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DPP - 01 Quantum Chemistry: CSIR-NET - IIT-GATE - IIT-JAM - Other Msc. Entrance

This document contains a practice test on quantum chemistry concepts with 15 multiple-choice questions. The questions cover topics such as operators, commutators, linear operators, and their properties. An answer key is provided at the end listing the correct response for each question.

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anurag pandey
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616 views

DPP - 01 Quantum Chemistry: CSIR-NET - IIT-GATE - IIT-JAM - Other Msc. Entrance

This document contains a practice test on quantum chemistry concepts with 15 multiple-choice questions. The questions cover topics such as operators, commutators, linear operators, and their properties. An answer key is provided at the end listing the correct response for each question.

Uploaded by

anurag pandey
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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CSIR-NET|IIT-GATE|IIT-JAM |Other Msc.

Entrance

DPP - 01 QUANTUM CHEMISTRY


1. The value of A2 [if A = x – (d/dx)] is
(a) x2 + (d2 / dx2) – 2x (d/dx) (b) (d2/dx2) – 2x (d/dx) + x2 – 1
(c) –(d2/dx2) – 2x(d/dx) + x2 – 1 (d) x2 + (d2/dx2) – 2x(d/dx) + 1
2. Consider the statement
(i) “SQRT” operator is Linear operator
(ii) An operator is linear if A (f + g) = Af + Ag A is operator f and g is the function.
(iii) In quantum mechanics operator used must be linear.
The Correct statement above are
(a) (i) (b) (ii) (c) (iii) (d) (ii) and (iii)

3. Two different non zero operator A and B  A  B  satisfy the relation (A + B) (A – B) = A2 – B2 when
(a) AB = A2 and BA = B2 (b) AB + BA = 0
(c) A and B are arbitary (d) AB – BA = 0
3
4. The value of commutator (x , px) is equal to
2
(a) x2 (b) -3x i (c) + 3x 2i (d) zero
5. Consider the statement
(i) If A is linear operator then the value of [Af(x)]2 = A2 f(x)
(ii) The value of commutator [x,(x,px2)] is equal to 0.
(iii) The multipliction of two liner operator is linear.
(iv) Square root is not linear but squrae is a linear operator
The correct statements above are
(a) (i) and (iii) (b) (ii) and (iv) (c) (i),(ii),(iii) (d) (iii) only
6. Consider the statement
(i) The commutator of d/dx with x is a unit operator.
(ii) Differentiation and integration operator are linear because for being a linear operator A {C1f1(x)| +
C2f2(x)} = C1Af1(x) + C2Af2(x) is the condition
(iii) Linear operator always commute with any number.
The correct statement above are
(a) (i) and (ii) (b) (ii) and (iii) (c) (i), (ii) and (iii) (d) None
st
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DPP-(1) / QUANTUM CHEMISTRY

7. Evaluate the commutator {x, d/dx} operating on arbitary wave function f(x)
(a) 0 (b) –1 (c) +1 (d) 
8. The value of [ x, px] is equal to
(a) 0 (b)  / i (c) i (d)  / i
9. The value of the commutator [x, [x, px]] is
(a) ix(2)  i (b) i (c) i (d) 0
10. The operator [x,[x,p2]] is identical with
(a) [px, [x,p]] (b) [xp,[x,p]] (c) –[p,[x2,p]] (d) [x,[x2,p]]
11. The value of commutator (1/x, px)
(a) (h / 2i)x 2 (b) (h / 2i)x 2

(c) (h / 2i) x 2 (d) (h / 2i) x 2


12. The value of commutator (x, px2) is given by

(a) 2 ih /  (b) (h2 / 22 ) (d / dx)

(c) (h2 / 4 2 ) (d / dx) (d) (h2 / 22 )(d / dx)

13.
2
2 2
 
When the operator   / 2m d / dx operates as a function e  ikx

(a) k 2 2e ikx (b) i k 2 2e ikx

(c) i 2e  ikx (d) 2e ikx


14. Denote the commutator of two matrices A and B by [A,B] = AB – BA the anti-commutator
{A, B} = AB + BA
(a) –B[A, C] (b) B[A, C]
(c) –B{A, C} (d) [A, C]B
15. The commutator of x with Hamiltonian H, [x, H2] is
(a) 0 (b) i (c) –( 2/2m) px (d) (i  / m) p x
×××××

ANSWERS
1.(b) 2. (d) 3. (d) 4. (c) 5. (d) 6. (c) 7. (b)
8. (d) 9. (d) 10.(c) 11. (a) 12. (b) 13. (a) 14. (c)
15. (d)

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