HANDLING AND STORAGE

Handling:
Precautions: Keep away from heat, sparks, and flame. To avoid ignition of vapors by
static electricity discharge, all metal parts of the equipment must be
grounded. Avoid contact with eyes. Do not get on skin or clothing. Wash
thoroughly after handling. Do not breathe vapors or spray mist.
Safe handling advice: Avoid contact with skin and eyes. Do not breathe vapors or spray mist.
Keep airborne concentrations below exposure limits. Wear suitable
protective equipment.
Technical measures/ Keep away from heat, sparks, and flame. Store out of direct sunlight in
storage conditions: well ventilated area. Keep container closed when not in use. Use with
adequate ventilation. Ground and bond containers when transferring
material.
Packaging requirements: Steel or high density polyethylene (HDPE) container approved for
flammables.
Incompatible products: Oxidizing agents.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures Control the source. Ensure adequate ventilation.

to reduce exposure:
Hygiene measures: Avoid contact with skin, eyes and clothing. Do not breathe vapors or
spray mist. Keep airborne concentrations below exposure limits.
Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment.
Use NIOSH approved respirator with organic vapor/acid gas protection
(color coded yellow). Use SCBA (self contained breathing apparatus) in
confined areas and for emergencies.
Eye protection: Tightly fitting safety goggles.
Hand protection: Impervious gloves made of:. Nitrile. Viton. PVA.
Skin and body protection: Chemical resistant apron. Chemical resistant boots. For spills and
emergencies, also wear boots and impervious suit.
Occupational Exposure Limits
ACGIH - TLVs OSHA - PELs
Component TWA / Ceiling STEL Skin TWA / C STEL Final PELs
- Skin
Propan-2-ol 200 ppm TWA 400 ppm 980 mg/m3 TWA
400 ppm TWA
Ethylbenzene 100 ppm TWA 125 ppm 435 mg/m3 TWA
100 ppm TWA

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Xylene 100 ppm TWA 150 ppm 435 mg/m³ TWA

100 ppm TWA
Naphthalene 10 ppm TWA 15 ppm Skin Notation 10 ppm TWA
50 mg/m³ TWA

Nuisance dust:
ACGIH: inhalable particulate TLV-TWA=10 mg/m3; respirable particulate TLV-TWA= 3 mg/m3

9. PHYSICAL AND CHEMICAL PROPERTIES

Fire hazard: Flammable liquid.

Form: Liquid
Color: Dark / Amber
Odor: Hydrocarbons
Odor threshold: No information available.
pH: No information available.
Boiling point/range: No data available.
Flash point: 27 °C / 80 °F
Method: Pensky-Martens CC.
Flammability limits in air:
Lower: No information available.
Upper: No information available.
Bulk density: Not applicable.
Melting point/range: No data available.
Decomposition temperature: No data available.
Solubility:
Water solubility: Insoluble.
Fat solubility: No information available.
Partition coefficient No information available.
(n-octanol/water):
Relative density: 0.95 (@ 16°C)
Vapor pressure: 8.1 kPa (@ 38°C)
Vapor density: No data available.
Viscosity: 16 cst (@ 40 °C)
Evaporation rate: No data available.
% Volatile: No data available.

10. STABILITY AND REACTIVITY

Stability:
Stable under recommended storage conditions

Conditions to avoid:
Keep away from heat, sparks, and flame. Keep product and empty container away from heat and sources
of ignition. Take precautionary measures against static discharges.

Incompatibility with other substances:

Oxidizers.

Hazardous decomposition products:

Nitrogen Oxides (NOx). When heated strongly or burned, oxides of carbon and harmful organic chemical
fumes are released.

Hazardous polymerization:
Hazardous polymerization does not occur.

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Other hazards:
Vapors may cause flash fire or explosion.

11. TOXICOLOGICAL INFORMATION

PRODUCT TOXICOLOGICAL INFORMATION

No toxicology studies have been conducted on this product. Hazard classification is estimated based on
available component information.

Acute Health Hazard

Eye contact: Contact with eyes may cause irritation.

Skin contact: Moderately irritating to the skin. Prolonged skin contact may defat the skin
and produce dermatitis.
Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhea. Aspiration may cause pulmonary edema and pneumonitis.
Inhalation: Inhalation of high vapor concentrations can cause CNS-depression and
narcosis. Inhalation of vapors in high concentration may cause irritation of
respiratory system.
Sensitization - lung: Not known to cause allergic reaction.
Sensitization - skin: Not known to cause allergic reaction.

Chronic Health Hazard

Carcinogenic effects: See COMPONENT TOXICOLOGICAL INFORMATION below.

Mutagenic effects: Not known to cause heritable genetic damage.
Teratogenic effects: See COMPONENT TOXICOLOGICAL INFORMATION below.
Reproductive toxicity: See COMPONENT TOXICOLOGICAL INFORMATION below.
Target organ effects: See COMPONENT TOXICOLOGICAL INFORMATION below.

COMPONENT TOXICOLOGICAL INFORMATION

Component Target Organ Effects LD50 / LC50

Naphtha (petroleum), > 3160 mg/kg (Dermal LD50; Rabbit)
hydrotreated heavy > 5000 mg/kg (Oral LD50; Rat)
Propan-2-ol eyes, skin, respiratory system = 12800 mg/kg (Dermal LD50; Rabbit)
= 16000 mg/kg (Inhalation LC50; Rat) 8hr
= 3600 mg/kg (Oral LD50; Mouse)
= 5045 mg/kg (Oral LD50; Rat)
Ethylbenzene eyes, respiratory system, skin, CNS = 15354 mg/kg (Dermal LD50; Rabbit)
= 17.2 mg/L (Inhalation LC50; Rat) 4 h
= 3500 mg/kg (Oral LD50; Rat)
Heavy aromatic naphtha = 2 mL/kg (Dermal LD50; Rabbit)
= 590 mg/m3 (Inhalation LC50; Rat) 4 h
= 7050 mg/kg (Oral LD50; Rat)
Xylene = 4300 mg/kg (Oral LD50; Rat)
= 5000 ppm (Inhalation LC50; Rat) 4 h
> 1700 mg/kg (Dermal LD50; Rabbit)
Naphthalene eyes, blood, liver, kidneys, skin, CNS = 2500 mg/kg (Dermal LD50; Rat)
= 490 mg/kg (Oral LD50; Rat)
> 20 g/kg (Dermal LD50; Rabbit)
> 340 mg/m3 (Inhalation LC50; Rat) 1 h

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Component IARC: ACGIH - OSHA Regulated NTP:

Carcinogens: Carcinogens
Propan-2-ol A4 - Not Classifiable as
a Human Carcinogen
Ethylbenzene Group 2B; Monograph A3 - Confirmed animal Listed
77, 2000 carcinogen with
unknown relevance to
humans
Xylene A4 - Not Classifiable as
a Human Carcinogen
Naphthalene Group 2B; Monograph A4 - Not Classifiable as Listed Listed
82, 2002 a Human Carcinogen

Component OTHER TOXICOLOGICAL INFORMATION

Naphtha (petroleum), Listed on EC Annex 1 as a carcinogen Category 2. Can be aspired into lungs during ingestion or
hydrotreated heavy vomiting. Aspiration can cause potentially fatal injury to the lungs.
Propan-2-ol Causes eye irritation. Inhalation of this chemical have been shown to produce effects on central
nervous and lungs in laboratory animals. Ingestion produces central nervous system effects such
as dizziness, drowsiness, narcosis, unconsciousness, hypertension, respiratory and cardiac
depression, in humans. Oral and inhalation controlled exposure produced fetotoxic effects in
laboratory animals. Can be aspired into lungs during ingestion or vomiting. Aspiration can cause
potentially fatal injury to the lungs. Exposure to vapors produced kidney and testicular effects in
experimental animals.
Heavy aromatic naphtha Can be aspired into lungs during ingestion or vomiting. Aspiration can cause potentially fatal injury
to the lungs.
Xylene Moderate skin irritation. Fetotoxic and teratogenic effects observed in controlled animal studies.
Central nervous system (CNS) depressant by repeated inhalation or ingestion of large amounts.
Naphthalene Based on animal studies: Toxic by ingestion. IARC Group 2B: Possibly carcinogenic to humans.

12. ECOLOGICAL INFORMATION

PRODUCT INFORMATION

Persistance / Degradability:
See component information below.

Bioaccumulation potential:
See component information below.

COMPONENT INFORMATION

Propan-2-ol
Bioaccumulation: Does not bioaccumulate
Persistence / degradability: Readily biodegradable.
Freshwater Algae Data > 1000 mg/L (EC50; Scenedesmus subspicatus)
Freshwater Fish Species Data = 61200 mg/L (LC50; Pimephales promelas)
= 94900 mg/L (LC50; Pimephales promelas)
= 9640 mg/L (LC50; Pimephales promelas)
Water Flea Data = 13299 mg/L (EC50; Daphnia magna)

Ethylbenzene
Freshwater Algae Data = 4.6 mg/L (EC50; Selenastrum capricornutum)
> 438 mg/L (EC50; Selenastrum capricornutum)
Freshwater Fish Species Data = 14.0 mg/L (LC50; Oncorhynchus mykiss)
= 150.0 mg/L (LC50; Lepomis macrochirus)
= 32 mg/L (LC50; Lepomis macrochirus)
= 4.2 mg/L (LC50; Oncorhynchus mykiss)
= 48.5 mg/L (LC50; Pimephales promelas)
= 9.09 mg/L (LC50; Pimephales promelas)
= 9.6 mg/L (LC50; Poecilia reticulata)
Water Flea Data 1.8 - 2.4 mg/L (EC50; Daphnia magna)

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Heavy aromatic naphtha

Bioaccumulation: log Pow = 5
Persistence / degradability: Readily biodegradable.

Xylene
Bioaccumulation: log Pow = 3.1
Persistence / degradability: Biodegradable.
Freshwater Fish Species Data = 13.4 mg/L (LC50; Pimephales promelas)
= 16.1 mg/L (LC50; Lepomis macrochirus)
= 26.7 mg/L (LC50; Pimephales promelas)
= 8.05 mg/L (LC50; Oncorhynchus mykiss)
Water Flea Data = 0.6 mg/L (LC50; Gammarus lacustris)
= 3.82 mg/L (EC50; water flea)

Naphthalene
Bioaccumulation: log Pow = 3.3
Freshwater Algae Data = 0.4 mg/L (EC50; Skeletonema costatum)
Freshwater Fish Species Data = 1.60 mg/L (LC50; Oncorhynchus mykiss)
= 1.99 mg/L (LC50; Pimephales promelas)
= 6.08 mg/L (LC50; Pimephales promelas)
= 6.14 mg/L (LC50; Pimephales promelas)
Water Flea Data = 2.16 mg/L (EC50; water flea)

13. DISPOSAL CONSIDERATIONS

Waste from residues / unused products:

Dispose of by injection or other acceptable method in accordance with local regulations.

Contaminated packaging:
Dispose of in accordance with local regulations. Triple rinse, crush and ship to sanitary landfill unless
prohibited by local regulations. If reusable containers are used, send them back to the product supplier,
after the required rinsing.

EPA RCRA Hazardous Waste Code:

D001, D018

14. TRANSPORT INFORMATION

DOT:
UN/NA Number: UN 1993
CERCLA RQ: 506 gallons (xylene)

Packing size: < 506 gals

Hazard class: 3
Proper shipping name: Flammable liquid, n.o.s. (contains isopropanol, ethylbenzene), 3, UN 1993, PG III
Label(s): Flammable Liquid 3

Packing size: > 506 gals

Hazard class: 3
Proper shipping name: Flammable liquid, n.o.s. (contains isopropanol, ethylbenzene), 3, UN 1993, PG III,
RQ (Xylene)
Label(s): Flammable Liquid 3

IMDG/IMO

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Shipping name: FLAMMABLE LIQUID, N.O.S. (contains isopropanol, ethylbenzene)

Label(s): Flammable Liquid 3
Class or Div.: 3
UN number: UN 1993
Packing group: III
EMS: F-E, S-E

ICAO/IATA
Shipping name: Flammable liquid, n.o.s. (contains isopropanol, ethylbenzene)
Label(s): Flammable Liquid 3
Class or Div.: 3
UN number: UN 1993
Packing group: III
Packing instruction 309 Max Net Qty/Pkg: 60 L
(passenger aircraft):
Packing instruction 310 Max Net Qty/Pkg: 220 L
(cargo aircraft):
TDG (Canada):
Shipping name: FLAMMABLE LIQUID, N.O.S. (contains isopropanol, ethylbenzene), 3, UN 1993,
PG III
Label(s): Flammable Liquid 3
PIN: UN 1993
Class: 3
Packing group: III

Note 1:
For the applicable placard selection refer to the appropriate transport regulations; the selection may vary depending
on the cargo size and categories of other hazardous materials in the cargo.

15. REGULATORY INFORMATION

International Chemical Inventories

Inventory - United States TSCA - This product complies with TSCA requirements.
Canada DSL Inventory List - This product complies with DSL requirements.
EC-No Some components of this material are not on the EINECS inventory, and
notification has not been made for ELINCS. This material can not be used
commercially in the European Community.
China inventory of existing This product does not comply with China inventory requirements.
chemical substances list -
Inventory - Japan - Existing This product does not comply with JPENCS
and New Chemicals list -
Australia (AICS): All the constituents of this material are listed on the Australian Inventory of
Chemical Substances (AICS).

U.S.A. Regulations

OSHA Hazard Communication Standard:

(Complies with USA OSHA 29 CFR 1910.1200 and ANSI Z 400.1)

EPA RCRA Hazardous Waste Code:

D001, D018

EPA, Sections 311 and 312 - Material Safety Data Sheet Requirements (40 CFR 370):

Immediate (Acute) Health Hazard: YES

Delayed (Chronic) Health Hazard: YES
Fire Hazard: YES
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Sudden Release or Pressure Hazard: None

Reactive Hazard: None

EPA, Sections 313 - List of Toxic Chemicals (40 CFR 372):

This product contains the following substance(s), which appear(s) on the List of Toxic Chemicals:

Additional Regulatory Information

Naphtha (petroleum), hydrotreated heavy
EPA, CERCLA Section 102a/103 Hazardous Substances (40 CFR 302.4): None
CERCLA/SARA - Hazardous Substances and their RQs: None
EPA, SARA TITLE III Section 304, Extremely Hazardous Substances (40 CFR 355.40): None
California Proposition 65: None
Propan-2-ol
EPA, CERCLA Section 102a/103 Hazardous Substances (40 CFR 302.4): Listed
CERCLA/SARA - Hazardous Substances and their RQs: None
EPA, SARA TITLE III Section 304, Extremely Hazardous Substances (40 CFR 355.40): None
California Proposition 65: None
Ethylbenzene
EPA, CERCLA Section 102a/103 Hazardous Substances (40 CFR 302.4): Listed
CERCLA/SARA - Hazardous Substances and their RQs: 1000 lb final RQ
454 kg final RQ
EPA, SARA TITLE III Section 304, Extremely Hazardous Substances (40 CFR 355.40): None
California Proposition 65: carcinogen, initial date 6/11/04
Heavy aromatic naphtha
EPA, CERCLA Section 102a/103 Hazardous Substances (40 CFR 302.4): None
CERCLA/SARA - Hazardous Substances and their RQs: None
EPA, SARA TITLE III Section 304, Extremely Hazardous Substances (40 CFR 355.40): None
California Proposition 65: None
Xylene
EPA, CERCLA Section 102a/103 Hazardous Substances (40 CFR 302.4): Listed
CERCLA/SARA - Hazardous Substances and their RQs: 100 lb final RQ
45.4 kg final RQ
EPA, SARA TITLE III Section 304, Extremely Hazardous Substances (40 CFR 355.40): None
California Proposition 65: None
Naphthalene
EPA, CERCLA Section 102a/103 Hazardous Substances (40 CFR 302.4): Listed
CERCLA/SARA - Hazardous Substances and their RQs: 100 lb final RQ
45.4 kg final RQ
EPA, SARA TITLE III Section 304, Extremely Hazardous Substances (40 CFR 355.40): None
California Proposition 65: carcinogen, initial date 4/19/02

International Hazard Class

WHMIS Hazard Class:
B2 (Flammable Liquids)
D2A (Other Toxic Effects - Very Toxic Material)
D2B (Other Toxic Effects - Toxic Material)

16. OTHER INFORMATION

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Current references:
1. Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices.
American Conference of Governmental Industrial Hygienists, Cincinnati OH.
2. IARC Monograms on the Evaluation of the Carcinogenic Risk of Chemicals to Man. World Health Organization,
International Agency for Research on Cancer. Geneva, Switzerland.
3. Annual Report on Carcinogens. National Toxicology Program. U.S. Department of Heath and Human Services,
Public Health Service.
4. NIOSH Registry of Toxic Effects of Chemical Substances (RTECS). National Institute for Occupational safety
and Health. Cincinnati, OH.
5. LOLI Database.

Explanation of terms:
ACGIH: American Conference of Governmental Industrial Hygienist
ACGIH-TL: Threshold Limit Value
DSL: Domestic Substance List
HMIRC: Hazardous Materials Information Review Commission
IARC: International Agency for Research on Cancer
NTP: National Toxicology Program
NIOSH: National Institute of Occupational Safety & Health
NIOSH-REL: Recommended Exposure Limit
OSHA: Occupational Safety & Health Administration
OSHA-PEL: Permissible Exposure Limit
TSCA: Toxic Substance Control Act (Inventory)

Occupational Exposure Limits indicators: TWA - Time Weighted Average; STEL - Short Term Limit; C - Ceiling
Limit;units: [mg/m3]

ACGIH Notations:
"Skin" refers to the potential significant contribution to the overall exposure by the cutaneous route, including mucous
membranes and the eyes, either by contact with vapors or by direct skin contact with the substance.
"A" notation indicates carcinogenicity as follows:
ACGIH classification: A1 - Confirmed Human Carcinogen; A2 - Suspected Human Carcinogen; A3 - Confirmed
Animal Carcinogen with Unknown Relevance to Humans; A4 - Not Classifiable as a Human Carcinogen; A5 - Not
suspected as a Human Carcinogen.
"SEN" refers to the potential for an agent to product sensitization as confirmed by human and animal data.

Section(s) revised: 2, 8, 15

Additional advice: Consult your supplier if the material is to be used for special applications such as
in the food industry or for hygiene, medical or surgical end-use.

Prepared by: Well Services Safety & Environment (WSSE)

Revision date: 06 June 2006

The information and recommendations contained herein are based upon tests believed to be reliable. However, Schlumberger does
not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY,
WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR
THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be
required. Schlumberger assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or
implied.

End of the Material Safety Data Sheet

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