2017 MSDS Procion Turquoise PX-GR 150

Safety Data Sheet
in accordance with regulation (EC) No 1907/2006 (EC No 453/2010)
Procion Turquoise PX-GR 150%

000055035375 Page 1/10
Version 3.3 / D / EN Revision Date: 22.06.2017
replaces version: 3.2 on 19.11.2014
generated on: 28.06.2001
SECTION 1: Identification of the substance/preparation and company
1.1 Product identifier
1.2 Relevant Identified uses of the substance or mixture and uses advised against
Use pattern :
Textile dye
1.3 Details of the supplier of the safety data sheet
DyStar Colours Distribution GmbH
Am Prime Park 10-12

D - 65479 Raunheim
Telephone no. +49 6142 4072 3172
Telefax no. +49 6142 4072 3000
[email protected]
1.4 Emergency telephone number
Emergency telephone number: +49 2365 4984140
SECTION 2: Hazards identification
2.1 Classification of the Substance or Mixture
According to regulation (EC) 1272/2008 on classification, labelling and packaging of

substances and mixtures
No labelling is required in accordance with GHS directives.
2.2 Label elements
Precautionary Statements (Prevention):

P260 Do not breathe dust.
Precautionary Statements (Response):
Precautionary Statements (Storage):

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Precautionary Statements (Disposal):
2.3 Other hazards
If applicable in this section are given hazards which are not part of the overall classification but can
contribute to the hazards which may be associated with the substance or mixture.
Not applicable
SECTION 3: Composition/information on ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical characterization
azo copper complex reactive dyestuff, dust free preparation
SECTION 4: First aid measures
4.1 Description of first aid measures
General information: Take off immediately all contaminated clothing.
After inhalation: Upon inhalation of aerosol/vapour/dust: Take the patient into the fresh air; if there is
difficulty in breathing, medical advice is required.
After contact with skin: Remove all contaminated clothing immediately. Cleansing with plenty of water,
soap or other non-irritating cleansing agents.
After contact with eyes: Contamination of the eyes must be treated by thorough irrigation with water, with
the eyelids held open. A doctor (or eye specialist ) should be consulted immediately.
After ingestion: If the product is swallowed, the patient must at once drink water repeatedly, if possible
with the addition of activated carbon. If the patient feels unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Please see hazard statements in section 2.2 if given and information in this section if stated.
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4.3 Indication of any immediate medical attention and special treatment needed
Please see precautionary statements in section 2.2 as well as first aid information in this section if
stated.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media: Water spray, foam, dry powder.
Extinguishing media that must not be used for safety reasons: CO2
5.2 Special hazards arising from the substance or mixture
not determined
5.3 Advice for firefighters
Special protective equipment for firefighting: Firemen have to wear self-contained breathing apparatus.
Further information: Fire residues and contaminated firefighting water must be disposed of in
accordance with the local regulations.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions: Avoid formation and deposition of dust.
6.2 Environmental precautions
Environmental precautions: Do not empty into drains or waters.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up/taking up: Take up spilled product with dust-binding material or suitable
vacuum cleaner. Fill into labelled, sealable containers.
6.4 Reference to other sections
Additional information: For further disposal measures see chapter 13.
SECTION 7: Handling and storage

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7.1 Precautions for safe handling
Advice on safe handling: Avoid formation and deposition of dust.

Keep container tightly closed and dry.
Advice on protection against fire and explosion: Observe the usual precautionary measures required for
chemicals with dust-explosive properties. Observe national regulations.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels: Store in original container in a cool, dry place.
In filling operations take precautionary measures against static discharges.
Do not allow product temperature to exceed 60 °C.
Storage class: 11 Combustible solids
Storage stability: Storage period: 36 Months
7.3 Specific end use(s)
not determined
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Ingredients with occupational exposure limits to be monitored :

Not applicable
8.2 Exposure controls
General protective measures: Do not breathe dust. Avoid contact with eyes and skin. Take off
immediately all contaminated clothing.
Inhalation of dust and aerosols must be absolutely prevented by either adequate ventilation or by a
suitable mask. People with chron ic respiratory problems should not work with reactive dyestuff
powders. If symptoms such as tightness in the chest or asthma occur w hile handling reactive dyestuff
powders, a physician should be consulted as soon as possible. If hypersensitivity is confirmed, all
contact with reactive dyestuff powders must cease immediately.
Hygiene measures: Keep away from food and drink stuffs.

Do not eat, drink or smoke at work.
Wash hands before breaks and at end of work and use skin-protecting ointment.
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Respiratory protection : Dust mask with particle filter.
Hand protection : Wear suitable gloves e.g. of PVC or nitrile rubber. In the event of
contamination, change protective gloves immediately.
Eye protection : safety glasses with side protection shield
Body protection : Wear protective clothing.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Form : powder
Colour : green to blue
Odour : odourless
Melting point : > 300 °C
Boiling point not determined
Flash point : not determined
flammability : not determined
Lower explosion limit : not determined
Upper explosion limit : not determined
Vapour pressure : not determined
Density : not determined
Solubility in water : 100 g/l (20 °C)
pH value : approx. 7,0 (20 °C, 30 g/l)
Octanol/water partition coefficient (log not determined

Pow) :
Viscosity (dynamic) : not determined
Viscosity (kinematic) : not determined

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Viscosity (flow time) : not determined
9.2 Other information
Combustion number : not determined
Dust explosion class : not determined
Bulk density : approx. 830 kg/m3
Further information (phys.-chem.) not necessary
SECTION 10: Stability and reactivity
10.1 Reactivity
No hazardous reactions when stored and handled according to prescribed instructions.
10.2 Chemical stability
Thermal decomposition No thermal decomposition when stored and handled correctly.
10.3 Possibility of hazardous reactions
Hazardous reactions: In the case of dusty organic products the possibility of a dust explosion should
always be considered.
Hazardous decomposition products: Not applicable
10.4 Conditions to avoid
For avoidable conditions: not necessary
10.5 Incompatible materials
For avoidable materials: not necessary
10.6 Hazardous decomposition products
Not applicable
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute oral toxicity : LD50 > 2.000 mg/kg (rat)

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Acute inhalation toxicity : LC50 > 16,1 mg/l (4 h, rat)
Acute dermal toxicity : not determined
Irritant effect on skin : non-irritant (rabbit)
Irritant effect on eyes : non-irritant (rabbit eye)
Sensitization :
This dye belongs to the class of reactive dyes. A sensitizing
effect on the respiratory tract has been noted with some
representativ es of this substance class. No reports of ill effects
provided product was correctly handled and processed.
Repeated dose toxicity not determined
Mutagenicity: not determined
Teratogenicity : not necessary
Carcinogenicity : not necessary
SECTION 12: Ecological information
12.1 Toxicity
Fish toxicity : LC50 > 100 mg/l (96 h, Brachydanio rerio)
Daphnia toxicity : not determined
Algae toxicity : not determined
Bacteria toxicity : IC50 > 100 mg/l (3 h, activated sludge)
Remarks: The data is based on the toxicological properties of the components of the product.
Contains organically bound halogen, but in hydrolysable form. This reactive dye can slightly increase
the adsorbable organic halogen content of the effluent.
This product contains approx. 2.1 % complex bonded copper.
The product does not release nitrogen which can contribute to eutrophication.
The product does not contain phosphates or organophosphorus compounds.
12.2 Persistence and degradability

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Physico-chemical eliminability : not determined
Biodegradability : < 20 % (DOC decrease)

Method : OECD 303A
Biodegradability :
If regulations are followed when introducing effluent into
biological waste water treatment plants, no adverse effect on the
degrada tion activity of activated sludge is to be expected.
Behaviour in environmental not determined

compartments:
Dissolved Organic carbon (DOC) : not determined
Chemical oxygen demand (COD) : 445 mg/g
Biochemical oxygen demand (BOD5): < 30 mg/g
12.3 Bioaccumulative potential
not determined
12.4 Mobility in soil
not determined
12.5 Results of PBT and vPvB assessment
not determined
12.6 Other adverse effects
not determined
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product: If utilisation or recycling of the product is not possible, it should be disposed of according to the
local regulations and laws, e. g. by incineration in a suitable plant.
European Waste Catalogue (EWC) code: 040217 Dyestuffs and pigments other than those
mentioned in 040216
Uncleaned packaging: Soiled, empty containers are to be treated in the same way as the contents.
SECTION 14: Transport information

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ADR Non dangerous goods

ADNR Non dangerous goods
RID Non dangerous goods
IMDG Non dangerous goods
IATA_C Non dangerous goods
IATA_P Non dangerous goods
14.1 UN number
See above entry at the respective regulation.
14.2 UN proper shipping name
14.3 Transport hazard class(es)
14.4 Packing group
14.5 Environmental hazards
14.6 Special precautions for user
Keep separated from foodstuffs.
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
No transport in bulk according to Annex II of MARPOL 73/78 and the IBC code foreseen for this
substance or mixture.:
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
TA-Luft (Ger.) : Not applicable

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Water Hazard Class (Ger.) : WGK 2 - impairment of water quality WGK = Classification in
accordance with the German Water Resources Act
Annex 2 VwVwS (Germany) dated Mai, 17th 1999
15.2 Chemical safety assessment
not determined
SECTION 16: Other information
Text of all shortcuts referred to in sections 2 and 3:
This information is based on our present state of knowledge. It should not therefore be
construed as guaranteeing specific properties of the products described or their suitability for a
particular application.

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Safety Data Sheet

in accordance with regulation (EC) No 1907/2006 (EC No 453/2010)

Procion Turquoise PX-GR 150%

SECTION 1: Identification of the substance/preparation and company

1.1 Product identifier

Procion Turquoise PX-GR 150%

1.3 Details of the supplier of the safety data sheet

DyStar Colours Distribution GmbH

Am Prime Park 10-12

1.4 Emergency telephone number

Emergency telephone number: +49 2365 4984140

SECTION 2: Hazards identification

2.1 Classification of the Substance or Mixture

According to regulation (EC) 1272/2008 on classification, labelling and packaging of

No labelling is required in accordance with GHS directives.

2.2 Label elements

Precautionary Statements (Prevention):

Precautionary Statements (Response):

Precautionary Statements (Storage):

Procion Turquoise PX-GR 150%

Precautionary Statements (Disposal):

2.3 Other hazards

SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

4.1 Description of first aid measures

General information: Take off immediately all contaminated clothing.

Procion Turquoise PX-GR 150%

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media: Water spray, foam, dry powder.

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions: Avoid formation and deposition of dust.

6.2 Environmental precautions

Environmental precautions: Do not empty into drains or waters.

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

Additional information: For further disposal measures see chapter 13.

SECTION 7: Handling and storage

Procion Turquoise PX-GR 150%

7.1 Precautions for safe handling

Advice on safe handling: Avoid formation and deposition of dust.

7.2 Conditions for safe storage, including any incompatibilities

Storage class: 11 Combustible solids

Storage stability: Storage period: 36 Months

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Ingredients with occupational exposure limits to be monitored :

8.2 Exposure controls

Hygiene measures: Keep away from food and drink stuffs.

Procion Turquoise PX-GR 150%

Respiratory protection : Dust mask with particle filter.

Eye protection : safety glasses with side protection shield

Body protection : Wear protective clothing.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties