Class 12 Chemistry Syllabus 2023-24

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3. Detection of Nitrogen in the given organic compound.

4. Detection of Halogen in the given organic compound.


Note: The above practicals may be carried out in an experiential manner rather than recording observations.
Prescribed Books:
1. Chemistry Part – I, Class-XI, Published by NCERT.
2. Chemistry Part – II, Class-XI, Published by NCERT.

CLASS XII (2023-24) (THEORY)


Time : 3 Hours 70 Marks

S.No. Title No. of Marks


Periods
1 Solutions 10 7
2 Electrochemistry 12 9
3 Chemical Kinetics 10 7
4 d -and f -Block Elements 12 7
5 Coordination Compounds 12 7
6 Haloalkanes and Haloarenes 10 6
7 Alcohols, Phenols and Ethers 10 6
8 Aldehydes, Ketones and Carboxylic Acids 10 8
9 Amines 10 6
10 Biomolecules 12 7
Total 70

Unit II: Solutions 10 Periods

Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gases in


liquids, solid solutions, Raoult's law, colligative properties - relative lowering of vapour pressure,
elevation of boiling point, depression of freezing point, osmotic pressure, determination of molecular
masses using colligative properties, abnormal molecular mass, Van't Hoff factor.

Unit III: Electrochemistry 12 Periods

Redox reactions, EMF of a cell, standard electrode potential, Nernst equation and its application to
chemical cells, Relation between Gibbs energy change and EMF of a cell, conductance in electrolytic
solutions, specific and molar conductivity, variations of conductivity with concentration, Kohlrausch's
Law, electrolysis and law of electrolysis (elementary idea), dry cell-electrolytic cells and Galvanic cells,
lead accumulator, fuel cells, corrosion.
Unit IV: Chemical Kinetics 10 Periods

Rate of a reaction (Average and instantaneous), factors affecting rate of reaction: concentration,
temperature, catalyst; order and molecularity of a reaction, rate law and specific rate constant,
integrated rate equations and half-life (only for zero and first order reactions), concept of collision
theory (elementary idea, no mathematical treatment), activation energy, Arrhenius equation.

Unit VIII: d and f Block Elements 12 Periods

General introduction, electronic configuration, occurrence and characteristics of transition metals,


general trends in properties of the first row transition metals – metallic character, ionization enthalpy,
oxidation states, ionic radii, colour, catalytic property, magnetic properties, interstitial compounds,
alloy formation, preparation and properties of K2Cr2O7 and KMnO4.

Lanthanoids - Electronic configuration, oxidation states, chemical reactivity and lanthanoid


contraction and its consequences.

Actinoids - Electronic configuration, oxidation states and comparison with lanthanoids.

Unit IX: Coordination Compounds 12 Periods

Coordination compounds - Introduction, ligands, coordination number, colour, magnetic properties


and shapes, IUPAC nomenclature of mononuclear coordination compounds. Bonding, Werner's
theory, VBT, and CFT; structure and stereoisomerism, importance of coordination compounds (in
qualitative analysis, extraction of metals and biological system).

Unit X: Haloalkanes and Haloarenes. 10 Periods

Haloalkanes: Nomenclature, nature of C–X bond, physical and chemical properties, optical rotation
mechanism of substitution reactions.

Haloarenes: Nature of C–X bond, substitution reactions (Directive influence of halogen in


monosubstituted compounds only).

Uses and environmental effects of - dichloromethane, trichloromethane, tetrachloromethane,


iodoform, freons, DDT.

Unit XI: Alcohols, Phenols and Ethers 10 Periods

Alcohols: Nomenclature, methods of preparation, physical and chemical properties (of primary
alcohols only), identification of primary, secondary and tertiary alcohols, mechanism of dehydration,
uses with special reference to methanol and ethanol.

Phenols: Nomenclature, methods of preparation, physical and chemical properties, acidic nature of
phenol, electrophillic substitution reactions, uses of phenols.

Ethers: Nomenclature, methods of preparation, physical and chemical properties, uses.


Unit XII: Aldehydes, Ketones and Carboxylic Acids 10 Periods

Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of preparation, physical
and chemical properties, mechanism of nucleophilic addition, reactivity of alpha hydrogen in
aldehydes, uses.

Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and chemical
properties; uses.

Unit XIII: Amines 10 Periods

Amines: Nomenclature, classification, structure, methods of preparation, physical and chemical


properties, uses, identification of primary, secondary and tertiary amines.

Diazonium salts: Preparation, chemical reactions and importance in synthetic organic chemistry.

Unit XIV: Biomolecules 12 Periods

Carbohydrates - Classification (aldoses and ketoses), monosaccahrides (glucose and fructose), D-L
configuration oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose,
glycogen); Importance of carbohydrates.

Proteins -Elementary idea of - amino acids, peptide bond, polypeptides, proteins, structure of proteins
- primary, secondary, tertiary structure and quaternary structures (qualitative idea only), denaturation
of proteins; enzymes. Hormones - Elementary idea excluding structure.

Vitamins - Classification and functions.


Nucleic Acids: DNA and RNA.

PRACTICALS

Evaluation Scheme for Examination Marks

Volumetric Analysis 08

Salt Analysis 08

Content Based Experiment 06

Project Work 04

Class record and viva 04

Total 30

PRACTICAL SYLLABUS 60Periods


Micro-chemical methods are available for several of the practical experiments. Wherever
possible, such techniques should be used.

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