Vidyamandir Classes

JEE Advanced Final Practice Assignment

Organic Chemistry
SINGLE CHOICE QUESTIONS
NaHSO3
1.  Sodium bisulphite (white ppt.) adduct is :
R  CHO 

Θ 
ONa O OH O
| ||
| || Θ 
(A) R  C  O  S  OH (B) R  C  O  S O N a
| || | ||
H O H O

Θ 
OH O ONa O
| ||
Θ  | ||
(C) R  C  S O N a (D) R  C — S  OH
| || | ||
H O H O

2.

(A) (B) (C) (D)

3.

Product is :

(A) (B)

(C) (D)

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4. Which of following give positive azo dye test :

(A) (B) (C) (D)

5. Which of the following compound will not given racemic mixture with LiAlH4 ?

(A) (B)

(C) (D)

6. Reduction of the molecule shown below produces :

(A) A single enantiomer (B) A pair of enantiomer

(C) A pair of diastereomers (D) A racemic mixture
7. In   D - glucopyranose if all 5 chiral centre are interchanged then new stereoisomer formed is :
(A)   D - glucopyranose (B)   D  glucopyranose
(C)   L  glucopyranose (D)   L  glucopyranose

8.

(A) (B) (C) (D)

9. :

(A) (B) (C) (D)

O
||
H3O
10. CH3  C  OCH3  CH3 MgBr   Major product is :
(1 mole) (1mole)

O OH O
|| | ||
(A) CH3  C  CH3 (B) CH3  C  CH3 (C) CH4 (D) CH3  C  OH
|
CH 3

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3O / Zn
11. C5 H8  CH3  CO  CHO  CH 2  O
Compound is :
(A) Isobutene (B) Isoprene (C) Neoprene (D) Isobutyne

12. For preparation of meta nitro ethyl benzene which is the best method :
HNO
3  (A) 
3 CH COCl
2  (C)
NH 2  NH
(A)   (B) 
H 2SO 4 AlCl3 KOH

CH COCl
3 HNO
3  (B) 
2 2 NH  NH
(B) 
 (A)   (C)
AlCl3 H 2SO4 KOH

CH COCl
3 2 2 NH  NH
3  (C) HNO
(C) 
 (A)   (B) 
AlCl3 KOH H 2SO 4

HNO
3  (A) 
2 2 NH  NH
3 CH COCl
(D)   (B) 
 (C)
H 2SO 4 KOH AlCl3

13.

Identify (A) and (B) respectively :

O O
|| ||
(A) CH3  C  CH3 , CH 3COONa (B) CH3  C  CH 2 CH3 , CH3COONa
O O
|| ||
(C) CH3  C  CH 2 CH3 , CH3 CH 2 COONa (D) CH3  C  CH 2 CH3 , CH 3COOH

O
||
AlCl3 Aq.KOH
14. Cl  C  CH 2  Cl   (A) (B)
Ph  H
Compound (B) give which type of test
(A) Aq. NaHCO3 (B) Tollen's test (C) Iodoform (D) Isocyanide test

15.

Identify the structure of X and Y :

(A) (B) (C) (D)

16.

Identify relation between X and Y :

(A) Position isomer (B) Chain isomer
(C) Functional isomer (D) Stereo isomer
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17.

Incorrect statement about the given structures :

(A) I, II, III, IV are having same D.B.E. value (B) I, II, are chain isomer
(C) II, III are position isomer (D) III, IV are metamer.

18. MATCH THE FOLLOWING :

Column I Column II

(P) 1. P>Q>R

(Q) 2. P>R>Q

(R) 3. R>Q>P

(S) 4. R>P>Q

Codes :
P Q R S P Q R S
(A) 3 2 1 4 (B) 4 3 2 1
(C) 2 1 4 3 (D) 1 2 3 4

19.

(X) and (Y) will be respectively :

(A) (B)

(C) (D)

20. How many pair of diastereomer is possible for 2-bromo 3-chloro butane ?
(A) 1 (B) 2 (C) 3 (D) 4

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21.

(A) (B) (C) (D)

22. Compound which will show geometrical, optical isomerism and give positive iodoform test ?

(A) (B) (C) (D)

O O
|| ||
Conc. KOH H
23. Ph  C  C  H  (A)   (B)

Cyclic compound

Number of stereoisomer of product (B) is :

(A) 2 (B) 3 (C) 4 (D) 5

Br Mg
2  (A) (B)  SOCl
3  (D) 
2  (C)  NH KOBr
24.  
 (E)
Fe CO2 ,H

Structure of (E) in given path will be :

(A) Ph – NH2 (B) Ph – CH2 – NH2 (C) Ph – NH – CH3 (D)

25. Which of the compound is most acidic in nature ?

(A) (B) (C) (D)

26.

How many stereoisomer of product A is fromed in above reaction..

(A) 1 (B) 2 (C) 4 (D) 5

27.

Relation between (X) and (Y) is :

(A) Enatiomers (B) Identical (C) Diastereomers (D) Racemic mixture

28.

x = number of alcohol including stereo isomers.

(A) 4 (B) 5 (C) 6 (D) 7

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29. In which of the following pairs of compounds is the second compound more stable than first compound.

(A) (B) (C) (D)

30. Lindane (hexa chloro cyclohexane) is an agricultural insecticide that can also be used in the treatment of head lice.

Draw the other chair conformation (B) of lindane and inspect which of the following statements are correct.
(A) B is more stable than A
(B) A is more stable than B
(C) A is not the correct representation of lindane
(D) The two chair conformations of lindane are degenerate. There is no difference in energy between them.

31.

The product (B) is :

(A) (B) (C) (D)

32.

The product (C) is :

(A) (B) (C) (D)

Red P/Br
2  (B)  KOH (alc) (NaOH  CaO)
3  1. O
33. C5 H10 O2   (C) 
 (D)   (E)
  Zn / H 2O
(A) gives pink colour
Carboxylic acid with schiff's reagent

Reactant (A) is :

(A) (B) (C) (D)

34.

(I) NH3 (II) dil.H2SO4 (III) (IV)

For transformation of (P) to (Q). Which reagents is/are used in a sequence ?
(A) I, III, IV, II (B) III, I, II, IV (C) I, III, IV, II (D) III, IV, I, II
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Paragraph for Questions 35 - 36
Phenol condenses with phthalic anhydride in presence of conc. H2SO4, to give phenolphthalein which give dark pink
colour with NaOH. This is called phthalein dye test.

35. Identify product :

(A) (B)

(C) (D) None of these

36. Which of following will not give Phthalein dye test ?

(A) (B) (C) (D)

Paragraph for Questions 37 - 38

37. Identify compound A and C respectively :

(A) (B)

(C) (D)

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38. If B and D both formed a mixture then for separation of binary mixture which reagent is required :
(A) Ag. NaHCO3 (B) Aq NaOH (C) Aq. HCl (D) Ether

Paragraph for Questions 39 - 41

PCC Br / KOH
2 1. KOH(aq) / 
C8 H10 O 
 (B) 
 (C) 

 (D)
An alcohol gives 2. H
fehling 's test
(A)

39. Alcohol (A) is :

(A) (B) (C) (D)

40 Product (D) is :

(A) (B)

(C) (D) Mixture of (B) and (C)

41. Which other reagents can convert B into D.

(A) 1. SeO2 2. KOH followed by H+ (B) 1. KCN/HCN 2. H+/H2O
(C) 1. NH 2 NH 2 2. H+/H2O (D) 1. CH3COOOH 2.H+/H2O

Paragraph for Questions 42 - 45

In the following scheme answer the following questions.

42. The compound(S) is :

(A) (B)

(C) (D)

43. In the transformation of [Q] into [R] (Reaction with NaOH only) the correct statement is
(A) Hydride transfer is rate determining
(B) Attack of HO  is rate determining
(C) Reaction is independent of HO  concentration
(D) Reaction is independent of reactant concentration

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44. Compound[R] is :

(A) (B) (C) (D)

45. Compound (P) is :

(A) (B) (C) (D)

Paragraph for Questions 46 - 48

It is convenient at times to represent the cyclic structures of a monosaccharide without specifying whether the
configuration of the anomeric carbon atom is  or  . When we do this, we shall use formulas such as the following :

46. Which of the following compound is a non reducing sugar ?

(A) (B) (C) (D)

47.  linkage is present in :
(A) Starch (B) Cellulose (C) Glycogen (D) Protein

48. How many moles of HIO4 are consumed by

given compound when it reacts with HIO4 ?
(A) 4
(B) 5
(C) 6
(D) 7

Paragraph for Questions 49 - 50

49. Structure of (R) is :

(A) (B) (C) (D)

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50. Most appropriate structure of (P) is :

(A) (B) (C) (D)

Paragraph for Questions 51 - 53

An organic compound ‘P’ (C15H14) on ozonolysis in the presence of Zn given Q(C8H8O) and R(C7H6O). R either reacts
with tollen’s reagent to gives product S or Q gives S product whenever reacts with I2 / OH  . Q can give T product with
dil. KOH.
51. Structure of ‘P’ is :

(A) (B)

(C) (D)

52. Structure of ‘Q’ is :

(A) (B) (C) (D)

53. Structure of ‘S’ is :

(A) (B) (C) (D)

Paragraph for Questions 54 - 56

HgSO
4  (B)  LiAlH
4  (C)  conc.H SO
2 4  (D) 
3 (i) O
(A)  
dil. H 2SO4  (2) Zn, H 2O

54. Structure of (A) is :

(A) (B) (C) (D)

55. Structure of (B) is :

(A) (B) (C) (D)

56. Structure of (D) is :

(A) (B) (C) (D)

Paragraph for Questions 57 - 58

Compound (A) gives iodoform test and when (A) reacts with conc. H2SO4 it gives
product (B) which reacts with Na metal to give the following polymer which is
known as polystyrene which is used in the manufacture of computer cases and as
household of items such as hairdryers, T.V., and kitchen appliances.

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57. Identify compound (A)
O
||
(A) Ph  CH  CH3 (B) Ph  C  CH3 (C) Ph  CH 2  CHO (D)
|
OH

58. Compound (B) is also used for the formation of which polymer
(A) BuNa – N (B) BuNa – S (C) Teflon (D) Bakelite

Paragraph for Questions 59 - 61

CHCl
3  (Y) 
2 Ac O / AcONa H
(X)   (Z) 

aq.NaOH 

59. Structure of (X) is :

(A) (B) (C) (D)

60. Structure of major product (Y) is :

(A) (B) (C) (D)

61. Structure of (Z) is :

(A) (B)

(C) (D)

MULTIPLE CHOICE CORRECT QUESTIONS

62. Which of the following is correct
NaNH
2   D O
2  DC  CD (B) 2Na D O
2  DC  CD
(A) CH  CH  CH  CH 
 
(excess)

ODΘ D O
2  DC  CD (D) 3 CH Li D O
2  DC  CD
(C) CH  CH   CH  CH  
(excess) (excess)

63. :

(A) Compound can show geometrical isomerism (B) During prolonged treatment 5H are replaced by 5D
(C) Most acidic hydrogen atom is C (D) This compound can show addition reaction
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 C HO 
64. Identify which compound on reductive ozonolysis give glyoxal  |  as one of the end product :
 CHO 
 

(A) (B) (C) (D)

65. Identify in which I is more stable than II.

(A) (B) (C) (D)

(I) (II) (I) (II) (I) (II) (I) (II)

66. Identify which compound give alkyne formation by reaction with PCl 5 followed by alc. NaNH2 in excess.

(A) CH3CHO (B) (C) (D) CH3 – O – CH2 – CH3

67.

Identify correct statement about product

(A) Product show iodoform test. (B) Product show Tollen test
(C) Enol is more stable than keto. (D) Enol show geometrical isomer.

68.

Correct statement about (x) and (y) :

(A) Both product belong to same functional group
(B) Both react with RMgX/H3O+ to give 3° product
(C) Both show Aldol condensation
(D) Both give iodoform test
69.

Correct Statement is :
(A) (A) and (D) is soluble in aq. NaOH
(B) B is soluble in aq. NaOH
(C) Molecular formula of B to D increases by C4 H4O2
(D) (C) is soluble in aq. NaHCO3
(E) A, B, C,. D are chiral

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70. In which of the following reactions Geometrical isomer will be formed as a product ?
O
||
H
(A) (B) Ph  C  H  NH 2  OH  


O
||
(1) KCN
(C) (D) CH3  C  H  

(2) H

71. In which of the reaction is the final product an aldehyde :

O
||
H2 H3O
(A) Ph  C  Cl  
 (B) R  C  N  SnCl 2  HCl 
 (A)   (B)
Pd  BaSO4
O
||
DIBAL  H DlBAL  H
(C) R  C  N  (D) Et  C  O  Et 
H 2O H 2O
2Cl
2  (A)  H O
2 (B)
(E) C6 H5 CH3 
hv

72. Which of the following compound reacts with hot KMnO4 to form phthalic acid ?

(A) (B) (C) (D)

73.

Which statement are correct ?

(A) Product B on reaction with aq. bleaching powder give sweet smelling colourless liquid
(B) Product C do not give Fehling test
(C) Product (A), (B) and (C) all give aldol condensation
(D) Product A give 2, 4-DNP test
74. In which of the following molecule both C2 and C3 axis of symmetry are present.

(A) (B) (C) (D)

75. Which of the following pair is separated by NaOH, NaHCO3 both ?

(A) (B)

(C) (D)

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76.

Correct statement regarding given reaction is :

(A) Reactant and product both are achiral
(B) It is an example of nucleophilic addition
(C) Reaction does take place when HCN is used
(D) Presence of small amount of base will accelerate the rate of reaction when it is mixed with pure HCN
77. Correct statement regarding given compound is :
(A) Compound undergoes nucleophilic addition
(B) Compound undergoes elimination
(C) Compound undergoes nucleophilic substitution
(D) Compound undergoes dehydrogenation

78. Find the correct statement(s).

(A) methyl amine in water reacts with FeCl3 to precipitate hydrated ferric oxide.
(B) Diazonium salt of aromatic amines are more stable than those of aliphatic amines
(C) Aniline does not undergo Friedal-craft’s reaction
(D) Gabriel pthalimide synthesis is preferred for 1° amine synthesis.

79. Identify which of the bonds is/are peptide bond

O O O O
|| || || ||
HOOC  CH 2  NH  C  CH 2  NH  C  C H  NH  C  C H  NH  CH 2  C  CH 3
(1) (2) | (3) | (4)
COOH CH 2 Ph
(A) 1 (B) 2 (C) 3 (D) 4

80. Which of the following alcohols yield 3° alkyl halide as a major product on a reaction with conc. HCl

(A) (B) (C) (D)

81. Which amide will give 2° amine on reduction by LiAlH4?

(A) (B) (C) (D)

82. Correct statement about the following sugar is :

(A) Reducing sugar

(B) Non-reducing sugar

(C)  -glucosidic linkage

(D) Ring (a) is pyranose

83.

In given reactions missing reagent (X) and (Y) is :

(A) x = CHCl3. KOH (B) x = CCl4/KOH
(C) y = CHCl3/KOH (D) y  CCl4 / H 

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84.

Correct statement regarding given reaction is

(A) It is a dehydration reaction (B) Carbanion is intermediate
(C) One of the step is Nucleophilic addition reaction (D) Final product is chiral

85. Which of the following compounds is aromatic :

(A) (B) (C) (D)

MATRIX MATCHING TYPE

86. MATCH THE FOLLOWING :

Column-I (Lassaigne test) Column-II

(A) N – test (p) White Precipitate
(B) S-test (q) Prussian blue
(C) N, S-test (r) Red colour
(D) Halogen test (s) Black Precipitate

87. MATCH THE FOLLOWING :

Column-I Column-II

(A) 2NaNO  2HCl (p) Yellow colour

  Naphthol 


(B) 2 NaNO  2HCl (q) Red colour

2 Amine 


(C) 2NaNO  2HCl (r) Green colour

Phenol 


(D) 2 NaNO  2HCl (s) Colourless

1 Amine 


87. MATCH THE FOLLOWING :

Column-I Column-II

(A) (p) Addition reaction

(B) EtOH, H  (q) Substitution reaction

EtO  CH  CH 


O O
(C) || || (r) Carbocation is intermediate
EtOH H
CH3  C  O  C  CH3  

O
(D) || (s) Acetal is major product
EtOH
CH3  C  Cl 
Pyridine

(t) Esterification reaction

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89. MATCH THE FOLLOWING :

Column-I Column-II

Carbene will be formed as an

(A) (p) intermediate in one of the
reaction.

Formation of new aromatic

(B) (q)
ring take place.

One of the stereoisomer of the

(C) (r) final product has plane of
symmetry

Formation of product (A) give

(D) (s)
best yield when (pH = 4 – 5)

90.
MATCH THE FOLLOWING :

Column-I Column-II

(A) (p) Addition reaction

(B) (q) Substitution reaction

Formation of cation is rate determining step

(C) (r)
(Classical or non-classical carbocation)

(D) (s) Raecemic mixture

(t) Free radical intermediate

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91. MATCH THE FOLLOWING :

Column-I (Sugar) Column-II (Types of links)

(A) (p) Hemiacetal linkage

(B) (q) Acetal linkage

(C) (r)  - 1, 4- glycosidic linkage

(D) (s)  - 1 , 4-glycosidic linkage

(t) Reducing sugar

92. Match the reactions is Column I with appropriate types of steps / reactive intermediate involved in these reactions
as given in Column II
Column-I Column-II
Carbocation intermediate

(A) (p)

(B) (q) Carbanion intermediate

(C) (r) Nucleophilic substitution

(D) (s) Nucleophilic addition

(t) Dehydration reaction

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93. MATCH THE FOLLOWING :

Column-I (Reactant) Column-II (Reaction possible)

(A) (p) Nucleophilic substitution

(B) (q) Elimination

(C) (r) Nucleophilic addition

(D) (s) Esterification with Ac2O

(t) Dehydrogenation

94. MATCH THE FOLLOWING :

Column-I Column-II
(A) Cellulose (p) Homopolymer
(B) Nylon – 6, 6 (q) Co polymer
(C) Protein (r) Amide linkage
(D) Sucrose (s) Glycoside linkage
(t) Natural polymer

95. MATCH THE FOLLOWING :

Column-I Column-II

(A) (p) Racemic mixture

(B) (q) Addition reaction

(C) (r) Substitution reaction

(D) (s) Coupling reaction

(t) Carbanion as an intermediate

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SUBJECTIVE TYPE QUESTIONS
96. Dibromobenzene has 3 isomer then how many isomer are possible if its exists as dibromo prismane.

97. Total number of isomer formed during reaction.

98. Identify in which reaction product is Benzoic acid or its salt.

Hot KMnO
4 conc. KOH
(a) C6 H5 CH 2 CH3  (b) C6 H5CHO 

conc. KOH conc. KOH
(c) C6 H5COOCH3  (d) C6 H5COCl 

 

2 CO H O
3 
(e) C6 H5 MgBr 

 (f) C6 H5CN  
H3O

2 KOH / I LiAlH
4
(g) C6 H5COCH3  (h) C6 H5 CN 

 H 3O
Enzyme
99.   D glucose  Maltose
x = number of (CH3CO)2O consumed by product
y = number of (CH3CO)2O consumed by reactant
Identify x – y is =

100. x : (CH3CO)2O y : HIO4 z : PhNHNH2

Identify moles of reagent consumed by Glucose and answer is given as such expression : x + y – z =
14
NaHCO
3 C H COOH  NaOH  CaO
101. Y(g)  6 5  X(g)

Difference between the molar mass of gas X and Y is :

102. X = DBE value of compound

Y = Locant or branch position (If two or more than it should be added)
Answer consider as X – Y

103. x = Number of tripeptide possible which on Hydrolysis give Glycine, Alanine, valine as product.
y = Number of dipeptide possible if the above 3 Amino acid are used. (Answer is given by x  y expression)

104. Total number of CHI3 formed by reaction with NaOH/I2 in excess.

O O O O
|| || || ||
(A) CH3  C  CH 3 (B) CH3  C  OH (C) CH3  C  CH 2  C  CH3

O
||
(D) (E) CH3  C  OC2 H5

105. Number of peptide bond are possible in

VMC | Chemistry 19 JEE Advanced Final Practice Assignment

 Vidyamandir Classes
106. Calculate the total number of compound evolve CO2 gas on heating ?

(a) (b) (c) (d)

(e) (f) (g) (h)

(i) (j) (k)

107. x = number of compound give odd number of mono-chloro product (including stereoisomer). What is value of x?

(a) (b) (c) (d)

(e) (f) (g) (h)

(i) (j) (k)

CH3  CH 2  C H  CH 2  CH3
(l) | (m) CH3  CH3 (n)
CH3

108.  x , CH3  CH  C  CH  CH 3 
CH3  CH  CH  CH3   y and
CH3  CH  C  C  CH  CH 3  z
x, y, z are geometrical isomers  sum of x + y + z is :
109. Compound which can show tautomerism.

(a) (b) (c) (d)

(e) (f) (g) (h)

O
||
(i) (j) CH3  C  H (k) (l)

110. a, b, c, d are number of hydrogen replaced by deuterium, when prolonged treatment with D2O takes place it given
compound. Find out the value of (a + b + c + d) – 20.

VMC | Chemistry 20 JEE Advanced Final Practice Assignment

 Vidyamandir Classes
111. Number of plane of symmetry is x, y and z.

Sum of x + y + z = ?

112. = Total number of products (including stereoisomers)

113. x = Number of compounds which become aromatic after reaction with KH.

(a) (b) (c) (d)

(e) (f) (g) (h)

114. (a) (b) (c)

‘x’, ‘y’ and ‘z’ are respectively moles of Br2 consumed during the reaction so the sum of x, y, z is :

115. (a) (b)

Double bond equivalent of A + B =

116. x = no. of compound undergo dehydrogenation

(a) Ph – CH2 – OH (b) (c) (d) CH3 – CH = CH – CH3

OH
|
(e) (f) Ph  C  Ph (g)
|
Ph

117.

In the scheme given below, the total number of intramolecular aldol addition products (excluding stereoisomers)
formed from above compound.

VMC | Chemistry 21 JEE Advanced Final Practice Assignment

 Vidyamandir Classes
118. x = number of compound which can undergo intra molecular aldol condensation product after reductive selective
ozonolysis.

(i) (ii) (iii)

(iv) (v) (iv)

(vii) (viii)

119. x = number of compound which are nucleophiles,

Θ Θ
HC  CH , H 2 C  CH 2 , , CH3 – CH2 – OH, IΘ, C N , CH3 – CH2 – Cl, , NH3, K S H ,

120.
(i) (ii)

O O
|| || 14
NaHCO3 NaH CO3
(iii) Ph  C  OH   (C) gas (iv) Ph  C  OH   (D) gas
14
O
||
NaCO3
(v) Ph  S  OH   (E) gas
||
O
Sum of molecular mass of A + B + C + D + E = ?

4 HIO 2  (B) x Ac O
121. 2HCHO  2HCO 2 H  (A) 
Value of x is :

122. x = Number of compounds which react with NaBH4

(a) (b) (c) (d)

(e) (f) (g) CH3 – CH3 (h) H2C = CH2

(i) HC  CH

123. Total number of E2 product obtained by the reaction of alc. KOH

(Including stereoisomers).

VMC | Chemistry 22 JEE Advanced Final Practice Assignment

 Vidyamandir Classes
124. X = Number of reaction in which 1-butene is the major product

(a)

(b)

(c) (d)

(e) (f)

(g) (h) (i)

125. x = Number of alkene which give chiral product on reductive ozonolysis,

(a) (b) (c) (d)

(e) (f) (g)

126. How many compounds have a stereoisomer that is a meso compound :

(a) (b) (c) (d) 2, 3-dichlorobutane

(e) (f) (g)

O
||
127. (i) Ph  C  OH  NaHCO3 
 A(gas) (ii) Ph  OH  NaNH 2 
 B(gas)
(iii) Ph  OH  NaH 
 C(gas) (iv) Ph  OH  Na 
 D(gas)
(Sum of molecular weight of A + B + C + D = ?)

128. x = Number of alkene (Including stereoisomers)

129. How many sugars are reducing in nature ?

(a)  -D-glucose (b) Fructose (c) Sucrose (d) Lactose
(e) Maltose (f)  -D-Glucoside (g) Starch

130. Number of moles of Grignard reagent that will be used when excess of PhMgBr reacts with the following
compound.

VMC | Chemistry 23 JEE Advanced Final Practice Assignment

 Vidyamandir Classes
131. Total number of structural as well as stereo isomers of Dichlorocyclobutane
132. How many optically active cyclic isomers are possible of compound, having molecular formula C6H12.

133. How many geometrical isomers are possible of alkene having molecular formula C2F2ClBr.

134. Among the following compounds how many substituents are ortho para directing.

(a) (b) (c) (d)

(e) (f) (g)

135. Among the following compounds how many is (are) unstable at room temperature in their pure form ?

(a) (b) (c) (d) (e) (f) (g) (h)

136. Phenol is less acidic than how many of the compounds given below.

(a) CH3COOH (b) (c) (d)

(e) (f) (g)

137. Number of isomers from molecular formula (Excluding stereoisomers)

138. x = Number of compound which give 3° alcohol when reacts with HNO2?

(a) (b) (c) (d) Ph  CH2  NH2

(e) (f) (g) (h)

(i) (j)

VMC | Chemistry 24 JEE Advanced Final Practice Assignment

 Vidyamandir Classes
139. x = Number of compound which give positive isocyanide test.

(a) (b) (c) (d)

(e) (f) (g) (h) (i)

(i)
140. If number of compound which give positive Tollen’s test is x then find out its value ?

(a) (b) (c) (d)

(e) (f) (g) (h)

(i) D – Glucose (j) D-Mannose (k) D-Fructose (l) Sucrose

141. x = Number of compound which react with LiAlH4 to form racemic mixture.

(a) (b) (c) (d) (e) (f) (g) (h)

142. x, y, z are number of stereoisomers of given compound

Sum of x + y + z is :
143. x = number of compound which are chiral.

(a) (b) (c) (d)

(e) (f) (g) (h)

(i) (j)

144. a, b, c are stereoisomers of given compound

(I) H 2 C  CH  CH  CH3 
 (a) (II) CH3  CH  CH  CH  CH3 
 (b)
| |
Cl Cl
(III) CH3  CH  C  CH 2  CH3 
 (c) Sum of a + b + c = ?
|
Cl
VMC | Chemistry 25 JEE Advanced Final Practice Assignment
 Vidyamandir Classes
145. Stereoisomers produced during given reactions is respectively x, y, z. So the sum x + y + z is

(i) (ii) (iii)

146. (a) Cholesterol has eight chiral centres

The specific stereoisomer shown above has ‘X’ number of theoretical possible diastereomers and ‘Y’
number of enantiomers. The sum of (X + Y) is :

(b) There are ‘X’ number of meso stereoisomers and ‘Y’ number of enantiomeric
pairs exist for. Find sum of X + Y.

(c) Compound A below has ‘X’ chiral carbons, ‘Y’

meso stereoisomers and ‘Z’ pair(s) of enantiomers. Find
sum X + Y + Z ?

(d) For the following reactions, how many

fractions could be collected by fractional
distillation or recrystallisation ?
The sum of (x + y) is

(e) z = number of reaction in which acetal is final product.

O
||
1. H
(i) HO  CH 2  CH 2  CH 2  CH 2  C  H  

2. CH3OH / H

EtOH
(ii) (iii) H 2 C  CH  OEt 
 H

2  H O
(iv) H 2 C  CH  OEt 

(v)
H

2EtOH / H 
(iv) (vii) CH3  CHO 


O
||
EtOH / H 
(viii) CH3  C  CH3   (ix)
O
||
H
(x) HO  CH 2  CH 2  CH 2  C  H  

147. Which is the number of optically active structural isomers of C4H8O3 which evolve CO2 with NaHCO3(aq) ?

VMC | Chemistry 26 JEE Advanced Final Practice Assignment

 Vidyamandir Classes
For Questions 148 - 153
Observe the following structures and answer the following questions ?

148. Number of aldohexoses which give the same osazone derivative.

149. Number of moles of acetic anhydride (Ac2O) that is consumed to react completely with compound 2.
150. Number of possible stereoisomers of L-glucose (mirror image of 1).
151. Total number of stereoisomers of  -D Fructofuranose

152. Number of  - amino acid obtained after hydrolysis of pentapeptide of different amino acid.

153.

x
If Molecular weight of (P) is x, then find value of ?
20

VMC | Chemistry 27 JEE Advanced Final Practice Assignment

 Vidyamandir Classes

Answers Advanced Chemistry Assignment - 2

Organic Chemistry
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15

C A A D B C D B D B B B C B C

16 17 18 19 20 21 22 23 24 25 26 27 28 29 30

C D D A D B C B A C A C D C D

31 32 33 34 35 36 37 38 39 40 41 42 43 44 45

C D C D A D C C C A A D A D C

46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

D B B A D C B A A A B A B D C

61 62 63 64 65 66 67 68 69 70 71 72 73 74 75

D ABD BCD ABCD BD ABC ABCD ABC ACDE ABC ABCDE B ACD C D

76 77 78 79 80 81 82 83 84 85 86

ABCD BCD ABCD ABC BCD CD BCD AC ABCD ABC [A-q] [B-s] [C-r] [D-p]

87 88 89

[A-q] [B-p] [C-q, r] [D-s] [A-p, r, s] [B-p, r, s] [C-q, r, t] [D-q, t] [A-p, q] [B-q, r, s] [C-p, q, r] [D-q, r]

90 91 92

[A-p, r, s] [B-q, s, t] [C-q, r] [D-q] [A-q] [B-p, q, r, t] [C-p, q, s, t] [D-p, t] [A-q, s, t] [B-r, s] [C-p, s] [D-p, t]

93 94 95

[A-p, q, t] [B-r, s] [C-p, q, r, s, t] [D-p] [A-p, s, t] [B-q, r] [C-q, r, t] [D-s] [A-r, s, t] [B-p, q] [C-p, r] [D-p, r]
96 97 98 99 100 101 102 103 104 105 106 107 108 109 110

4 1 7 3 7 2 0 3 4 3 5 5 4 5 9

111 112 113 114 115 116 117 118 119 120 121 122 123 124 125

5 6 2 8 14 4 4 5 8 224 4 3 5 6 2

126 127 128 129 130 131 132 133 134 135 136 137 138 139 140

5 65 5 4 4 6 8 2 4 3 4 5 4 4 7

141 142 143 144 145 146 147 148 149 150 151 152 153

2 8 4 8 5 (a) 255 (b) 3 (c) 7 (d) 4 4 2 5 16 16 5 5

(e) 4

VMC | Chemistry 28 JEE Advanced Final Practice Assignment