SAFETY DATA SHEET

MIRACLE S240

Revision Date : 18.09.2019

SECTION 1 - IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Company : G-Planter Sdn Bhd Product Name: Miracle S240
(643873-X)
No. 11 A, Jalan Mahsuri, Chemical: Polyethersiloxane
Kawasan Industri, Jalan Characterization Industrial Use
Mersing, 86000, Kluang, Use:
Johor.

Office Phone No. : +6 07-7878488

Fax No. : +6 07-7878480
SECTION 2 – HAZARD IDENTIFICATION
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (Inhalation) Category 4 H332
Eye irritation Category 2 H319

2.2. Label elements

Constituent decisive for : Polyether modified trisiloxane; CAS-No.: 134180-76-0
hazardous -substance
labelingSymbol(s) :

Signal word : Warning

hazard statement : H319 - Causes serious eye irritation. H332 - Harmful if inhaled.

Precautionary : P261 - Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
Statement P271 - Use only outdoors or in a well-ventilated area.
(Prevention) P280 - Wear eye protection/ face protection.
Precautionary Statement : P304 + P340 - IF INHALED: Remove person to fresh air and
(Response) keep comfortable for breathing.
P337 + P313 - If eye irritation persists: Get medical
advice/attention.

Other hazards : None known

Page 1 of 11
P337 + P313 - If eye irritation persists: Get medical advice/
attention.
SECTION 3 – COMPOSITION /INFORMATION ON INGREDIENTS

Components CAS-No. EC No. Concentration [%] Classification

Polyether modified 134180-76-0 603-798-4 >=75 % Acute Tox., 4, H32,
trisiloxane Inhalation Eye
Irritation., 2, H 319

SECTION 4 – FIRST AID MEASURES

4.1. Description on first aid measures
General advice : Remove soiled or soaked clothing immediately.
Inhalation : If inhalated remove from side of exposure to fresh air, seek
medical advice.

Skin contact : In case of contact with skin wash off with soap and water.
In the event of symptoms seek medical advice.

Eye contact : In case of contact with eyes rinse thoroughly with plenty
of water. If symptoms persist, seek medical advice

: Thoroughly clean the mouth with water. In the event of

Ingestion symptoms seek medical advice.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms : Eye irritation
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically

SECTION 5 – FIRE FIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing : Foam, Carbon dioxide, Dry Powder, Water Spray

Unsuitable extinguishing media : Full water jet

5.2. Special hazards arising from the substances or mixture

In the event of fire the following can be released:

- Carbon monoxide, carbon dioxide, silicon dioxide

5.3. Advice for firefighters

Do not inhale explosion and / or combustion gases

Use self-contained breathing apparatus

Page 2 of 11
SECTION 6 – ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective : Use personal protective equipment.

equipment and emergency procedures
6.2. Environmental precautions : Do not allow to enter drains or waterways
Do not discharge into the subsoil/soil.
6.3. Methods and material for containment : Take up with absorbent material (e.g sand,
cleaning up Kieselguhr, acid binder, universal binder,
sawdust). Dispose of absorbed material in
accordance with the regulations.

6.4. Reference to other sections : For further information on exposure monitoring and
disposal. See Section 8 and 13.

material in accordance with the

SECTION 7 – HANDLING AND STORAGE
regulations.
7.1. Precautions for safe handling
Advice on safe handling : No special measures necessary if stored and
handled as prescribed.

Hygiene measures : Do not eat, drink or smoke when working. Wash

hands before breaks and after work. Remove
soiled or soaked clothing immediately.

General protective : Avoid contact with eyes and skin. Do not inhale
measures gases/ vapours/ aerosols.

7.2. Conditions for safe storage, including any incompatabilities

Prevention of fire and explosion

Information : No special measures required.
Storage
Information : None.
Further information on storage conditions : Keep container tightly closed and dry.

7.3. Specific end use(s)

No further recommendations.

Page 3 of 11
SECTION 8 – EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1. Control parameters

DNEL : No DNEL/DMEL values on file.

PNEC : No PNEC values on file.

8.2 Exposure controls

Eye protection
: Safety glasses.

Hand protection : Glove material : gloves made of nitrile (NBR)

Break through time : > 480 min
Glove thickness : 0.11 mm

Body protection : Protective clothing

Respiratory protection : In case of formation of vapours/aerosols

A protective ointment is recommended.

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES

Form : Liquid
Color : Dark blue
Odour : No odour

Melting temperature : Not measured

Boiling temperature : Not measured

Flash point : Not measured
Lower explosion limit : Not measured
Upper explosion limit : Not measured
Vapour pressure : Not measured
Density : 1.0881 g/ml

Water solubility : Soluble

pH : 6.8

Viscosity, dynamic : 0.4 dpas

Page 4 of 11
SECTION 10 – STABILITY AND REACTIVITY
10.1. Reactivity
See section "Possibility of hazardous reactions"

10.2. Chemical stability

The product is stable under normal conditions.

10.3. Possibility of hazardous reactions

No hazardous reactions with proper storage and handling.

10.4. Conditions to avoid

None with proper storage and handling.

10.5. Incompatible materials

Unknown

10.6. Hazardous decomposition products

None with proper storage and handling.

SECTION 11 – TOXICOLOGY INFORMATION

11.1. Information on toxicological effects

Acute oral toxicity : LD50 Species: rat

Dose : > 2,000 mg/kg
Method : OECD Test Guideline 401.
Remarks : The data are derived from the evaluations or
test results achieved with similar products (conclusion by
analogy).

Acute inhalation toxicity : LC50.

Species: Rat
Exposure time: 4 h
Test atmosphere : Dust/mist
Dose: 1.08 mg/l
Method: OECD Test Guideline 403
Remarks : The data are derived from the evaluations or
test results achieved with similar products (conclusion by
analogy).

Acute dermal toxicity : LD50

Species: Rat
Dose: > 2,000 mg/kg
Method: OECD Test Guideline 402
Remarks : The data are derived from the evaluations or
test results achieved with similar products (conclusion by
analogy).
Page 5 of 11
 Irritation / corrosion of the skin : Result : Slight irritant effect – does not require labelling
Remarks : The data are derived from the evaluations or
test results achieved with similar products (conclusion by
analogy).

Serious eye damage / eye irritation : Species : Rabbit

Result : Strong irritant
Remarks : The data are derived from the evaluations or
test results achieved with similar products (conclusion by
analogy).

Respiratory / skin sensitization : Species : Guinea pig

Result: Non-sensitizing
Classification: Did not cause sensitization on laboratory
animals.
Remarks : The data are derived from the evaluations or
test results achieved with similar products (conclusion by
analogy).
: Species : Rat
Repeated dose toxicity
Application Route : Oral: gavage
Exposure duration: 28 day
Frequency of exposure: daily
No observed adverse effect level : 200 mg/kg
Method: OECD 407
Remarks : The data are derived from the evaluations or
test results achieved with similar products (conclusion by
analogy).

CMR assessment
Carcinogenicity : No data available

Mutagenicity : In vitro and animal experiments revealed no evidence of

potential for hereditary genetic changes.
Teratogenicity : No data available

Toxicity to reproduction : No data available

Genotoxicity in vitro : Chromosome aberration test in vitro
Chinese hamster ovary cells
Metabolic activation : with or without
Result: Non clastogenic
Method: OECD 473
GLP: yes
Remarks : The data are derived from the evaluations or
test results achieved with the individual substances.

Page 6 of 11
 Gentoxicity in vivo : In vivo micronucleus test
Species : Mouse
Cell Type: Bone marrow
Application Route:
intraperitoneal Method: US-
EPA-method
Result: Negative
The data are derived from the evaluations or test results
achieved with similar products (conclusion by analogy).

Specific Target Organ Toxicity -

: No data available
Single Exposure
Specific Target Organ
: No data available
Toxicity - Repeated exposure

Aspiration hazard : No aspiration toxicity classification

Other information : Irritant to eyes.
Harmful by inhalation.

SECTION 12 – ECOLOGICAL INFORMATION

Ecotoxicology Assessment

Acute aquatic toxicity : Contains no substances known to be hazardous

to the environment.

Chronic aquatic toxicity : Labelling not required according to EU-CLP

Ordinance (1272/2008).

12.1. Toxicity
Aquatoxicity, fish : Species : rainbow trout
Exposure duration: 96 h
LC 50: 2.1 mg/l
Method: OECD 203
Remarks : The data are derived from the
evaluations or test results achieved with similar
products (conclusion by analogy).

Aquatoxicity, invertebrates : Species : Daphnia magna

Exposure duration : 48 h EC50: 1.1 mg/l

Page 7 of 11
 Method : OECD 202
The data are derived from the evaluations or test
results achieved with similar products (conclusion
by analogy).

Toxicity in microorganisms : No data available

Chronic toxicity in fish : No data available
Chronic toxicity in aquatic : No data available
Invertebrates

Toxicity in organisms which : No data available

live in the soil
Toxicity in terrestrial plants : No data available
Toxicity to Above-Ground : No data available
12.2. Persistence and degradability
Photodegradation : No data available
Biological degradability : Aerobic
Biological degradability : > 60 % Exposure duration: 28 d
Result : Readily biodegradable.
Method : OECD 301 F GLP: yes
Remarks : Own study
Biochemical Oxygen Demand : No data available
(BOD)
Chemical Oxygen Demand : No data available
(COD)
Relation of BOD/COD : No data available

12.3. Bioaccumulative potential

Bioaccumulation : No data available
12.4. Mobility in soil
Environmental distribution : No data available
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment : No data available

12.6. Other adverse effects

General Information : The product is considered to be a water pollutant
(German law). Do not allow to enter soil, waterways
or waste water canal.

Page 8 of 11
SECTION 13 – DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods

Product : With respect to local regulations, e.g. dispose of to

waste incineration plant or dispose of to biological
sewage treatment plant (after neutralisation and
after sufficient dilution).
Contaminated packaging : If empty contaminated containers are recycled or
disposed of, the receiver must be informed about
possible hazards.

SECTION 14 – TRANSPORT INFORMATION

Not dangerous according to transport
regulations.
14.1. UN number : --

14.2. UN proper shipping name : --

14.3. Transport haard class(es) : --

14.4. Packing group : --

14.5. Environmental hazards : --

14.6 Special precautions for user : No

SECTION 15 – REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National legislation
Technical instructions on Air Quality : 5.2.5 (no class)
Major Accident Hazard Legislation : -
Water contaminating class (Germany) : Water endangering
Classification acc. to German law
Risk classification according : -
to BetrSichV (Germany)
Other regulations : Precautions to be observed for storage of hazardous
substances: TRGS 510. "Storage of Hazardous
Substances in Movable Containers". Special local
regulations must be adhered to when using
products containing irritating or corrosive
substances. BG Info Sheet M 050 "Activities
Involving Hazardous Substances"

Page 9 of 11
15.2. Chemical safety assessment : No chemical safety assessment was carried out for
this product.

SECTION 16 – OTHER INFORMATION

List of references

Other information : Comply with national laws regulating employee

instruction.

Classification and applied procedure to derive the classification of mixtures according to EU Regulation (EC)
No. 1272/2008 (CLP)

Classification Classification procedure

Acute Tox., 4 , H332 Calculation method
Eye Irrit., 2 , H319 Calculation method

Relevant H phrases from Chapter 3

H319 : Causes serious eye irritation.

H332 : Harmful if inhaled.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.
This information and all further technical advice is based on our present knowledge and experience.
However, it implies no liability or other legal responsibility on our part, including with regard to existing third
party intellectual property rights, especially patent rights. In particular, no warranty, whether express or
implied, or guarantee of product properties in the legal sense is intended or implied. We reserve the right to
make any changes according to technological progress or further developments. The customer is not released
from the obligation to conduct careful inspection and testing of incoming goods. Performance of the product
described herein should be verified by testing, which should be carried out only by qualified experts in the
sole responsibility of a customer. Reference to trade names used by other companies is neither a
recommendation, nor does it imply that similar products could not be used.

Page 10 of 11
Legend

ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ADNR European agreement concerning the international carriage of dangerous goods by inland waterways (ADN)
ASTM American Society for Testing and Materials
ATP Adaptation to Technical Progress
BCF Bioconcentration factor
BetrSichV German Ordinance on Industrial Safety and Health
c.c. closed cup
CAS Chemical Abstract Services
CESIO European Committee of Organic Surfactants and their Intermediates
Chem G German Chemicals Act
CMR Carcinogenic-mutagenic-toxic for reproduction
DIN German Institute for Standardization
DMEL Derived minimum effect level
DNEL Derived no effect level
EINECS European Inventory of Existing Commercial Chemical Substances
EC50 Half maximal effective concentration
GefStoffV German Ordinance on Hazardous Substances
GGVSEB German ordinance for road, rail and inland waterway transportation of dangerous goods
GGVSee German ordinance for sea transportation of dangerous goods
GLP Good Laboratory Practice
GMO Genetic Modified Organism
IATA International Air Transport Association
ICAO International Civil Aviation Organization
IMDG International Maritime Dangerous Goods
ISO International Organization For Standardization
LOAEL Lowest observed adverse effect level
LOEL Lowest observed effect level
NOAEL No observed adverse effect level
NOEC No observed effect concentration
NOEL No observed effect level
o. c. open cup
OECD Organisation for Economic Cooperation and Development
OEL Occupational Exposure Limit
PBT Persistent, bioaccumulative, toxic
PEC Predicted effect concentration
PNEC Predicted no effect concentration
REACH REACH registration
RID Convention concerning International Carriage by Rail
STOT Specific Target Organ Toxicity
SVHC Substances of Very High Concern
TA Technical Instructions
TPR
Technical Third PartyInstructions
Technical Representative (Art. 4)
TRGS
TA Technical Rules for Hazardous Substances
VCI German chemical industry association
vPvB Very persistent, very bioaccumulative
VOC Volatile organic compounds
VwVwS German Administrative Regulation on the Classification of Substances Hazardous to Waters into Water
Hazard Classes
WGK Water Hazard Class
WHO World Health Organization

-End of SDS-

Page 11 of 11