DT-3000 SDS 090115

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DT-3000 Safety Data Sheet (SDS)

Delta Tech Service, Inc.

1 PRODUCT AND COMPANY IDENTIFICATION

Manufacturer
Delta Tech Service, Inc. Revision date: 9/1/2015
397 West Channel Road Version: 2.0
Benicia, California 94510-1117 SDS number: 295

Contact: Delta Tech Service, Inc


Telephone: 1-707-745-2080
Fax: 1-707-745-2292
Website: www.deltatechservice.com

Product name: DT-3000


Common name: Citri-Sweet HD
CAS number: Mixture
Chemical family: Degreaser
Chemical formula: ***Proprietary***
Synonyms: DT3000
Product use: Heavy duty industrial cleaning concentrate of maintenance and turnaround applications in oil
refineries.

Product emergency telephone: 1-707-745-2080


Transportation emergency telephone: 1-707-745-2080

2 HAZARDS IDENTIFICATION

NFPA: Health = 1 / Fire = 1 / Reactivity = 0


HMIS III: H 1 / F 2 / PH 0

01

1 20

B – Eye protection and


gloves

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DT-3000 Safety Data Sheet (SDS)
Delta Tech Service, Inc.

GHS Signal Word: GHS Hazard Pictograms:


DANGER

GHS Phrases:
H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation

3 COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients:
CAS # | Percentage | Chemical Name
5989-27-5 | 10 – 20% | Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4R)-
62789-31-9 I 1 – 10% I Fatty acid, coco, sodium salts
141-43-5 I 1 – 10% I Ethanol, 2-amino-
25155-30-0 I 1 – 10% I Benzenesulfonic acid, dodecyl-, sodium salt

4 FIRST AID MEASURES


Inhalation: Give oxygen or artificial respiration if needed. If symptoms develop, move victim to fresh air. If symptoms
persist, obtain medical attention.

Skin contact: Take off contaminated clothing and shoes immediately. Promptly flush skin with water for at least 15
minutes to ensure all chemical is removed. If reddening develops or persists, obtain medical attention.

Eye contact: Flush with large amounts of fresh water for at least 15 minutes, lifting upper and lower lids occasionally.
If irritation persists, obtain medical attention.

Ingestion: Rinse mouth with water. DO NOT induce vomiting. Never give anything by mouth to an unconscious
person. If symptoms develop and/or persist, obtain medical attention. Show this Safety Data Sheet to
the attending physician.

5 FIRE FIGHTING MEASURES


Extinguishing media:
Water spray, water fog, carbon dioxide, alcohol-resistant foam, dry chemical

Special hazards arising from the substance or mixture:


Aldehydes, carbon oxides, hydrogen cyanide gas, nitrogen oxides (NOx), phosphorous oxides, potassium oxides, sodium
oxides, sulfur oxides
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DT-3000 Safety Data Sheet (SDS)
Delta Tech Service, Inc.

Advice for firefighters:


Firefighters should wear full-face, positive-pressure respirators.

6 ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment, including fire/flame resistant/retardant clothing.
Keep from contacting skin or eyes.
Ensure adequate ventilation.
Eliminate all sources of ignition.
Evacuate personnel to safe areas.

Environmental precautions:
Prevent further release (leakage/spillage) if safe to do so.
Do not allow product to enter drains.
Do not allow to drain to environment.

Methods and materials for contaminants and cleaning up:


Absorb with liquid-binding, non-combustible material (sand, dolomite, non-acidic clay and sawdust).
Place contaminated material into suitable, closed containers for disposal.
Dispose of contaminated materials according to Section 13.
After spillage has been collected, area may be flushed with water or wet-brushed.
Ensure adequate ventilation.

References to other sections:


Comply with federal, state and local regulations on reporting spills.
See Section 7 for information on safe handling.
See Section 8 for information on personal protective equipment.
See Section 13 for information on proper disposal.

7 HANDLING AND STORAGE


Handling precautions: Wear protective clothing
Avoid contact with eyes, skin or clothing
Use approved original containers only
Keep containers closed when not in use
Do not expose containers to excessive heat or direct sunlight
Avoid contamination of material
Do not puncture or drop containers
Handle with care and avoid spillage on the floor
Keep material out of reach of children
Keep material away from incompatible materials
Wash thoroughly after handling
Ensure adequate ventilation
o o
Storage requirements: Do not store at temperatures exceeding 49 C (120 F)
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DT-3000 Safety Data Sheet (SDS)
Delta Tech Service, Inc.

Do not allow product to freeze

8 EXPOSURE CONTROLS/PERSONAL PROTECTION


Engineering controls: All ventilation should be designed in accordance with OSHA standard (29 CFR 1910.94).
Use appropriate ventilation as required to keep exposure limits in air below TLV and PEL
limits.

Personal protective equipment:


Eye/face protection:
When using material use safety glasses according to HMIS PP, A. All safety equipment
should be tested and approved under appropriate government standards such as NIOSH
(US) or EN 166 (EU).

Skin protection:
Handle with gloves made from PVC, butyl-rubber, neoprene or nitrile. Gloves must be
inspected prior to use. Use proper glove removal technique (without touching glove’s
outer surface) to avoid skin contact. Dispose of contaminated gloves according to
applicable laws and laboratory practices.

Body protection:
The type of protective equipment should be based on concentration amount and
conditions of use of this material.

Respiratory protection:
A vapor respirator may be required as backup to engineering controls when proper
engineering controls are not in place to keep TLV and PEL limits below defined
thresholds.

Control of environmental exposure:


Prevent leakage or spillage if safe to do so. Do not let material enter drains.

Components with workplace control parameters:


Component(s): Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4R)-; Ethanol, 2-amino-
CAS No(s): 5898-27-5; 141-43-5
USA NIOSH (TWA/REL): 3 ppm
USA NIOSH (TWA/REL): 6 ppm
USA ACGIH (TWA): 3 ppm
USA ACGIH (TWA): 6 ppm
USA OSHA – Table Z-1 Limits for Air Contaminants (TWA): 3 ppm
USA OSHA – Table Z-1 Limits for Air Contaminants (STEL): 6 ppm
OSA OSHA Occupational Exposure Limits Table Z-1 Limits for Air Contaminants (TWA): 3 ppm

Biological occupational exposure limits:


Contains no substances with biological occupational exposure limit values

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DT-3000 Safety Data Sheet (SDS)
Delta Tech Service, Inc.

9 PHYSICAL AND CHEMICAL PROPERTIES


Appearance: Clear, slightly amber liquid Odor: Citrus mixture
Physical state: Liquid Molecular formula: MIXTURE
Odor threshold: Not determined Solubility: Completely miscible
Particle size: Not determined Softening point: Not determined
Specific gravity/Density: 0.983 g/ml (8.20 lbs/gal) Percent volatile: Not determined
Viscosity: Not determined Heat value: Not determined
Sat. vapor concentration: Does not apply Freezing/melting point: 37oF
o o o
Boiling point: 98 C (208 F) Flash point: 120 F
Flammability: Combustible Liquid Class Octanol: Not determined
Partition coefficient: Not determined Vapor density: Not determined
Vapor pressure: (mm Hg @ 100oF): 10.34 VOC: Not determined
pH: @ 1% solution: 8.0 – 9.0 Bulk density: Not determined
Evaporation rate: Not determined Autoignition temperature: Not determined
Molecular weight: MIXTURE UFL/LFL: Not determined
Decomposition temperature: Not determined

10 STABILITY AND REACTIVITY


Stability: Product is stable under normal conditions.
o
Conditions to avoid: Store at temperatures above 40 F. Avoid excessive heat, sparks and flames.
Materials to avoid: Keep away from strong oxidizing agents.

Hazardous decomposition: Aldehydes, carbon oxides, hydrogen cyanide gas, nitrogen oxides (NOx), phosphorous
oxides, potassium oxides, sodium oxides, sulfur oxides.

Hazardous polymerization: Will not occur.

11 TOXICOLOGICAL INFORMATION
Components: Cyclohexene, 1-methyl-4-(1-methlyethenyl)-, (4R)-; Fatty acid, coco, sodium salts; Ethanol, 2-amino-;
Benzenesulfonic acid, dodecyl-, sodium salt
CAS #(s): 5989-27-5; 61789-31-9; 141-43-5; 25155-30-0

Acute toxicity:
LD50 oral - rat: 438 mg/kg
LD50 dermal – rabbit: 1015 mg/kg

Skin corrosion/irritation: Rabbit skin – Irritating to skin (24 h)

Serious eye damage/eye irritation: Rabbit eyes –Severe eye irritation (24 h)

Respiratory or skin sensitization: Mouse skin – May cause sensitization by skin contact

Germ cell mutagenicity: No data available

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DT-3000 Safety Data Sheet (SDS)
Delta Tech Service, Inc.

Carcinogenicity:
Carcinogenicity oral – rat: Carcinogenic by RTECS criteria (kidney, ureter, bladder, kidney tumors, testicular tumors)
Carcinogenicity oral – mouse: Equivocal tumorigenic agent by RTECS criteria (gastrointestinal tumors)

This product is or contains a component that is not classifiable as to its carcinogenicity (Cyclohexene, 1-methly-4-(1-
methylethenyl)-, (4R)-) to humans based on its IARC, ACGIH, NTP or OSHA classification.

IARC: 3 – Group 3: Not classifiable as to its carcinogenicity to humans (Cyclohexene, 1-methly-4-(1-methylethenyl)-,


(4R)-).
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen
or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen
or potential carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen
or potential carcinogen by OSHA.

Reproductive toxicity: No data available

Specific target organ toxicity – single exposure: Respiratory system – may cause respiratory irritation
Specific target organ toxicity – repeated exposure: No data available

Aspiration hazard: May be fatal is swallowed and enters airways

Additional information:
Component: Cyclohexene, 1-methly-4-(1-methylethenyl)-, (4R)-; RTECS: GW6360000
Component: Fatty acid, coco, sodium salts; RTECS: N/A
Component: Ethanol, 2-amino-; RTECS: KJ5775000
Component: Benzenesulfonic acid, dodecyl-, sodium salt; RTECS: DB6825000

12 ECOLOGICAL INFORMATION
Components: Cyclohexene, 1-methyl-4-(1-methlyethenyl)-, (4R)-; Fatty acid, coco, sodium salts; Ethanol, 2-amino-;
Benzenesulfonic acid, dodecyl-, sodium salt
CAS #(s): 5989-27-5; 61789-31-9; 141-43-5; 25155-30-0

Toxicity:

Toxicity to fish:
LC50 – Oncorhynchus mykiss (Rainbow trout): 32 mg/l (96 h)
LC50 – Gasterosteus aculeatus (Three-spine stickleback) – 18 mg/l (96 h)

Toxicity to daphnia and other aquatic invertebrates:


Mortality NOEC – Daphnia magna (Water flea): 4 mg/l (7 d)
Immobilization EC50 – Daphnia magna (Water flea) – 0.36 mg/l (48 h)

Toxicity to algae:
EC50 – Desmodesmus subspicatus (Green algae) – 15 mg/l (72 h)

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DT-3000 Safety Data Sheet (SDS)
Delta Tech Service, Inc.

Persistence and degradability:


Bioaccumulation – Lepomis macrochirus (Bluegill): 64µg/l (28 d)
Bioconcentration factor (BCF): 220

Bioaccumulative potential: No data available

Mobility in soil: No data available

Results of PBT and vPvB assessment: No required/conducted

Other adverse effects:


An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.

13 DISPOSAL CONSIDERATIONS
Product: Hazardous wastes shall be managed responsibly. All entities that store, transport or handle hazardous waste
shall take the necessary measures to prevent risk of pollution, release into the environment or damage to people and
animals. Contact a licensed professional waste disposal service to dispose of this material.

Contaminated packaging: Dispose of as unused product.

14 TRANSPORTATION INFORMATION
DOT (US)
Non regulated material, liquid

IMDG
Non regulated material, liquid

IATA
Non regulated material, liquid

15 REGULATORY INFORMATION
Component / (CAS/Percentage) / Codes
Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4R)- / (5989-27-5, 10-20%) / NJHS, PA, SARA 311/312, TSCA
Fatty acids, coco, sodium salts / (61789-31-9, 1 – 10%) / CERCLA, TSCA
Ethanol, 2-amino- / (141-43-5, 1 10%) / HAP, MASS, NJHS, OSHAWAC, PA, SARA 311/312, TSCA, TXAIR
Benzenesulfonic acid, dodecyl-, sodium salt / (25155-30-0, 1-10%) / CERCLA, CSWHS, MASS, NJHS, PA, SARA
311/312, TSCA

Regulator key descriptions


CERCLA – Superfund Clean Up Substance
HAP – Hazardous Air Pollutants
MASS – Massachusetts Hazardous Substances List
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DT-3000 Safety Data Sheet (SDS)
Delta Tech Service, Inc.

NJHS – New Jersey Right to Know Hazardous Substances


OSHAWAC – OSHA Workplace Air Contaminants
PA – Pennsylvania Right to Know List of Hazardous Substances
SARA 311/312 – SARA 311/312 Hazardous Chemical Program
TSCA – Toxic Substances Control Act
TXAIR – Texas Air Contaminants with Health Effects Screening Level

16 OTHER INFORMATION
Disclaimer:
The data in this Safety Data Sheet relates only to the specific material designated herein and does not relate to use in
combination with any other material in any process. The information set forth herein is furnished free of charge and is
based on technical data that Delta Tech Service Inc. believes to be reliable. It is intended for use by persons having
technical skill and at their own discretion and risk. Since conditions of use are outside of Delta Tech Service Inc.’s control,
Delta Tech Service, Inc. makes no warranties, express or implied, and assumes no liability in connection with any use of
this information. Nothing herein is to be taken as a license to operate under, or a recommendation to infringe upon, any
patents.

Preparation information:
Delta Tech Service, Inc.
[email protected]
707-745-2080

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