Salt Analysis
Salt Analysis
Salt Analysis
Basic radicals
GROUP EXPERIMENT OBSERVATION INFERENCE
Confirmatory test:
1). Gp. 0- salt + NaOH + Nessler’s reagent-brown ppt. (NH4+)
3). Gp.2-a) salt+ water+ acetic acid + potassium ferrocyanide – chocolate brown ppt. (Cu+2)
(when black ppt comes)
4). Gp.3- a) salt+ water + blue litmus sol.-blue lake (Al+3), cobalt nitrate test- blue mass
5). Gp.4-a) ppt + HCl+ potassium ferrocyanide - bluish white ppt (Zn+2),
b) Second part adds amm. Sulphate-white ppt.Sr+2 c) Third part –add amm.oxalate-white
ppt.Ca+2 Flame test- Ba+2 apple green,Sr+2 –crimson red and Ca+2 – brick red
Acidic radicals
For SO4-2
For PO4-3
Salt sol. + AgNO3 gives pale yellow ppt. ,. partially soluble in NH4OH
For I- ---
For NO3- --
Salt + FeSO4 + conc. H2SO4 gives black brown ring (ring test)