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FOAM 2000 CL Page 1 of 8

SAFETY DATA SHEET


FOAM 2000 CL
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
Date issued 15.03.2012
1.1. Product identifier
Product name FOAM 2000 CL
Article no. 12211, 12212, 12423, 56445
1.2. Relevant identified uses of the substance or mixture and uses advised against
Product group Alkaline foam cleaning agent with chlorine.
Use of the substance/preparation Strong alkaline foam detergent.
Relevant identified uses SU3 Industrial uses: Uses of substances as such or in preparations at
industrial sites
SU4 Manufacture of food products
PC35 Washing and cleaning products (including solvent based products)
PROC10 Roller application or brushing
ERC8A Wide dispersive indoor use of processing aids in open systems
Uses advised against No specific uses advised against are identified.
1.3. Details of the supplier of the safety data sheet

Company name Novadan ApS


Postal address Platinvej 21
Postcode DK-6000
City Kolding
Country Danmark
Tel + 45 76 34 84 00
Fax + 45 75 50 43 70
E-mail [email protected]
Website http://www.novadan.dk
1.4. Emergency telephone number
Emergency telephone Link to national poison
centers:http://echa.europa.eu/help/nationalhelp_contact_en.asp:

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification according to C; R31,R35
67/548/EEC or 1999/45/EC
Substance / mixture hazardous For further information, please refer to section 11.
properties
2.2. Label elements
Hazard symbol
FOAM 2000 CL Page 2 of 8
R phrases R31 Contact with acids liberates toxic gas.
R35 Causes severe burns.
S phrases S23 Do not breathe vapour.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice
immediately (show the lable where possible).
S51 Use only in well-ventilated areas.
Composition on the label Caustic potash, Sodium hydroxide, Sodium hypochlorite; active chlorine
EEC-directive Regulation (EC) No 648/2004 of the European Parliament and of the Council
of 31 March 2004 on detergents.
Dangerous Preparations Directive 1999/45/EC.
Dangerous Substance Directive 67/548/EEC.
2.3. Other hazards
Health effect Corrosive to skin and eyes. May cause permanent damage to the eyes,
especially if the product is not washed away IMMEDIATELY. See section 11
for additional information on health hazards.
Environmental effect Substantial amounts of the product may lead to a local change in acidity in
small water systems which may have adverse effects on aquatic organisms.
This product does not contain any PBT or vPvB substances.

SECTION 3: Composition/information on ingredients


3.2. Mixtures
Component name Identification Classification Contents
Sodium hypochlorite, solution ...% CAS no.: 7681-52-9 C; R34 15 - 30 %
Cl active EC no.: 231-668-3 R31
Index no.: 017-011-00-1 N; R50
Skin Corr. 1B; H314
Aquatic Acute 1; H400

Caustic potash CAS no.: 1310-58-3 C; R35 5 - 15 %


EC no.: 215-181-3 Xn; R22
Index no.: 019-002-00-8 Acute tox. 4; H302
Synonyms: Potassium hydroxide Skin Corr. 1A; H314
Sodium hydroxide CAS no.: 1310-73-2 C; R35 1-5%
EC no.: 215-185-5 Skin Corr 1A;H314
2-Phosphonobutan-1,2,4- CAS no.: 37971-36-1 Xi; R36/38 1-5%
tricarboxylic acid EC no.: 253-733-5
Dodecyldimethylamine oxide CAS no.: 1643-20-5 Xi; R38,R41 1-5%
EC no.: 216-700-6
Component comments 15-30%: Chlorine-containing bleaching agent.
5-15%: nonionic surfactant
<5%: phosphonate , anionic surfactant
The Full Text for all R-Phrases and Hazard Statements are Displayed in
Section 16.

SECTION 4: First aid measures


4.1. Description of first aid measures
General Remove affected person from source of contamination.
Inhalation Move injured person into fresh air and keep person calm under observation. If
uncomfortable: Seek hospital and bring these instructions. In case of chlorine
poisoning: Move injured person to fresh air and after that to hospital.
Skin contact Wash off promptly and flush contaminated skin with water. Promptly remove
clothing if soaked through and flush skin with water. Get medical attention if
FOAM 2000 CL Page 3 of 8
any discomfort continues.
Eye contact Important! Immediately rinse with water for at least 15 minutes. May cause
permanent damage if eye is not immediately irrigated. Make sure to remove
any contact lenses from the eyes before rinsing. Immediately transport to
hospital or eye specialist. Continue flushing during transport to hospital.
Ingestion Immediately rinse mouth and drink plenty of water. Call an ambulance. Bring
along these instructions. Do not induce vomiting. If vomiting occurs, the head
should be kept low so that stomach vomit doesn't enter the lungs. Do not
give victim anything to drink if he is unconscious.
Recommended personal protective Wear necessary protective equipment. For personal protection, see section 8.
equipment for first aid responders
4.2. Most important symptoms and effects, both acute and delayed
Acute symptoms and effects As described in section 2.2 and 2.3.
Delayed symptoms and effects The etching penetrates deeply into the tissue and is first noticed after a
while.
4.3. Indication of any immediate medical attention and special treatment needed
Other Information In case of unconsciousness, ingestion or eye contact: Immediately call a
doctor / ambulance. Show this safety data sheet.

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media Use fire-extinguishing media appropriate for surrounding materials.
5.2. Special hazards arising from the substance or mixture
Fire and explosion hazards This product is not flammable. During fire, gases hazardous to health may be
formed. Water used for fire extinguishing, which has been in contact with the
product, may be corrosive.
Hazardous combustion products Toxic gases/vapours/fumes of: Chlorine. Hydrogen chloride (HCl).
5.3. Advice for firefighters
Personal protective equipment Wear necessary protective equipment. For personal protection, see section 8.
Fire fighting procedures Reference is made to the company fire procedure. If risk of water pollution
occurs, notify appropriate authorities. Avoid breathing fire vapours.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Look out! The product is corrosive. Use protective gloves, goggles and
suitable protective clothing. In case of inadequate ventilation, use respiratory
protection. For personal protection, see section 8.
6.2. Environmental precautions
Environmental precautions Avoid discharge into water courses or onto the ground. Contact local
authorities in case of spillage to drain/aquatic environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning Dam and absorb spillage with sand, sawdust or other absorbent. Wash
contaminated area with water.
6.4. Reference to other sections
Other instructions See section 8 and section 13.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Handling Avoid inhalation of vapours. Avoid spilling, skin and eye contact. Do not mix
with acidic products.
7.2. Conditions for safe storage, including any incompatibilities
FOAM 2000 CL Page 4 of 8
Storage Store in tightly closed original container. Keep away from food, drink and
animal feeding stuffs. Store protected from acids.
Storage Temperature Value: -5-20 °C
Storage Stabilit Durability: 12 months.
7.3. Specific end use(s)
Specific use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters
Exposure limit values
Component name Identification Value Year
Caustic potash CAS no.: 1310-58-3 15 min.: 2 mg/m3 2007
EC no.: 215-181-3
Index no.: 019-002-00-8
Synonyms: Potassium hydroxide
Sodium hydroxide CAS no.: 1310-73-2 8 h.: 2 mg/m3 2007
EC no.: 215-185-5
Chlorine CAS no.: 7782-50-5 15 min.: 0,5 ppm 2007
EC no.: 231-959-5 15 min.: 1,5 mg/m3
Index no.: 017-001-00-7
Synonyms: Chlorine
DNEL / PNEC
Summary of risk management Data lacking.
measures, man
Summary of risk management Data lacking.
measures, environment
8.2. Exposure controls
Recommended monitoring Not available.
procedures
Occupational exposure controls Personal protection equipment should be chosen according to the CEN
standards and in discussion with the supplier of the personal protective
equipment. An eye wash bottle must be available at the work site.
Safety signs

Respiratory protection
Respiratory protection In case of inadequate ventilation use suitable respirator. Wear respiratory
protection with combination filter (dust and gas filter). Type B/P2.
Hand protection
Hand protection Use protective gloves made of: Butyl rubber. Neoprene. Nitrile.
Eye / face protection
Eye protection Use eye protection.
Skin protection
Skin protection (other than of the Wear apron or protective clothing in case of contact. Wear rubber footwear.
hands)
Thermal hazards
Thermal hazards See section 5.
Appropriate environmental exposure control
Environmental exposure controls See section 6.
FOAM 2000 CL Page 5 of 8

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state Fluid.
Colour Colourless to pale yellow.
Odour Chlorine.
pH (as supplied) Value: > 13,0
Solubility description Completely soluble in water.
Viscosity Value: < 50 mPas
9.2. Other information
Bulk density Value: ~ 1,15 kg/l
Other physical and chemical properties
Comments No data recorded.

SECTION 10: Stability and reactivity


10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stability Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions Generates toxic gas when in contact with acid. Reacts violently with strong
acids. Reacts strongly with water. Do not add water directly to the product. It
may cause a violent reaction. Risk of bumping (splashes).
10.4. Conditions to avoid
Conditions to avoid Heating. Extremes of temperatures. Avoid contact with acids.
10.5. Incompatible materials
Materials to avoid Strong acids. Acids, oxidising. Alkali-sensitive metals such as aluminium, tin,
lead and zinc and alloys with these metals.
10.6. Hazardous decomposition products
Hazardous decomposition products In case of fire, toxic gases (CO, CO2, NOx) may be formed. Chlorine gas
and hydrogen chloride may be formed in a fire or by heating.

SECTION 11: Toxicological information


11.1. Information on toxicological effects
Toxicological Information:
Other toxicological data Toxicological tests on the product has not been performed.
Components' toxicological data
Component No data available for ingredient(s).
LD50 oral Value: - -
Test animal species: -
Duration: -
Comments: -
Other information regarding health hazards
General This substance is corrosive.
Potential acute effects
Inhalation Aerosols may be corrosive. Inhalation may cause: Serious damage to the
lining of nose, throat and lungs.
Skin contact Strongly corrosive. May cause deep tissue damage.
Eye contact Strongly corrosive. Causes severe burns and serious eye damage. Immediate
first aid is imperative. Contact with concentrated chemical may very rapidly
FOAM 2000 CL Page 6 of 8
cause severe eye damage, possibly loss of sight.
Ingestion Strongly corrosive. Even small amounts may be fatal. Symptoms are severe
burning pains in mouth, throat and stomach. May cause burns in mucous
membranes, throat, oesophagus and stomach.

SECTION 12: Ecological information


12.1. Toxicity
Ecotoxicity Large amounts of the product may affect the acidity (pH-factor) in water with
possible risk of harmful effects to aquatic organisms. Contains a substance,
which is very toxic to aquatic organisms, however, it is easily degradable
and, therefore, needs not be classified as harmful to the environment.
Aquatic, comments No data recorded.
12.2. Persistence and degradability
Chemical oxygen demand (COD) Value: < 100
Comment COD mg O2/ g.
Persistence and degradability The product is expected to be biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.
12.4. Mobility in soil
Mobility The product is water soluble and may spread in water systems.
12.5. Results of PBT and vPvB assessment
PBT assessment results Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
Environmental details, conclusion For this product no classification is required for environmental hazards.

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Specify the appropriate methods of Dispose of waste and residues in accordance with local authority
disposal requirements.
Product classified as hazardous Yes
waste
Packaging classified as hazardous Yes
waste
EWC waste code EWC: 0706 wastes from the MFSU of fats, grease, soaps, detergents,
disinfectants and cosmetics
Other Information When handling waste, consideration should be made to the safety precautions
applying to handling of the product. Waste code applies to product remnants
in pure form.

SECTION 14: Transport information


14.1. UN number
ADR 1719
RID 1719
IMDG 1719
ICAO/IATA 1719
14.2. UN proper shipping name
ADR CAUSTIC ALKALI LIQUID, N.O.S. (Sodium hydroxide, Sodium hypochlorite).
RID CAUSTIC ALKALI LIQUID, N.O.S. (Sodium hydroxide, Sodium hypochlorite).
IMDG CAUSTIC ALKALI LIQUID, N.O.S. (Sodium hydroxide, Sodium hypochlorite).
ICAO/IATA CAUSTIC ALKALI LIQUID, N.O.S. (Sodium hydroxide, Sodium hypochlorite).
14.3. Transport hazard class(es)
FOAM 2000 CL Page 7 of 8
ADR 8
Hazard no. 80
RID 8
IMDG 8
ICAO/IATA 8
14.4. Packing group
ADR II
RID II
IMDG II
ICAO/IATA II
14.5. Environmental hazards
IMDG Marine pollutant No.
14.6. Special precautions for user
EmS F-A, S-B
Special precautions for user Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Other applicable information.
Other applicable information. Not relevant.

SECTION 15: Regulatory information


15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Other Label Information For professional users only.
As a general rule, persons under 18 years of age are not allowed to work
with this product. Users must be carefully instructed in the proper work
procedure, the dangerous properties of the product and the necessary safety
instructions.
Legislation and regulations The Management of Health and Safety at Work Regulations 1999 (SI 1999
No. 3242).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council
of 18 December 2006 concerning the Registration, Evaluation, Authorisation
and Restriction of Chemicals (REACH), establishing a European Chemicals
Agency, amending Directive 1999/45/EC and repealing Council Regulation
(EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as
Council Directive 76/769/EEC and Commission Directives 91/155/EEC,
93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
The List of Wastes (England) (Amendment) Regulations 2005. (SI 2005 No.
895).
15.2. Chemical safety assessment
chemical safety assessment has No
been carried out

SECTION 16: Other information


List of relevant R phrases (under R22 Harmful if swallowed.
headings 2 and 3). R31 Contact with acids liberates toxic gas.
R34 Causes burns.
R35 Causes severe burns.
R36/38 Irritating to eyes and skin.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R50 Very toxic to aquatic organisms.
List of relevant H-phrases (Section H302 Harmful if swallowed.
2 and 3). H314 Causes Severe skin burns and eye damage.
FOAM 2000 CL Page 8 of 8
H400 Very toxic to aquatic life.
Training advice Users must be carefully instructed in the proper work procedure, the
dangerous properties of the product and the necessary safety instructions.
Information which has been added, All sections of the safety data sheet is updated.
deleted or revised
Responsible for safety data sheet Novadan ApS
Prepared by TLT

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