MATERIAL SAFETY DATA SHEET

PRODUCT

3D TRASAR 3DT129

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME : 3D TRASAR 3DT129

APPLICATION : CORROSION/SCALE INHIBITOR

Date issued : 11/08/2005

COMPANY IDENTIFICATION

CHINA: NALCO INDUSTRIAL SERVICES (SUZHOU) CO LTD TEL: 86-512-68255001 FAX: 86-512-68250130
INDIA: NALCO INDIA LIMITED TEL: 91-33-22172066 FAX: 91-33-22296858
INDONESIA: PT NALCO INDONESIA TEL: 62-21-8753175 FAX: 62-21-8753167
KOREA: NALCO KOREA LIMITED TEL: 82-2-789-6961 FAX: 82-2-786-3140
MALAYSIA: NALCO INDUSTRIAL SERVICES MALAYSIA SDN BHD TEL: 603-5569 4118 FAX: 603-5569 5955
THE PHILIPPINES: NALCO PHILIPPINES INC TEL: 63-49-5451550 FAX: 63-49-5453442
SINGAPORE: NALCO PACIFIC PTE LTD TEL: 65-6861-4011 FAX: 65-6862 0850
THAILAND: NALCO INDUSTRIAL SERVICES (THAILAND) CO LTD TEL: 66-38-955-160 FAX: 66-38-955-166

See Section 16 for address information.

EMERGENCY TELEPHONE NUMBER(S) : See section 16, for Emergency Telephone Numbers.

2. COMPOSITION/INFORMATION ON INGREDIENTS

CHEMICAL DESCRIPTION : Phosphoric acid, zinc chloride, polymer, water.

Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for
the nature of the hazard(s).

CHEMICAL NAME CAS NO % (w/w)

Zinc Chloride 7646-85-7 10.0 - 30.0

Phosphoric Acid 7664-38-2 10.0 - 30.0
Other ingredients determined not to be hazardous to 100%

3. HAZARDS IDENTIFICATION

HUMAN HEALTH HAZARDS - ACUTE

EYE CONTACT
Corrosive. Will cause eye burns and permanent tissue damage.

SKIN CONTACT
May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid
administered.

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3D TRASAR 3DT129

INGESTION
Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach.

INHALATION
Not a likely route of exposure. Elevated temperatures or mechanical action may form vapors, mists or fumes
which may be irritating to the eyes, nose, throat and lungs.

HUMAN HEALTH HAZARDS - CHRONIC

No adverse effects expected other than those mentioned above.

ENVIRONMENTAL HAZARDS
Keep out of waterways. Spilled product may pose a risk to the aquatic ecosystem if released.

4. FIRST AID MEASURES

EYE CONTACT
Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately
flush eye with water for at least 15 minutes while holding eyelids open.

SKIN CONTACT
Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes. For a large
splash, flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with
plenty of water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.

INGESTION
Get immediate medical attention. DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to
drink.

INHALATION
Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.

NOTE TO PHYSICIAN
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of
the patient, the physician's judgement should be used to control symptoms and clinical condition.

5. FIRE FIGHTING MEASURES

FLASH POINT : Not flammable

EXTINGUISHING MEDIA
This product would not be expected to burn unless all the water is boiled away. The remaining organics may be
ignitable. Use extinguishing media appropriate for surrounding fire.

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3D TRASAR 3DT129

FIRE AND EXPLOSION HAZARD

May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of phosphorus (POx) under fire
conditions. May evolve oxides of nitrogen (NOx) under fire conditions. May evolve ammonia (NH4) under fire
conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS
Restrict access to area as appropriate until clean-up operations are complete. Use personal protective
equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is
safe to do so. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Do not
touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify
appropriate government, occupational health and safety and environmental authorities.

METHODS FOR CLEANING UP

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches
or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated
surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated
recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal
Considerations).

ENVIRONMENTAL PRECAUTIONS
Prevent material from entering sewers or waterways. Spilled product may pose a risk to the aquatic ecosystem if
released. If drains, streams, soil or sewers become contaminated, notify local authority.

7. HANDLING AND STORAGE

HANDLING
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe
vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills,
leaks, etc.) readily available. Ensure all containers are labelled.

STORAGE CONDITIONS
Store in suitable labelled containers. Store the containers tightly closed. Store separately from bases.

SENSITIVITY TO STATIC DISCHARGE

Not expected to be sensitive to static discharge.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

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3D TRASAR 3DT129

OCCUPATIONAL EXPOSURE LIMITS

Exposure guidelines have not been established for this product. Available exposure limits for the substance(s)
are shown below.

OCCUPATIONAL EXPOSURE LIMITS TWA TWA STEL STEL

ppm mg/m3 ppm mg/m3
ACGIH/TLV
PHOSPHORIC ACID 1 3
ZINC CHLORIDE FUME 1 2
CHINA
PHOSPHORIC ACID 1 3
ZINC CHLORIDE FUME 1 2
Hong Kong
PHOSPHORIC ACID 1 3
ZINC CHLORIDE FUME 1 2
Indonesia
PHOSPHORIC ACID 1 3
ZINC CHLORIDE FUME 1 2
JAPAN
PHOSPHORIC ACID 1
KOREA
PHOSPHORIC ACID 1 3
ZINC CHLORIDE FUME 1 2
MALAYSIA
PHOSPHORIC ACID 1
ZINC CHLORIDE FUME 1
OSHA/PEL
PHOSPHORIC ACID 1 3
ZINC CHLORIDE FUME 1 2
THE PHILIPPINES
PHOSPHORIC ACID 1
ZINC CHLORIDE FUME 1
SINGAPORE
PHOSPHORIC ACID 1 3
ZINC CHLORIDE FUME 1 2
Taiwan
PHOSPHORIC ACID 1
ZINC CHLORIDE FUME 1
THAILAND
PHOSPHORIC ACID 1
ZINC CHLORIDE FUME 1

MONITORING MEASURES
A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be
desorbed or removed and analyzed as referenced below:

Substance(s) Method Analysis Absorbant

Phosphoric Acid US NIOSH: 7903 Ion chromatography Silica gel

ENGINEERING MEASURES
The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples
should be handled in a fumehood. Provide mechanical ventilation of confined spaces.

PERSONAL PROTECTION

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GENERAL ADVICE
The use and choice of personal protection equipment is related to the hazard of the product, the workplace and
the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area
where this product is handled should at least wear safety glasses with side-shields.

RESPIRATORY PROTECTION
An approved respirator must be worn if the occupational exposure limit is likely to be exceeded. An organic
vapor/acid gas cartridge with dust/mist prefilter may be used. In event of emergency or planned entry into
unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is
required, institute a complete respiratory protection program including selection, fit testing, training,
maintenance and inspection.

HAND PROTECTION
Neoprene gloves, nitrile gloves. Gloves should be replaced immediately if signs of degradation are observed.

SKIN PROTECTION
Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots. A full slicker suit is
recommended if gross exposure is possible.

EYE PROTECTION
Wear a face shield with chemical splash goggles.

HYGIENE RECOMMENDATIONS
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep
a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area.
Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling
this product never eat, drink or smoke.

ENVIRONMENTAL EXPOSURE CONTROL PRECAUTIONS

Consider the provision of containment around storage vessels.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE Liquid

APPEARANCE Clear Amber
ODOR None
FLASH POINT Not flammable
SPECIFIC GRAVITY 1.33 - 1.41 @ 25 °C
SOLUBILITY IN WATER Complete

Note: These physical properties are typical values for this product and are subject to change.

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10. STABILITY AND REACTIVITY

STABILITY
Stable under normal conditions.

HAZARDOUS POLYMERIZATION
Hazardous polymerization will not occur.

CONDITIONS TO AVOID
Freezing temperatures.

MATERIALS TO AVOID
Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium
hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or
boiling and toxic vapors.

HAZARDOUS DECOMPOSITION PRODUCTS

Under fire conditions: Oxides of phosphorus
Oxides of carbon
Oxides of nitrogen
Ammonia

11. TOXICOLOGICAL INFORMATION

ACUTE TOXICITY DATA

No toxicity studies have been conducted on this product.

SENSITIZATION
This product is not expected to be a sensitizer.

CARCINOGENICITY
None of the substances in this product are listed as carcinogens by the International Agency for Research on
Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial
Hygienists (ACGIH).

HUMAN HAZARD CHARACTERIZATION

Based on our hazard characterization, the potential human hazard is: High

12. ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL EFFECTS
No toxicity studies have been conducted on this product.

MOBILITY AND BIOACCUMULATION POTENTIAL

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3D TRASAR 3DT129

This preparation or material is not expected to bioaccumulate.

ENVIRONMENTAL HAZARD CHARACTERIZATION

Based on our hazard characterization, the potential environmental hazard is: Moderate

13. DISPOSAL CONSIDERATIONS

Hazardous wastes must be transported by a licensed hazardous waste transporter and disposed of or treated in a
properly licensed hazardous waste treatment, storage, disposal or recycling facility. Consult local, state, and
federal regulations for specific requirements.

Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed
contractor.

NATIONAL REGULATIONS, CHINA

Comply with local regulations.

NATIONAL REGULATIONS, INDIA

Dispose of unused product in accordance with the "Hazardous Wastes (Management and Handling) Rules 1989"
and local and State legislation, as applicable.

NATIONAL REGULATIONS, INDONESIA

Dispose of unused product in accordance with "Government Regulation No.19/1994 On the Treatment of
Dangerous And Toxic Waste" (and amendments) as applicable.

NATIONAL REGULATIONS, KOREA

Waste disposal should comply with the Waste Control Act.

NATIONAL REGULATIONS, MALAYSIA

Dispose of in accordance with the Environmental Quality (Scheduled Wastes) Regulation 1989 and other
guidelines issued by DOE and/or local authorities.

NATIONAL REGULATIONS, PHILIPPINES

Dispose of in accordance with Presidential Decree No. 984-1976 ("The Pollution Control Law"); DENR
Department Administrative Order No.29-92 ("The Implementing Rules or Regulations of RA6969") and
Presidential Decree No.825.

NATIONAL REGULATIONS, SINGAPORE

Dispose of waste in accordance with the Environmental Health Act (Chapter 95, Rg 11), Environmental Public
Health (Toxic Industrial Waste) Regulations 1990 Ed.

NATIONAL REGULATIONS, THAILAND

Dispose of hazardous waste in accordance with the "The Notification of the Ministry of Industry No. 6B.E. 2450,
subject : Disposal of Wastes or Unusable Materials ", "The Notification of the Ministry of Industry No. 1B.E. 2451,
subject : Disposal of Wastes or Unusable Materials ".

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14. TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of
lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.:

LAND TRANSPORT

Proper Shipping Name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

Technical Name(s) PHOSPHORIC ACID, ZINC CHLORIDE
UN/ID No UN 3264
Hazard Class - Primary 8
Packing Group III
HAZCHEM CODE: 2X

NATIONAL REGULATIONS, CHINA

Comply with local regulations.

NATIONAL REGULATIONS, INDIA

Transport in accordance with the Central Motor Vehicles Rules 1989.

NATIONAL REGULATIONS, INDONESIA

Transport in accordance with all government regulations, including "Regulation of the Minister of Health
No.453/Man.Kes/PER/XI/1983.

NATIONAL REGULATIONS, KOREA

Land transport should comply with the Ministerial Decree of Toxic Chemicals Control Law and the Regulations
Regarding the Fire Fighting Techniques Standards, as applicable.

NATIONAL REGULATIONS, MALAYSIA

There are no regulations specifically governing the transport of chemicals. Use best practice.

NATIONAL REGULATIONS, PHILIPPINES

Transport in accordance with the following legislation (as applicable): Presidential Decree No. 1185, 1977
("Fire Code of the Philippines") and implementing rules and regulations; Presidential Decree No. 856, 1975
("Code of Sanitation"); Republic Act No 6969, 1990 ("Toxic Substances and Hazardous and Nuclear Wastes
Control Act") and implementing rules and regulations.

NATIONAL REGULATIONS, SINGAPORE

Land Transport complies with the Environmental Pollution Control (Hazardous Substances) Regulations 1999,
which follows the "Specification for Caution Labelling for Hazardous Substances" - Singapore Standard 286
(1984).

NATIONAL REGULATIONS, THAILAND

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The product should be transported in accordance with "Hazardous Substances Acts B.E.2535", "Notification of
Ministry of Public Health Re: Label and Level of Toxicity of Dangerous Articles Which are Under the
Responsibility of Food and Drug Administration 2534 (If applicable)" and "Notification of Land Transportation
Department, Subject : Label of truck which contain hazardous material, Notification date : 14 November
B.E.2543 (14 November 2000)".

AIR TRANSPORT (ICAO/IATA)

Proper Shipping Name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

Technical Name(s) PHOSPHORIC ACID, ZINC CHLORIDE
UN/ID No UN 3264
Hazard Class - Primary 8
Packing Group III
IATA Cargo Packing Instructions 820
IATA Cargo Aircraft Limit 60 L
IATA Passenger Packing Instructions Y818 / 818
IATA Passenger Aircraft Limit 1L/5L

MARINE TRANSPORT (IMDG/IMO)

Proper Shipping Name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

Technical Name(s) PHOSPHORIC ACID, ZINC CHLORIDE
UN/ID No UN 3264
Hazard Class - Primary 8
Packing Group III
EmS-Nr. F-A, S-B

15. REGULATORY INFORMATION

NATIONAL REGULATIONS, EUROPE AND MALAYSIA

European:

HAZARD SYMBOLS:

CLASSIFICATION: CORROSIVE / CDANGEROUS FOR THE ENVIRONMENT / N

Contains: Phosphoric Acid, Zinc Chloride

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3D TRASAR 3DT129

RISK PHRASES:

R34 Causes burns.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Malaysian:

HAZARD SYMBOLS:

CLASSIFICATION: CORROSIVE / C

Contains: Phosphoric Acid, Zinc Chloride

RISK PHRASES:

R34 Causes burns.

SAFETY PHRASES:

S24/25 Avoid contact with skin and eyes.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
S57 Use appropriate containment to avoid environmental contamination.

INTERNATIONAL REGULATIONS :

NFPA RATING
HEALTH : 3 FLAMMABILITY : 1 INSTABILITY : 0 OTHER : -
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme

INTERNATIONAL CHEMICAL CONTROL LAWS :

TOXIC SUBSTANCES CONTROL ACT (TSCA)

The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710).

EUROPE

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3D TRASAR 3DT129

The substance(s) in this preparation are included in or exempted from the EINECS or ELINCS inventories.

CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA)

The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been
reported in accordance with the New Substances Notification Regulations.

JAPAN
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical
Substances and are listed on the Ministry of International Trade & industry List (MITI).

KOREA
All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing
Chemicals List (ECL).

THE PHILIPPINES
All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine
Inventory of Chemicals & Chemical Substances (PICCS).

CHINA
All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing
Chemical Substances China (IECSC).

16. OTHER INFORMATION

This product material safety data sheet provides health and safety information. The product is to be used in
applications consistent with our product literature. Individuals handling this product should be informed of the
recommended safety precautions and should have access to this information. For any other uses, exposures
should be evaluated so that appropriate handling practices and training programs can be established to insure
safe workplace operations. Please consult your local sales representative for any further information.

ADDRESSES AND CONTACT POINTS:

NALCO INDUSTRIAL SERVICES (SUZHOU) CO LTD; 88 Ta Yuan Road, Suzhou New Development Zone,
Jiangsu 215011 PRC Contact: Sam Chen, 86-512-68255001

NALCO INDIA LIMITED; 20/A Park St, Culcutta 700016 India

PT NALCO INDONESIA; Jl. Pahlawan, Desa Karang Asem Timur, Citeureup, Bogor, Indonesia

NALCO KOREA LIMITED; 11th Fl, 63BLDG, 60, Yoido-dong Young Deung Po-Gu, Seoul, Korea

NALCO INDUSTRIAL SERVICES MALAYSIA SDN BHD; No 1, Jalan Jururancang U1/21, Seksyen U1, Hicom-
Glenmarie Industrial Park, 40150 Shah Alam, Selangor Darul Ehsan, Malaysia

NALCO PHILIPPINES INC; Barrio Real, Calamba, Laguna, Philippines

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NALCO PACIFIC PTE LTD; 21 Gul Lane, Jurong Town, Singapore 629416

NALCO INDUSTRIAL SERVICES (THAILAND) CO LTD; Rayong Plant, 109/19 M00 4, Eastern Seaboard
Industrial Estate, Soi ESIE 6, T. Pluakdaeng, A. Pluakdaeng Rayong 21140 Thailand

EMERGENCY TELEPHONE NUMBER(S):

CHINA: 512-68255001
KOREA: 02-789-6961
INDIA: 0-33-6740395
INDONESIA: 62-21-8753175
MALAYSIA: 603-5569 4118
THE PHILIPPINES: 63-49-5451550
SINGAPORE: 65-6861-4011
THAILAND: 38-955-160

Prepared By Nalco Asia Pacific, Safety, Health and Environment (SHE) Specialist
Date issued: 11-Aug-05
Replaces: -

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