Balancing Redox Reactions in General Chemistry 2

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Balancing Redox Reactions in General

Chemistry 2
A. Acidic
1. Separate the half-reactions.
2. First Balance Elements other than O and H:
a. Add H2O to Balance Oxygen
b. Add H+ to balance H.
3. Then check if both equation reactions are balanced together with the e -.
4. Add both the half equation reactions and cancel common terms.

B. Basic
1. Separate the half-reactions
2. First Balance Elements other than O and H:
c. Add H2O to Balance Oxygen
d. Add H+ to balance H.
3. Each H+ count will be directly proportional to the OH - that is to be added to both sides of the
equation.
a. Add the H+ and OH- present on the same side to form H2O
4. Then check if both equation reactions are balanced together with the e -.
5. Add both the half equation reactions and cancel common terms.

Given example on the 5th group for this demonstration: Cl2 + SO2 -> Cl- + SO4-2

Identify oxidation number, then which among is oxidation and reduction:

A. Oxidation Number
1. SO2 = 0
a. S + (2)(-2) = 0
b. S–4=0
c. S = +4

2. SO4-2 = -2
a. S + (4)(-2) = -2
b. S + (-8) = -2
c. S=8–2
d. S = +6

B. Oxidation and reduction identification:


1. Cl2 -> Cl-
a. Cl2 from reactant has 0 ion and to Cl- product has -1 ion.
b. Conclusion this is reduction.
2. SO2 -> SO4-2
a. SO2 from reactant has +4 ions and to product SO 4-2 has +6 ions.
b. Conclusion this is oxidation.

Acidic application of balancing equation:

1. Oxidation: (SO2 -> SO4-2 + 2e-)


a. We can take a shortcut to cancel and balance the e - to match the other half reaction.
b. This equation is equal to SO2 -> SO4-2
c. Apply steps from the guide, 2H2O + SO2 -> SO4-2
d. Balanced half reaction: 2H2O + SO2 -> SO4-2 + 4H+

2. Reduction: (Cl2 + e- -> Cl-)


a. We can take a shortcut to cancel and balance the e - to match the other half reaction above
[multiplied dissimilar reactant and product count with 2].
b. This equation is equal to Cl2 -> 2Cl-

3. Balanced combined reaction: 2H2O + SO2 + Cl2 -> SO4-2 + 4H+ + 2Cl-

Basic application of balancing equation:

1. 2H2O + SO2 + Cl2 -> SO4-2 + 4H+ + 2Cl-

a. 4OH- + 2H2O + SO2 + Cl2 -> SO4-2 + 4H+ + 2Cl- + 4OH-

b. 4OH- + 2H2O + SO2 + Cl2 -> SO4-2 + 4H2O + 2Cl-

c. Balanced simplified reaction: 4OH- + SO2 + Cl2 -> SO4-2 + 2H2O + 2Cl-

Conclusion:

It is concluded that this topic in Electrochemistry can be applied in real life. Achieving the
competency of balancing unequal amounts induced by reactants and products, to reach a certain
magnitude or goal.

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