SAFETY DATA SHEET

TECHSEAL SILVER SL G
Version 1.0 SDS Number: 1688059-0025-1-
SDS_VN 000 Revision Date: 2015/09/15

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : TECHSEAL SILVER SL G

Product code : 1688059-0025-1-000

Manufacturer or supplier's details

Company : Atotech Deutschland GmbH

Address : Erasmusstrasse 20
Berlin 10553
Germany

Company : Công ty TNHH Atotech Việt Nam

Address : Lầu 5, Tòa nhà Hải Âu

TP. Hồ Chí Minh
Vietnam

Prepared by
Product Safety Department (PSD): [email protected]

Inquiries
Questions about content of Safety Data Sheets: [email protected]

Emergency telephone : CARECHEM24 INTERNATIONAL (MULTILINGUAL

SERVICE) +6531581074

Recommended use of the chemical and restrictions on use

Recommended use : Plating agents and metal surface treating agents
Surface treatment

Restrictions on use : For industrial use only.

2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 3

Skin corrosion/irritation : Category 2

Serious eye damage/eye irri- : Category 2A

tation

Skin sensitization : Category 1

GHS Label element

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 SAFETY DATA SHEET

TECHSEAL SILVER SL G
Version 1.0 SDS Number: 1688059-0025-1-
SDS_VN 000 Revision Date: 2015/09/15

Hazard pictograms :

Signal Word : Warning

Hazard Statements : H226 Flammable liquid and vapor.

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.

Precautionary Statements : Prevention:

P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/
equipment.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical ad-
vice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ at-
tention.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam for extinction.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification

No information available.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Paint

Hazardous ingredients
Chemical Name CAS-No. Concentration (% w/w)
Bisphenol A diglycidyl ether - bisphenol A copol- 25036-25-3 >= 15 - < 30
ymer
1-Methoxy-2-Propanol 107-98-2 >= 10 - < 13
1,3,5-Triazine-2,4,6-triamine, polymer with for- 68036-97-5 >= 3 - < 5

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 SAFETY DATA SHEET

TECHSEAL SILVER SL G
Version 1.0 SDS Number: 1688059-0025-1-
SDS_VN 000 Revision Date: 2015/09/15

maldehyde, butylatedmethylated
Aluminum 7429-90-5 >= 3 -<5
n-Butyl alcohol 71-36-3 >= 1.5 -<3
Kaolin 1332-58-7 >= 1 - < 1.5
Aliphatic Alcohol Not Assigned >= 0.1 - < 0.5

4. FIRST AID MEASURES

General advice : Get medical attention.

If inhaled : Move to fresh air.

In case of skin contact : Wash off immediately with plenty of water for at least 15
minutes.
Take off all contaminated clothing immediately.
Wash contaminated clothing before reuse.
Get medical attention if irritation develops and persists.

In case of eye contact : If eye irritation persists, consult a specialist.

If swallowed : Never give anything by mouth to an unconscious person.

Call a physician or poison control center immediately.
Do not induce vomiting without medical advice.

Most important symptoms : Causes skin irritation.

and effects, both acute and May cause an allergic skin reaction.
delayed Causes serious eye irritation.
Redness
Dermatitis
Eczema

Protection of first-aiders : First Aid responders should pay attention to self-protection

and use the recommended protective clothing

Notes to physician : None known.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.

Unsuitable extinguishing : High volume water jet

media

Hazardous combustion prod- : Carbon oxides

ucts hydrogen fluoride
Nitrogen oxides (NOx)
Metal oxides

Specific extinguishing meth- : Use a water spray to cool fully closed containers.
ods Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.

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 SAFETY DATA SHEET

TECHSEAL SILVER SL G
Version 1.0 SDS Number: 1688059-0025-1-
SDS_VN 000 Revision Date: 2015/09/15

Fire residues and contaminated fire extinguishing water must

be disposed of in accordance with local regulations.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Avoid contact with skin, eyes and clothing.
gency procedures Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapors accumulating to form explosive concentra-
tions. Vapors can accumulate in low areas.
Prevent unauthorized access.

Environmental precautions : Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Avoid formation of aerosol.

containment and cleaning up Soak up with inert absorbent material.
Keep in suitable, closed containers for disposal.
Clean contaminated surface thoroughly.
Dispose of in accordance with local regulations.

7. HANDLING AND STORAGE

Advice on protection against : Take necessary action to avoid static electricity discharge
fire and explosion (which might cause ignition of organic vapors). Use only ex-
plosion-proof equipment. Keep away from open flames, hot
surfaces and sources of ignition.

Advice on safe handling : Avoid formation of aerosol.

For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national
regulations.
Handle in accordance with good industrial hygiene and safety
practice.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Keep away from sources of ignition - No smoking.

Recommended storage tem- : -5 - 40 °C

perature

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 SAFETY DATA SHEET

TECHSEAL SILVER SL G
Version 1.0 SDS Number: 1688059-0025-1-
SDS_VN 000 Revision Date: 2015/09/15

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Ingredients CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
1-Methoxy-2-Propanol 107-98-2 TWA 50 ppm ACGIH
STEL 100 ppm ACGIH
Aluminum 7429-90-5 TWA 2 mg/m3 VN OEL
STEL 4 mg/m3 VN OEL
TWA (Res- 1 mg/m3 ACGIH
pirable frac- (Aluminum)
tion)
n-Butyl alcohol 71-36-3 TWA 150 mg/m3 VN OEL
STEL 250 mg/m3 VN OEL
TWA 20 ppm ACGIH
Kaolin 1332-58-7 TWA 2 mg/m3 VN OEL
(Aluminum)
STEL 4 mg/m3 VN OEL
(Aluminum)
TWA (Res- 2 mg/m3 ACGIH
pirable frac-
tion)
Personal protective equipment
Respiratory protection : In case of mist, spray or aerosol exposure wear suitable per-
sonal respiratory protection and protective suit.

In case of insufficient ventilation, wear suitable respiratory

equipment.
When workers are facing concentrations above the exposure
limit they must use appropriate certified respirators.

Hand protection
Material : Nitrile rubber
Break through time : 60 min
Glove thickness : 0.4 mm
Manufacturer : e.g. KCL

Material : butyl-rubber
Break through time : 480 min
Glove thickness : 0.7 mm
Manufacturer : e.g. KCL

Remarks : The selected protective gloves have to satisfy the specifica-

tions of EU Directive 89/689/EEC and the standard EN 374
derived from it. The information is based on our own tests, on
data from literature and information from protective glove
producers or is based on data obtained from similar sub-
stances.
If used in solution, or mixed with other substances, and un-
der conditions which differ from EN 374, contact the supplier

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 SAFETY DATA SHEET

TECHSEAL SILVER SL G
Version 1.0 SDS Number: 1688059-0025-1-
SDS_VN 000 Revision Date: 2015/09/15

of the EC approved gloves. Be aware that in daily use the

durability of a chemical resistant protective glove can be no-
tably shorter than the break through time measured accord-
ing to EN 374, due to the numerous outside influences (e.g.
temperature). Gloves should be discarded and replaced if
there is any indication of degradation or chemical break-
through.

Eye protection : Tightly fitting safety goggles

Ensure that eyewash stations and safety showers are close
to the workstation location.

Skin and body protection : Impervious clothing

Choose body protection according to the amount and con-
centration of the dangerous substance at the work place.

Protective measures / Engi- : Ensure adequate ventilation, especially in confined areas.

neering measures

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : silver

Odor : No information available.

Odor Threshold : No data available

pH : not determined

Melting point/range : not determined

Boiling point/boiling range : not determined

Flash point : 36.5 °C

Method: closed cup

Evaporation rate : No data available

Flammability (solid, gas) : Not applicable

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapor pressure : ca. 23 hPa (20 °C)

Relative vapor density : No data available

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 SAFETY DATA SHEET

TECHSEAL SILVER SL G
Version 1.0 SDS Number: 1688059-0025-1-
SDS_VN 000 Revision Date: 2015/09/15

Density : 1.02 - 1.10 g/cm3

Solubility(ies)
Water solubility : partly miscible

Partition coefficient: n- : No data available

octanol/water

Autoignition temperature : No data available

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : No data available

Oxidizing properties : Not applicable

10. STABILITY AND REACTIVITY

Reactivity : In use, may form flammable/explosive vapor-air mixture.

Chemical stability : Stable under recommended storage conditions.

Possibility of hazardous reac- : Risk of ignition

tions

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : Oxidizing agents

Strong acids and strong bases

Hazardous decomposition : No hazardous decomposition products are known.

products

11. TOXICOLOGICAL INFORMATION

Routes of exposure : Inhalation

Ingestion
Eye contact
Skin Absorption

Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg
Method: Calculation method

Ingredients:
n-Butyl alcohol:

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 SAFETY DATA SHEET

TECHSEAL SILVER SL G
Version 1.0 SDS Number: 1688059-0025-1-
SDS_VN 000 Revision Date: 2015/09/15

Acute oral toxicity : LD50 Oral (Rat): 790 mg/kg

Acute dermal toxicity : LD50 Dermal: 3,400 mg/kg

Skin corrosion/irritation
Causes skin irritation.
Product:
Remarks: May cause skin irritation and/or dermatitis.

Serious eye damage/eye irritation

Causes serious eye irritation.
Product:
Remarks: Vapors may cause irritation to the eyes, respiratory system and the skin.

Respiratory or skin sensitization

Skin sensitization: May cause an allergic skin reaction.
Respiratory sensitization: Not classified based on available information.
Product:
Remarks: Causes sensitization.

Germ cell mutagenicity

Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
Further information

Product:
Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vom-
iting.
Concentrations substantially above the TLV value may cause narcotic effects.
Solvents may degrease the skin.

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 SAFETY DATA SHEET

TECHSEAL SILVER SL G
Version 1.0 SDS Number: 1688059-0025-1-
SDS_VN 000 Revision Date: 2015/09/15

12. ECOLOGICAL INFORMATION

Ecotoxicity

Ingredients:
n-Butyl alcohol:
Toxicity to daphnia and other : EC50: 1,983 mg/l
aquatic invertebrates Exposure time: 48 h

Aliphatic Alcohol:
Toxicity to fish : LC50 (Fish): 4.6 - 10 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia): 0.19 mg/l

aquatic invertebrates Exposure time: 48 h

Toxicity to algae : IC50 (Chlorella vulgaris (Fresh water algae)): 1.8 mg/l
Exposure time: 72 h

Persistence and degradability

No data available
Bioaccumulative potential

Ingredients:
1-Methoxy-2-Propanol:
Partition coefficient: n- : log Pow: 0.37
octanol/water

n-Butyl alcohol:
Bioaccumulation : Bioconcentration factor (BCF): 0.38

Partition coefficient: n- : log Pow: 0.84

octanol/water

Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : No data available
mation

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with local regulations.

Contaminated packaging : Empty containers should be taken to an approved waste han-

dling site for recycling or disposal.

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 SAFETY DATA SHEET

TECHSEAL SILVER SL G
Version 1.0 SDS Number: 1688059-0025-1-
SDS_VN 000 Revision Date: 2015/09/15

14. TRANSPORT INFORMATION

International Regulation

UNRTDG
UN number : UN 1263
Proper shipping name : PAINT
Class : 3
Packing group : III
Labels : 3
IATA-DGR
UN/ID No. : UN 1263
Proper shipping name : Paint
Class : 3
Packing group : III
Labels : Flammable Liquids
Packing instruction (cargo : 366
aircraft)
Packing instruction (passen- : 355
ger aircraft)
IMDG-Code
UN number : UN 1263
Proper shipping name : PAINT

Class : 3
Packing group : III
Labels : 3
EmS Code : F-E, S-E
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mix-
ture

Substances currently restricted by WEEE/RoHS (European Directive 2012/19/EC ,

2011/65/EC) or ELV (European Directive 2000/53/EC):

PBDE PBB CrVI Hg Pb Cd

- - - - - -

Please note: Current legislation restricting the use of certain substances applies to „homogene-
ous material“ in finished articles being supplied to the market. Substances deposited during sur-
face finishing may have a composition (weight percent) higher than the weight percent of the
substance in the operating solution from which the deposit is made. Atotech encourages its cus-
tomers to implement systems to ensure their finished products comply with the regulations in

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 SAFETY DATA SHEET

TECHSEAL SILVER SL G
Version 1.0 SDS Number: 1688059-0025-1-
SDS_VN 000 Revision Date: 2015/09/15

force.

16. OTHER INFORMATION

Full text of other abbreviations

(Q)SAR - (Quantitative) Structure Activity Relationship; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CPR -
Controlled Products Regulations; DIN - Standard of the German Institute for Standardisation; ECx
- Concentration associated with x% response; ELx - Loading rate associated with x% response;
EmS - Emergency Schedule; ErCx - Concentration associated with x% growth rate response;
ERG - Emergency Response Guide; GHS - Globally Harmonized System; IARC - International
Agency for Research on Cancer; IATA - International Air Transport Association; IBC - Interna-
tional Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk;
IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization;
IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISO
- International Organisation for Standardization; LC50 - Lethal Concentration to 50 % of a test
population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - In-
ternational Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Speci-
fied; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL -
No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Offi-
cial Mexican Norm; NTP - National Toxicology Program; OECD - Organization for Economic Co-
operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT -
Persistent, Bioaccumulative and Toxic substance; REACH - Regulation (EC) No 1907/2006 of the
European Parliament and of the Council concerning the Registration, Evaluation, Authorisation
and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Temperature; SDS - Safe-
ty Data Sheet; TDG - Transportation of Dangerous Goods; UN - United Nations; UNRTDG - Unit-
ed Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and
Very Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; GLP - Good Laboratory Practice
Date format : yyyy/mm/dd

The information provided in this Material Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transportation, disposal and re-
lease and is not to be considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.

VN / EN

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