SAFETY DATA SHEET

Creation Date 06-Apr-2011 Revision Date 09-May-2022 Revision Number 7

1. Identification
Product Name Dibutyltin dilaurate

Cat No. : AC382690000; AC382690050

CAS No 77-58-7
Synonyms No information available

Recommended Use Laboratory chemicals.

Uses advised against Food, drug, pesticide or biocidal product use.

Details of the supplier of the safety data sheet

Company
Fisher Scientific Company Acros Organics
One Reagent Lane One Reagent Lane
Fair Lawn, NJ 07410 Fair Lawn, NJ 07410
Tel: (201) 796-7100

Emergency Telephone Number

For information US call: 001-800-ACROS-01 / Europe call: +32 14 57 52 11
Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99
CHEMTREC Tel. No.US:001-800-424-9300 / Europe:001-703-527-3887

2. Hazard(s) identification
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious Eye Damage/Eye Irritation Category 2

Skin Sensitization Category 1
Germ Cell Mutagenicity Category 2
Reproductive Toxicity Category 1B
Specific target organ toxicity (single exposure) Category 1
Target Organs - Thymus, Respiratory system, Central nervous system (CNS).
Specific target organ toxicity - (repeated exposure) Category 1
Target Organs - Immune system, Thymus.

Label Elements

Signal Word

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Danger

Hazard Statements
May cause an allergic skin reaction
Causes serious eye irritation
Suspected of causing genetic defects
May damage fertility or the unborn child
Causes damage to organs
Causes damage to organs through prolonged or repeated exposure

Precautionary Statements
Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Contaminated work clothing should not be allowed out of the workplace
Do not breathe dust/fume/gas/mist/vapors/spray
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Response
IF exposed: Call a POISON CENTER or doctor/physician
Skin
IF ON SKIN: Wash with plenty of soap and water
If skin irritation or rash occurs: Get medical advice/attention
Wash contaminated clothing before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Storage
Store locked up
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Very toxic to aquatic life with long lasting effects

3. Composition/Information on Ingredients
Component CAS No Weight %
Dibutyltin dilaurate 77-58-7 >95

4. First-aid measures
General Advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In
the case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.

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Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Immediate medical
attention is required.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Do not use mouth-to-mouth
method if victim ingested or inhaled the substance; give artificial respiration with the aid of a
pocket mask equipped with a one-way valve or other proper respiratory medical device.
Immediate medical attention is required.

Ingestion Do NOT induce vomiting. Call a physician or poison control center immediately.

Most important symptoms and May cause allergic skin reaction. Product is a corrosive material. Use of gastric lavage or
effects emesis is contraindicated. Possible perforation of stomach or esophagus should be
investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and
danger of perforation: Symptoms of overexposure may be headache, dizziness, tiredness,
nausea and vomiting: Symptoms of allergic reaction may include rash, itching, swelling,
trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain,
muscle pain or flushing
Notes to Physician Treat symptomatically

5. Fire-fighting measures

Suitable Extinguishing Media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable Extinguishing Media No information available

Flash Point 149 °C / 300.2 °F

Method - No information available

Autoignition Temperature No information available

Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available

Specific Hazards Arising from the Chemical

Thermal decomposition can lead to release of irritating gases and vapors. The product causes burns of eyes, skin and mucous
membranes. Do not allow run-off from fire-fighting to enter drains or water courses.

Hazardous Combustion Products

Carbon monoxide (CO). Carbon dioxide (CO2). Metal oxides. Thermal decomposition can lead to release of irritating gases and
vapors.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

NFPA
Health Flammability Instability Physical hazards
3 1 0 N/A

6. Accidental release measures

Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Keep people
away from and upwind of spill/leak. Evacuate personnel to safe areas.
Environmental Precautions Do not flush into surface water or sanitary sewer system. Do not allow material to
contaminate ground water system. Prevent product from entering drains. Local authorities
should be advised if significant spillages cannot be contained. Should not be released into
the environment.

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Methods for Containment and Clean Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.
Up

7. Handling and storage

Handling Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on
clothing. Use only under a chemical fume hood. Do not breathe mist/vapors/spray. Do not
ingest. If swallowed then seek immediate medical assistance.

Storage. Corrosives area. Store indoors. Keep containers tightly closed in a dry, cool and
well-ventilated place. Incompatible Materials. Strong oxidizing agents.

8. Exposure controls / personal protection

Exposure Guidelines

Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA)
Dibutyltin dilaurate TWA: 0.1 mg/m3 (Vacated) TWA: 0.1 mg/m3 IDLH: 25 mg/m3 TWA: 0.1 mg/m3
STEL: 0.2 mg/m3 Skin TWA: 0.1 mg/m3 STEL: 0.2 mg/m3
Skin

Legend

ACGIH - American Conference of Governmental Industrial Hygienists

OSHA - Occupational Safety and Health Administration
NIOSH IDLH: NIOSH - National Institute for Occupational Safety and Health

Engineering Measures Use only under a chemical fume hood. Ensure that eyewash stations and safety showers
are close to the workstation location.

Personal Protective Equipment

Eye/face Protection Tight sealing safety goggles. Face protection shield.

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.

Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

9. Physical and chemical properties

Physical State Liquid Viscous liquid
Appearance Clear, Light yellow
Odor Characteristic
Odor Threshold No information available
pH Not applicable
Melting Point/Range 16 - 18 °C / 60.8 - 64.4 °F
Boiling Point/Range 205 °C / 401 °F @ 12 mmHg
Flash Point 149 °C / 300.2 °F
Evaporation Rate No information available
Flammability (solid,gas) Not applicable
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density No information available
Specific Gravity 1.05

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Solubility Insoluble in water

Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity No information available
Molecular Formula C32 H65 O4 Sn
Molecular Weight 631.57

10. Stability and reactivity

Reactive Hazard None known, based on information available

Stability Stable under recommended storage conditions.

Conditions to Avoid Incompatible products. Excess heat.

Incompatible Materials Strong oxidizing agents

Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Metal oxides, Thermal decomposition can
lead to release of irritating gases and vapors

Hazardous Polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

11. Toxicological information

Acute Toxicity

Product Information
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
Dibutyltin dilaurate 2071 mg/kg ( Rat ) >2000 mg/kg ( Rat ) Not listed
Toxicologically Synergistic No information available
Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure

Irritation Causes burns by all exposure routes

Sensitization May cause sensitization by skin contact

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Component CAS No IARC NTP ACGIH OSHA Mexico

Dibutyltin dilaurate 77-58-7 Not listed Not listed Not listed Not listed Not listed
Mutagenic Effects No information available

Reproductive Effects Experiments have shown reproductive toxicity effects on laboratory animals.

Developmental Effects Developmental effects have occurred in experimental animals.

Teratogenicity No information available.

STOT - single exposure Thymus Respiratory system Central nervous system (CNS)
STOT - repeated exposure Immune system Thymus

Aspiration hazard No information available

Symptoms / effects,both acute and Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.
delayed Possible perforation of stomach or esophagus should be investigated: Ingestion causes
severe swelling, severe damage to the delicate tissue and danger of perforation: Symptoms

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of overexposure may be headache, dizziness, tiredness, nausea and vomiting: Symptoms

of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the
hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing

Endocrine Disruptor Information No information available

Other Adverse Effects The toxicological properties have not been fully investigated.

12. Ecological information

Ecotoxicity
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do not allow material to
contaminate ground water system. The product contains following substances which are hazardous for the environment.

Component Freshwater Algae Freshwater Fish Microtox Water Flea

Dibutyltin dilaurate Not listed LC50 = 2 mg/L, 48h (Oryzias EC50 = 0.576 mg/L 30 min LC50 = 0.463 mg/L 48h
latipes)

Persistence and Degradability May persist based on information available.

Bioaccumulation/ Accumulation No information available.

Mobility Is not likely mobile in the environment due its low water solubility.

Component log Pow

Dibutyltin dilaurate 3.12

13. Disposal considerations

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.

14. Transport information

DOT
UN-No UN3082
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Technical Name Dibutyltin dilaurate
Hazard Class 9
Packing Group III
TDG
UN-No UN3082
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazard Class 9
Packing Group III
IATA
UN-No UN3082
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazard Class 9
Packing Group III
IMDG/IMO
UN-No UN3082
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazard Class 9
Packing Group III
15. Regulatory information
United States of America Inventory

Component CAS No TSCA TSCA Inventory notification - TSCA - EPA Regulatory

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Active-Inactive Flags
Dibutyltin dilaurate 77-58-7 X ACTIVE -

Legend:
TSCA US EPA (TSCA) - Toxic Substances Control Act, (40 CFR Part 710)
X - Listed
'-' - Not Listed

TSCA - Per 40 CFR 751, Regulation of Certain Chemical Not applicable

Substances & Mixtures, Under TSCA Section 6(h) (PBT)

TSCA 12(b) - Notices of Export Not applicable

International Inventories
China, X = listed, Australia, U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Australia (AICS), Korea (KECL), China (IECSC),
Japan (ENCS), Philippines (PICCS), Taiwan (TCSI), Japan (ISHL), New Zealand (NZIoC), Japan (ISHL).

Component CAS No DSL NDSL EINECS PICCS ENCS ISHL AICS IECSC KECL
Dibutyltin dilaurate 77-58-7 X - 201-039-8 X X X X X KE-09969

KECL - NIER number or KE number (http://ncis.nier.go.kr/en/main.do)

U.S. Federal Regulations

SARA 313 Not applicable

SARA 311/312 Hazard Categories See section 2 for more information

CWA (Clean Water Act) Not applicable

Clean Air Act Not applicable

OSHA - Occupational Safety and Not applicable

Health Administration

CERCLA Not applicable

California Proposition 65 This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know

Regulations

Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island

Dibutyltin dilaurate - - - - X

U.S. Department of Transportation

Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N

U.S. Department of Homeland This product does not contain any DHS chemicals.
Security

Other International Regulations

Mexico - Grade Slight risk, Grade 1

Authorisation/Restrictions according to EU REACH

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Component CAS No REACH (1907/2006) - REACH (1907/2006) - REACH Regulation (EC

Annex XIV - Substances Annex XVII - Restrictions 1907/2006) article 59 -
Subject to Authorization on Certain Dangerous Candidate List of
Substances Substances of Very High
Concern (SVHC)
Dibutyltin dilaurate 77-58-7 - Use restricted. See item -
30.
(see link for restriction
details)
Use restricted. See item
75.
(see link for restriction
details)
Use restricted. See item
20.
(see link for restriction
details)

https://echa.europa.eu/substances-restricted-under-reach

Safety, health and environmental regulations/legislation specific for the substance or mixture

Component CAS No OECD HPV Persistent Organic Ozone Depletion Restriction of

Pollutant Potential Hazardous
Substances (RoHS)
Dibutyltin dilaurate 77-58-7 Listed Not applicable Not applicable Not applicable

Component CAS No Seveso III Directive Seveso III Directive Rotterdam Basel Convention
(2012/18/EC) - (2012/18/EC) - Convention (PIC) (Hazardous Waste)
Qualifying Quantities Qualifying Quantities
for Major Accident for Safety Report
Notification Requirements
Dibutyltin dilaurate 77-58-7 Not applicable Not applicable Not applicable Not applicable

16. Other information

Prepared By Regulatory Affairs
Thermo Fisher Scientific
Email: [email protected]

Creation Date 06-Apr-2011

Revision Date 09-May-2022
Print Date 09-May-2022
Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standard
replacing the current legislation under 29 CFR 1910.1200 to align with the Globally
Harmonized System of Classification and Labeling of Chemicals (GHS).

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text

End of SDS

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