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Magallana bilineata (Oyster) and Acetic Acid (Vinegar) Fire Retardant Spray as

Fire Asphyxiator

__________

A Research Paper Presented to the Faculty of the Senior High School STEM

Department of Cabatuan National Comprehensive High School

Cabatuan, Iloilo

__________

In Partial Fulfillment of the Requirements for the Subject Research Capstone

of the Science and Technology, Engineering and Mathematics Program

Secondary Education

__________

By:

Ashley June M. Montalban

Alea Nicole C. Fajardo


Francis C. Romallosa
Lara May S. Mediodia
Jezyl R. Simaurio
Jergen Athea Q. Titular
Ghia D. Berbegal
12 – Aphrodite
CABATUAN NATIONAL COMPREHENSIVE HIGH SCHOOL
SENIOR HIGH SCHOOL
Cabatuan, Iloilo

Research Report of: Ashley June M. Montalban, Alea Nicole C. Fajardo,


Francis C. Romallosa, Lara ay S. Mediodia, Jezyl S. Simaurio, Jergen Athea Q.
Titular, Ghia D. Berbegal

Title of Research Study: Magallana bilineata (Oyster) and Acetic Acid


(Vinegar) Fire Retardant Spray as Fire Asphyxiator

Recommended:
VINCENT JOHN ARTIEDA ____________________
Practical Research II Teacher Date

Approved:
NOEL EDUARDO C. CATOLIN ____________________
Research Teacher & Adviser Date

Approved:
TEDDY B. GABINETE ____________________
Asst. Principal II, SHS Date

Approved:
VALENTE L. LAURO ____________________
Principal III Date

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OFFICIAL ABSTRACT and CERTIFICATION


TITLE: Magallana bilineata (Oyster) and Acetic Acid (Vinegar) Fire Category
Pick one only—
Retardant Spray as Fire Asphyxiator mark an “X” in box at
NAME: Ashley June M. Montalban, Alea Nicole C. Fajardo, Francis C. right
Romallosa, Lara May S. Mediodia, Jezyl R. Simaurio, Jergen Athea Q. ● Animal Sciences
Titular, Ghia D. Berbegal ● Behavioral and
Social Science
SCHOOL: Cabatuan National Comprehensive High School ● Biochemistry
Cellular &
● Molecular Biology
ABSTRACT Chemistry
● Computer
Fires can consume anything in its path if not prevented. This Science
study was conducted to find out whether the Magallana bilineata and ●

Earth Science
Eng: Electrical &
Acetic Acid Fire Retardant Spray as Fire Asphyxiator was effective in Mechanical
● Eng: Materials &
putting off Class A fire. The study was conducted at the Cabatuan Bioengineering
National Comprehensive High School. The researchers used a portable ● Energy &
Transportation
pressure sprayer as the fire extinguisher container. The Fire Retardant ● Environmental
Management
Spray was made by putting 16.68 grams of powdered Oyster Shells ● Environmental
Sciences
wrapped in a tissue and net held on top of the container by a thread. 400 ● Mathematical
milliliters of Vinegar was put into the lower part of the container. A ●
Sciences
Medicine and
pressure gauge was placed on the container to measure the pressure. 20 Health
● Microbiology
psi of pressure was pumped into the sprayer before shaking the solution, ● Plant Sciences
therefore, reaching the desired pressure of 40 psi before spraying the ● Physics and
Astronomy
solution at the base of the fire. The product was applied to Class A fire
which was made by combusting kerosene into wood. The time was
recorded in seconds as the Fire Retardant Spray and commercial Fire
Extinguisher put off the fire. T-test for two independent samples revealed
that the use of the Fire Retardant Spray and commercial Fire Extinguisher
has no significant difference in putting off Class A fires. The researchers
concluded that the Fire Retardant Spray has a significant effect in putting
off Class A Fire. The researcher recommends using the Fire Retardant
Spray as an alternative fire extinguisher.
1. As a part of this research project, the student directly handled, manipulated, or
interacted with (check ALL that applies):
human subjects potentially hazardous biological agents
vertebrate animals microorganisms rDNA tissue
2. This abstract describes only procedures performed by me/us, reflects
my/our own independent research, and represents one year’s work only Yes No
3. I/we worked or used equipment in a regulated
research institution or industrial setting: Yes No
4. This project is a continuation of previous research. Yes No
I/we hereby certify that the abstract and responses to the above statements are
correct and properly reflect my/our own work.
_____________________________ __________________________
Signature of the Researcher Date Signed
Acknowledgment

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“Gratitude can transform common days into thanksgivings, turn routine

jobs into joy, and change ordinary opportunities into blessings.”

– William Arthur Ward

We extend our deepest gratitude to those, who in one way or the

other, extended their help and assistance that contributed to the completion

of this study.

To God Almighty for granting us wisdom and strength during times

when this study was being undertaken, thank you Lord for guiding us;

To our beloved parents, with their love, care, and financial support

during the conduct of this study;

To our Research teacher, Mr. Noel Eduardo C. Catolin for the

invaluable advices he extended and for the comfort and encouragement that

boosted our determination to perform and finish this research work;

To the Bureau of Fire Station, for their supervision and assistance

during the conduct of our research experiment.

A special thanks to Mr. Vincent John E. Artieda for his endless

suggestions, support, and guidance during our study.

And to our friends and classmates who manifested their support, giving

us inspiration and encouragement for the completion of our research work;

Thank you to all!

Table of Contents

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Page No.

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Title Page…………………………………………………………..……………….

Approval Sheet…………………………………………………………………...

Abstract…………………………………………………………………………..…

Acknowledgement……………………………………………………………….

Table of Contents…………………………………………………………………

List of Figures……………………………………………………………………..

List of Tables……………………………………………………………………….

List of Appendices…………………………………………….…………………

CHAPTER 1…………………………………………………………………………

Introduction……………………………………………………………………

Conceptual Framework…………………………………………………….

Statement of the Problem…………………………………………………

Hypothesis……………………………………………….…………………….

Significance of the Study………………………………………………….

Definition of Terms…………………………………………….……………

Scope and Delimitation of the Study……………….…………………

CHAPTER 2…………………………………………………………….………….

Review of Related Literature…………………………………………….

Related Studies………………………………………………………….……

CHAPTER 3…………………………………………………………………………

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Methodology……………………………………………………………………

Description of Study Variables…………………………………….……

Gathering of Materials………………………………………………….……

Preparing of Oyster Shells…………………………………………..…….

Preparing the Fire Retardant Spray……………………………………

Preparation Before Testing………………………………………………..

Testing of Fire Extinguishers……………………………………..………

Experimental Design and Layout…………………………….…………

Experiment Proper……………………………………………………………

Data Collection………………………………..………………………………

Data Analysis…………………………………………………………..………

CHAPTER 4……………………………………………………………….…………

Results and Discussion……………………………..………………………

CHAPTER 5………………………………………………….………………………

Summary………………………………………………………..……………….

Conclusion……………………………………………………………………….

Recommendations…………………………………………………………….

References………………………………………………….……………………

APPENDICES…………………….………………………………………………..

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List of Figures

Page No.

Figure 1.1. Conceptual Framework of the Study……………………… 3

Figure 2.1 Schematic Diagram of Research Methodology…………. 22

Figure 3.1 Fire Retardant Spray……………………………………………..

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List of Tables

Page No.

Table 1.1 Experimental Layout……………………..…………………………

Table 2.1 Recorded time of Magallana bilineata (Oyster) and

Acetic acid Fire Retardant Spray and Commercial Fire

Extinguisher…………………………………………………………………….……

Table 2.2 Significant difference between Magallana bilineata

(Oyster) and Acetic Acid (Vinegar) Fire Retardant Spray and

Commercial Fire Extinguisher…………………………………………….……

Table 2.3 Computed T-value and Tabular T-

value………………………

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List of Appendices

Page No.

APPENDIX A CALENDAR OF EVENTS………………………………………

March 2023………………………………………………………………………

April 2023…………………………………………………………………………

APPENDIX B EXPENDITURES……….…………………………………………

APPENDIX C RAW DATA AND CERTIFICATIONS………………….……

APPENDIX D
COMPUTATIONS…………………………………………………

APPENDIX E PICTORIALS ……………………………….……………….……

Plate 1. Magallana bilineata Oyster Shells…………………….……

Plate 2. Pressure Gauge……………………………………………………

Plate 3. 500 ml Beaker………………………………………………………

Plate 4. Powdered Oyster Shells…………………………………….……

Plate 5. Vinegar…………………………………………………….…………

Plate 6. Fire Retardant Spray ……………………………………………

Plate 7. Fire Extinguisher……………………………………………………

Plate 8. Kerosene………………………………………………………………

Plate 9. Gathering of Oyster Shells………………………………………

Plate 10. Cleaning the Oyster Shells……………………………….…

Plate 11. Drying the Oyster Shells………………………………………

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Plate 12. Pulverizing the Oyster Shells……………………………….

Plate 13. Weighing the needed amount of powdered Oyster


Shells…………………………………………………………………………………..

Plate 14. Packaging the powdered Oyster Shells…………………..

Plate 15. Tying and securing the powdered Oyster Shells………

Plate 16. Measuring the needed amount of vinegar………………

Plate 17. Putting the measured amount of vinegar in the


sprayer…………………………………………………………………………………

Plate 18. Putting the packaged Oyster Shells inside the


sprayer………………………………………….……………………………………..

Plate 19. Firefighter lighting up the fire using kerosene…….….

Plate 20. Pumping the container…………………………………….…..

Plate 21. Shaking the container…………………………………………

Plate 22. Spraying the solution at the base of the fire…………

Plate 23. Doing the

T.P.A.S.S………………………………………………

Plate 24. Testing the commercial fire extinguisher………………..

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CHAPTER I

Introduction of the study

Fire is important and is beneficial for the ecosystem. Fire heats the

ground, causing seed coverings to split and increasing germination as it

promotes new growth that produces food for a variety of species (NSW

Government, 2021). Fire is used to cook on a daily basis and keep us warm

on cold nights. We also utilize fire to light the area around us and to burn any

garbage that may be safely incinerated, such as cardboard, paper, and

household trash. However, fire consumes houses and all your hard-earned

properties in seconds and even can cause our life. High temperatures

contribute to the occurrence of fire and the lack of readily available fire

hydrants causes the fire to be uncontrollable. As for our country, we have a

contributing factor wherein during the warm season, fires are most likely to

happen due to the hot weather, and houses are mostly built of light materials.

Fire is extremely difficult to contain once it starts, thus we must

understand the occurrence and factors that contribute to it. Fire is the

phenomenon of combustion manifested in light, flame, and heat (Fire

Definition & Meaning, 2022). Fire is one of the most common accidents here

in the Philippines that we experience every year. The Bureau of Fire

Protection (BFP) is alerted by the number of fire incidents that rose by 13% in

the first two months of 2022 compared to the year 2021 (Lloyd, 2022).

According to the NFPA (National Fire Protection Association), they report that

the top four causes of home fires are cooking, heating, electrical distribution,
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and lighting equipment (installed wiring, outlets, switches, cords, plugs,

power supplies, and lighting), and careless smoking (Koorsen Fire & Security,

2020).

An increase in the incident fire occurred with the factors stated. It is

mandatory that all precaution and prevention be applied or implemented. The

Philippines is an archipelago and is abundant in natural resources which can

be diverted into alternative solutions to disasters such as fire. Magallana

bilineata (talaba) commonly known as the Philippine cupped oyster or slipper

oyster, is an economically important species of true oyster found in the

western Pacific Ocean. Aside from being one of the country’s delicacies, it has

other functions too. Oyster Shells contain 95% Calcium carbonate (CaCO3)

(Becker et al., 2012). Calcium carbonate is known to be an effective fire

retardant. Vinegar will be used in this study as it contains 4-6% acetic acid

which is suitable to use. When calcium carbonate and vinegar are combined,

it generates carbon dioxide gas which can be used to put out fires.

Most of the houses in the Philippines are made of fire susceptible

materials. Given the fact and the possibilities of creating a more available and

cheap fire hydrant, the researchers decided to produce a fire asphyxiator as

an alternative. Therefore, this study aims to determine Magallana bilineata

(Oyster) shells and Acetic Acid as a Fire Retardant spray as Fire Asphyxiator.

Conceptual Framework

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Figure 1.1. The system approach (Input - Process - Output System) will

be used in describing the conceptual framework of the study. As shown in

Figure 1.1, the input consists of the identified dependent variable which is the

Oyster (Magallana bilineata) shells and the Vinegar (Acetic Acid). These

variables will be used to make the Fire Retardant Spray.

INPUT PROCESS OUTPUT

• Oyster (Magallana • Gathering of materials • Fire Retardant


bilineata) shells Spray
• Preparing of materials
• Vinegar (Acetic
• Designing prototype
Acid)
• Assembling materials
into pressure container

• Forming of Fire
Retardant Spray

Figure 1.1. Conceptual Framework of the Study.

Statement of the Problem

Generally, this study aims to determine the effectiveness of Magallana

bilineata (Oyster) and Acetic Acid (Vinegar) Fire Retardant Spray as Fire

Asphyxiator.

Specifically, this study aims to answer the following questions:

1. What is the effectiveness of Magallana bilineata (Oyster) Shells and

Vinegar (Acetic Acid) Fire Retardant Spray as Fire Asphyxiator?

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2. What is the efficiency of Magallana bilineata (Oyster) Shells and

Vinegar (Acetic Acid) Fire Retardant Spray as Fire Asphyxiator in

extinguishing Class A Fire?

3. Is there a significant difference between the Magallana bilineata

(Oyster) and Vinegar (Acetic Acid) Fire Retardant Spray as Fire

Asphyxiator from a commercial fire extinguisher?

Hypothesis

There is no significant difference between the Magallana bilineata

(Oyster) and Vinegar (Acetic Acid) Fire Retardant Spray as Fire Asphyxiator

from other commercialized fire extinguishers.

Significance of the Study

The result of the study will benefit the following:

Firefighters

This study aims to show expert firefighters the efficacy of Magallana

bilineata (Oyster) Shells and Vinegar (Acetic Acid) fire retardant spray as a

fire asphyxiator and a partner to fire extinguishers in containing fire.

Home

The output of this study is to develop an alternative to fire extinguisher

that is easily retrievable in an event of fire.

Schools

The product of this study is useful for schools since it can be utilized to

protect schools against fire. In the event of a fire emergency, these

frequently disregarded materials may be crucial to maintaining school safety.


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Rural Areas

The purpose of this study is to assist locals in rural locations in case of

fire due to the inability of responders to reach certain areas.

Urban Areas

This study will be beneficial to urban residents without the means to

purchase a commercial fire extinguisher. It is a cheaper option.

Future Researcher

This research study may serve as a guide for future investigations into

the efficacy of Magallana bilineata (Oyster) Shells and Vinegar (Acetic Acid)

fire retardant spray as fire asphyxiator in putting out Class A fire.

Definition of Terms

For the purpose of clarity and understanding, the following terms were

specified with their conceptual and operational definitions.

In this study, the commercial fire extinguisher will serve as our base

to show how effective our spray is.

Fire Extinguisher. Portable or moveable equipment used to extinguish

small fires by spraying the flame with a liquid that cools the material being

burned reduces the flame of oxygen or prevents the chemical processes

taking place in the flame (Pallardy, 2023).

In this study, an oyster shell contains 95% of calcium carbonate

(CaCO3), which makes it a strong agent against fire.

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Oyster. Any member of the family Ostreidae (true oysters) bivalve

mollusks found in temperate and warm coastal waters of all oceans (The

Editor of Encyclopedia Britannica, 2022).

In this study, a liquid that is pressurized and driven out of a particular

container to form a cloud-like mass of tiny liquid drops.

Pressure Gauge. A pressure gauge is a device that measures the state

of a liquid or gas by calculating the force that the fluid would apply to a unit

area if it were at rest, such as pounds per square inch or newtons per square

centimeter.(Britannica, T. Editors of Encyclopaedia, 2022)

In this study, it is used to monitor the pressure inside our sprayer.

Spray. An ensemble of water droplets torn by the wind from the

surface of an extensive body of water and carried upward a short distance

into the air (Cambridge English Dictionary, 2022).

In this study, the acetic acid of vinegar serves as the base of our

chemical mixture in making fire asphyxiator.

Acetic Acid. Acetic acid is a colorless acid. It is the main substance in

vinegar (Scott, 2016).

In this study, chemicals known as flame retardants are added to

materials to stop or delay the spread of fire.

Fire Retardant. Substances make the thing that they are applied to

burn more slowly (The Collins Dictionary, 2019).

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In this study, the class A fires will serve as our variable/combustion.

Class A fire. Refers to a fire that involves solid combustibles such as

wood, coal, paper, plastic, straw, cloth, rubber or any other solid materials.

These solid substances are mainly of organic origin and contain carbon and its

compounds (Safeopedia Inc. 2017).

In this study, a fire asphyxiator traps oxygen that can put out small

fires from combusting kerosene.

Fire Asphyxiator. A manually operated device for extinguishing small

fires (Free Dictionary, 2021).

Scope and Delimitation of the Study

This study will be conducted to determine the effectiveness of

Magallana bilineata and acetic acid in asphyxiating Class A fire. The prototype

will also be compared to a commercial fire extinguisher to discern if the fire

retardant spray is effective to use. The effectiveness and efficiency of

Magallana bilineata (Oyster) and Acetic Acid (Vinegar) Fire Retardant Spray as

fire asphyxiator will be determined by comparing the time in seconds it took

to put off fire to the time in seconds the commercial fire extinguisher is able

to extinguish the fire.

It will be performed in Cabatuan National Comprehensive High School

in the month of April 2023. The materials to use are Magallana bilineata shells

and vinegar. The Magallana bilineata shells will be gathered at a local

restaurant in Cabatuan and the acetic acid will be obtained from a local store

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in Passi City. The study will be conducted under the supervision of the

research adviser and firefighters.

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CHAPTER II

Review of Related Literature

This portion contains the following parts: I) Magallana bilineata, its

taxonomic classification, definition, benefits, structure, distribution and uses,

and the related studies are presented in this part. II) Fire Retardant, its

definition, importance, functions and uses, its features, advantages and

disadvantages and related studies are presented in this part. III) Acetic Acid,

its definition, importance, and benefits of Acetic Acid as Vinegar are

presented in this part.

Magallana bilineata

Definition. Magallana bilineata is one of the huge saltwater bivalve

mollusks in the Ostreidae family. It frequently resembles an oval or pear

structure with its shells length reaching 18cm and its shape varies it cannot

be differentiated from other tropical rock oysters until they reach its unique

size which is larger than other species this makes early life cycle identification

challenging and severely reduces the alternatives for selective treatment as a

control tool (Black Scar Oyster, 2020).

Taxonomic Classification. Magallana bilineata falls under Animalia

(Kingdom) > Mollusca (Phylum) > Bivalvia (Class) > Autobranchia (Subclass)

> Pteriomorphia (Infraclass) > Ostreida (Order) > Ostreoidea (Superfamily) >

Ostreidae (Family) > Crassostreinae (Subfamily) > Magallana (Genus)>

Magallana bilineata (Species)

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Benefits of Magallana bilineata. Oyster shells are mostly made out of

calcium carbonate, which produces calcium oxide and carbon dioxide when

heated thus preventing fire from access to oxygen by the produced carbon

dioxide. This property of oysters can help people escape their homes when

fire happens (Hetherington & Fang, 2020). Oyster shell powder was

discovered to be mostly made of calcium carbonate. As the temperature goes

up higher than 800°C, calcium carbonate decomposes to calcium oxide and

carbon dioxide, blocking oxygen from being attracted to the fire by the carbon

dioxide that was created (Cho et al., 2005). Oyster shell is an effective fire

retardant due to its 95% calcium carbonate (CaCO3) content (Han et al.,

2003). A non-combustible ingredient known as calcium carbonate is reported

to be able to make polymer-based composites more fire resistant

(Occupational Safety and Health Guideline for Calcium Carbonate , 1995).

Structure of Magallana bilineata . According to Piti Amparyup (2022),

“Oyster shell is composed of prismatic layer, cross lamellar and foliate layer

from outside to inside that are all made of CaCO3. Small amount of organic

matrix 3 components possibly play important roles to produce the structure of

crystal structures specific for each layer.” Layers of foliated microstructure

and lenses of chalk, a substance that is highly porous, superficially

disorganized, and mechanically weak, make up the majority of oyster shells.

We investigated the structural and crystallographic properties of these

materials, focusing on their interfaces. The laths that make up these

microstructures have comparable morphologies and crystal structures.

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Generally speaking, texture and crystallographic orientation were the key

variations. The sheet texture of the chalk is considerably softer than that of

the foliated microstructure, which has a definite 001 maximum. The

considerably more jumbled nature of the chalk makes this stunning. We

propose that, possibly by twinning, a portion of the unexpected order is

inherited from the foliated microstructure. According to growth line

distribution, the mantle separates from the preceding shell during chalk

formation several times faster than it does for foliated material. The chalk

becomes extremely porous due to a lack of structural material, which enables

crystals to reorient themselves at a sharp angle to the mantle surface while

still maintaining contact with it. In conclusion, the structural similarity of the

two materials simply explains the reasons for the disparities in orientation and

aspect. (Checa et al., 2018).

Distribution and Uses. Magallana bilineata is an important aquaculture

species in the Philippines (Lebata-Ramos et al., 2021). In many coastal towns

around Asia, oyster farming is a significant source of income (Szuster, 2008).

Because they are accessible to people with low incomes, they are among the

most sought-after bivalves. They are gourmet and luxury food in developed

countries but cheap food in developing countries, such as the Philippines

(Delmendo, 1989). According to Rosell (1991), they are found on tidal rivers,

channels, gulfs, and land-locked bays. Along the coast, where oyster farming

is a significant industry, different substrates (such as bamboo, recycled

bicycle tires, hanging ropes with oyster shells, etc.) used for collecting spat

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and/or growing oysters are frequently seen. The bamboo stake method,

which dates back to 1935 when oyster farming started in Hinigaran, Negros

Occidental, is one of the country's oldest cultural practices (Lebata-Ramos et

al., 2021).

Acetic Acid

Definition. An organic substance having the chemical formula

CH3COOH is acetic acid. It is a carboxylic acid with a functional group of

carboxyl linked to a methyl group. The chemical formula for acetic acid is

C2H4O2, and its systematic IUPAC name is ethanoic acid. A mixture of acetic

acid and water, vinegar has a volume percentage of ethanoic acid ranging

from 5% to 20%. The acetic acid that is present in it gives it a strong scent

and sour taste (Acetic Acid (CH3COOH), 2022).

Importance. Acetic acid is frequently employed as a chemical reagent

for the creation of a number of chemical compounds like acetic anhydride,

ester, vinyl acetate monomer, vinegar, and many other polymeric materials.

Acetic acid is also utilized in many industrial processes for the production of

substrates (Acetic Acid (CH3COOH), 2022).

Benefits of Acetic Acid (Vinegar). A chemical reaction between vinegar

and dissolving baking soda produces carbon dioxide (CO2) in a short period of

time. The candle will go out if the chemical reaction takes place in a beaker

with a lit candle inside because the carbon dioxide that is produced will build

up and drive out the oxygen (Schultz & Lien, 1995). Sodium bicarbonate is a

chemical compound that goes by the name "baking soda." Any acid, including

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vinegar, interacts with it to produce gaseous carbon dioxide (CO2). When you

pour the vinegar into the glass dish, you can really see it creating the bubbles

and froth that you see. When you combine an acid with sodium bicarbonate,

the same carbon dioxide reaction causes a baking soda volcano to erupt or

inflate a balloon. The carbon dioxide (CO2) in this experiment puts out the

candle flame. Although it is invisible, the carbon dioxide (CO2) created by the

vinegar-baking soda interaction begins to fill the glass dish from the bottom

up. The flame eventually dies out when there is no more oxygen available to

burn after all of the air in the glass dish has been replaced by carbon dioxide.

The match also burns out when it touches the carbon dioxide layer in the

glass dish, so if you try to light the candle again, it will not light (Lohner,

2017).

Fire Retardant

Benefits of Fire Retardant Spray. Flame retardants provide an

important layer of fire protection by helping to prevent or slow the spread of

fire. They lessen the amount of heat emitted by a fire as well as its capacity

to spread. Your time to flee or put out the fire is extended thanks to the spray

foam. To claim that fire retardant spray "puts out" a fire in the same manner

as water would be inaccurate. It is a race against time to put out a fire. The

fight is easier to win thanks to the fire retardant spray's extended duration.

This spray's ability to considerably reduce the spread of fire on treated items

has been demonstrated. Because the flames are not bursting into the air, it

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also lessens the likelihood that the surface will catch fire in the first place

(Stafford, 2021).

Disadvantages of Fire Retardant Spray. According to the United States

Forest Service (USFS), 2021 “Fire Retardant spray should not be used within

300 feet of lakes, creeks, streams, or any body of water. The high

concentration of ammonia and phosphate will cause some negative effects on

aquatic life that can also kill fish. This can also create algae blooms. There are

some cases that report skin irritation, but generally, the safety benefits

outweigh these incidents. While it is non-toxic, it should not be digested by

people or animals ” (Ingram, 2021).

Related Studies

Chemical Reaction Between Calcium carbonate and Acetic Acid. In

(Chan et al., 2019)’s study, they determine whether the amount of baking

soda (sodium bicarbonate) used affects or does not affect the amount of

carbon dioxide produced when reacting with vinegar (acetic acid). The

researchers determined that 5 g of baking soda would be required to react

with 70 mL of vinegar. Before adding the baking soda to the liquid measuring

cup, they set up their phones to capture the reaction. They then marked the

cup with the quantity of baking soda that would be utilized for the study using

a 500-mL liquid measuring cup. They halted the recording when the reaction

was finished, then carried out the same procedure five times, varying the

amount of baking soda used for each experiment by 2x, 1.5x, 0.75x, 0.5x,

and 0.25x, respectively. They folded a piece of paper in half and set it on the

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baking scale to transfer the baking soda. The liquid measuring cup was filled

with 5 mL of dish soap and 70 mL of vinegar (5% acetic acid), which they

combined. They measured 5 g of baking soda after zeroing the scale and

placing the piece of paper on top. Because the reaction for this experiment

happened quickly and the bubbles did not stay at their highest point for very

long, it is crucial to both observe and record the reaction with different

equipment. They implemented Experimental Research Design as their

research design. The materials used are Baking Soda (Sodium bicarbonate),

Vinegar (Acetic acid), and Liquid Soap. They used observation as their

research instrument. The quantity of baking soda used has an impact on how

much carbon dioxide is created when vinegar and baking soda are combined.

Given that the amount of baking soda used has no bearing on the amount of

carbon dioxide created, the null hypothesis was that if different amounts of

baking soda react with 70mL of vinegar, the mean volume of bubbles formed

should be the same. The experiment tested how the product affects the

outcome by varying

the amount of baking soda in the reaction with vinegar. The vinegar and

baking soda combustion can be useful for baking as the carbon dioxide

produced acts as a leavening agent.

Alternative Fire Extinguisher. According to (Reolo, 2019), the

objective of the study is to produce a fire retardant spray that can be used as

an alternative fire extinguisher containing calcium carbonate from eggshells

and oxaloacetic acid from kamias (Averrhoa bilimbi). The process of making

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this fire retardant spray consists of the following Seeking, Preparing,

Extracting, Measuring, and Putting. They found Kamias ( Averrhoa bilimbi) and

wasted eggshells, after that, they extracted the kamias (Averrhoa bilimbi) and

turned the eggshells into powder. This mixture was put into a pump hand

sprayer to test its effectiveness in different combustions. The research design

used is Experimental Research Design. The materials used are calcium

carbonate from eggshells and oxaloacetic acid from kamias (Averrhoa

bilimbi). They used observation as their research instrument in their study.

When combined, the calcium carbonate from powdered eggshells and the

oxaloacetic acid from kamias (Averrhoa bilimbi) will produce CO2, which will

be used to extinguish the oxygen in areas where there are mild fires.

According to the test results, the fire retardant spray was successful and

efficient in putting out fires caused by various reactants. The reaction caused

by the calcium carbonate from eggshells and oxaloacetic acid from kamias

(Averrhoa bilimbi) was able to create an alternative fire extinguisher.

Citrusoda. According to the study, Citrusoda significantly contributes to

Class A fire suppression. It serves as a substitute fire extinguisher. As an

alternate fire extinguisher, citric acid and baking soda solution were used. The

goal of the study was to ascertain whether Citrusoda, a mixture of baking

soda and citric acid, can be used as a substitute fire extinguisher to put out

Class A flames. The Citrusoda (Citric Acid and Baking Soda) solution was

shaken by the researcher as part of the experiment. The sprayer's mouth was

pressed during combustion and pointed directly at the fire's base by the

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researchers. It was attached to the upper portion of the two combined cans.

The information was gathered by keeping track of how long it takes the

Citrusoda to put out the fire. (Surmion et al., 2013).

Fire Incidents in the Philippines. According to (Velasco, 2013), fires are

relatively unstudied and it is also the most costly preventable emergency. This

study aims to assess the epidemiology in the Philippines of fire and fire-

related casualties. This study used data from the OpCen of the HEMS and

included all fires reported in the HEARS Plus Reports from 2010 to 2012.

The HEARS Plus Reports underwent three stages of evaluation. In order to

ascertain the degree of fire documentation, a preliminary review of the

HEARS Plus Reports was conducted. A second evaluation was carried out to

determine what to include individual reports of fires and a comprehensive

summary of all fire events. Fire incidents were arranged in time order and

given a special code for event identification. Prior to data, the final evaluation

was completed. encoding. A data extraction tool in the form of a

questionnaire was created using EpiInfo 2000 in order to extract significant

data.

From 2010 to 2012, half of all fires took place during the day. Real fire

risks exist in physical structures, especially while residents may be sleeping or

otherwise physically gone from the buildings. The usage of open flames

during the evenings, such as candles and lamps, is some of the reasons.

Fires burn for longer between midnight and three in the morning because

people are asleep and firefighters take longer to respond. Reporting of fires

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and fire-related casualties has increased in the HEARS, although the extent of

reporting has been limited in scope. The information available from the

present reporting system does not allow for a more in-depth investigation of

the effects and determinants of fires. Reporting of the effects of fires and the

factors that could affect their occurrence should be improved.

Commercial Fire Extinguisher. Stated by (Du et al., 2018), The

existing fire extinguishing powder was improved by Magnesium hydroxide

that was used to prepare a compound superfine powder, which was tested by

a modified cup-burner and showed advantages in minimum extinguishing

concentration, temperature, and extinguishing time.The experimental results

showed that the minimum extinguishing concentration of compound superfine

powder was much lower than the other two, and the temperature drop rate

was greater in the process of suppressing flame.

According to (Benfer & Williams, 2016), Portable fire extinguishers play

a main role in reducing the impact of fires. In its early stages, a fire that can

be put out with an extinguisher will not spread to materials nearby. Water,

clean gaseous agents, dry chemicals, and foam are some of the common

extinguishing agents utilized in museums and libraries. Their effects on

collection materials have not been adequately studied. The following variables

were evaluated through eleven tests: exposure with and without fire, the kind

of extinguisher, the kind of material, and sample exposure (direct vs.

indirect). For exposing a large number of materials to the effects of

extinguisher agents, the established test method was found to be sufficient.

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There was no single extinguisher that did not affect any of the materials

tested, including the cleaning agents, according to the findings.In point of

fact, the fire tests were more affected by the corrosive effects of the thermal

decomposition products from the clean agents. Damage to samples was

found to be immediate and did not appear to progress over time.

In (Su et al., 2014) study, Taiwan’s most important fire safety

equipment is the fire extinguisher. The ABC powder fire extinguisher is a

common fire safety equipment as it can extinguish different classes of fire,

such as papers, gasoline, and electrical fire. The DSC was used in this study

to inspect the ABC powder of fire extinguishers, and the thermal

decomposition values of constituents of powder were analyzed directly. Not

determining the phosphorus content indirectly is the key concept in this

study. The results showed that the variation curves of ammonium dihydrogen

phosphate and ammonium sulfate have their particularities, and they will not

disturb each other.

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CHAPTER III

METHODOLOGY

This chapter presents the materials and procedure employed in this

study.

For an overview refer to the Schematic Diagram in Figure 2.1

Magallana bilineata
Acetic Acid (Vinegar)
(Oyster) Shells

Gathering Gathering

Pulverizing Weighing

Preparing Preparing

Fire Retardant Spray

Experiment Proper

Collecting Data

Analyzing and
Interpreting Data

Figure 2.1 Schematic Diagram of Research Methodology

Description of Study Variables

Magallana bilineata shells. Two kilograms of discarded whitish-gray

slipper oyster shells will be used in the study.

Vinegar. Five-hundred milliliters of sour and cloudy vinegar will be used

in the study.

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Gathering of Materials

Magallana bilineata (Oyster) Shells. The researchers will obtain oyster

shells in Zea Ser Talabahan & Tinu-om Restaurant at Rizal Ilawod Street,

Cabatuan. This is to be cleaned and pulverized afterward. Vinegar. The

researchers will buy 4 liters of Vinegar at a local store in Cabatuan,Iloilo.

Portable Pressure Sprayer Container. The researchers will buy pressure

sprayers in a local store. Fire Extinguisher. The school will provide a fire

extinguisher. Laboratory Apparatus. The researchers will use a weighing scale

to measure the mass of the pulverized oyster shells and a beaker to measure

the volume of the vinegar. Class A fire. Piles of wood will be gathered around

the conduct area and kerosene will be bought at a local store which will be

used to light the piles of wood on fire.

Preparing of Oyster Shells

The Oyster shells are to be scrubbed thoroughly using water and a

brush. After cleaning the shells, they will be left under the sun to dry for 48

hours. Then, the shells will be prepared for the pounding process and turn

them into fine grains providing the researchers the calcium carbonate. This

process is repeated until all the shells are completely pulverized. The

granulated shells will be sifted to separate oyster shell crumbs from refined

powdered shells.

Preparing the Fire Retardant Spray

The researchers will use a portable pressure sprayer. The container

will have two parts. The circular-shaped net with tissue in which will hold the

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grains of oyster shells and the lower chamber where the vinegar will be

poured into. 16.68 grams of powdered Magallana bilineata shells and four-

hundred milliliters (400mL) will be utilized.

Figure 3.1 Fire Retardant Spray

Preparation Before Testing

The researchers will be guided and assisted by firemen of the

Cabatuan fire station on how to handle the commercial fire extinguisher and

for safety concerns as handling fire is involved. The researchers will wear

protective gear for proper protection against fire.

Testing of Fire Extinguishers

In testing the Fire Retardant Spray, the researchers will prepare the

spray by mixing the substance incorporated into the pressured container

making an acid-base chemical reaction. During the experiment, the

researchers will open the container and spray it directly on the fire. A

considerable amount of solution will be sprayed until the fire is put off.
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In testing the commercial fire extinguisher, the same procedure in the

testing of the Fire Retardant spray solution will be used. The researchers will

remove the safety pin and open it towards the fire, putting it off.

The data will be gathered upon the application of the fire asphyxiator

and the commercial fire extinguisher in each replication from the moment the

Fire Retardant spray and commercial fire extinguisher are opened and pointed

directly at the base of the fire.

Experimental Design and Layout

The Experimental Method of Quantitative Research will be used to

answer the objectives of the study. The objective of this study is to find out

how successfully the fire asphyxiator can contain Class A fire. In doing so, the

researcher tries to ascertain or predict how effective the fire asphyxiator is

compared to a commercial fire extinguisher.

The researchers will run one trial using the provided variables to find

the mixture that best puts out fires. The given amount of solution will be

repeated five times in a Class A fire. The identical process will be repeated for

the commercial fire extinguisher for comparison.

Table 1.1. Experimental Layout


Treatment Time in putting off Class A fires

Oyster and Vinegar R1 R2 R3 R4 R5


Fire Retardant Spray

Commercial Fire R1 R2 R3 R4 R5
Extinguisher
Legend:

R1 - 1st Replication

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R2 - 2nd Replication

R3 - 3rd Replication

R4 - 4th Replication

R5 - 5th Replication

Calculations:

To determine how much calcium carbonate is needed to react with 400

mL of vinegar containing 5% acetic acid, we need to use stoichiometry to

calculate the amount of acetic acid in moles and then determine the

corresponding amount of calcium carbonate needed.

First, we need to convert the volume of vinegar to moles of acetic acid:

Molarity of acetic acid in vinegar = 5% = 0.05

Density of vinegar = 1.00 g/mL (Assuming it's at room temperature

and atmospheric pressure)

The molar mass of acetic acid is 60.05 g/mol, so the concentration of acetic

acid in the vinegar is:

0.05 mol/L = 3.003 g/60.05 g/L = 0.04996 g/mL

The amount of acetic acid in 400 mL of vinegar is:

0.04996 g/mL x 400 mL = 19.984 g = 0.3333 moles of acetic acid

Now that we know we have 0.3333 moles of acetic acid, we can use

the balanced equation to determine the amount of calcium carbonate needed:

2 CH₃COOH + CaCO₃ → Ca(CH₃COO)2 + H2O + CO2

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From the balanced equation, we see that 1 mole of calcium carbonate

reacts with 2 moles of acetic acid. So, 0.3333 moles of acetic acid will require

(0.3333/2) = 0.1667 moles of calcium carbonate.

The molar mass of calcium carbonate is 100.09 g/mol, so the amount

of calcium carbonate needed is:

0.1667 moles x 100.09 g/mol = 16.68 g

Therefore, 16.68 g of calcium carbonate is needed to react with 400

mL of vinegar containing 5% acetic acid.

Experiment Proper

The researchers will test the trial with the supervision of the experts by

the variables given to determine the effectiveness and efficiency of the Fire

Retardant spray. The setup will determine the extinguishing capability of the

fire extinguishing prototype when compared to a commercial fire extinguisher.

The researchers will go to an open area and perform the experiment.

First, the researchers will gather materials for the Class A fire. This includes

500 milliliters of kerosene and match. The open area will prevent the

researchers and the experts from inhaling the fumes of the Class A fire. The

experiment will commence until 5 replications are done.

20 psi of pressure will be incorporated by pumping the device of the

container before the experiment. The mixture in the container will activate by

shaking the container, and mixing the vinegar and the powdered oysters

inside. A circular-shaped net will be put on the upper part of the container

where the refined oyster will be contained. Once the researcher shakes the

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sprayer, the vinegar will react with the oyster shell powder which will cause a

chemical reaction that will expand itself greatly, creating a foam-like

substance. Pressure will be built up that is needed to spray the solution. This

pressure will add up the pressure put beforehand and will have a total

amount of 40 psi. Once the desired amount of pressure is reached, the nozzle

should be directed to the fire. Then extinguish the fire by pressing the trigger.

Data Collection

The researchers will document the time in seconds the Magallana

bilineata (Oyster) and Acetic Acid (Vinegar) Fire Retardant Spray and

commercial fire extinguisher completely extinguish the fire. A stopwatch will

be utilized in recording the time. The data will be recorded the moment the

researchers spray the alternative fire extinguisher at the base of the fire and

it will end when the fire is completely put off. The researchers will record the

effectiveness and efficiency of the Fire Retardant Spray by recording the time

of the spray in putting off combustibles.

Data Analysis

The following statistical tools were used to analyze and represent the

data gathered during the study. Microsoft Excel was used to compute the

following statistical tools:

Mean. This will be used to summarize the arbitrary rating per

treatment.

T-test. The T-Test will be used to interpret the comparison of results

between the Fire Retardant Spray and the commercial fire extinguisher.

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CHAPTER IV

RESULT AND DISCUSSION

This chapter presents the data gathered after testing the Magallana

bilineata (Oyster) and Acetic Acid (Vinegar) Fire Retardant Spray as Fire

Asphyxiator. In this study, the researchers used Experimental Method in

determining the effectiveness and efficiency of the study against Class A fires

and its significant difference when compared to a commercial fire

extinguisher. The time in extinguishing the fire in both the improvised fire

extinguisher and commercial fire extinguisher was recorded using a stopwatch

and was recorded the moment the researchers spray the Fire Retardant Spray

at the base of the fire and ends when the fire is no longer visible.

Table 2.1. Recorded time of Magallana bilineata (Oyster) and Acetic Acid
(Vinegar) Fire Retardant Spray and Commercial Fire Extinguisher
Recorded Time in Putting off Class A Fires
Treatment
1st 2nd 3rd 4th 5th
Replication Replicatio Replication Replication Replication
n
Oyster and 38.30 secs 37.98 sec 34.75 secs 38.07 sec 38.58 sec
Vinegar Fire
Retardant Spray
Commercial Fire 2.01 secs 1.95 sec 2.04 sec 1.91 sec 1.82 sec
Extinguisher
The table shows the length of time the Magallana bilineata (Oyster)

and Acetic Acid (Vinegar) Fire Retardant Spray as Fire Asphyxiator and

Commercial Fire Extinguisher put off fire completely.

Table 2.2. Significant difference between Magallana bilineata (Oyster) and


Acetic Acid (Vinegar) Fire Retardant Spray and Commercial Fire Extinguisher

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Recorded Time in Putting off Class A Fires


Total Total
Treatment Replications
Length Mean
R1 R2 R3 R4 R5 of Time
Fire Retardant 38.30 37.98 34.75 38.07 38.58 187.68 37.536
Spray secs secs secs secs secs secs
Commercial Fire 2.01 1.95 2.04 1.91 1.82 9.73 1.946
Extinguisher secs secs secs secs sec secs
Grand Total 197.41

Grand Mean

Table 2.3. Computed T-value and Tabular T-value.


Computed T Tabular T

1.062 2.776

The T-test for two independent samples revealed that the use of the

Magallana bilineata (Oyster) and Acetic Acid (Vinegar) Fire Retardant Spray as

Fire Asphyxiator and commercial Fire Extinguisher has no significant

difference in putting off Class A fires. There is no significant difference

between theMagallana bilineata (Oyster) and Acetic Acid (Vinegar) Fire

Retardant Spray as Fire Asphyxiator and commercial made Fire Extinguisher

since the Computed T is less than the Tabular T at 0.05 level of significance.

The effectiveness of Magallana bilineata (Oyster) and Acetic Acid

(Vinegar) Fire Retardant Spray as Fire Asphyxiator in putting off Class A fire is

unparalleled to the commercial fire extinguisher, though, still as effective and

has the ability to put off fire efficiently, therefore, the Magallana bilineata

(Oyster) and Acetic Acid (Vinegar) Fire Retardant Spray as Fire Asphyxiator

can be an alternative fire extinguisher.

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CHAPTER V

SUMMARY, CONCLUSION, AND RECOMMENDATIONS

Summary

The objective of this study is to determine the effectiveness and

efficiency of Magallana bilineata (Oyster) and Acetic Acid (Vinegar) Fire

Retardant Spray as Fire Asphyxiator and to know if there is a significant

difference between Magallana bilineata (Oyster) and Acetic Acid (Vinegar) Fire

Retardant Spray as Fire Asphyxiator and commercial fire extinguisher. This

study was conducted on April 14, 2023 at Cabatuan National Comprehensive

High School, Cabatuan, Iloilo.

Magallana bilineata (Oyster) shells were gathered at a local seafood

restaurant and acetic acid at a local store. The researchers performed 1 trial

and 5 replications with the replication all having the same amount of solution

which contains 400 mL of vinegar and 16.68 grams of pulverized oyster

shells. The researchers prepared the spray by pumping it to 20 psi

beforehand then proceeded to shake the container which resulted in the

substance being mixed adding up to 40 psi where it incorporated pressure

inside, making an acid-base chemical reaction used to extinguish the Class A

fire.

Results showed that Magallana bilineata (Oyster) and Acetic Acid

(Vinegar) Fire Retardant Spray as Fire Asphyxiator can put out Class A fires

but compared to the commercial fire extinguisher, the latter was able to

extinguish Class A fires more quickly.

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Conclusion

The Magallana bilineata (Oyster) and Acetic Acid (Vinegar) Fire

Retardant Spray as Fire Asphyxiator is effective and efficient against Class A

fires but there is no significant difference when compared to the commercial

fire extinguisher. The researchers concluded that the Magallana bilineata

(Oyster) and Acetic Acid (Vinegar) Fire Retardant Spray is effective and can

be used efficiently against Class A fire. Therefore, the Retardant Spray can be

used as an alternative fire extinguisher.

Recommendations

The researchers recommend using a steel container rather than plastic

to prevent any pressure leaks that may be brought on by the expanding of

the container. In addition to this, the researchers also recommend adding

dishwashing liquid to the mixture to increase the efficiency of trapping CO2 by

creating foam when the mixture is shaken.

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[22] Ingram, B. (2021, September 24). 7 things to know about fire

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retardant

[23] Lebata-Ramos, M. J. H. L., Dionela, C. S., Novilla, S. R. M., Sibonga, R.

C., Solis, E. F. D., & Mediavilla, J. P. (2021, March 15). Growth and

survival of oyster Crassostrea iredalei (Faustino, 1932): A comparison

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[24] Lohner, S. (2017, March 2). Fire-Fighting Foam. Scientific American.

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[25] Reolo, M. L. (2019, January 18). Fire Retardant Spray: An Alternative

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APPENDICES

APPENDIX A

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CABATUAN NATIONAL COMPREHENSIVE HIGH SCHOOL
SENIOR HIGH SCHOOL
Cabatuan, Iloilo

CALENDAR OF EVENTS

MARCH 2023

SUN MON TUE WED THUR FRI SAT

1 2 3 4

5 6 7 8 9 10 11

12 13 14 15 16 17 18

19 20 21 22 23 24 25
Gathering Cleaning Drying of Drying of Pulverizin Pulverizin Pulverizin
of Oyster and oyster oyster g of g of g of
Shells Drying of shells shells Oyster Oyster Oyster
Oyster Shells Shells Shells
Shells

26 27 28 29 30 31
Pulverizin Pulverizin Pulverizin Pulverizin Pulverizin Pulverizin
g of g of g of g of g of g of
Oyster Oyster Oyster Oyster Oyster Oyster
Shells Shells Shells Shells Shells Shells

APRIL 2023

SUN MON TUE WED THUR FRI SAT

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CABATUAN NATIONAL COMPREHENSIVE HIGH SCHOOL
SENIOR HIGH SCHOOL
Cabatuan, Iloilo

1
Pulverizin
g of
Oyster
Shells

2 3 4 5 6 7 8
Pulverizin Preliminar Preliminar
g of y Conduct y Conduct
Oyster
Shells

9 10 11 12 13 14 15
Preliminar Preparing Handing Conductin
y Conduct of over the g of Study
Materials letter to
the
Bureau of
Fire
Station

16 17 18 19 20 21 22

23 24 25 26 27 28 29

30

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CABATUAN NATIONAL COMPREHENSIVE HIGH SCHOOL
SENIOR HIGH SCHOOL
Cabatuan, Iloilo

APPENDIX B

EXPENDITURES

Materials Quantity Price per Item Total Cost

Sprayer 3 bottles Php 130.00 Php 390.00

Epoxy 1 piece Php 90.00 Php 90.00

Pressure Gauge 3 pieces Php 150.00 Php 450.00

Vinegar 2 liters Php 48.00 Php 96.00

Kerosene 2 liters Php 72.00 Php 144.00

TOTAL Php 1170.00

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CABATUAN NATIONAL COMPREHENSIVE HIGH SCHOOL
SENIOR HIGH SCHOOL
Cabatuan, Iloilo

APPENDIX C

RAW DATA AND CERTIFICATION

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CABATUAN NATIONAL COMPREHENSIVE HIGH SCHOOL
SENIOR HIGH SCHOOL
Cabatuan, Iloilo

APPENDIX D

COMPUTATIONS

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CABATUAN NATIONAL COMPREHENSIVE HIGH SCHOOL
SENIOR HIGH SCHOOL
Cabatuan, Iloilo

APPENDIX E

PICTORIALS

Plate 1. Magallana bilineata Plate 2. Pressure Gauge


Oyster Shells

Plate 3. 500 ml Beaker Plate 4. Powdered Oyster Shells

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CABATUAN NATIONAL COMPREHENSIVE HIGH SCHOOL
SENIOR HIGH SCHOOL
Cabatuan, Iloilo

Plate 5. Vinegar Plate 6. Fire Retardant Spray

Plate 7. Fire Extinguisher Plate 8. Kerosene

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CABATUAN NATIONAL COMPREHENSIVE HIGH SCHOOL
SENIOR HIGH SCHOOL
Cabatuan, Iloilo

Plate 9. Gathering of Oyster Shells Plate 10. Cleaning the Oyster


Shells

Plate 11. Drying the Oyster Shells Plate 12. Pulverizing the
Oyster Shells

Plate 14. Packaging the Powdered


Oyster Shells

Plate 13. Weighing the needed


amount of powdered Oyster Shells

Plate 15. Tying and securing Plate 16. Measuring the the
powdered Oyster Shells needed amount of Vinegar

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CABATUAN NATIONAL COMPREHENSIVE HIGH SCHOOL
SENIOR HIGH SCHOOL
Cabatuan, Iloilo

Plate 17. Putting the measured Plate 18. Putting the packaged
amount vinegar inside the sprayer powdered Oyster Shell inside
the sprayer

Plate 19. Firefighter lighting up the


Plate 21.Shaking the container
fire using kerosene

Plate 20. Pumping the container

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CABATUAN NATIONAL COMPREHENSIVE HIGH SCHOOL
SENIOR HIGH SCHOOL
Cabatuan, Iloilo

at the base of the fire

Plate 22. Spraying the solution


Plate 23. Doing the T.P.A.S.S. Plate 24. Testing using the
commercial fire extinguisher

47

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