BOSTIK Ardacolor Xtrem Easy Submittal Rev1 120823

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ATTACHED TO YOUR WORLD

Bostik Smart Solutions for


Professional Tiling
TECHNICAL SUBMITTAL FOR
ARDACOLOR XTREM EASY
EPOXY TILE ADHESIVE AND TILE GROUT - R2T CLASS
PRODUCT LEAFLET

www.bostik.com
TILING BY BOSTIK
TECHNICAL DATASHEET

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Ardacolor Xtrem Easy
COLOURED EPOXY-JOINT SEALER

TECHNICAL DATA SHEET


SMART PRODUCT BENEFIT
- For walls and floors
- Resistant to chemicals
- Also for bonding
- For indoor, outdoor, underwater applications

PRODUCT INFORMATION
ARDACOLOR XTREM EASY is a highly chemically and me-
chanically-resilient joint sealant for ceramic wall and floor PREPARATION OF MIXTURE
tiles, glass, porcelain mosaic and acid clinker. It can also be The best application properties are provided by the mate-
used as an adhesive particularly if colour uniformity be- rial at approx. + 20 °C. At lower temperatures, the mass
tween adhesive and joint sealant is important (e.g. in case should be heated up before mixing, if necessary; at high
of glass, porcelain and miniature mosaics). After curing, temperatures we recommend cooling Ardacolor Xtrem
Ardacolor Xtrem Easy is resistant to a number of chemi- Easy in a water bath. After the hardener has completely
cals, concrete-aggressive water, aggressive cleaning been put in the bucket containing component A, mix it us-
agents, hot steam and water erosion. Because it cures free ing a drilling machine and mixing screw to obtain a fully
from crakes, it forms a tight joint; with this it protects also homogenous mixture; agitation time is at least 3 minutes.
water-sensitive substrates like gypsum boards and chip The mixed material must be processed and washed away
boards as they are used in the living area and as kitchen from the tile surfaces within a certain time. The pot life
work tops or desk tops. A properly performed joint is near- depends on the temperature; at + 20 °C it is approx. 50
ly resistant to dirt deposits and can be cleaned easily and minutes, at + 30 °C approx. 40 minutes. If partial quanti-
therefore it is hygienic. Ardacolor Xtrem Easy consists of: ties shall be processed, the components A and B must be
Component A – paste-like, epoxy-resin based mass exactly dosed. The mixing ration to be met strictly is:
Component B – paste-like hardener Specific weight of the 3 parts by weight of A : 1 part by weight of B.
mixture: approx.1.6 g/ml It can be applied by the grout floating method. For pro-
Ardacolor Xtrem Easy is approved according to DIN 13888 cessing with an air gun we recommend using the product
- RG and DIN 12004- R2T. range type Ardacolor Xtrem Easy P.
FIELDS OF APPLICATION GROUT FLOATING METHOD
Showers, swimming pools, baths, sanitary facilities, hos- The mixture is put into the clean and dry joints in a way
pitals, canteen kitchens, businesses in the food and drinks that they are fully filled. Then, the excess material is re-
industry, breweries, dairies, businesses in the paper, leath- moved from the tile surface by screeding in diagonal di-
er, textiles and chemical industry, water processing instal- rection using a trowel. For extremely wide joints on the
lations, battery charging rooms, galvanizing shops, kitch- wall, the stability can be set with Ardacolor Mix, if
en worktops, laboratories. Suitable for contact with necessary.
foodstuffs in accordance with recommendation XL (47th
notification) of the Plastics Commission of the Federal POINTING WITH COMPRESSED AIR SPRAY GUN
Health Authority. For processing with air guns, Ardacolor Xtrem Easy P is
filled into a special cylindrical canister. A pressure plate in
PROCESSING
the canister is then actuated to fill the air gun. The appli-
Horizontal and vertical joints can be pointed up to an ap- cation of Ardacolor Xtrem Easy with the compressed air
proximate width of 1.5 - 12 mm. The temperature of the spray gun requires a compressor with an output of at least
surface to be jointed shall not be below + 10 °C. It is also 10 bar and a suction capacity of 140 - 160 l/min.
required not to work on surfaces that, for instance, have
been heated up strongly due to sun radiation. If Ardacolor WASHING
Xtrem Easy is used as adhesive, make sure that the tem- After the excess material has been screeded using a plas-
peratures of ambient air, substrate and tile material are tic trowel, the residual joint material on the surface is
not below + 15 °C and after bonding, it may not drop be- emulsified with as few water as possible. For this purpose,
low + 12 °C for 48 hours. the Spezial-Pad WCPW or WCPB with holder WDB offered
in our range of accessories will be suitable. Then the aris- CONSUMPTION
ing slurry can be soaked up using a soft sponge, e.g. vis- The material usage can be calculated using the following
cous sponge. After that, it is strictly required to clean the formula:
tile surfaces again using a clean, soft sponge while the Joint depth (mm) x Joint width (mm) x Total joint length
sponge is well and often washed in clean water. This clean- per m² (m) x Specific weight (1.6) = approx. Consumption in
ing procedure should only take place after Ardacolor g/m².
Xtrem Easy has set a bit. Depending on the object temper-
ature, this waiting time is 1-5 hours. Especially for un- TOOL CLEANING
glazed tiles and tiles with eggshell glaze, residues have to The used tools can easily be cleaned with water before the
be removed completely before curing. Later it will not be joint sealant has been cured.
possible to remove these residues completely. We recom-
STORAGE
mend checking the surfaces for cleanliness after drying.
Ardacolor Xtrem Easy is neither inflammable no frost-sen-
On glazed surfaces, it will be possible to remove a veil by
sitive and can be stored in the not-opened original pack-
wiping away with spirit within 6 hours. With hot water it
ages for at least 12 months.
will be easier to wash it away.
DELIVERY FORM
SPECIAL HINTS FOR RESTORING DAMAGED OR WASHED
OUT CEMENT JOINTS Types suitable for grout floating:
The high demands on durability can only be met when Item-No. 30606760 5-kg-bucket, beige (842)
a) The material is inserted in the joint with a layer Item-No. 30606754 5-kg-bucket, medium grey (843)
thickness of at least 2-3 mm, Item-No. 30606753 5-kg-bucket, old white (845)
b) Ardacolor Xtrem Easy directly adheres to the tile Item-No. 30606757 5-kg-bucket, anthracite (846)
flank. Item-No. 30606752 5-kg-bucket, silver grey (849)
Therefore, the following preparing works are required for Types ready for spraying:
a successful joint restoration: Item-No. 30822142 5-kg-canister, medium grey (P-843)
1. Rake out, chase out or mill out the joint to a
COMMENTS
depth of 2-3 mm.
In case unglazed ceramics are used, check by testing if the
2. Remove mortar residues from the tile flank.
surfaces can be cleaned to be free from residues.
3. Thoroughly clean the joints using decalcifying or
de greasing cleaning agents. (Grease residues TECHNICAL SPECIFICATIONS AND DATA
are particularly dangerous because they act like
Pressure resistance 60 N/mm2
a separating layer and prevent the material
from adhering.) Shear strength 14 N/mm² (steel/steel)
4. Dry the joints; use compressed air or hot air, if
necessary. Adhesive tensile strength 25 N/mm² (stoneware/stoneware)

Remark: During the preparation works it should be


4200 N/mm² (determined in the bending
checked if the tiles are still tight. Individual, loose tiles can E-module
test)
be glued on again using Ardacolor Xtrem Easy. If larger ar-
eas are loose, penetration could have taken place under Specific weight approx. 1.6 g/ml
the tiles, e.g. by grease. This requires the complete renew-
Can be walked on: after 16 hours at + 20 °C
al of the covering. Curing time Fully load-bearing: after approx. 7 days at
+ 20 °C after approx. 14 days at 10° C
HEALTH AND SAFETY AT WORK
Ardacolor Xtrem Easy includes epoxy resin and aminic cur- GISCODE RE 1
ing agent. It may cause sensitization in case of skin con-
tact. In case of skin contact, immediately wash with a lot
of water and soap. Wear suitable protective gloves and
protective glasses. Please observe the hazard notes and
safety advice on the containers and in the safety data
sheets as well as the instructions “Epoxy resin in the build- R2T RG
ing industry”, available at: Industrieverband Klebstoffe. V.,
P.O. box 23 01 69, 40087 Düsseldorf.

These instructions reflect the extent of our current knowledge and are the result of extensive
testing and practical experience. In view of the multiplicity of the possible applications and stor-
age and processing factors over which we have no control, we cannot guarantee good results in BOSTIK HOTLINE
each individual case. We recommend you test the product first before final application. Slight dis-
colouration of sealants can occur under UV-radiation. Slight colour differences between the batch-
es are possible through the production process. No liability can be accepted for absolute colour
fidelity. Use material of the same charge-number for a building object. Our technical and commer-
cial advisory service will be pleased to answer your queries.
Smart help
+ 49 (0) 5425 801-0
This data sheet supersedes all previous issues. Issued: 02/21

Bostik GmbH Bostik GmbH


An der Bundesstraße 16 · D-33829 Borgholzhausen Papierfabrikstraße 1 · A-4600 Wels
Tel.: +49 (0) 5425 801-0 · Fax: +49 (0) 5425 801-140 Tel.: +43 (0) 72 42 5 30 -10 · Fax: +43 (0) 72 42 5 30 - 12
E-Mail: [email protected] E-Mail: [email protected]
www.bostik.de www.bostik.de
METHOD STATEMENT

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METHOD STATEMENT FOR BOSTIK ARDACOLOR XTREM EASY
EPOXY-BASED TILE ADHESIVE AND TILE GROUT – CLASS R2T

This statement is prepared in order to assist the end users in the preparation and application of BOSTIK
ARDACOLOR XTREM EASY, R2T class, two-part, high-performance epoxy-based tile adhesive and tile grout.
The product is produced in accordance with EN 12004. It is used for the adhesion of finishing materials
such as ceramic, porcelain, glass tiles and mosaic on floor and walls of demanding applications wet areasm
swimming pools, chemical-processing facilities, battery and generator rooms, galvanizing shops,
laboratories, breweries, wastewater treatment facilities, etc. The performance and procedural
information regarding this product are accurate and we will use our best efforts to keep it up.

A. Product
ARDACOLOR XTREM EASY

B. Application Tools & Equipment

1. Drill mixer fitted with paddle 4. Serrated trowel (notch size depending
2. Palette knife or spatula on tile size)
3. Trowel 5. Cleaning pads / rags

C. Product Delivery & Storage

Deliver materials to jobsite in sealed, undamaged bags. Each bag shall be identified with material name,
dates of manufacture / expiry and store in covered/roofed areas.

D. Surface Preparation

1. Make sure the substrate has been correctly installed according to relevant standards and
manufacturer recommendations.
2. Allow for minimum curing time for new concrete (7 days).
3. Remove all material that will interfere with bond; these include concrete laitance, oils, grease/wax,
release agents, curing compounds, dust and any loose material.
4. Ensure surface is sound; weak or friable material must be removed.
5. Very porous surfaces and most non-porous surfaces may need priming prior application of the tile
adhesive. Please consult with Bostik Technical support for further assistance.

www.bostik.com
E. Mixing

Mix the pre-proportioned Part A and B by a hand-held mixer set to slow speed. If partial mixing is done,
ensure proper quantities are followed: Part A and B are mixed together at a ratio of 3 : 1 (by weight).
1. Add Part B into Part A.
2. Mix powder into water with mechanical stirring.
3. Mix for 3 minutes or until consistency is smooth.

F. Application

As Tile Adhesive and Bedding


1. Apply the mortar by trowel to the required thickness for the tile bedding. Ensure correctly-sized
notched trowels are used.
2. For large format tiles and special tiles (like glass), apply and spread a small amount of adhesive
mortar on the bottom and sides of the tiles.
3. Immediately press the tiles firmly into place.
4. Remove adhesive spills from the tile face using clean water.

All workmanship must be carried out in accordance with good workmanship practices. This product is
not designed to be applied as a thick-set adhesive. Concrete surface should be sufficiently level and even
enough prior receiving the tile adhesive.

As Tile Grout
1. Apply tile grout mortar directly to the joints using palette knife / grout trowel / spatula.
2. Remove excess / spill material from the tile face using damp cleaning pads / rags / sponge. Use
as few water as possible.
3. Polish the tiles using a dry lint-free cloth.

F. Coverage

On site coverage will vary widely as it is dependent on a large number of variables. These include but are
not limited to: application technique, substrate texture, wastage, trowel angle, trowel wear, contact
coverage and flatness.
As such the following coverage is intended as a guide only. As such coverage estimates are inaccurate. It
is advised that comparisons between products are based on the mixed volume.

As tile adhesive: 1.0 – 1.5 kg / sqm


As tile grout: Size of tiles Joint width Coverage
10x10 cm 2 mm 0.30 kg/m2
15x15 cm 3 mm 0.35 kg/m2
20x20 cm 3 mm 0.40 kg/m2
25x25 cm 5 mm 0.45 kg/m2
30x30 cm 6 mm 0.60 kg/m2

www.bostik.com
H. Clean Up

Remove using water and wet cloth before the product hardens. If allowed to set, it must be removed
mechanically.

I. Health and Safety

For health and safety instruction, first aid measures and spillage and disposal instructions, see separate
Safety Data Sheet.

For further inquiries, please consult with BOSTIK Technical Department.

Ref: ACM-MS-ARDAXTR-082023-REV1

www.bostik.com
SAFETY DATASHEET

www.bostik.com
SAFETY DATA SHEET
This safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006 and Regulation (EC) No. 1272/2008
This SDS is for generic information purposes and does not reflect required country specific
information for OEL

BK ARDACOLOR XTREM EASY OLD WHITE RESIN Revision Date: 07-Oct-2020


Supercedes Date: 16-Sep-2020 Revision Number 3.01

_____________________________________________________________________________________

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product Identifier

Product Name BK ARDACOLOR XTREM EASY OLD WHITE RESIN


Pure substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Resin.


Uses advised against None known.

1.3. Details of the supplier of the safety data sheet

Company Name
Bostik GmbH
An der Bundesstrasse 16
33829 Borgholzhausen, Germany
Tel: +49 (0) 5425 / 801 0
Fax: +49 (0) 5425 / 801 140

E-mail address [email protected]

1.4. Emergency telephone number

Emergency Telephone

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture

Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 2 - (H315)


Serious eye damage/eye irritation Category 2 - (H319)
Skin sensitisation Category 1 - (H317)
Chronic aquatic toxicity Category 3 - (H412)

2.2. Label Elements

Contains: 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane, 2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(4-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane, Oxirane, mono[(C12-14-alkyloxy)methyl] derivs.

Signal word
WARNING

Hazard statements

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SAFETY DATA SHEET
BK ARDACOLOR XTREM EASY OLD WHITE RESIN Revision Date: 07-Oct-2020
Supercedes Date: 16-Sep-2020 Revision Number 3.01

_____________________________________________________________________________________
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H412 - Harmful to aquatic life with long lasting effects.

EU Specific Hazard Statements


EUH211 - Warning! Hazardous respirable droplets may be formed when sprayed. Do not breathe spray or mist.

Precautionary statements
P261 - Avoid breathing vapours/spray.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 - IF ON SKIN: Wash with plenty of water and soap.
P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention.
P501 - Dispose of contents/ container to an approved waste disposal plant.

Additional information
Please refer also to Safety Data Sheet of Part B.

2.3. Other Hazards

No information available

PBT & vPvB


This mixture contains no substance considered to be persistent, bioaccumulating or toxic (PBT) This mixture contains no
substance considered to be very persistent nor very bioaccumulating (vPvB)

SECTION 3: Composition/information on ingredients


3.1 Substances

Not applicable

Mixtures

Chemical name EC No CAS No Weight-% Classification Specific REACH


according to concentration limit Registration
Regulation (EC) (SCL) Number
No. 1272/2008
[CLP]
Quartz 238-878-4 14808-60-7 40 - <80 ^ [4]
2,2'-[(1-methylethylidene 216-823-5 1675-54-3 10 - <20 Skin Irrit. 2 Eye Irrit. 2 :: C>=5% 01-2119456619-
)bis(4,1-phenyleneoxym (H315) Skin Irrit. 2 :: C>=5% 26-xxxx
ethylene)]bisoxirane Eye Irrit. 2
(H319)
Skin Sens. 1
(H317)
Aquatic Chronic
2 (H411)
2-(2-{ 701-263-0 -- 5 - <10 Aquatic Chronic 01-2119454392-
[2-(oxiran-2-ylmethoxy)p 2 (H411) 40-XXXX
henyl]methyl} Skin Irrit. 2
phenoxymethyl)oxirane; (H315)
2-(2-{ Skin Sens. 1
[4-(oxiran-2-ylmethoxy)p (H317)
henyl]methyl}
phenoxymethyl)oxirane;
2-(4-{
[4-(oxiran-2-ylmethoxy)p
henyl]methyl}
phenoxymethyl)oxirane
Crystobalite 238-455-4 14464-46-1 5 - <10 - --

Europe - BE Page 2 / 15
SAFETY DATA SHEET
BK ARDACOLOR XTREM EASY OLD WHITE RESIN Revision Date: 07-Oct-2020
Supercedes Date: 16-Sep-2020 Revision Number 3.01

_____________________________________________________________________________________
Titanium dioxide 236-675-5 13463-67-7 1 - <5 Carc. 2 (H351i) 01-2119489379-
17-XXXX
Oxirane, 271-846-8 68609-97-2 1 - <5 Skin Irrit. 2 01-2119485289-
mono[(C12-14-alkyloxy) (H315) 22-XXXX
methyl] derivs. Skin Sens. 1
(H317)
Quartz (fine fraction) 238-878-4 14808-60-7 0.1- <1 STOT RE 1 [4]
(H372)

NOTE [4] - This substance is exempted from registration according to the provisions of Article 2(7)(a) and Annex IV of REACH

Full text of H- and EUH-phrases: see section 16


Note: ^ indicates not classified, however, the substance is listed in section 3 as it has an OEL

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

SECTION 4: First aid measures


4.1. Description of first aid measures

General advice If medical advice is needed, have product container or label at hand.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Consult an
ophthalmologist.

Skin contact Wash off immediately with soap and plenty of water. In the case of skin irritation or
allergic reactions see a doctor.

Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person. Call a doctor or poison control
centre immediately.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section
8).

4.2. Most important symptoms and effects, both acute and delayed

Symptoms Itching. Rashes. Hives. May cause redness and tearing of the eyes. Burning sensation.

4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors May cause sensitisation in susceptible persons. Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable extinguishing media Full water jet.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the Thermal decomposition can lead to release of irritating gases and vapours.
chemical

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SAFETY DATA SHEET
BK ARDACOLOR XTREM EASY OLD WHITE RESIN Revision Date: 07-Oct-2020
Supercedes Date: 16-Sep-2020 Revision Number 3.01

_____________________________________________________________________________________
Hazardous combustion products Carbon monoxide. Carbon dioxide (CO2).

5.3. Advice for firefighters

Special protective equipment for Wear self contained breathing apparatus for fire fighting if necessary.
fire-fighters

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure adequate ventilation. Do not breathe vapour or mist. Use personal protective
equipment as required. Avoid contact with skin, eyes or clothing.

Other information Refer to protective measures listed in Sections 7 and 8.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.
Do not allow to enter into soil/subsoil.

6.3. Methods and material for containment and cleaning up

Methods for containment Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal.

Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.

6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage


7.1. Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. Do not breathe vapour or mist. Use personal protective
equipment as required. Avoid contact with skin, eyes or clothing. Please refer also to
Safety Data Sheet of Part B.

General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and
immediately after handling the product. Take off contaminated clothing and wash it
before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
food, drink and animal feedingstuffs.

7.3. Specific end use(s)

Specific Use(s)
Resin.

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

Other information Observe technical data sheet.

Europe - BE Page 4 / 15
SAFETY DATA SHEET
BK ARDACOLOR XTREM EASY OLD WHITE RESIN Revision Date: 07-Oct-2020
Supercedes Date: 16-Sep-2020 Revision Number 3.01

_____________________________________________________________________________________

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Exposure Limits This product contains titanium dioxide in a non-respirable form. Inhalation of titanium
dioxide is unlikely to occur from exposure to this product

Only European Community Occupational Exposure Limits will be shown in this document. Please refer to regional
SDS for further information.

Chemical name European Union


Quartz TWA: 0.1 mg/m3
14808-60-7
Crystobalite TWA: 0.1 mg/m3
14464-46-1
Quartz (fine fraction) TWA: 0.1 mg/m3
14808-60-7

Derived No Effect Level (DNEL) No information available

Derived No Effect Level (DNEL)


Quartz (14808-60-7)
2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
worker Inhalation 12.25 mg/m³
Long term
Systemic health effects
worker Inhalation 12.25 mg/m³
Short term
Systemic health effects
worker Dermal 8.33 mg/kg bw/d
Long term
Systemic health effects
worker Dermal 8.33 mg/kg bw/d
Short term
Systemic health effects

2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane (--
)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
worker Inhalation 29,39 mg/m³
Long term
Systemic health effects
worker Dermal 104,15 mg/kg bw/d
Long term
Systemic health effects

Titanium dioxide (13463-67-7)


Type Exposure route Derived No Effect Level Safety factor
(DNEL)
worker Inhalation 10 mg/m³
Long term
Local health effects

Derived No Effect Level (DNEL)


2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Type Exposure route Derived No Effect Level Safety factor

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SAFETY DATA SHEET
BK ARDACOLOR XTREM EASY OLD WHITE RESIN Revision Date: 07-Oct-2020
Supercedes Date: 16-Sep-2020 Revision Number 3.01

_____________________________________________________________________________________
(DNEL)
Consumer Dermal 3.571 mg/kg bw/d
Long term
Systemic health effects
Consumer Dermal 3.571 mg/kg bw/d
Short term
Systemic health effects
Consumer Oral 0.75 mg/kg bw/d
Long term
Systemic health effects
Consumer Dermal 0.75 mg/kg bw/d
Short term
Systemic health effects

2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane (--
)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
Consumer Inhalation 8,7 mg/m³
Long term
Systemic health effects
Consumer Dermal 62,5 mg/kg bw/d
Long term
Systemic health effects
Consumer Oral 6,25 mg/kg bw/d
Long term
Systemic health effects

Titanium dioxide (13463-67-7)


Type Exposure route Derived No Effect Level Safety factor
(DNEL)
Consumer Oral 700 mg/kg bw/d
Long term
Systemic health effects

Quartz (fine fraction) (14808-60-7)

Predicted No Effect Concentration No information available.


(PNEC)

Predicted No Effect Concentration (PNEC)


2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0.006 mg/l
Marine water 0.001 mg/l
Sewage treatment plant 10 mg/l
Freshwater sediment 0.996 mg/kg dry weight
Marine sediment 0.1 mg/kg dry weight
Soil 0.196 mg/kg dry weight

2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane (--
)
Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0,003 mg/l
Freshwater - intermittent 0,025 mg/l
Sewage treatment plant 10 mg/l
Marine water 0 mg/l
Freshwater sediment 0,294 mg/kg dry weight
Marine sediment 0,029 mg/kg dry weight
Soil 0,237 mg/kg dry weight

Europe - BE Page 6 / 15
SAFETY DATA SHEET
BK ARDACOLOR XTREM EASY OLD WHITE RESIN Revision Date: 07-Oct-2020
Supercedes Date: 16-Sep-2020 Revision Number 3.01

_____________________________________________________________________________________

Crystobalite (14464-46-1)
Titanium dioxide (13463-67-7)
Environmental compartment Predicted No Effect Concentration (PNEC)
Marine water 0.0184 mg/l
Freshwater sediment 1000 mg/kg
Freshwater 0.184 mg/l
Marine sediment 100 mg/kg
Soil 100 mg/kg
Microorganisms in sewage treatment 100 mg/l
Freshwater - intermittent 0.193 mg/l

Quartz (fine fraction) (14808-60-7)


8.2. Exposure controls

Engineering controls Ensure adequate ventilation, especially in confined areas.

Personal Protective Equipment


Eye/face protection Wear safety glasses with side shields (or goggles). Eye protection must conform to
standard EN 166
Hand protection Recommended Use: Nitrile rubber. Butyl rubber. Glove thickness > 0.7mm. The
breakthrough time for the mentioned glove material is in general greater than 480 min.
Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove
supplier for information on breakthrough time for specific gloves. The breakthrough time
of the gloves depends on the material and the thickness as well as the temperature.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material. Unsuitable gloves materials:. Disposable gloves. Leather. Gloves must
conform to standard EN 374
Skin and body protection Wear suitable protective clothing.
Respiratory protection During spraying wear suitable respiratory equipment. In case of inadequate ventilation
wear respiratory protection.
Recommended filter type: Wear a respirator conforming to EN 140 with Type A/P2 filter or better. Organic gases
and vapours filter conforming to EN 14387.

Environmental exposure controls Do not allow uncontrolled discharge of product into the environment.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties

Physical state Liquid


Appearance Paste
Colour White Beige
Odour Characteristic
Odour threshold No information available

Property Values Remarks • Method


pH No data available Not applicable
Melting point / freezing point No data available
Boiling point / boiling range No data available
Flash point 154 °C CC (closed cup)
Evaporation rate No data available
Flammability (solid, gas) Not applicable for liquids .
Flammability Limit in Air
Upper flammability or explosive No data available
limits
Lower flammability or explosive No data available
limits
Vapour pressure No data available
Vapour density No data available
Relative density 1.7 - 1.8
Water solubility Insoluble in water

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Solubility(ies) No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity No data available
Explosive properties No data available
Oxidising properties No data available

9.2. Other information


Solid content (%) No information available
VOC Content (%) No information available
Density 1.7 - 1.8 g/cm³

SECTION 10: Stability and reactivity


10.1. Reactivity

Reactivity Stable under recommended storage conditions.

10.2. Chemical stability

Stability Stable under normal conditions.

Explosion data
Sensitivity to mechanical None.
impact
Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid None known based on information supplied.

10.5. Incompatible materials

Incompatible materials Strong acids. Strong bases. Strong oxidising agents.

10.6. Hazardous decomposition products

Hazardous decomposition None under normal use conditions.


products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure

Product Information .

Inhalation Based on available data, the classification criteria are not met.

Eye contact Causes serious eye irritation.

Skin contact May cause sensitisation by skin contact. Causes skin irritation.

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Ingestion Based on available data, the classification criteria are not met.

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Itching. Rashes. Hives. Redness. May cause redness and tearing of the eyes.

Numerical measures of toxicity

Acute toxicity

The following values are calculated based on chapter 3.1 of the GHS document

Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50


Quartz >2000 mg/kg (Rattus)
14808-60-7
2,2'-[(1-methylethylidene)bis(4, =11300 µL/kg (Rattus) LD50 >2000 mg/Kg (Rattus)
1-phenyleneoxymethylene)]bis
oxirane
1675-54-3
2-(2-{ LD50 > 5000 mg/kg (rattus) LD50 > 2000 mg/kg (rattus)
[2-(oxiran-2-ylmethoxy)phenyl] OECD Guideline 402
methyl}
phenoxymethyl)oxirane; 2-(2-{
[4-(oxiran-2-ylmethoxy)phenyl]
methyl}
phenoxymethyl)oxirane; 2-(4-{
[4-(oxiran-2-ylmethoxy)phenyl]
methyl}
phenoxymethyl)oxirane
--

Titanium dioxide >10000 mg/kg (Rattus) LD50 > 10000 mg/Kg >5 mg/l
13463-67-7
Oxirane, =17100 mg/kg (Rattus) LD50 >4000 mg/Kg Rabbit
mono[(C12-14-alkyloxy)methyl]
derivs.
68609-97-2
Quartz (fine fraction) >2000 mg/kg (Rattus)
14808-60-7

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Causes skin irritation.

Component Information
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. (68609-97-2)
Method Species Exposure route Effective dose Exposure time Results
OECD Test No. 404: Rabbit Dermal 24 hours Product score 5.75
Acute Dermal irritant
Irritation/Corrosion

Quartz (fine fraction) (14808-60-7)

Serious eye damage/eye irritation Causes serious eye irritation.

Component Information
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. (68609-97-2)
Method Species Exposure route Effective dose Exposure time Results

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OECD Test No. 405: Rabbit Corneal Product score 2
Acute Eye irritant
Irritation/Corrosion

Respiratory or skin sensitisation May cause an allergic skin reaction.

Component Information
Titanium dioxide (13463-67-7)
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. (68609-97-2)
Method Species Exposure route Results
OECD Test No. 406: Skin Guinea pig Dermal sensitising
Sensitisation

Germ cell mutagenicity Based on available data, the classification criteria are not met.

Carcinogenicity Based on available data, the classification criteria are not met.
Chemical name European Union
Titanium dioxide Carc. 2
13463-67-7

The table below indicates whether each agency has listed any ingredient as a carcinogen.

Reproductive toxicity Based on available data, the classification criteria are not met.

STOT - single exposure Based on available data, the classification criteria are not met.

STOT - repeated exposure Based on available data, the classification criteria are not met.

Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information


12.1. Toxicity

Ecotoxicity Harmful to aquatic life with long lasting effects.

Chemical name Algae/aquatic Fish Toxicity to Crustacea M-Factor M-Factor


plants microorganisms (long-term)
2,2'-[(1-methylethyliden EC50 (72h) = 1.5 mg/l 96Hr - LD50 (48h) =2.7
e)bis(4,1-phenyleneoxy 9.4 mg/L (Oncorhynchus mg/L (Daphnia
methylene)]bisoxirane (Scenedesmus mykiss) magna)
1675-54-3 capricornutum) (OECD 203) (OECD 202)
EPA-660/3-75-0
09
2-(2-{ EC50 (72h) = LC50 (96h) = - EC50 (48h) =
[2-(oxiran-2-ylmethoxy) 1.8 mg/l 2.54 mg/l 2.55 mg/l
phenyl]methyl} (Daphnia
phenoxymethyl)oxirane magna)
; 2-(2-{
[4-(oxiran-2-ylmethoxy)
phenyl]methyl}
phenoxymethyl)oxirane

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; 2-(4-{
[4-(oxiran-2-ylmethoxy)
phenyl]methyl}
phenoxymethyl)oxirane
--

Titanium dioxide LC50 (96h) - - -


13463-67-7 >10000 mg/l
(Cyprinodon
variegatus)
OECD 203

12.2. Persistence and degradability

Persistence and degradability No information available.

12.3. Bioaccumulative potential

Bioaccumulation There is no data for this product.

Component Information

Chemical name Partition coefficient Bioconcentration factor (BCF)


Quartz - 0
14808-60-7
2,2'-[(1-methylethylidene)bis(4,1-phenylen 3.78 -
eoxymethylene)]bisoxirane
1675-54-3
2-(2-{ 3.6 -
[2-(oxiran-2-ylmethoxy)phenyl]methyl}
phenoxymethyl)oxirane; 2-(2-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl}
phenoxymethyl)oxirane; 2-(4-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl}
phenoxymethyl)oxirane
--

Oxirane, mono[(C12-14-alkyloxy)methyl] 3.77 -


derivs.
68609-97-2

12.4. Mobility in soil

Mobility in soil No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment The components in this formulation do not meet the criteria for classification as PBT or
vPvB.

Chemical name PBT and vPvB assessment


2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxiran The substance is not PBT / vPvB
e
1675-54-3
2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} The substance is not PBT / vPvB
phenoxymethyl)oxirane; 2-(2-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane;
2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane
--

Titanium dioxide The substance is not PBT / vPvB

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13463-67-7 PBT assessment does not apply
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. The substance is not PBT / vPvB
68609-97-2

12.6. Other adverse effects

Other adverse effects No information available.

Endocrine Disruptor Information .

Chemical name EU - Endocrine Disrupters EU - Endocrine Disruptors -


Candidate List Evaluated Substances
2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]biso Group II Chemical -
xirane

SECTION 13: Disposal considerations


13.1. Waste treatment methods

Waste from residues/unused Dispose of contents/container in accordance with local, regional, national, and
products international regulations as applicable. Uncured product should be disposed of as
hazardous waste.

Contaminated packaging Handle contaminated packages in the same way as the product itself.

European Waste Catalogue 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous
substances
15 01 10*: Packaging containing residues of or contaminated by dangerous substances

Other information Waste codes should be assigned by the user based on the application for which the
product was used.

SECTION 14: Transport information


Land transport (ADR/RID)
14.1 UN number Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing group Not regulated
14.5 Environmental hazards Not applicable
14.6 Special Provisions None

IMDG
14.1 UN number Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing group Not regulated
14.5 Marine pollutant Np
14.6 Special Provisions None
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable

Air transport (ICAO-TI / IATA-DGR)


14.1 UN number Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing group Not regulated
14.5 Environmental hazards Not applicable
14.6 Special Provisions None

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Section 15: REGULATORY INFORMATION


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work

Check whether measures in accordance with Directive 94/33/EC for the protection of young people at work must be taken.

Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work

Registration, Evaluation, Authorization, and Restriction of Chemicals (REACh) Regulation (EC 1907/2006)

SVHC: Substances of Very High Concern for Authorisation:


This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

EU-REACH (1907/2006) - Annex XVII - Substances subject to Restriction


This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII).

Substance subject to authorisation per REACH Annex XIV


This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV)

Ozone-depleting substances (ODS) regulation (EC) 1005/2009


Not applicable

Persistent Organic Pollutants


Not applicable

National regulations

France

Chemical name French RG number


Quartz RG 25
14808-60-7
Crystobalite RG 25
14464-46-1
Quartz (fine fraction) RG 25
14808-60-7

Germany

Ordinance on Industrial Safety and Health - Germany - BetrSichV


No flammable liquids in accordance with BetrSichV

Water hazard class (WGK) obviously hazardous to water (WGK 2)

TRGS - 510 Storage Class Storage Class 10 : Combustible liquids

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Netherlands

List of Carcinogenic, mutagenic and reproductive toxin substances in accordance with Inspectorate SZW
(Netherlands)

Chemical name Netherlands


Quartz Present (respirable dust, crystalline)
14808-60-7
Crystobalite Present (respirable dust, crystalline)
14464-46-1
Quartz (fine fraction) Present (respirable dust, crystalline)
14808-60-7

15.2. Chemical safety assessment

Chemical Safety Assessments have been carried out by the Reach registrants for substances registered at >10 tpa. No
Chemical Safety Assessment has been carried out for this mixture

SECTION 16: Other information


Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3


H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H372 - Causes damage to organs through prolonged or repeated exposure
H411 - Toxic to aquatic life with long lasting effects

Legend
TWA TWA (time-weighted average)
STEL STEL (Short Term Exposure Limit)
Ceiling Ceiling Limit Value
* Skin designation
SVHC Substance(s) of Very High Concern
PBT Persistent, Bioaccumulative, and Toxic (PBT) Chemicals
vPvB Very Persistent and very Bioaccumulative (vPvB) Chemicals
STOT RE Specific target organ toxicity - Repeated exposure
STOT SE Specific target organ toxicity - Single exposure
EWC European Waste Catalogue

Key literature references and sources for data


No information available

Prepared By Product Safety & Regulatory Affairs

Revision Date: 07-Oct-2020

Indication of changes

Revision note SDS sections updated: 3, 8, 11, 12, 15.

Training Advice When working with hazardous materials, regular training of operators is required by law

Further information No information available

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of

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its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process, unless specified in the text.

End of Safety Data Sheet

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SAFETY DATA SHEET
This safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006 and Regulation (EC) No. 1272/2008
This SDS is for generic information purposes and does not reflect required country specific
information for OEL

BK ARDACOLOR XTREM EASY MEDIUM GREY - PART A Revision Date: 07-Oct-2020


Supercedes Date: 15-Sep-2020 Revision Number 1.08

_____________________________________________________________________________________

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product Identifier

Product Name BK ARDACOLOR XTREM EASY MEDIUM GREY - PART A


Pure substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Resin.


Uses advised against None known.

1.3. Details of the supplier of the safety data sheet

Company Name
Bostik GmbH
An der Bundesstrasse 16
33829 Borgholzhausen, Germany
Tel: +49 (0) 5425 / 801 0
Fax: +49 (0) 5425 / 801 140

E-mail address [email protected]

1.4. Emergency telephone number

Emergency Telephone

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture

Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 2 - (H315)


Serious eye damage/eye irritation Category 2 - (H319)
Skin sensitisation Category 1 - (H317)
Chronic aquatic toxicity Category 3 - (H412)

2.2. Label Elements

Contains: 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane, 2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(4-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane, Oxirane, mono[(C12-14-alkyloxy)methyl] derivs.

Signal word
WARNING

Hazard statements

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H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H412 - Harmful to aquatic life with long lasting effects.

Precautionary statements
P261 - Avoid breathing vapours/spray.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 - IF ON SKIN: Wash with plenty of water and soap.
P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
P501 - Dispose of contents/ container to an approved waste disposal plant.

Additional information
Please refer also to Safety Data Sheet of Part B.

2.3. Other Hazards

No information available

PBT & vPvB


This mixture contains no substance considered to be persistent, bioaccumulating or toxic (PBT) This mixture contains no
substance considered to be very persistent nor very bioaccumulating (vPvB)

SECTION 3: Composition/information on ingredients


3.1 Substances

Not applicable

Mixtures

Chemical name EC No CAS No Weight-% Classification Specific REACH


according to concentration limit Registration
Regulation (EC) (SCL) Number
No. 1272/2008
[CLP]
Quartz 238-878-4 14808-60-7 40 - <80 ^ [4]
2,2'-[(1-methylethylidene 216-823-5 1675-54-3 10 - <20 Skin Irrit. 2 Eye Irrit. 2 :: C>=5% 01-2119456619-
)bis(4,1-phenyleneoxym (H315) Skin Irrit. 2 :: C>=5% 26-xxxx
ethylene)]bisoxirane Eye Irrit. 2
(H319)
Skin Sens. 1
(H317)
Aquatic Chronic
2 (H411)
2-(2-{ 701-263-0 -- 5 - <10 Aquatic Chronic 01-2119454392-
[2-(oxiran-2-ylmethoxy)p 2 (H411) 40-XXXX
henyl]methyl} Skin Irrit. 2
phenoxymethyl)oxirane; (H315)
2-(2-{ Skin Sens. 1
[4-(oxiran-2-ylmethoxy)p (H317)
henyl]methyl}
phenoxymethyl)oxirane;
2-(4-{
[4-(oxiran-2-ylmethoxy)p
henyl]methyl}
phenoxymethyl)oxirane

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Crystobalite 238-455-4 14464-46-1 5 - <10 - --
Oxirane, 271-846-8 68609-97-2 1 - <5 Skin Irrit. 2 01-2119485289-
mono[(C12-14-alkyloxy) (H315) 22-XXXX
methyl] derivs. Skin Sens. 1
(H317)
Titanium dioxide 236-675-5 13463-67-7 0.1- <1 Carc. 2 (H351i) 01-2119489379-
17-XXXX
Quartz (fine fraction) 238-878-4 14808-60-7 0.1- <1 STOT RE 1 [4]
(H372)

Full text of H- and EUH-phrases: see section 16


Note: ^ indicates not classified, however, the substance is listed in section 3 as it has an OEL

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

SECTION 4: First aid measures


4.1. Description of first aid measures

General advice If medical advice is needed, have product container or label at hand.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Consult an
ophthalmologist.

Skin contact Wash off immediately with soap and plenty of water. In the case of skin irritation or
allergic reactions see a doctor.

Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person. Call a doctor or poison control
centre immediately.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section
8).

4.2. Most important symptoms and effects, both acute and delayed

Symptoms Itching. Rashes. Hives. May cause redness and tearing of the eyes. Burning sensation.

4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors May cause sensitisation in susceptible persons. Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable extinguishing media Full water jet. Do not scatter spilled material with high pressure water streams.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the Thermal decomposition can lead to release of irritating gases and vapours.
chemical

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Hazardous combustion products Carbon monoxide. Carbon dioxide (CO2).

5.3. Advice for firefighters

Special protective equipment for Wear self contained breathing apparatus for fire fighting if necessary.
fire-fighters

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.
Ensure adequate ventilation. Avoid contact with skin, eyes or clothing. Use personal
protective equipment as required.

Other information Refer to protective measures listed in Sections 7 and 8.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.
Do not allow to enter into soil/subsoil.

6.3. Methods and material for containment and cleaning up

Methods for containment Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal.

Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.

6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage


7.1. Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. Do not breathe vapour or mist. Use personal protective
equipment as required. Avoid contact with skin, eyes or clothing. Please refer also to
Safety Data Sheet of Part B.

General hygiene considerations When using do not eat, drink or smoke. Wash hands before breaks and immediately
after handling the product. Take off all contaminated clothing and wash it before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
food, drink and animal feedingstuffs.

7.3. Specific end use(s)

Specific Use(s)
Resin.

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

Other information Observe technical data sheet.

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SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Exposure Limits

Only European Community Occupational Exposure Limits will be shown in this document. Please refer to regional
SDS for further information.

Chemical name European Union


Quartz TWA: 0.1 mg/m3
14808-60-7
Crystobalite TWA: 0.1 mg/m3
14464-46-1
Quartz (fine fraction) TWA: 0.1 mg/m3
14808-60-7

Derived No Effect Level (DNEL) No information available

Derived No Effect Level (DNEL)


Quartz (14808-60-7)
2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
worker Inhalation 12.25 mg/m³
Long term
Systemic health effects
worker Inhalation 12.25 mg/m³
Short term
Systemic health effects
worker Dermal 8.33 mg/kg bw/d
Long term
Systemic health effects
worker Dermal 8.33 mg/kg bw/d
Short term
Systemic health effects

2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane (--
)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
worker Inhalation 29,39 mg/m³
Long term
Systemic health effects
worker Dermal 104,15 mg/kg bw/d
Long term
Systemic health effects

Titanium dioxide (13463-67-7)


Type Exposure route Derived No Effect Level Safety factor
(DNEL)
worker Inhalation 10 mg/m³
Long term
Local health effects

Derived No Effect Level (DNEL)


2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Type Exposure route Derived No Effect Level Safety factor

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(DNEL)
Consumer Dermal 3.571 mg/kg bw/d
Long term
Systemic health effects
Consumer Dermal 3.571 mg/kg bw/d
Short term
Systemic health effects
Consumer Oral 0.75 mg/kg bw/d
Long term
Systemic health effects
Consumer Dermal 0.75 mg/kg bw/d
Short term
Systemic health effects

2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane (--
)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
Consumer Inhalation 8,7 mg/m³
Long term
Systemic health effects
Consumer Dermal 62,5 mg/kg bw/d
Long term
Systemic health effects
Consumer Oral 6,25 mg/kg bw/d
Long term
Systemic health effects

Titanium dioxide (13463-67-7)


Type Exposure route Derived No Effect Level Safety factor
(DNEL)
Consumer Oral 700 mg/kg bw/d
Long term
Systemic health effects

Quartz (fine fraction) (14808-60-7)

Predicted No Effect Concentration No information available.


(PNEC)

Predicted No Effect Concentration (PNEC)


2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0.006 mg/l
Marine water 0.001 mg/l
Sewage treatment plant 10 mg/l
Freshwater sediment 0.996 mg/kg dry weight
Marine sediment 0.1 mg/kg dry weight
Soil 0.196 mg/kg dry weight

2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane (--
)
Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0,003 mg/l
Freshwater - intermittent 0,025 mg/l
Sewage treatment plant 10 mg/l
Marine water 0 mg/l
Freshwater sediment 0,294 mg/kg dry weight
Marine sediment 0,029 mg/kg dry weight
Soil 0,237 mg/kg dry weight

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Crystobalite (14464-46-1)
Titanium dioxide (13463-67-7)
Environmental compartment Predicted No Effect Concentration (PNEC)
Marine water 0.0184 mg/l
Freshwater sediment 1000 mg/kg
Freshwater 0.184 mg/l
Marine sediment 100 mg/kg
Soil 100 mg/kg
Microorganisms in sewage treatment 100 mg/l
Freshwater - intermittent 0.193 mg/l

Quartz (fine fraction) (14808-60-7)


8.2. Exposure controls

Engineering controls Ensure adequate ventilation, especially in confined areas.

Personal Protective Equipment


Eye/face protection Wear safety glasses with side shields (or goggles). Eye protection must conform to
standard EN 166
Hand protection Recommended Use: Nitrile rubber. Butyl rubber. Glove thickness > 0.7mm. The
breakthrough time for the mentioned glove material is in general greater than 480 min.
Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove
supplier for information on breakthrough time for specific gloves. Gloves should be
replaced regularly and if there is any sign of damage to the glove material. Unsuitable
gloves materials: Disposable gloves. Leather. Gloves must conform to standard EN 374
Skin and body protection Wear suitable protective clothing.
Respiratory protection During spraying wear suitable respiratory equipment. In case of inadequate ventilation
wear respiratory protection.
Recommended filter type: Wear a respirator conforming to EN 140 with Type A/P2 filter or better. Organic gases
and vapours filter conforming to EN 14387.

Environmental exposure controls Do not allow uncontrolled discharge of product into the environment.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties

Physical state Liquid


Appearance Paste
Colour Grey
Odour Characteristic
Odour threshold No information available

Property Values Remarks • Method


pH No data available Not applicable
Melting point / freezing point No data available
Boiling point / boiling range No data available
Flash point 154 °C CC (closed cup)
Evaporation rate No data available
Flammability (solid, gas) Not applicable for liquids .
Flammability Limit in Air
Upper flammability or explosive No data available
limits
Lower flammability or explosive No data available
limits
Vapour pressure No data available
Vapour density No data available
Relative density 1.7 - 1.8
Water solubility Insoluble in water
Solubility(ies) No data available
Partition coefficient No data available

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Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity No data available
Explosive properties No data available
Oxidising properties No data available

9.2. Other information


Solid content (%) No information available
VOC Content (%) No information available
Density 1.7 - 1.8 g/cm³

SECTION 10: Stability and reactivity


10.1. Reactivity

Reactivity Stable under recommended storage conditions.

10.2. Chemical stability

Stability Stable under normal conditions.

Explosion data
Sensitivity to mechanical None.
impact
Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid None known based on information supplied.

10.5. Incompatible materials

Incompatible materials Strong acids. Strong bases. Strong oxidising agents.

10.6. Hazardous decomposition products

Hazardous decomposition None under normal use conditions.


products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure

Product Information .

Inhalation Based on available data, the classification criteria are not met.

Eye contact Causes serious eye irritation.

Skin contact May cause sensitisation by skin contact. Causes skin irritation.

Ingestion Based on available data, the classification criteria are not met.

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Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Itching. Rashes. Hives. Redness. May cause redness and tearing of the eyes.

Numerical measures of toxicity

Acute toxicity

The following values are calculated based on chapter 3.1 of the GHS document

Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50


Quartz >2000 mg/kg (Rattus)
14808-60-7
2,2'-[(1-methylethylidene)bis(4, =11300 µL/kg (Rattus) LD50 >2000 mg/Kg (Rattus)
1-phenyleneoxymethylene)]bis
oxirane
1675-54-3
2-(2-{ LD50 > 5000 mg/kg (rattus) LD50 > 2000 mg/kg (rattus)
[2-(oxiran-2-ylmethoxy)phenyl] OECD Guideline 402
methyl}
phenoxymethyl)oxirane; 2-(2-{
[4-(oxiran-2-ylmethoxy)phenyl]
methyl}
phenoxymethyl)oxirane; 2-(4-{
[4-(oxiran-2-ylmethoxy)phenyl]
methyl}
phenoxymethyl)oxirane
--

Oxirane, =17100 mg/kg (Rattus) LD50 >4000 mg/Kg Rabbit


mono[(C12-14-alkyloxy)methyl]
derivs.
68609-97-2
Titanium dioxide >10000 mg/kg (Rattus) LD50 > 10000 mg/Kg >5 mg/l
13463-67-7
Quartz (fine fraction) >2000 mg/kg (Rattus)
14808-60-7

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Causes skin irritation.

Component Information
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. (68609-97-2)
Method Species Exposure route Effective dose Exposure time Results
OECD Test No. 404: Rabbit Dermal 24 hours Product score 5.75
Acute Dermal irritant
Irritation/Corrosion

Quartz (fine fraction) (14808-60-7)

Serious eye damage/eye irritation Causes serious eye irritation.

Component Information
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. (68609-97-2)
Method Species Exposure route Effective dose Exposure time Results
OECD Test No. 405: Rabbit Corneal Product score 2
Acute Eye irritant

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Irritation/Corrosion

Respiratory or skin sensitisation May cause an allergic skin reaction.

Component Information
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. (68609-97-2)
Method Species Exposure route Results
OECD Test No. 406: Skin Guinea pig Dermal sensitising
Sensitisation

Titanium dioxide (13463-67-7)

Germ cell mutagenicity Based on available data, the classification criteria are not met.

Carcinogenicity Based on available data, the classification criteria are not met.
Chemical name European Union
Titanium dioxide Carc. 2
13463-67-7

The table below indicates whether each agency has listed any ingredient as a carcinogen.

Reproductive toxicity Based on available data, the classification criteria are not met.

STOT - single exposure Based on available data, the classification criteria are not met.

STOT - repeated exposure Based on available data, the classification criteria are not met.

Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information


12.1. Toxicity

Ecotoxicity Harmful to aquatic life with long lasting effects.

Chemical name Algae/aquatic Fish Toxicity to Crustacea M-Factor M-Factor


plants microorganisms (long-term)
2,2'-[(1-methylethyliden EC50 (72h) = 1.5 mg/l 96Hr - LD50 (48h) =2.7
e)bis(4,1-phenyleneoxy 9.4 mg/L (Oncorhynchus mg/L (Daphnia
methylene)]bisoxirane (Scenedesmus mykiss) magna)
1675-54-3 capricornutum) (OECD 203) (OECD 202)
EPA-660/3-75-0
09
2-(2-{ EC50 (72h) = LC50 (96h) = - EC50 (48h) =
[2-(oxiran-2-ylmethoxy) 1.8 mg/l 2.54 mg/l 2.55 mg/l
phenyl]methyl} (Daphnia
phenoxymethyl)oxirane magna)
; 2-(2-{
[4-(oxiran-2-ylmethoxy)
phenyl]methyl}
phenoxymethyl)oxirane
; 2-(4-{
[4-(oxiran-2-ylmethoxy)

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phenyl]methyl}
phenoxymethyl)oxirane
--

Titanium dioxide LC50 (96h) - - -


13463-67-7 >10000 mg/l
(Cyprinodon
variegatus)
OECD 203

12.2. Persistence and degradability

Persistence and degradability No information available.

12.3. Bioaccumulative potential

Bioaccumulation There is no data for this product.

Component Information

Chemical name Partition coefficient Bioconcentration factor (BCF)


Quartz - 0
14808-60-7
2,2'-[(1-methylethylidene)bis(4,1-phenylen 3.78 -
eoxymethylene)]bisoxirane
1675-54-3
2-(2-{ 3.6 -
[2-(oxiran-2-ylmethoxy)phenyl]methyl}
phenoxymethyl)oxirane; 2-(2-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl}
phenoxymethyl)oxirane; 2-(4-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl}
phenoxymethyl)oxirane
--

Oxirane, mono[(C12-14-alkyloxy)methyl] 3.77 -


derivs.
68609-97-2

12.4. Mobility in soil

Mobility in soil No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment The components in this formulation do not meet the criteria for classification as PBT or
vPvB. .

Chemical name PBT and vPvB assessment


2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxiran The substance is not PBT / vPvB
e
1675-54-3
2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} The substance is not PBT / vPvB
phenoxymethyl)oxirane; 2-(2-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane;
2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane
--

Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. The substance is not PBT / vPvB


68609-97-2
Titanium dioxide The substance is not PBT / vPvB

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13463-67-7 PBT assessment does not apply

12.6. Other adverse effects

Other adverse effects No information available.

Endocrine Disruptor Information .

Chemical name EU - Endocrine Disrupters EU - Endocrine Disruptors -


Candidate List Evaluated Substances
2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]biso Group II Chemical -
xirane

SECTION 13: Disposal considerations


13.1. Waste treatment methods

Waste from residues/unused Dispose of contents/container in accordance with local, regional, national, and
products international regulations as applicable. Uncured product should be disposed of as
hazardous waste.

Contaminated packaging Handle contaminated packages in the same way as the product itself.

European Waste Catalogue 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous
substances

Other information Waste codes should be assigned by the user based on the application for which the
product was used.

SECTION 14: Transport information


Land transport (ADR/RID)
14.1 UN number Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing group Not regulated
14.5 Environmental hazards Not applicable
14.6 Special Provisions None

IMDG
14.1 UN number Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing group Not regulated
14.5 Marine pollutant Np
14.6 Special Provisions None
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable

Air transport (ICAO-TI / IATA-DGR)


14.1 UN number Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing group Not regulated
14.5 Environmental hazards Not applicable
14.6 Special Provisions None

Section 15: REGULATORY INFORMATION

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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work

Check whether measures in accordance with Directive 94/33/EC for the protection of young people at work must be taken.

Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work

Registration, Evaluation, Authorization, and Restriction of Chemicals (REACh) Regulation (EC 1907/2006)

SVHC: Substances of Very High Concern for Authorisation:


This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

EU-REACH (1907/2006) - Annex XVII - Substances subject to Restriction


This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII).

Substance subject to authorisation per REACH Annex XIV


This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV)

Ozone-depleting substances (ODS) regulation (EC) 1005/2009


Not applicable

Persistent Organic Pollutants


Not applicable

National regulations

France

Chemical name French RG number


Quartz RG 25
14808-60-7
Crystobalite RG 25
14464-46-1
Quartz (fine fraction) RG 25
14808-60-7

Germany

Ordinance on Industrial Safety and Health - Germany - BetrSichV


No flammable liquids in accordance with BetrSichV

Water hazard class (WGK) obviously hazardous to water (WGK 2)

TRGS - 510 Storage Class Storage Class 10 : Combustible liquids

Netherlands

List of Carcinogenic, mutagenic and reproductive toxin substances in accordance with Inspectorate SZW

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(Netherlands)

Chemical name Netherlands


Quartz Present (respirable dust, crystalline)
14808-60-7
Crystobalite Present (respirable dust, crystalline)
14464-46-1
Quartz (fine fraction) Present (respirable dust, crystalline)
14808-60-7

15.2. Chemical safety assessment

Chemical Safety Assessments have been carried out by the Reach registrants for substances registered at >10 tpa. No
Chemical Safety Assessment has been carried out for this mixture

SECTION 16: Other information


Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3


H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H372 - Causes damage to organs through prolonged or repeated exposure
H411 - Toxic to aquatic life with long lasting effects

Legend
TWA TWA (time-weighted average)
STEL STEL (Short Term Exposure Limit)
Ceiling Ceiling Limit Value
* Skin designation
SVHC Substance(s) of Very High Concern
PBT Persistent, Bioaccumulative, and Toxic (PBT) Chemicals
vPvB Very Persistent and very Bioaccumulative (vPvB) Chemicals
STOT RE Specific target organ toxicity - Repeated exposure
STOT SE Specific target organ toxicity - Single exposure
EWC European Waste Catalogue

Key literature references and sources for data


No information available

Prepared By Product Safety & Regulatory Affairs

Revision Date: 07-Oct-2020

Indication of changes

Revision note SDS sections updated: 3, 8, 11, 12, 15.

Training Advice When working with hazardous materials, regular training of operators is required by law

Further information No information available

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material used in combination with any other materials or in

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any process, unless specified in the text.

End of Safety Data Sheet

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SAFETY DATA SHEET
This safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006 and Regulation (EC) No. 1272/2008
This SDS is for generic information purposes and does not reflect required country specific
information for OEL

BK ARDACOLOR XTREM EASY ANTHRACITE RESIN Revision Date: 07-Oct-2020


Supercedes Date: 23-Jul-2020 Revision Number 1.04

_____________________________________________________________________________________

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product Identifier

Product Name BK ARDACOLOR XTREM EASY ANTHRACITE RESIN


Pure substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Resin.


Uses advised against None known.

1.3. Details of the supplier of the safety data sheet

Company Name
Bostik GmbH
An der Bundesstrasse 16
33829 Borgholzhausen, Germany
Tel: +49 (0) 5425 / 801 0
Fax: +49 (0) 5425 / 801 140

E-mail address [email protected]

1.4. Emergency telephone number

Emergency Telephone

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture

Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 2 - (H315)


Serious eye damage/eye irritation Category 2 - (H319)
Skin sensitisation Category 1 - (H317)
Chronic aquatic toxicity Category 3 - (H412)

2.2. Label Elements

Contains: 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane, 2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(4-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane, Oxirane, mono[(C12-14-alkyloxy)methyl] derivs.

Signal word
WARNING

Hazard statements

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H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H412 - Harmful to aquatic life with long lasting effects.

Precautionary statements
P261 - Avoid breathing vapours/spray.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 - IF ON SKIN: Wash with plenty of water and soap.
P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
P501 - Dispose of contents/ container to an approved waste disposal plant.

Additional information
Please refer also to Safety Data Sheet of Part B.

2.3. Other Hazards

No information available

PBT & vPvB


This mixture contains no substance considered to be persistent, bioaccumulating or toxic (PBT) This mixture contains no
substance considered to be very persistent nor very bioaccumulating (vPvB)

SECTION 3: Composition/information on ingredients


3.1 Substances

Not applicable

Mixtures

Chemical name EC No CAS No Weight-% Classification Specific REACH


according to concentration limit Registration
Regulation (EC) (SCL) Number
No. 1272/2008
[CLP]
Quartz 238-878-4 14808-60-7 40 - <80 ^ [4]
2,2'-[(1-methylethylidene 216-823-5 1675-54-3 10 - <20 Skin Irrit. 2 Eye Irrit. 2 :: C>=5% 01-2119456619-
)bis(4,1-phenyleneoxym (H315) Skin Irrit. 2 :: C>=5% 26-xxxx
ethylene)]bisoxirane Eye Irrit. 2
(H319)
Skin Sens. 1
(H317)
Aquatic Chronic
2 (H411)
2-(2-{ 701-263-0 -- 5 - <10 Aquatic Chronic 01-2119454392-
[2-(oxiran-2-ylmethoxy)p 2 (H411) 40-XXXX
henyl]methyl} Skin Irrit. 2
phenoxymethyl)oxirane; (H315)
2-(2-{ Skin Sens. 1
[4-(oxiran-2-ylmethoxy)p (H317)
henyl]methyl}
phenoxymethyl)oxirane;
2-(4-{
[4-(oxiran-2-ylmethoxy)p
henyl]methyl}
phenoxymethyl)oxirane

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_____________________________________________________________________________________
Crystobalite 238-455-4 14464-46-1 5 - <10 - --
Oxirane, 271-846-8 68609-97-2 1 - <5 Skin Irrit. 2 01-2119485289-
mono[(C12-14-alkyloxy) (H315) 22-XXXX
methyl] derivs. Skin Sens. 1
(H317)
Quartz (fine fraction) 238-878-4 14808-60-7 0.1- <1 STOT RE 1 [4]
(H372)

Titanium dioxide 236-675-5 13463-67-7 0.1- <1 Carc. 2 (H351i) 01-2119489379-


17-XXXX
NOTE [4] - This substance is exempted from registration according to the provisions of Article 2(7)(a) and Annex IV of REACH

Full text of H- and EUH-phrases: see section 16


Note: ^ indicates not classified, however, the substance is listed in section 3 as it has an OEL

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

SECTION 4: First aid measures


4.1. Description of first aid measures

General advice If medical advice is needed, have product container or label at hand.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Consult an
ophthalmologist.

Skin contact Wash off immediately with soap and plenty of water. In the case of skin irritation or
allergic reactions see a doctor.

Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person. Call a doctor or poison control
centre immediately.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section
8).

4.2. Most important symptoms and effects, both acute and delayed

Symptoms Itching. Rashes. Hives. May cause redness and tearing of the eyes. Burning sensation.

4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors May cause sensitisation in susceptible persons. Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable extinguishing media Full water jet.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the Thermal decomposition can lead to release of irritating gases and vapours.
chemical

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_____________________________________________________________________________________

Hazardous combustion products Carbon monoxide. Carbon dioxide (CO2).

5.3. Advice for firefighters

Special protective equipment for Wear self contained breathing apparatus for fire fighting if necessary.
fire-fighters

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure adequate ventilation. Do not breathe vapour or mist. Use personal protective
equipment as required. Avoid contact with skin, eyes or clothing.

Other information Refer to protective measures listed in Sections 7 and 8.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.
Do not allow to enter into soil/subsoil.

6.3. Methods and material for containment and cleaning up

Methods for containment Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal.

Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.

6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage


7.1. Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. Do not breathe vapour or mist. Use personal protective
equipment as required. Avoid contact with skin, eyes or clothing. Please refer also to
Safety Data Sheet of Part B.

General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and
immediately after handling the product. Take off all contaminated clothing and wash it
before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
food, drink and animal feedingstuffs.

7.3. Specific end use(s)

Specific Use(s)
Resin.

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

Other information Observe technical data sheet.

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SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Exposure Limits

Only European Community Occupational Exposure Limits will be shown in this document. Please refer to regional
SDS for further information.

Chemical name European Union


Quartz TWA: 0.1 mg/m3
14808-60-7
Crystobalite TWA: 0.1 mg/m3
14464-46-1
Quartz (fine fraction) TWA: 0.1 mg/m3
14808-60-7

Derived No Effect Level (DNEL) No information available

Derived No Effect Level (DNEL)


Quartz (14808-60-7)
2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
worker Inhalation 12.25 mg/m³
Long term
Systemic health effects
worker Inhalation 12.25 mg/m³
Short term
Systemic health effects
worker Dermal 8.33 mg/kg bw/d
Long term
Systemic health effects
worker Dermal 8.33 mg/kg bw/d
Short term
Systemic health effects

2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane (--
)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
worker Inhalation 29,39 mg/m³
Long term
Systemic health effects
worker Dermal 104,15 mg/kg bw/d
Long term
Systemic health effects

Titanium dioxide (13463-67-7)


Type Exposure route Derived No Effect Level Safety factor
(DNEL)
worker Inhalation 10 mg/m³
Long term
Local health effects

Derived No Effect Level (DNEL)


2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Type Exposure route Derived No Effect Level Safety factor

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(DNEL)
Consumer Dermal 3.571 mg/kg bw/d
Long term
Systemic health effects
Consumer Dermal 3.571 mg/kg bw/d
Short term
Systemic health effects
Consumer Oral 0.75 mg/kg bw/d
Long term
Systemic health effects
Consumer Dermal 0.75 mg/kg bw/d
Short term
Systemic health effects

2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane (--
)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
Consumer Inhalation 8,7 mg/m³
Long term
Systemic health effects
Consumer Dermal 62,5 mg/kg bw/d
Long term
Systemic health effects
Consumer Oral 6,25 mg/kg bw/d
Long term
Systemic health effects

Quartz (fine fraction) (14808-60-7)


Titanium dioxide (13463-67-7)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
Consumer Oral 700 mg/kg bw/d
Long term
Systemic health effects

Predicted No Effect Concentration No information available.


(PNEC)

Predicted No Effect Concentration (PNEC)


2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0.006 mg/l
Marine water 0.001 mg/l
Sewage treatment plant 10 mg/l
Freshwater sediment 0.996 mg/kg dry weight
Marine sediment 0.1 mg/kg dry weight
Soil 0.196 mg/kg dry weight

2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane (--
)
Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0,003 mg/l
Freshwater - intermittent 0,025 mg/l
Sewage treatment plant 10 mg/l
Marine water 0 mg/l
Freshwater sediment 0,294 mg/kg dry weight
Marine sediment 0,029 mg/kg dry weight
Soil 0,237 mg/kg dry weight

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Crystobalite (14464-46-1)
Quartz (fine fraction) (14808-60-7)
Titanium dioxide (13463-67-7)
Environmental compartment Predicted No Effect Concentration (PNEC)
Marine water 0.0184 mg/l
Freshwater sediment 1000 mg/kg
Freshwater 0.184 mg/l
Marine sediment 100 mg/kg
Soil 100 mg/kg
Microorganisms in sewage treatment 100 mg/l
Freshwater - intermittent 0.193 mg/l

8.2. Exposure controls

Engineering controls Ensure adequate ventilation, especially in confined areas. Please refer also to Safety
Data Sheet of Part B.

Personal Protective Equipment


Eye/face protection Wear safety glasses with side shields (or goggles). Eye protection must conform to
standard EN 166
Hand protection Recommended Use: Nitrile rubber. Butyl rubber. Glove thickness > 0.7mm. The
breakthrough time for the mentioned glove material is in general greater than 480 min.
Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove
supplier for information on breakthrough time for specific gloves. Gloves should be
replaced regularly and if there is any sign of damage to the glove material. Unsuitable
gloves materials: Disposable gloves. Leather. Gloves must conform to standard EN 374
Skin and body protection Wear suitable protective clothing.
Respiratory protection During spraying wear suitable respiratory equipment. In case of inadequate ventilation
wear respiratory protection.
Recommended filter type: Wear a respirator conforming to EN 140 with Type A/P2 filter or better. Organic gases
and vapours filter conforming to EN 14387.

Environmental exposure controls Do not allow uncontrolled discharge of product into the environment.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties

Physical state Liquid


Appearance Paste
Colour Grey
Odour Characteristic
Odour threshold No information available

Property Values Remarks • Method


pH No data available Not applicable
Melting point / freezing point No data available
Boiling point / boiling range No data available
Flash point 154 °C CC (closed cup)
Evaporation rate No data available
Flammability (solid, gas) Not applicable for liquids .
Flammability Limit in Air
Upper flammability or explosive No data available
limits
Lower flammability or explosive No data available
limits
Vapour pressure No data available
Vapour density No data available
Relative density 1.7 - 1.8
Water solubility Insoluble in water
Solubility(ies) No data available
Partition coefficient No data available

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Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity No data available
Explosive properties No data available
Oxidising properties No data available

9.2. Other information


Solid content (%) No information available
VOC Content (%) No information available
Density 1.7 - 1.8 g/cm³

SECTION 10: Stability and reactivity


10.1. Reactivity

Reactivity Stable under recommended storage conditions.

10.2. Chemical stability

Stability Stable under normal conditions.

Explosion data
Sensitivity to mechanical None.
impact
Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid None known based on information supplied.

10.5. Incompatible materials

Incompatible materials Strong acids. Strong bases. Strong oxidising agents.

10.6. Hazardous decomposition products

Hazardous decomposition None under normal use conditions.


products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure

Product Information .

Inhalation Based on available data, the classification criteria are not met.

Eye contact Causes serious eye irritation.

Skin contact May cause sensitisation by skin contact. Causes skin irritation.

Ingestion Based on available data, the classification criteria are not met.

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Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Itching. Rashes. Hives. Redness. May cause redness and tearing of the eyes.

Numerical measures of toxicity

Acute toxicity

The following values are calculated based on chapter 3.1 of the GHS document

Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50


Quartz >2000 mg/kg (Rattus)
14808-60-7
2,2'-[(1-methylethylidene)bis(4, =11300 µL/kg (Rattus) LD50 >2000 mg/Kg (Rattus)
1-phenyleneoxymethylene)]bis
oxirane
1675-54-3
2-(2-{ LD50 > 5000 mg/kg (rattus) LD50 > 2000 mg/kg (rattus)
[2-(oxiran-2-ylmethoxy)phenyl] OECD Guideline 402
methyl}
phenoxymethyl)oxirane; 2-(2-{
[4-(oxiran-2-ylmethoxy)phenyl]
methyl}
phenoxymethyl)oxirane; 2-(4-{
[4-(oxiran-2-ylmethoxy)phenyl]
methyl}
phenoxymethyl)oxirane
--

Oxirane, =17100 mg/kg (Rattus) LD50 >4000 mg/Kg Rabbit


mono[(C12-14-alkyloxy)methyl]
derivs.
68609-97-2
Quartz (fine fraction) >2000 mg/kg (Rattus)
14808-60-7
Titanium dioxide >10000 mg/kg (Rattus) LD50 > 10000 mg/Kg >5 mg/l
13463-67-7

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Causes skin irritation.

Component Information
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. (68609-97-2)
Method Species Exposure route Effective dose Exposure time Results
OECD Test No. 404: Rabbit Dermal 24 hours Product score 5.75
Acute Dermal irritant
Irritation/Corrosion

Quartz (fine fraction) (14808-60-7)

Serious eye damage/eye irritation Causes serious eye irritation.

Component Information
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. (68609-97-2)
Method Species Exposure route Effective dose Exposure time Results
OECD Test No. 405: Rabbit Corneal Product score 2
Acute Eye irritant

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Irritation/Corrosion

Respiratory or skin sensitisation May cause an allergic skin reaction.

Component Information
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. (68609-97-2)
Method Species Exposure route Results
OECD Test No. 406: Skin Guinea pig Dermal sensitising
Sensitisation

Titanium dioxide (13463-67-7)

Germ cell mutagenicity Based on available data, the classification criteria are not met.

Carcinogenicity Based on available data, the classification criteria are not met.
Chemical name European Union
Titanium dioxide Carc. 2
13463-67-7

The table below indicates whether each agency has listed any ingredient as a carcinogen.

Reproductive toxicity Based on available data, the classification criteria are not met.

STOT - single exposure Based on available data, the classification criteria are not met.

STOT - repeated exposure Based on available data, the classification criteria are not met.

Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information


12.1. Toxicity

Ecotoxicity Harmful to aquatic life with long lasting effects.

Chemical name Algae/aquatic Fish Toxicity to Crustacea M-Factor M-Factor


plants microorganisms (long-term)
2,2'-[(1-methylethyliden EC50 (72h) = 1.5 mg/l 96Hr - LD50 (48h) =2.7
e)bis(4,1-phenyleneoxy 9.4 mg/L (Oncorhynchus mg/L (Daphnia
methylene)]bisoxirane (Scenedesmus mykiss) magna)
1675-54-3 capricornutum) (OECD 203) (OECD 202)
EPA-660/3-75-0
09
2-(2-{ EC50 (72h) = LC50 (96h) = - EC50 (48h) =
[2-(oxiran-2-ylmethoxy) 1.8 mg/l 2.54 mg/l 2.55 mg/l
phenyl]methyl} (Daphnia
phenoxymethyl)oxirane magna)
; 2-(2-{
[4-(oxiran-2-ylmethoxy)
phenyl]methyl}
phenoxymethyl)oxirane
; 2-(4-{
[4-(oxiran-2-ylmethoxy)

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phenyl]methyl}
phenoxymethyl)oxirane
--

Titanium dioxide LC50 (96h) - - -


13463-67-7 >10000 mg/l
(Cyprinodon
variegatus)
OECD 203

12.2. Persistence and degradability

Persistence and degradability No information available.

12.3. Bioaccumulative potential

Bioaccumulation There is no data for this product.

Component Information

Chemical name Partition coefficient Bioconcentration factor (BCF)


Quartz - 0
14808-60-7
2,2'-[(1-methylethylidene)bis(4,1-phenylen 3.78 -
eoxymethylene)]bisoxirane
1675-54-3
2-(2-{ 3.6 -
[2-(oxiran-2-ylmethoxy)phenyl]methyl}
phenoxymethyl)oxirane; 2-(2-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl}
phenoxymethyl)oxirane; 2-(4-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl}
phenoxymethyl)oxirane
--

Oxirane, mono[(C12-14-alkyloxy)methyl] 3.77 -


derivs.
68609-97-2

12.4. Mobility in soil

Mobility in soil No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment . The components in this formulation do not meet the criteria for classification as PBT or
vPvB.

Chemical name PBT and vPvB assessment


2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxiran The substance is not PBT / vPvB
e
1675-54-3
2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} The substance is not PBT / vPvB
phenoxymethyl)oxirane; 2-(2-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane;
2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane
--

Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. The substance is not PBT / vPvB


68609-97-2
Titanium dioxide The substance is not PBT / vPvB

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13463-67-7 PBT assessment does not apply

12.6. Other adverse effects

Other adverse effects No information available.

Endocrine Disruptor Information .

Chemical name EU - Endocrine Disrupters EU - Endocrine Disruptors -


Candidate List Evaluated Substances
2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]biso Group II Chemical -
xirane

SECTION 13: Disposal considerations


13.1. Waste treatment methods

Waste from residues/unused Dispose of contents/container in accordance with local, regional, national, and
products international regulations as applicable. Uncured product should be disposed of as
hazardous waste.

Contaminated packaging Handle contaminated packages in the same way as the product itself.

European Waste Catalogue 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous
substances

Other information Waste codes should be assigned by the user based on the application for which the
product was used.

SECTION 14: Transport information


Land transport (ADR/RID)
14.1 UN number Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing group Not regulated
14.5 Environmental hazards Not applicable
14.6 Special Provisions None

IMDG
14.1 UN number Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing group Not regulated
14.5 Marine pollutant Np
14.6 Special Provisions None
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable

Air transport (ICAO-TI / IATA-DGR)


14.1 UN number Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing group Not regulated
14.5 Environmental hazards Not applicable
14.6 Special Provisions None

Section 15: REGULATORY INFORMATION

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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work

Check whether measures in accordance with Directive 94/33/EC for the protection of young people at work must be taken.

Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work

Registration, Evaluation, Authorization, and Restriction of Chemicals (REACh) Regulation (EC 1907/2006)

SVHC: Substances of Very High Concern for Authorisation:


This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

EU-REACH (1907/2006) - Annex XVII - Substances subject to Restriction


This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII).

Substance subject to authorisation per REACH Annex XIV


This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV)

Ozone-depleting substances (ODS) regulation (EC) 1005/2009


Not applicable

Persistent Organic Pollutants


Not applicable

National regulations

France

Chemical name French RG number


Quartz RG 25
14808-60-7
Crystobalite RG 25
14464-46-1
Quartz (fine fraction) RG 25
14808-60-7

Germany

Ordinance on Industrial Safety and Health - Germany - BetrSichV


No flammable liquids in accordance with BetrSichV

Water hazard class (WGK) obviously hazardous to water (WGK 2)

TRGS - 510 Storage Class Storage Class 10 : Combustible liquids

Netherlands

List of Carcinogenic, mutagenic and reproductive toxin substances in accordance with Inspectorate SZW

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(Netherlands)

Chemical name Netherlands


Quartz Present (respirable dust, crystalline)
14808-60-7
Crystobalite Present (respirable dust, crystalline)
14464-46-1
Quartz (fine fraction) Present (respirable dust, crystalline)
14808-60-7

15.2. Chemical safety assessment

Chemical Safety Assessments have been carried out by the Reach registrants for substances registered at >10 tpa. No
Chemical Safety Assessment has been carried out for this mixture

SECTION 16: Other information


Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3


H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H372 - Causes damage to organs through prolonged or repeated exposure
H411 - Toxic to aquatic life with long lasting effects

Legend
TWA TWA (time-weighted average)
STEL STEL (Short Term Exposure Limit)
Ceiling Ceiling Limit Value
* Skin designation
SVHC Substance(s) of Very High Concern
PBT Persistent, Bioaccumulative, and Toxic (PBT) Chemicals
vPvB Very Persistent and very Bioaccumulative (vPvB) Chemicals
STOT RE Specific target organ toxicity - Repeated exposure
STOT SE Specific target organ toxicity - Single exposure
EWC European Waste Catalogue

Key literature references and sources for data


No information available

Prepared By Product Safety & Regulatory Affairs

Revision Date: 07-Oct-2020

Indication of changes

Revision note SDS sections updated 3, 8, 11, 12, 15.

Training Advice When working with hazardous materials, regular training of operators is required by law

Further information No information available

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material used in combination with any other materials or in

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any process, unless specified in the text.

End of Safety Data Sheet

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SAFETY DATA SHEET
This safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006 and Regulation (EC) No. 1272/2008
This SDS is for generic information purposes and does not reflect required country specific
information for OEL

BK ARDACOLOR XTREM EASY BEIGE RESIN Revision Date: 07-Oct-2020


Supercedes Date: 16-Sep-2020 Revision Number 2.01

_____________________________________________________________________________________

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product Identifier

Product Name BK ARDACOLOR XTREM EASY BEIGE RESIN


Pure substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Resin.


Uses advised against None known.

1.3. Details of the supplier of the safety data sheet

Company Name
Bostik GmbH
An der Bundesstrasse 16
33829 Borgholzhausen, Germany
Tel: +49 (0) 5425 / 801 0
Fax: +49 (0) 5425 / 801 140

E-mail address [email protected]

1.4. Emergency telephone number

Emergency Telephone

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture

Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 2 - (H315)


Serious eye damage/eye irritation Category 2 - (H319)
Skin sensitisation Category 1 - (H317)
Chronic aquatic toxicity Category 3 - (H412)

2.2. Label Elements

Contains: 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane, 2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(4-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane, Oxirane, mono[(C12-14-alkyloxy)methyl] derivs.

Signal word
WARNING

Hazard statements

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H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H412 - Harmful to aquatic life with long lasting effects.

EU Specific Hazard Statements


EUH211 - Warning! Hazardous respirable droplets may be formed when sprayed. Do not breathe spray or mist.

Precautionary statements
P261 - Avoid breathing vapours/spray.
P280 - Wear protective gloves and eye/face protection.
P302 + P352 - IF ON SKIN: Wash with plenty of water and soap.
P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
P501 - Dispose of contents/ container to an approved waste disposal plant.

Additional information
Please refer also to Safety Data Sheet of Part B.

2.3. Other Hazards

No information available

PBT & vPvB


This mixture contains no substance considered to be persistent, bioaccumulating or toxic (PBT) This mixture contains no
substance considered to be very persistent nor very bioaccumulating (vPvB)

SECTION 3: Composition/information on ingredients


3.1 Substances

Not applicable

Mixtures

Chemical name EC No CAS No Weight-% Classification Specific REACH


according to concentration limit Registration
Regulation (EC) (SCL) Number
No. 1272/2008
[CLP]
Quartz 238-878-4 14808-60-7 40 - <80 ^ [4]
2,2'-[(1-methylethylidene 216-823-5 1675-54-3 10 - <20 Skin Irrit. 2 Eye Irrit. 2 :: C>=5% 01-2119456619-
)bis(4,1-phenyleneoxym (H315) Skin Irrit. 2 :: C>=5% 26-xxxx
ethylene)]bisoxirane Eye Irrit. 2
(H319)
Skin Sens. 1
(H317)
Aquatic Chronic
2 (H411)
2-(2-{ 701-263-0 -- 5 - <10 Aquatic Chronic 01-2119454392-
[2-(oxiran-2-ylmethoxy)p 2 (H411) 40-XXXX
henyl]methyl} Skin Irrit. 2
phenoxymethyl)oxirane; (H315)
2-(2-{ Skin Sens. 1
[4-(oxiran-2-ylmethoxy)p (H317)
henyl]methyl}
phenoxymethyl)oxirane;
2-(4-{
[4-(oxiran-2-ylmethoxy)p
henyl]methyl}

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phenoxymethyl)oxirane
Crystobalite 238-455-4 14464-46-1 5 - <10 - --
Oxirane, 271-846-8 68609-97-2 1 - <5 Skin Irrit. 2 01-2119485289-
mono[(C12-14-alkyloxy) (H315) 22-XXXX
methyl] derivs. Skin Sens. 1
(H317)
Titanium dioxide 236-675-5 13463-67-7 1 - <2.5 Carc. 2 (H351i) 01-2119489379-
17-XXXX
Quartz (fine fraction) 238-878-4 14808-60-7 0.1- <1 STOT RE 1 [4]
(H372)

NOTE [4] - This substance is exempted from registration according to the provisions of Article 2(7)(a) and Annex IV of REACH

Full text of H- and EUH-phrases: see section 16


Note: ^ indicates not classified, however, the substance is listed in section 3 as it has an OEL

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

SECTION 4: First aid measures


4.1. Description of first aid measures

General advice If medical advice is needed, have product container or label at hand.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Consult an
ophthalmologist.

Skin contact May cause an allergic skin reaction. In the case of skin irritation or allergic reactions see
a doctor. Wash off immediately with soap and plenty of water for at least 15 minutes.

Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person. Call a doctor or poison control
centre immediately.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section
8).

4.2. Most important symptoms and effects, both acute and delayed

Symptoms Itching. Rashes. Hives. May cause redness and tearing of the eyes. Burning sensation.

4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors May cause sensitisation in susceptible persons. Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable extinguishing media Full water jet. Do not scatter spilled material with high pressure water streams.

5.2. Special hazards arising from the substance or mixture

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Specific hazards arising from the Product is or contains a sensitiser. May cause sensitisation by skin contact.
chemical

Hazardous combustion products Carbon monoxide. Carbon dioxide (CO2).

5.3. Advice for firefighters

Special protective equipment for Wear self contained breathing apparatus for fire fighting if necessary.
fire-fighters

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure adequate ventilation. Do not breathe vapour or mist. Use personal protective
equipment as required. Avoid contact with skin, eyes or clothing.

Other information Refer to protective measures listed in Sections 7 and 8.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.
Do not allow to enter into soil/subsoil.

6.3. Methods and material for containment and cleaning up

Methods for containment Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal.

Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.

6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage


7.1. Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. Avoid breathing vapours or mists. Use personal protective
equipment as required. Avoid contact with skin, eyes or clothing. Please refer also to
Safety Data Sheet of Part B.

General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and
immediately after handling the product. Take off contaminated clothing and wash it
before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
food, drink and animal feedingstuffs.

7.3. Specific end use(s)

Specific Use(s)
Resin.

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

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Other information Observe technical data sheet.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Exposure Limits

Only European Community Occupational Exposure Limits will be shown in this document. Please refer to regional
SDS for further information.

Chemical name European Union


Quartz TWA: 0.1 mg/m3
14808-60-7
Crystobalite TWA: 0.1 mg/m3
14464-46-1
Quartz (fine fraction) TWA: 0.1 mg/m3
14808-60-7

Derived No Effect Level (DNEL) No information available

Derived No Effect Level (DNEL)


Quartz (14808-60-7)
2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
worker Inhalation 12.25 mg/m³
Long term
Systemic health effects
worker Inhalation 12.25 mg/m³
Short term
Systemic health effects
worker Dermal 8.33 mg/kg bw/d
Long term
Systemic health effects
worker Dermal 8.33 mg/kg bw/d
Short term
Systemic health effects

2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane (--
)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
worker Inhalation 29,39 mg/m³
Long term
Systemic health effects
worker Dermal 104,15 mg/kg bw/d
Long term
Systemic health effects

Titanium dioxide (13463-67-7)


Type Exposure route Derived No Effect Level Safety factor
(DNEL)
worker Inhalation 10 mg/m³
Long term
Local health effects

Derived No Effect Level (DNEL)

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2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
Consumer Dermal 3.571 mg/kg bw/d
Long term
Systemic health effects
Consumer Dermal 3.571 mg/kg bw/d
Short term
Systemic health effects
Consumer Oral 0.75 mg/kg bw/d
Long term
Systemic health effects
Consumer Dermal 0.75 mg/kg bw/d
Short term
Systemic health effects

2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane (--
)
Type Exposure route Derived No Effect Level Safety factor
(DNEL)
Consumer Inhalation 8,7 mg/m³
Long term
Systemic health effects
Consumer Dermal 62,5 mg/kg bw/d
Long term
Systemic health effects
Consumer Oral 6,25 mg/kg bw/d
Long term
Systemic health effects

Titanium dioxide (13463-67-7)


Type Exposure route Derived No Effect Level Safety factor
(DNEL)
Consumer Oral 700 mg/kg bw/d
Long term
Systemic health effects

Quartz (fine fraction) (14808-60-7)

Predicted No Effect Concentration No information available.


(PNEC)

Predicted No Effect Concentration (PNEC)


2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane (1675-54-3)
Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0.006 mg/l
Marine water 0.001 mg/l
Sewage treatment plant 10 mg/l
Freshwater sediment 0.996 mg/kg dry weight
Marine sediment 0.1 mg/kg dry weight
Soil 0.196 mg/kg dry weight

2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane; 2-(2-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl}


phenoxymethyl)oxirane; 2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane (--
)
Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0,003 mg/l
Freshwater - intermittent 0,025 mg/l
Sewage treatment plant 10 mg/l
Marine water 0 mg/l
Freshwater sediment 0,294 mg/kg dry weight

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Marine sediment 0,029 mg/kg dry weight
Soil 0,237 mg/kg dry weight

Crystobalite (14464-46-1)
Titanium dioxide (13463-67-7)
Environmental compartment Predicted No Effect Concentration (PNEC)
Marine water 0.0184 mg/l
Freshwater sediment 1000 mg/kg
Freshwater 0.184 mg/l
Marine sediment 100 mg/kg
Soil 100 mg/kg
Microorganisms in sewage treatment 100 mg/l
Freshwater - intermittent 0.193 mg/l

Quartz (fine fraction) (14808-60-7)


8.2. Exposure controls

Engineering controls Ensure adequate ventilation, especially in confined areas. Please refer also to Safety
Data Sheet of Part B.

Personal Protective Equipment


Eye/face protection Wear safety glasses with side shields (or goggles). Eye protection must conform to
standard EN 166
Hand protection Wear suitable gloves: Nitrile rubber. Butyl rubber. The breakthrough time for the
mentioned glove material is in general greater than 480 min. Ensure that the
breakthrough time of the glove material is not exceeded. Refer to glove supplier for
information on breakthrough time for specific gloves. Gloves should be replaced
regularly and if there is any sign of damage to the glove material. Unsuitable gloves
materials: Leather. Disposable gloves. Gloves must conform to standard EN 374
Skin and body protection Wear suitable protective clothing.
Respiratory protection In case of inadequate ventilation wear respiratory protection. During spraying wear
suitable respiratory equipment.
Recommended filter type: Wear a respirator conforming to EN 140 with Type A/P2 filter or better. Organic gases
and vapours filter conforming to EN 14387.

Environmental exposure controls Do not allow uncontrolled discharge of product into the environment.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties

Physical state Liquid


Appearance Paste
Colour Beige
Odour Characteristic
Odour threshold No information available

Property Values Remarks • Method


pH No data available Not applicable
Melting point / freezing point No data available
Boiling point / boiling range No data available
Flash point 154 °C CC (closed cup)
Evaporation rate No data available
Flammability (solid, gas) Not applicable for liquids .
Flammability Limit in Air
Upper flammability or explosive No data available
limits
Lower flammability or explosive No data available
limits
Vapour pressure No data available
Vapour density No data available
Relative density 1.7 - 1.8
Water solubility Insoluble in water

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Solubility(ies) No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity No data available
Explosive properties No data available
Oxidising properties No data available

9.2. Other information


Solid content (%) No information available
VOC Content (%) No information available
Density 1.7 - 1.8 g/cm³

SECTION 10: Stability and reactivity


10.1. Reactivity

Reactivity Stable under recommended storage conditions.

10.2. Chemical stability

Stability Stable under normal conditions.

Explosion data
Sensitivity to mechanical None.
impact
Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid None known based on information supplied.

10.5. Incompatible materials

Incompatible materials Strong acids. Strong bases. Strong oxidising agents.

10.6. Hazardous decomposition products

Hazardous decomposition None under normal use conditions.


products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure

Product Information .

Inhalation Based on available data, the classification criteria are not met.

Eye contact Causes serious eye irritation.

Skin contact Causes skin irritation. May cause sensitisation by skin contact.

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Ingestion Based on available data, the classification criteria are not met.

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Itching. Rashes. Hives. Redness. May cause redness and tearing of the eyes.

Numerical measures of toxicity

Acute toxicity

The following values are calculated based on chapter 3.1 of the GHS document

Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50


Quartz >2000 mg/kg (Rattus)
14808-60-7
2,2'-[(1-methylethylidene)bis(4, =11300 µL/kg (Rattus) LD50 >2000 mg/Kg (Rattus)
1-phenyleneoxymethylene)]bis
oxirane
1675-54-3
2-(2-{ LD50 > 5000 mg/kg (rattus) LD50 > 2000 mg/kg (rattus)
[2-(oxiran-2-ylmethoxy)phenyl] OECD Guideline 402
methyl}
phenoxymethyl)oxirane; 2-(2-{
[4-(oxiran-2-ylmethoxy)phenyl]
methyl}
phenoxymethyl)oxirane; 2-(4-{
[4-(oxiran-2-ylmethoxy)phenyl]
methyl}
phenoxymethyl)oxirane
--

Oxirane, =17100 mg/kg (Rattus) LD50 >4000 mg/Kg Rabbit


mono[(C12-14-alkyloxy)methyl]
derivs.
68609-97-2
Titanium dioxide >10000 mg/kg (Rattus) LD50 > 10000 mg/Kg >5 mg/l
13463-67-7
Quartz (fine fraction) >2000 mg/kg (Rattus)
14808-60-7

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Causes skin irritation.

Component Information
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. (68609-97-2)
Method Species Exposure route Effective dose Exposure time Results
OECD Test No. 404: Rabbit Dermal 24 hours Product score 5.75
Acute Dermal irritant
Irritation/Corrosion

Quartz (fine fraction) (14808-60-7)

Serious eye damage/eye irritation Causes serious eye irritation.

Component Information
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. (68609-97-2)
Method Species Exposure route Effective dose Exposure time Results

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OECD Test No. 405: Rabbit Corneal Product score 2
Acute Eye irritant
Irritation/Corrosion

Respiratory or skin sensitisation May cause an allergic skin reaction.

Component Information
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. (68609-97-2)
Method Species Exposure route Results
OECD Test No. 406: Skin Guinea pig Dermal sensitising
Sensitisation

Titanium dioxide (13463-67-7)

Germ cell mutagenicity Based on available data, the classification criteria are not met.

Carcinogenicity Based on available data, the classification criteria are not met.
Chemical name European Union
Titanium dioxide Carc. 2
13463-67-7

The table below indicates whether each agency has listed any ingredient as a carcinogen.

Reproductive toxicity Based on available data, the classification criteria are not met.

STOT - single exposure Based on available data, the classification criteria are not met.

STOT - repeated exposure Based on available data, the classification criteria are not met.

Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information


12.1. Toxicity

Ecotoxicity Harmful to aquatic life with long lasting effects.

Chemical name Algae/aquatic Fish Toxicity to Crustacea M-Factor M-Factor


plants microorganisms (long-term)
2,2'-[(1-methylethyliden EC50 (72h) = 1.5 mg/l 96Hr - LD50 (48h) =2.7
e)bis(4,1-phenyleneoxy 9.4 mg/L (Oncorhynchus mg/L (Daphnia
methylene)]bisoxirane (Scenedesmus mykiss) magna)
1675-54-3 capricornutum) (OECD 203) (OECD 202)
EPA-660/3-75-0
09
2-(2-{ EC50 (72h) = LC50 (96h) = - EC50 (48h) =
[2-(oxiran-2-ylmethoxy) 1.8 mg/l 2.54 mg/l 2.55 mg/l
phenyl]methyl} (Daphnia
phenoxymethyl)oxirane magna)
; 2-(2-{
[4-(oxiran-2-ylmethoxy)
phenyl]methyl}
phenoxymethyl)oxirane

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; 2-(4-{
[4-(oxiran-2-ylmethoxy)
phenyl]methyl}
phenoxymethyl)oxirane
--

Titanium dioxide LC50 (96h) - - -


13463-67-7 >10000 mg/l
(Cyprinodon
variegatus)
OECD 203

12.2. Persistence and degradability

Persistence and degradability No information available.

12.3. Bioaccumulative potential

Bioaccumulation There is no data for this product.

Component Information

Chemical name Partition coefficient Bioconcentration factor (BCF)


Quartz - 0
14808-60-7
2,2'-[(1-methylethylidene)bis(4,1-phenylen 3.78 -
eoxymethylene)]bisoxirane
1675-54-3
2-(2-{ 3.6 -
[2-(oxiran-2-ylmethoxy)phenyl]methyl}
phenoxymethyl)oxirane; 2-(2-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl}
phenoxymethyl)oxirane; 2-(4-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl}
phenoxymethyl)oxirane
--

Oxirane, mono[(C12-14-alkyloxy)methyl] 3.77 -


derivs.
68609-97-2

12.4. Mobility in soil

Mobility in soil No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment The components in this formulation do not meet the criteria for classification as PBT or
vPvB. .

Chemical name PBT and vPvB assessment


2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxiran The substance is not PBT / vPvB
e
1675-54-3
2-(2-{ [2-(oxiran-2-ylmethoxy)phenyl]methyl} The substance is not PBT / vPvB
phenoxymethyl)oxirane; 2-(2-{
[4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane;
2-(4-{ [4-(oxiran-2-ylmethoxy)phenyl]methyl} phenoxymethyl)oxirane
--

Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. The substance is not PBT / vPvB

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68609-97-2
Titanium dioxide The substance is not PBT / vPvB
13463-67-7 PBT assessment does not apply

12.6. Other adverse effects

Other adverse effects No information available.

Endocrine Disruptor Information .

Chemical name EU - Endocrine Disrupters EU - Endocrine Disruptors -


Candidate List Evaluated Substances
2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]biso Group II Chemical -
xirane

SECTION 13: Disposal considerations


13.1. Waste treatment methods

Waste from residues/unused Dispose of contents/container in accordance with local, regional, national, and
products international regulations as applicable. Uncured product should be disposed of as
hazardous waste.

Contaminated packaging Handle contaminated packages in the same way as the product itself.

European Waste Catalogue 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous
substances

Other information Waste codes should be assigned by the user based on the application for which the
product was used.

SECTION 14: Transport information


Land transport (ADR/RID)
14.1 UN number Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing group Not regulated
14.5 Environmental hazards Not applicable
14.6 Special Provisions None

IMDG
14.1 UN number Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing group Not regulated
14.5 Marine pollutant Np
14.6 Special Provisions None
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable

Air transport (ICAO-TI / IATA-DGR)


14.1 UN number Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing group Not regulated
14.5 Environmental hazards Not applicable
14.6 Special Provisions None

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Section 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work

Check whether measures in accordance with Directive 94/33/EC for the protection of young people at work must be taken.

Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work

Registration, Evaluation, Authorization, and Restriction of Chemicals (REACh) Regulation (EC 1907/2006)

SVHC: Substances of Very High Concern for Authorisation:


This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

EU-REACH (1907/2006) - Annex XVII - Substances subject to Restriction


This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII).

Substance subject to authorisation per REACH Annex XIV


This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV)

Ozone-depleting substances (ODS) regulation (EC) 1005/2009


Not applicable

Persistent Organic Pollutants


Not applicable

National regulations

France

Chemical name French RG number


Quartz RG 25
14808-60-7
Crystobalite RG 25
14464-46-1
Quartz (fine fraction) RG 25
14808-60-7

Germany

Ordinance on Industrial Safety and Health - Germany - BetrSichV


No flammable liquids in accordance with BetrSichV

Water hazard class (WGK) obviously hazardous to water (WGK 2)

TRGS - 510 Storage Class Storage Class 10 : Combustible liquids

Netherlands

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List of Carcinogenic, mutagenic and reproductive toxin substances in accordance with Inspectorate SZW
(Netherlands)

Chemical name Netherlands


Quartz Present (respirable dust, crystalline)
14808-60-7
Crystobalite Present (respirable dust, crystalline)
14464-46-1
Quartz (fine fraction) Present (respirable dust, crystalline)
14808-60-7

15.2. Chemical safety assessment

Chemical Safety Assessments have been carried out by the Reach registrants for substances registered at >10 tpa. No
Chemical Safety Assessment has been carried out for this mixture

SECTION 16: Other information


Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3


H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H372 - Causes damage to organs through prolonged or repeated exposure
H411 - Toxic to aquatic life with long lasting effects

Legend
TWA TWA (time-weighted average)
STEL STEL (Short Term Exposure Limit)
Ceiling Ceiling Limit Value
* Skin designation
SVHC Substance(s) of Very High Concern
PBT Persistent, Bioaccumulative, and Toxic (PBT) Chemicals
vPvB Very Persistent and very Bioaccumulative (vPvB) Chemicals
STOT RE Specific target organ toxicity - Repeated exposure
STOT SE Specific target organ toxicity - Single exposure
EWC European Waste Catalogue

Key literature references and sources for data


No information available

Prepared By Product Safety & Regulatory Affairs

Revision Date: 07-Oct-2020

Indication of changes

Revision note SDS sections updated: 3, 8, 11, 12, 15.

Training Advice When working with hazardous materials, regular training of operators is required by law

Further information No information available

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,

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transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process, unless specified in the text.

End of Safety Data Sheet

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SAFETY DATA SHEET
This safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006 and Regulation (EC) No. 1272/2008
This SDS is for generic information purposes and does not reflect required country specific
information for OEL

BOSTIK ARDACOLOR XTREM EASY OLD WHITE - PART Revision date 05-May-2020
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Supercedes Date: 04-May-2020 Revision Number 2.06

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SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product Identifier

Product Name BOSTIK ARDACOLOR XTREM EASY OLD WHITE - PART B


Pure substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Curing chemical.


Uses advised against Consumer use.

1.3. Details of the supplier of the safety data sheet

Company Name
Bostik GmbH
An der Bundesstrasse 16
33829 Borgholzhausen, Germany
Tel: +49 (0) 5425 / 801 0
Fax: +49 (0) 5425 / 801 140

E-mail address [email protected]

1.4. Emergency telephone number

Emergency Telephone

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture

Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 1 Sub-category B -


(H314)
Serious eye damage/eye irritation Category 1 - (H318)
Skin sensitisation Category 1 - (H317)

2.2. Label Elements

Contains: Fatty acids, C18-unsatd., dimers, polymeric reaction products with tall-oil fatty acids and triethylenetetramine,
Isophorone diamine, 3-(Triethoxysilyl) propylamine

Signal word
DANGER

Hazard statements

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H317 - May cause an allergic skin reaction.
H314 - Causes severe skin burns and eye damage.

Precautionary statements
P101 - If medical advice is needed, have product container or label at hand.
P260 - Do not breathe mist/vapours/spray.
P280 - Wear protective gloves/protective clothing and eye/face protection.
P302 + P352 - IF ON SKIN: Wash with plenty of water and soap.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER or doctor.
P501 - Dispose of contents/ container to an approved waste disposal plant.

Additional information
This product requires tactile warnings if supplied to the general public. This product requires child resistant fastenings if
supplied to the general public. Please refer also to Safety Data Sheet of Part A.

2.3. Other Hazards

Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product
Small amounts of ethanol (CAS 64-17-5) are formed by hydrolysis and released upon curing

PBT & vPvB


This mixture contains no substance considered to be persistent, bioaccumulating or toxic (PBT) This mixture contains no
substance considered to be very persistent nor very bioaccumulating (vPvB)

SECTION 3: Composition/information on ingredients


3.1 Substances

Mixture

3.2. Mixtures Mixtures

Chemical name EC No CAS No Weight-% Classification Specific REACH


according to concentration limit Registration
Regulation (EC) (SCL) Number
No. 1272/2008
[CLP]
Fatty acids, - 68082-29-1 10 - <20 Eye Irrit. 2 [7]
C18-unsatd., dimers, (H319)
polymeric reaction Skin Irrit. 2
products with tall-oil fatty (H315)
acids and Skin Sens. 1
triethylenetetramine (H317)

Isophorone diamine 220-666-8 2855-13-2 5 - <10 Acute Tox. 4 01-2119514687-


(H302) 32-XXXX
Acute Tox. 4
(H312)
Skin Corr. 1B
(H314)
Eye Dam. 1
(H318)
Skin Sens. 1
(H317)
Aquatic Chronic
3 (H412)
Benzyl alcohol 202-859-9 100-51-6 1 - <5 Acute Tox. 4 01-2119492630-
(H302) 38-XXXX

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Acute Tox. 4
(H332)
Eye Irrit. 2
(H319)

3-(Triethoxysilyl) 213-048-4 919-30-2 1 - <2.5 Skin Corr. 1B 01-2119480479-


propylamine (H314) 24-XXXX
Skin Sens. 1
(H317)
Acute Tox. 4
(H302)

Benzyldimethylamine 203-149-1 103-83-3 0.1- <1 Acute Tox. 4 01-2119529232-


(H302) 48-XXXX
Acute Tox. 4
(H312)
Acute Tox. 3
(H331)
Skin Corr. 1B
(H314)
Aquatic Chronic
3 (H412)
Flam. Liq. 3
(H226)
NOTE [7] - No registration number is given for this substance because it is a polymer exempted from registration according to the provisions of
Article 2(9) of REACH. All monomers or other substances within the polymer are registered or exempt from registration

Full text of H- and EUH-phrases: see section 16


Note: ^ indicates not classified, however, the substance is listed in section 3 as it has an OEL

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

SECTION 4: First aid measures


4.1. Description of first aid measures

General advice If medical advice is needed, have product container or label at hand. Take a copy of the
Safety Data Sheet when going for medical treatment.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses
and continue flushing for at least 15 minutes. Consult an ophthalmologist.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Get immediate medical advice/attention. May cause an allergic skin
reaction.

Ingestion Do NOT induce vomiting. Rinse mouth thoroughly with water. Never give anything by
mouth to an unconscious person. Call a doctor or poison control centre immediately.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section
8).

4.2. Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation. Itching. Rashes. Hives.

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4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors Product is a corrosive material. Use of gastric lavage or emesis is contra-indicated.
Possible perforation of stomach or esophagus should be investigated. Do not give
chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood
pressure may occur with moist rales, frothy sputum, and high pulse pressure. May cause
sensitisation in susceptible persons. Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable extinguishing media Full water jet. Do not scatter spilled material with high pressure water streams.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the Thermal decomposition can lead to release of irritating gases and vapours.
chemical

Hazardous combustion products Carbon monoxide. Carbon dioxide (CO2). Nitrogen oxides (NOx). Ammonia.

5.3. Advice for firefighters

Special protective equipment for Wear self contained breathing apparatus for fire fighting if necessary.
fire-fighters

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Attention! Corrosive material. Ensure adequate ventilation. Do not breathe
dust/fume/gas/mist/vapours/spray. Use personal protective equipment as required. Avoid
contact with skin, eyes or clothing.

Other information Refer to protective measures listed in Sections 7 and 8.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions Prevent product from entering drains. Do not allow to enter into soil/subsoil.

6.3. Methods and material for containment and cleaning up

Methods for containment Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal.

Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.

6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage


7.1. Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. Do not breathe dust/fume/gas/mist/vapours/spray. In case

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of insufficient ventilation, wear suitable respiratory equipment. Use personal protection
equipment. Avoid contact with skin, eyes or clothing. Please refer also to Safety Data
Sheet of Part A.

General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and
immediately after handling the product. Take off contaminated clothing and wash it
before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from
moisture.

7.3. Specific end use(s)

Specific Use(s)
Curing chemical.

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

Other information Observe technical data sheet.

SECTION 8: Exposure controls/Personal protection


8.1. Control parameters

Exposure Limits Small amounts of ethanol (CAS 64-17-5) are formed by hydrolysis and released upon
curing This product contains crystalline silica (quartz) in a non-respirable form. Inhalation
of crystalline silica is unlikely to occur from exposure to this product

Only European Community Occupational Exposure Limits will be shown in this document. Please refer to regional
SDS for further information.

Chemical name European Union


Quartz TWA: 0.1 mg/m3
14808-60-7
Quartz (fine fraction) TWA: 0.1 mg/m3
14808-60-7

Derived No Effect Level (DNEL) No information available

Derived No Effect Level (DNEL)


Isophorone diamine (2855-13-2)
Type worker
Exposure route Inhalation
Derived No Effect Level (DNEL) 0.073 mg/m³

Benzyl alcohol (100-51-6)


Type worker Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 22 mg/m³

Type worker Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 110 mg/m³

Type worker Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 8 mg/kg bw/d

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Type worker Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 40 mg/kg bw/d

3-(Triethoxysilyl) propylamine (919-30-2)


Type worker Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 59 mg/m³

Type worker Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 59 mg/m³

Type worker Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 8.3 mg/kg bw/d

Type worker Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 8.3 mg/kg bw/d

Derived No Effect Level (DNEL)


Benzyl alcohol (100-51-6)
Type Consumer Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 5.4 mg/m³

Type Consumer Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 27 mg/m³

Type Consumer Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 4 mg/kg bw/d

Type Consumer Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 20 mg/kg bw/d

Type Consumer Long term Systemic health effects


Exposure route Oral
Derived No Effect Level (DNEL) 4 mg/kg bw/d

Type Consumer Short term Systemic health effects


Exposure route Oral
Derived No Effect Level (DNEL) 20 mg/kg bw/d

3-(Triethoxysilyl) propylamine (919-30-2)


Type Consumer Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 17 mg/m³

Type Consumer Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 17.4 mg/m³

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Type Consumer Long term Systemic health effects
Exposure route Dermal
Derived No Effect Level (DNEL) 5 mg/kg bw/d

Type Consumer Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 5 mg/kg bw/d

Predicted No Effect Concentration No information available.


(PNEC)

Predicted No Effect Concentration (PNEC)


Isophorone diamine (2855-13-2)
Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0.094 mg/l
Marine water 0.0094 mg/l

Benzyl alcohol (100-51-6)


Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 1 mg/l
Marine water 0.1 mg/l
Microorganisms in sewage treatment 39 mg/l
Freshwater sediment 5.27 mg/kg dry weight
Marine sediment 0.527 mg/kg dry weight
Soil 0.456 mg/kg dry weight
Freshwater - intermittent 2,3 mg/l

3-(Triethoxysilyl) propylamine (919-30-2)


Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0.33 mg/l
Marine water 0.033 mg/l

8.2. Exposure controls

Engineering controls Use with local exhaust ventilation. Ensure adequate ventilation, especially in confined
areas.

Personal Protective Equipment


Eye/face protection Goggles. or. Face protection shield. Eye protection must conform to standard EN 166
Hand protection Wear suitable gloves. Recommended Use:. Nitrile rubber. Butyl rubber. Glove thickness
> 0.7mm. Ensure that the breakthrough time of the glove material is not exceeded. Refer
to glove supplier for information on breakthrough time for specific gloves. The
breakthrough time for the mentioned glove material is in general greater than 240 min.
Unsuitable gloves materials:. Leather. Disposable gloves. Gloves must conform to
standard EN 374
Skin and body protection Suitable protective clothing.
Respiratory protection During spraying wear suitable respiratory equipment. In case of insufficient ventilation,
wear suitable respiratory equipment.
Recommended filter type: Wear a respirator conforming to EN 140 with Type A/P2 filter or better. Organic gases
and vapours filter conforming to EN 14387.

Environmental exposure controls Do not allow uncontrolled discharge of product into the environment.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties

Physical state Liquid


Appearance Viscous
Colour Beige White

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Odour Amine
Odour threshold No information available

Property Values Remarks • Method


pH No data available
Melting point / freezing point No data available
Boiling point / boiling range No data available
Flash point No data available
Evaporation rate No data available
Flammability (solid, gas) Not applicable for liquids .
Flammability Limit in Air
Upper flammability or explosive No data available
limits
Lower flammability or explosive No data available
limits
Vapour pressure No data available
Vapour density No data available
Relative density 1.6
Water solubility Insoluble
Solubility(ies) No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity No data available
Explosive properties No data available
Oxidising properties No data available

9.2. Other information


Solid content (%) No information available
VOC Content (%) approx. 5% Swiss ordinance on the Incentive Tax on Volatile
Organic Compounds of 12 Nov 1997
Density 1.5 - 1.7 g/cm³

SECTION 10: Stability and reactivity


10.1. Reactivity

Reactivity Stable under recommended storage conditions.

10.2. Chemical stability

Stability Stable under normal conditions.

Explosion Data
Sensitivity to mechanical None.
impact
Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid Exposure to air or moisture over prolonged periods.

10.5. Incompatible materials

Incompatible materials Oxidising agent. Acids. Bases.

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10.6. Hazardous decomposition products

Hazardous decomposition Stable under recommended storage conditions.


products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure

Product Information .

Inhalation Based on available data, the classification criteria are not met.

Eye contact Causes serious eye damage.

Skin contact Causes severe burns. May cause sensitisation by skin contact.

Ingestion Based on available data, the classification criteria are not met.

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Redness. Burning. May cause blindness. Coughing and/ or wheezing. Itching. Rashes.
Hives.

Numerical measures of toxicity

Acute Toxicity

The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 6,036.70 mg/kg
ATEmix (dermal) 9,273.60 mg/kg
ATEmix (inhalation-dust/mist) 32.73 mg/l
ATEmix (inhalation-vapour) 320.80 mg/l

Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50


Isophorone diamine =1040 mg/kg (Rattus) LD50 > 2000 mg/kg (Rattus)
2855-13-2 OECD 402
LD50 = 1840 mg/kg
(Oryctolagus cuniculus)
Benzyl alcohol LD50 = 1620 mg/kg (Rattus) = 2 g/kg (Oryctolagus >4.17 mg/L (Rattus) 4 h
100-51-6 cuniculus)
3-(Triethoxysilyl) propylamine LD50 = 1490 mg/kg (Rat, LD50 = 4075 mg/kg LC50 >144 mg/L (6h) Rat
919-30-2 female) EPA OTS 798.1175 (Oryctolagus cuniculus) EPA (Vapour)
OTS 798.1100
Benzyldimethylamine =579 mg/kg (Rattus) = 1.66 mL/kg (Oryctolagus LC50 (4h) =2.052 mg/L
103-83-3 cuniculus) = 1660 mg/kg (Rattus)
(Oryctolagus cuniculus)

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Causes severe burns.

Serious eye damage/eye irritation Causes serious eye damage.

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Respiratory or skin sensitisation May cause an allergic skin reaction.

Germ cell mutagenicity Based on available data, the classification criteria are not met.

Carcinogenicity Based on available data, the classification criteria are not met.

Reproductive toxicity Based on available data, the classification criteria are not met.

STOT - single exposure Based on available data, the classification criteria are not met.

STOT - repeated exposure Based on available data, the classification criteria are not met.

Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information


12.1. Toxicity

Ecotoxicity .

Chemical name Algae/aquatic Fish Toxicity to Crustacea M-Factor M-Factor


plants Micro-organisms (long-term)
Fatty acids, - LC50: - -
C18-unsatd., dimers, =7.07mg/L (96h,
polymeric reaction Danio rerio)
products with tall-oil
fatty acids and
triethylenetetramine
68082-29-1
Isophorone diamine EC50: =37mg/L LC50: - EC50: =42mg/L
2855-13-2 (72h, =110mg/L (96h, (24h, Daphnia
Desmodesmus Leuciscus idus) magna) EC50:
subspicatus) 14.6 - 21.5mg/L
(48h, Daphnia
magna)
Benzyl alcohol EC 50 (72h) = LC50 96 h = EC50 = 50 mg/L EC50 48 h =
100-51-6 700 mg/L 460 mg/L 5 min 230 mg/L
(Pseudokirchner (Pimephales EC50 = 63.7 (Daphnia
ella subcapitata) promelas static) mg/L 15 min magna)
OECD 201 EC50 = 63.7
mg/L 5 min
EC50 = 71.4
mg/L 30 min
3-(Triethoxysilyl) EC50 (72h) LC50 (96h) - EC50 (48h)
propylamine >1000 mg/L >934 mg/L =331 mg/L
919-30-2 Green algae (Brachydanio Daphnia magna
(desmodesmus rerio) (OECD (OECD TG 202)
subspicatus) TG 203)
(OECD TG 201)
Benzyldimethylamine - LC50: 35.8 - - -
103-83-3 39.9mg/L (96h,
Pimephales
promelas)

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12.2. Persistence and degradability

Persistence and degradability No information available.

12.3. Bioaccumulative potential

Bioaccumulation There is no data for this product.

Component Information

Chemical name Partition coefficient Bioconcentration factor (BCF)


Isophorone diamine 0.79 -
2855-13-2
Benzyl alcohol 1.1 -
100-51-6
3-(Triethoxysilyl) propylamine 1.7 3.4
919-30-2

12.4. Mobility in soil

Mobility in soil No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment . The components in this formulation do not meet the criteria for classification as PBT or
vPvB.

Chemical name PBT and vPvB assessment


Fatty acids, C18-unsatd., dimers, polymeric reaction products with The substance is not PBT / vPvB
tall-oil fatty acids and triethylenetetramine
68082-29-1
Isophorone diamine The substance is not PBT / vPvB
2855-13-2
Benzyl alcohol The substance is not PBT / vPvB
100-51-6
3-(Triethoxysilyl) propylamine The substance is not PBT / vPvB
919-30-2
Benzyldimethylamine The substance is not PBT / vPvB
103-83-3

12.6. Other adverse effects

Other adverse effects No information available.

SECTION 13: Disposal considerations


13.1. Waste treatment methods

Waste from residues/unused Uncured product should be disposed of as hazardous waste. Dispose of
products contents/container in accordance with local, regional, national, and international
regulations as applicable.

Contaminated packaging Do not reuse empty containers. Handle contaminated packages in the same way as the
product itself.

European Waste Catalogue 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous
substances

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15 01 10*: Packaging containing residues of or contaminated by dangerous substances

Other information Waste codes should be assigned by the user based on the application for which the
product was used.

SECTION 14: Transport information


Land transport (ADR/RID)
14.1 UN Number UN2735
14.2 Proper Shipping Name Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl) propylamine)
14.3 Transport hazard class(es) 8
Labels 8
14.4 Packing Group III
Description UN2735, Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl)
propylamine), 8, III, (E)
14.5 Environmental hazards Not applicable
14.6 Special Provisions 274
Classification Code C7
Tunnel restriction code (E)
Limited Quantity (LQ) 5L
ADR Hazard Id (Kemmler 80
Number)

IMDG
14.1 UN number UN2735
14.2 Proper Shipping Name Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl) propylamine)
14.3 Transport hazard class(es) 8
14.4 Packing group III
Description UN2735, Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl)
propylamine), 8, III
14.5 Marine Pollutant Np
14.6 Special Provisions 223, 274
Limited Quantity (LQ) 5L
EmS-No. F-A, S-B
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable

Air transport (ICAO-TI / IATA-DGR)


14.1 UN number UN2735
14.2 Proper Shipping Name Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl) propylamine)
14.3 Transport hazard class(es) 8
14.4 Packing group III
Description UN2735, Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl)
propylamine), 8, III
14.5 Environmental hazards Not applicable
14.6 Special Provisions A3, A803
Limited Quantity (LQ) 1L
ERG Code 8L

Section 15: REGULATORY INFORMATION


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work

Check whether measures in accordance with Directive 94/33/EC for the protection of young people at work must be taken.

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Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work

Registration, Evaluation, Authorization, and Restriction of Chemicals (REACh) Regulation (EC 1907/2006)

SVHC: Substances of Very High Concern for Authorisation:


This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

EU-REACH (1907/2006) - Annex XVII - Substances subject to Restriction


This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII).

Substance subject to authorisation per REACH Annex XIV


This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV)

Ozone-depleting substances (ODS) regulation (EC) 1005/2009


Not applicable

Persistent Organic Pollutants


Not applicable

National Regulations

France

Occupational Illnesses (R-463-3, France)

Chemical name French RG number


Isophorone diamine RG 49,RG 49bis,RG 66
2855-13-2
Benzyl alcohol RG 84
100-51-6

Germany

Ordinance on Industrial Safety and Health - Germany - BetrSichV


No flammable liquids in accordance with BetrSichV

Water hazard class (WGK) obviously hazardous to water (WGK 2)

TRGS - 510 Storage Class Storage Class 8A: Combustible corrosive substances

Netherlands

List of Carcinogenic, mutagenic and reproductive toxin substances in accordance with Inspectorate SZW
(Netherlands)

15.2. Chemical safety assessment

Chemical Safety Assessments have been carried out by the Reach registrants for substances registered at >10 tpa. No
Chemical Safety Assessment has been carried out for this mixture

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SECTION 16: Other information
Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3


H226 - Flammable liquid and vapour
H302 - Harmful if swallowed
H312 - Harmful in contact with skin
H314 - Causes severe skin burns and eye damage
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H319 - Causes serious eye irritation
H331 - Toxic if inhaled
H332 - Harmful if inhaled
H412 - Harmful to aquatic life with long lasting effects

Legend
TWA TWA (time-weighted average)
STEL STEL (Short Term Exposure Limit)
Ceiling Ceiling Limit Value
* Skin designation
SVHC Substance(s) of Very High Concern
PBT Persistent, Bioaccumulative, and Toxic (PBT) Chemicals
vPvB Very Persistent and very Bioaccumulative (vPvB) Chemicals
STOT RE Specific target organ toxicity - Repeated exposure
STOT SE Specific target organ toxicity - Single exposure
EWC European Waste Catalogue

Key literature references and sources for data


No information available

Prepared By Product Safety & Regulatory Affairs

Revision date 05-May-2020

Indication of changes

Revision note SDS sections updated: 1, 11, 13.

Training Advice When working with hazardous materials, regular training of operators is required by law

Further information No information available

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process, unless specified in the text.

End of Safety Data Sheet

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SAFETY DATA SHEET
This safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006 and Regulation (EC) No. 1272/2008
This SDS is for generic information purposes and does not reflect required country specific
information for OEL

BOSTIK ARDACOLOR XTREM EASY MEDIUM GREY - Revision date 05-May-2020


PART B
Supercedes Date: 04-May-2020 Revision Number 2.06

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SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product Identifier

Product Name BOSTIK ARDACOLOR XTREM EASY MEDIUM GREY - PART B


Pure substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Curing chemical.


Uses advised against Consumer use.

1.3. Details of the supplier of the safety data sheet

Company Name
Bostik GmbH
An der Bundesstrasse 16
33829 Borgholzhausen, Germany
Tel: +49 (0) 5425 / 801 0
Fax: +49 (0) 5425 / 801 140

E-mail address [email protected]

1.4. Emergency telephone number

Emergency Telephone

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture

Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 1 Sub-category B -


(H314)
Serious eye damage/eye irritation Category 1 - (H318)
Skin sensitisation Category 1 - (H317)

2.2. Label Elements

Contains: Fatty acids, C18-unsatd., dimers, polymeric reaction products with tall-oil fatty acids and triethylenetetramine,
Isophorone diamine, 3-(Triethoxysilyl) propylamine

Signal word
DANGER

Hazard statements

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H317 - May cause an allergic skin reaction.
H314 - Causes severe skin burns and eye damage.

Precautionary statements
P101 - If medical advice is needed, have product container or label at hand.
P260 - Do not breathe mist/vapours/spray.
P280 - Wear protective gloves/protective clothing and eye/face protection.
P302 + P352 - IF ON SKIN: Wash with plenty of water and soap.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER or doctor.
P501 - Dispose of contents/ container to an approved waste disposal plant.

Additional information
This product requires tactile warnings if supplied to the general public. This product requires child resistant fastenings if
supplied to the general public. Please refer also to Safety Data Sheet of Part A.

2.3. Other Hazards

Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product
Small amounts of ethanol (CAS 64-17-5) are formed by hydrolysis and released upon curing

PBT & vPvB


This mixture contains no substance considered to be persistent, bioaccumulating or toxic (PBT) This mixture contains no
substance considered to be very persistent nor very bioaccumulating (vPvB)

SECTION 3: Composition/information on ingredients


3.1 Substances

Mixture

3.2. Mixtures Mixtures

Chemical name EC No CAS No Weight-% Classification Specific REACH


according to concentration limit Registration
Regulation (EC) (SCL) Number
No. 1272/2008
[CLP]
Fatty acids, - 68082-29-1 10 - <20 Eye Irrit. 2 [7]
C18-unsatd., dimers, (H319)
polymeric reaction Skin Irrit. 2
products with tall-oil fatty (H315)
acids and Skin Sens. 1
triethylenetetramine (H317)

Isophorone diamine 220-666-8 2855-13-2 5 - <10 Acute Tox. 4 01-2119514687-


(H302) 32-XXXX
Acute Tox. 4
(H312)
Skin Corr. 1B
(H314)
Eye Dam. 1
(H318)
Skin Sens. 1
(H317)
Aquatic Chronic
3 (H412)
Benzyl alcohol 202-859-9 100-51-6 1 - <5 Acute Tox. 4 01-2119492630-
(H302) 38-XXXX

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Acute Tox. 4
(H332)
Eye Irrit. 2
(H319)

3-(Triethoxysilyl) 213-048-4 919-30-2 1 - <2.5 Skin Corr. 1B 01-2119480479-


propylamine (H314) 24-XXXX
Skin Sens. 1
(H317)
Acute Tox. 4
(H302)

Benzyldimethylamine 203-149-1 103-83-3 0.1- <1 Acute Tox. 4 01-2119529232-


(H302) 48-XXXX
Acute Tox. 4
(H312)
Acute Tox. 3
(H331)
Skin Corr. 1B
(H314)
Aquatic Chronic
3 (H412)
Flam. Liq. 3
(H226)
NOTE [7] - No registration number is given for this substance because it is a polymer exempted from registration according to the provisions of
Article 2(9) of REACH. All monomers or other substances within the polymer are registered or exempt from registration

Full text of H- and EUH-phrases: see section 16


Note: ^ indicates not classified, however, the substance is listed in section 3 as it has an OEL

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

SECTION 4: First aid measures


4.1. Description of first aid measures

General advice If medical advice is needed, have product container or label at hand. Take a copy of the
Safety Data Sheet when going for medical treatment.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses
and continue flushing for at least 15 minutes. Consult an ophthalmologist.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Get immediate medical advice/attention. May cause an allergic skin
reaction.

Ingestion Do NOT induce vomiting. Rinse mouth thoroughly with water. Never give anything by
mouth to an unconscious person. Call a doctor or poison control centre immediately.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section
8).

4.2. Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation. Itching. Rashes. Hives.

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4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors Product is a corrosive material. Use of gastric lavage or emesis is contra-indicated.
Possible perforation of stomach or esophagus should be investigated. Do not give
chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood
pressure may occur with moist rales, frothy sputum, and high pulse pressure. May cause
sensitisation in susceptible persons. Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable extinguishing media Full water jet. Do not scatter spilled material with high pressure water streams.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the Thermal decomposition can lead to release of irritating gases and vapours.
chemical

Hazardous combustion products Carbon monoxide. Carbon dioxide (CO2). Nitrogen oxides (NOx). Ammonia.

5.3. Advice for firefighters

Special protective equipment for Wear self contained breathing apparatus for fire fighting if necessary.
fire-fighters

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Attention! Corrosive material. Ensure adequate ventilation. Do not breathe
dust/fume/gas/mist/vapours/spray. Use personal protective equipment as required. Avoid
contact with skin, eyes or clothing.

Other information Refer to protective measures listed in Sections 7 and 8.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions Prevent product from entering drains. Do not allow to enter into soil/subsoil.

6.3. Methods and material for containment and cleaning up

Methods for containment Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal.

Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.

6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage


7.1. Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. Do not breathe dust/fume/gas/mist/vapours/spray. In case

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of insufficient ventilation, wear suitable respiratory equipment. Use personal protection
equipment. Avoid contact with skin, eyes or clothing. Please refer also to Safety Data
Sheet of Part A.

General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and
immediately after handling the product. Take off contaminated clothing and wash it
before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from
moisture.

7.3. Specific end use(s)

Specific Use(s)
Curing chemical.

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

Other information Observe technical data sheet.

SECTION 8: Exposure controls/Personal protection


8.1. Control parameters

Exposure Limits Small amounts of ethanol (CAS 64-17-5) are formed by hydrolysis and released upon
curing This product contains crystalline silica (quartz) in a non-respirable form. Inhalation
of crystalline silica is unlikely to occur from exposure to this product

Only European Community Occupational Exposure Limits will be shown in this document. Please refer to regional
SDS for further information.

Chemical name European Union


Quartz TWA: 0.1 mg/m3
14808-60-7
Quartz (fine fraction) TWA: 0.1 mg/m3
14808-60-7

Derived No Effect Level (DNEL) No information available

Derived No Effect Level (DNEL)


Isophorone diamine (2855-13-2)
Type worker
Exposure route Inhalation
Derived No Effect Level (DNEL) 0.073 mg/m³

Benzyl alcohol (100-51-6)


Type worker Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 22 mg/m³

Type worker Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 110 mg/m³

Type worker Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 8 mg/kg bw/d

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Type worker Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 40 mg/kg bw/d

3-(Triethoxysilyl) propylamine (919-30-2)


Type worker Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 59 mg/m³

Type worker Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 59 mg/m³

Type worker Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 8.3 mg/kg bw/d

Type worker Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 8.3 mg/kg bw/d

Derived No Effect Level (DNEL)


Benzyl alcohol (100-51-6)
Type Consumer Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 5.4 mg/m³

Type Consumer Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 27 mg/m³

Type Consumer Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 4 mg/kg bw/d

Type Consumer Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 20 mg/kg bw/d

Type Consumer Long term Systemic health effects


Exposure route Oral
Derived No Effect Level (DNEL) 4 mg/kg bw/d

Type Consumer Short term Systemic health effects


Exposure route Oral
Derived No Effect Level (DNEL) 20 mg/kg bw/d

3-(Triethoxysilyl) propylamine (919-30-2)


Type Consumer Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 17 mg/m³

Type Consumer Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 17.4 mg/m³

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Type Consumer Long term Systemic health effects
Exposure route Dermal
Derived No Effect Level (DNEL) 5 mg/kg bw/d

Type Consumer Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 5 mg/kg bw/d

Predicted No Effect Concentration No information available.


(PNEC)

Predicted No Effect Concentration (PNEC)


Isophorone diamine (2855-13-2)
Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0.094 mg/l
Marine water 0.0094 mg/l

Benzyl alcohol (100-51-6)


Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 1 mg/l
Marine water 0.1 mg/l
Microorganisms in sewage treatment 39 mg/l
Freshwater sediment 5.27 mg/kg dry weight
Marine sediment 0.527 mg/kg dry weight
Soil 0.456 mg/kg dry weight
Freshwater - intermittent 2,3 mg/l

3-(Triethoxysilyl) propylamine (919-30-2)


Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0.33 mg/l
Marine water 0.033 mg/l

8.2. Exposure controls

Engineering controls Use with local exhaust ventilation. Ensure adequate ventilation, especially in confined
areas.

Personal Protective Equipment


Eye/face protection Goggles. or. Face protection shield. Eye protection must conform to standard EN 166
Hand protection Wear suitable gloves. Recommended Use:. Nitrile rubber. Butyl rubber. Glove thickness
> 0.7mm. Ensure that the breakthrough time of the glove material is not exceeded. Refer
to glove supplier for information on breakthrough time for specific gloves. The
breakthrough time for the mentioned glove material is in general greater than 240 min.
Unsuitable gloves materials:. Leather. Disposable gloves. Gloves must conform to
standard EN 374
Skin and body protection Suitable protective clothing.
Respiratory protection During spraying wear suitable respiratory equipment. In case of insufficient ventilation,
wear suitable respiratory equipment.
Recommended filter type: Wear a respirator conforming to EN 140 with Type A/P2 filter or better. Organic gases
and vapours filter conforming to EN 14387.

Environmental exposure controls Do not allow uncontrolled discharge of product into the environment.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties

Physical state Liquid


Appearance Viscous
Colour Beige White

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Odour Amine
Odour threshold No information available

Property Values Remarks • Method


pH No data available
Melting point / freezing point No data available
Boiling point / boiling range No data available
Flash point No data available
Evaporation rate No data available
Flammability (solid, gas) Not applicable for liquids .
Flammability Limit in Air
Upper flammability or explosive No data available
limits
Lower flammability or explosive No data available
limits
Vapour pressure No data available
Vapour density No data available
Relative density 1.6
Water solubility Insoluble
Solubility(ies) No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity No data available
Explosive properties No data available
Oxidising properties No data available

9.2. Other information


Solid content (%) No information available
VOC Content (%) approx. 5% Swiss ordinance on the Incentive Tax on Volatile
Organic Compounds of 12 Nov 1997
Density 1.5 - 1.7 g/cm³

SECTION 10: Stability and reactivity


10.1. Reactivity

Reactivity Stable under recommended storage conditions.

10.2. Chemical stability

Stability Stable under normal conditions.

Explosion Data
Sensitivity to mechanical None.
impact
Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid Exposure to air or moisture over prolonged periods.

10.5. Incompatible materials

Incompatible materials Oxidising agent. Acids. Bases.

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10.6. Hazardous decomposition products

Hazardous decomposition Stable under recommended storage conditions.


products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure

Product Information .

Inhalation Based on available data, the classification criteria are not met.

Eye contact Causes serious eye damage.

Skin contact Causes severe burns. May cause sensitisation by skin contact.

Ingestion Based on available data, the classification criteria are not met.

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Redness. Burning. May cause blindness. Coughing and/ or wheezing. Itching. Rashes.
Hives.

Numerical measures of toxicity

Acute Toxicity

The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 6,036.70 mg/kg
ATEmix (dermal) 9,273.60 mg/kg
ATEmix (inhalation-dust/mist) 32.73 mg/l
ATEmix (inhalation-vapour) 320.80 mg/l

Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50


Isophorone diamine =1040 mg/kg (Rattus) LD50 > 2000 mg/kg (Rattus)
2855-13-2 OECD 402
LD50 = 1840 mg/kg
(Oryctolagus cuniculus)
Benzyl alcohol LD50 = 1620 mg/kg (Rattus) = 2 g/kg (Oryctolagus >4.17 mg/L (Rattus) 4 h
100-51-6 cuniculus)
3-(Triethoxysilyl) propylamine LD50 = 1490 mg/kg (Rat, LD50 = 4075 mg/kg LC50 >144 mg/L (6h) Rat
919-30-2 female) EPA OTS 798.1175 (Oryctolagus cuniculus) EPA (Vapour)
OTS 798.1100
Benzyldimethylamine =579 mg/kg (Rattus) = 1.66 mL/kg (Oryctolagus LC50 (4h) =2.052 mg/L
103-83-3 cuniculus) = 1660 mg/kg (Rattus)
(Oryctolagus cuniculus)

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Causes severe burns.

Serious eye damage/eye irritation Causes serious eye damage.

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Respiratory or skin sensitisation May cause an allergic skin reaction.

Germ cell mutagenicity Based on available data, the classification criteria are not met.

Carcinogenicity Based on available data, the classification criteria are not met.

Reproductive toxicity Based on available data, the classification criteria are not met.

STOT - single exposure Based on available data, the classification criteria are not met.

STOT - repeated exposure Based on available data, the classification criteria are not met.

Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information


12.1. Toxicity

Ecotoxicity .

Chemical name Algae/aquatic Fish Toxicity to Crustacea M-Factor M-Factor


plants Micro-organisms (long-term)
Fatty acids, - LC50: - -
C18-unsatd., dimers, =7.07mg/L (96h,
polymeric reaction Danio rerio)
products with tall-oil
fatty acids and
triethylenetetramine
68082-29-1
Isophorone diamine EC50: =37mg/L LC50: - EC50: =42mg/L
2855-13-2 (72h, =110mg/L (96h, (24h, Daphnia
Desmodesmus Leuciscus idus) magna) EC50:
subspicatus) 14.6 - 21.5mg/L
(48h, Daphnia
magna)
Benzyl alcohol EC 50 (72h) = LC50 96 h = EC50 = 50 mg/L EC50 48 h =
100-51-6 700 mg/L 460 mg/L 5 min 230 mg/L
(Pseudokirchner (Pimephales EC50 = 63.7 (Daphnia
ella subcapitata) promelas static) mg/L 15 min magna)
OECD 201 EC50 = 63.7
mg/L 5 min
EC50 = 71.4
mg/L 30 min
3-(Triethoxysilyl) EC50 (72h) LC50 (96h) - EC50 (48h)
propylamine >1000 mg/L >934 mg/L =331 mg/L
919-30-2 Green algae (Brachydanio Daphnia magna
(desmodesmus rerio) (OECD (OECD TG 202)
subspicatus) TG 203)
(OECD TG 201)
Benzyldimethylamine - LC50: 35.8 - - -
103-83-3 39.9mg/L (96h,
Pimephales
promelas)

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12.2. Persistence and degradability

Persistence and degradability No information available.

12.3. Bioaccumulative potential

Bioaccumulation There is no data for this product.

Component Information

Chemical name Partition coefficient Bioconcentration factor (BCF)


Isophorone diamine 0.79 -
2855-13-2
Benzyl alcohol 1.1 -
100-51-6
3-(Triethoxysilyl) propylamine 1.7 3.4
919-30-2

12.4. Mobility in soil

Mobility in soil No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment . The components in this formulation do not meet the criteria for classification as PBT or
vPvB.

Chemical name PBT and vPvB assessment


Fatty acids, C18-unsatd., dimers, polymeric reaction products with The substance is not PBT / vPvB
tall-oil fatty acids and triethylenetetramine
68082-29-1
Isophorone diamine The substance is not PBT / vPvB
2855-13-2
Benzyl alcohol The substance is not PBT / vPvB
100-51-6
3-(Triethoxysilyl) propylamine The substance is not PBT / vPvB
919-30-2
Benzyldimethylamine The substance is not PBT / vPvB
103-83-3

12.6. Other adverse effects

Other adverse effects No information available.

SECTION 13: Disposal considerations


13.1. Waste treatment methods

Waste from residues/unused Uncured product should be disposed of as hazardous waste. Dispose of
products contents/container in accordance with local, regional, national, and international
regulations as applicable.

Contaminated packaging Do not reuse empty containers. Handle contaminated packages in the same way as the
product itself.

European Waste Catalogue 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous
substances

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15 01 10*: Packaging containing residues of or contaminated by dangerous substances

Other information Waste codes should be assigned by the user based on the application for which the
product was used.

SECTION 14: Transport information


Land transport (ADR/RID)
14.1 UN Number UN2735
14.2 Proper Shipping Name Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl) propylamine)
14.3 Transport hazard class(es) 8
Labels 8
14.4 Packing Group III
Description UN2735, Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl)
propylamine), 8, III, (E)
14.5 Environmental hazards Not applicable
14.6 Special Provisions 274
Classification Code C7
Tunnel restriction code (E)
Limited Quantity (LQ) 5L
ADR Hazard Id (Kemmler 80
Number)

IMDG
14.1 UN number UN2735
14.2 Proper Shipping Name Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl) propylamine)
14.3 Transport hazard class(es) 8
14.4 Packing group III
Description UN2735, Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl)
propylamine), 8, III
14.5 Marine Pollutant Np
14.6 Special Provisions 223, 274
Limited Quantity (LQ) 5L
EmS-No. F-A, S-B
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable

Air transport (ICAO-TI / IATA-DGR)


14.1 UN number UN2735
14.2 Proper Shipping Name Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl) propylamine)
14.3 Transport hazard class(es) 8
14.4 Packing group III
Description UN2735, Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl)
propylamine), 8, III
14.5 Environmental hazards Not applicable
14.6 Special Provisions A3, A803
Limited Quantity (LQ) 1L
ERG Code 8L

Section 15: REGULATORY INFORMATION


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work

Check whether measures in accordance with Directive 94/33/EC for the protection of young people at work must be taken.

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Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work

Registration, Evaluation, Authorization, and Restriction of Chemicals (REACh) Regulation (EC 1907/2006)

SVHC: Substances of Very High Concern for Authorisation:


This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

EU-REACH (1907/2006) - Annex XVII - Substances subject to Restriction


This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII).

Substance subject to authorisation per REACH Annex XIV


This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV)

Ozone-depleting substances (ODS) regulation (EC) 1005/2009


Not applicable

Persistent Organic Pollutants


Not applicable

National Regulations

France

Occupational Illnesses (R-463-3, France)

Chemical name French RG number


Isophorone diamine RG 49,RG 49bis,RG 66
2855-13-2
Benzyl alcohol RG 84
100-51-6

Germany

Ordinance on Industrial Safety and Health - Germany - BetrSichV


No flammable liquids in accordance with BetrSichV

Water hazard class (WGK) obviously hazardous to water (WGK 2)

TRGS - 510 Storage Class Storage Class 8A: Combustible corrosive substances

Netherlands

List of Carcinogenic, mutagenic and reproductive toxin substances in accordance with Inspectorate SZW
(Netherlands)

15.2. Chemical safety assessment

Chemical Safety Assessments have been carried out by the Reach registrants for substances registered at >10 tpa. No
Chemical Safety Assessment has been carried out for this mixture

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SECTION 16: Other information
Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3


H226 - Flammable liquid and vapour
H302 - Harmful if swallowed
H312 - Harmful in contact with skin
H314 - Causes severe skin burns and eye damage
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H319 - Causes serious eye irritation
H331 - Toxic if inhaled
H332 - Harmful if inhaled
H412 - Harmful to aquatic life with long lasting effects

Legend
TWA TWA (time-weighted average)
STEL STEL (Short Term Exposure Limit)
Ceiling Ceiling Limit Value
* Skin designation
SVHC Substance(s) of Very High Concern
PBT Persistent, Bioaccumulative, and Toxic (PBT) Chemicals
vPvB Very Persistent and very Bioaccumulative (vPvB) Chemicals
STOT RE Specific target organ toxicity - Repeated exposure
STOT SE Specific target organ toxicity - Single exposure
EWC European Waste Catalogue

Key literature references and sources for data


No information available

Prepared By Product Safety & Regulatory Affairs

Revision date 05-May-2020

Indication of changes

Revision note SDS sections updated: 1, 11, 13.

Training Advice When working with hazardous materials, regular training of operators is required by law

Further information No information available

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process, unless specified in the text.

End of Safety Data Sheet

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SAFETY DATA SHEET
This safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006 and Regulation (EC) No. 1272/2008
This SDS is for generic information purposes and does not reflect required country specific
information for OEL

BOSTIK ARDACOLOR XTREM EASY ANTHRACITE - PART Revision date 05-May-2020


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SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product Identifier

Product Name BOSTIK ARDACOLOR XTREM EASY ANTHRACITE - PART B


Pure substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Curing chemical.


Uses advised against Consumer use.

1.3. Details of the supplier of the safety data sheet

Company Name
Bostik GmbH
An der Bundesstrasse 16
33829 Borgholzhausen, Germany
Tel: +49 (0) 5425 / 801 0
Fax: +49 (0) 5425 / 801 140

E-mail address [email protected]

1.4. Emergency telephone number

Emergency Telephone

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture

Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 1 Sub-category B -


(H314)
Serious eye damage/eye irritation Category 1 - (H318)
Skin sensitisation Category 1 - (H317)

2.2. Label Elements

Contains: Fatty acids, C18-unsatd., dimers, polymeric reaction products with tall-oil fatty acids and triethylenetetramine,
Isophorone diamine, 3-(Triethoxysilyl) propylamine

Signal word
DANGER

Hazard statements

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H317 - May cause an allergic skin reaction.
H314 - Causes severe skin burns and eye damage.

Precautionary statements
P101 - If medical advice is needed, have product container or label at hand.
P260 - Do not breathe mist/vapours/spray.
P280 - Wear protective gloves/protective clothing and eye/face protection.
P302 + P352 - IF ON SKIN: Wash with plenty of water and soap.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER or doctor.
P501 - Dispose of contents/ container to an approved waste disposal plant.

Additional information
This product requires tactile warnings if supplied to the general public. This product requires child resistant fastenings if
supplied to the general public. Please refer also to Safety Data Sheet of Part A.

2.3. Other Hazards

Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product
Small amounts of ethanol (CAS 64-17-5) are formed by hydrolysis and released upon curing

PBT & vPvB


This mixture contains no substance considered to be persistent, bioaccumulating or toxic (PBT) This mixture contains no
substance considered to be very persistent nor very bioaccumulating (vPvB)

SECTION 3: Composition/information on ingredients


3.1 Substances

Mixture

3.2. Mixtures Mixtures

Chemical name EC No CAS No Weight-% Classification Specific REACH


according to concentration limit Registration
Regulation (EC) (SCL) Number
No. 1272/2008
[CLP]
Fatty acids, - 68082-29-1 10 - <20 Eye Irrit. 2 [7]
C18-unsatd., dimers, (H319)
polymeric reaction Skin Irrit. 2
products with tall-oil fatty (H315)
acids and Skin Sens. 1
triethylenetetramine (H317)

Isophorone diamine 220-666-8 2855-13-2 5 - <10 Acute Tox. 4 01-2119514687-


(H302) 32-XXXX
Acute Tox. 4
(H312)
Skin Corr. 1B
(H314)
Eye Dam. 1
(H318)
Skin Sens. 1
(H317)
Aquatic Chronic
3 (H412)
Benzyl alcohol 202-859-9 100-51-6 1 - <5 Acute Tox. 4 01-2119492630-
(H302) 38-XXXX

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Acute Tox. 4
(H332)
Eye Irrit. 2
(H319)

3-(Triethoxysilyl) 213-048-4 919-30-2 1 - <2.5 Skin Corr. 1B 01-2119480479-


propylamine (H314) 24-XXXX
Skin Sens. 1
(H317)
Acute Tox. 4
(H302)

Benzyldimethylamine 203-149-1 103-83-3 0.1- <1 Acute Tox. 4 01-2119529232-


(H302) 48-XXXX
Acute Tox. 4
(H312)
Acute Tox. 3
(H331)
Skin Corr. 1B
(H314)
Aquatic Chronic
3 (H412)
Flam. Liq. 3
(H226)
NOTE [7] - No registration number is given for this substance because it is a polymer exempted from registration according to the provisions of
Article 2(9) of REACH. All monomers or other substances within the polymer are registered or exempt from registration

Full text of H- and EUH-phrases: see section 16


Note: ^ indicates not classified, however, the substance is listed in section 3 as it has an OEL

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

SECTION 4: First aid measures


4.1. Description of first aid measures

General advice If medical advice is needed, have product container or label at hand. Take a copy of the
Safety Data Sheet when going for medical treatment.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses
and continue flushing for at least 15 minutes. Consult an ophthalmologist.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Get immediate medical advice/attention. May cause an allergic skin
reaction.

Ingestion Do NOT induce vomiting. Rinse mouth thoroughly with water. Never give anything by
mouth to an unconscious person. Call a doctor or poison control centre immediately.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section
8).

4.2. Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation. Itching. Rashes. Hives.

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4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors Product is a corrosive material. Use of gastric lavage or emesis is contra-indicated.
Possible perforation of stomach or esophagus should be investigated. Do not give
chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood
pressure may occur with moist rales, frothy sputum, and high pulse pressure. May cause
sensitisation in susceptible persons. Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable extinguishing media Full water jet. Do not scatter spilled material with high pressure water streams.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the Thermal decomposition can lead to release of irritating gases and vapours.
chemical

Hazardous combustion products Carbon monoxide. Carbon dioxide (CO2). Nitrogen oxides (NOx). Ammonia.

5.3. Advice for firefighters

Special protective equipment for Wear self contained breathing apparatus for fire fighting if necessary.
fire-fighters

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Attention! Corrosive material. Ensure adequate ventilation. Do not breathe
dust/fume/gas/mist/vapours/spray. Use personal protective equipment as required. Avoid
contact with skin, eyes or clothing.

Other information Refer to protective measures listed in Sections 7 and 8.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions Prevent product from entering drains. Do not allow to enter into soil/subsoil.

6.3. Methods and material for containment and cleaning up

Methods for containment Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal.

Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.

6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage


7.1. Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. Do not breathe dust/fume/gas/mist/vapours/spray. In case

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of insufficient ventilation, wear suitable respiratory equipment. Use personal protection
equipment. Avoid contact with skin, eyes or clothing. Please refer also to Safety Data
Sheet of Part A.

General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and
immediately after handling the product. Take off contaminated clothing and wash it
before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from
moisture.

7.3. Specific end use(s)

Specific Use(s)
Curing chemical.

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

Other information Observe technical data sheet.

SECTION 8: Exposure controls/Personal protection


8.1. Control parameters

Exposure Limits Small amounts of ethanol (CAS 64-17-5) are formed by hydrolysis and released upon
curing This product contains crystalline silica (quartz) in a non-respirable form. Inhalation
of crystalline silica is unlikely to occur from exposure to this product

Only European Community Occupational Exposure Limits will be shown in this document. Please refer to regional
SDS for further information.

Chemical name European Union


Quartz TWA: 0.1 mg/m3
14808-60-7
Quartz (fine fraction) TWA: 0.1 mg/m3
14808-60-7

Derived No Effect Level (DNEL) No information available

Derived No Effect Level (DNEL)


Isophorone diamine (2855-13-2)
Type worker
Exposure route Inhalation
Derived No Effect Level (DNEL) 0.073 mg/m³

Benzyl alcohol (100-51-6)


Type worker Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 22 mg/m³

Type worker Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 110 mg/m³

Type worker Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 8 mg/kg bw/d

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Type worker Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 40 mg/kg bw/d

3-(Triethoxysilyl) propylamine (919-30-2)


Type worker Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 59 mg/m³

Type worker Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 59 mg/m³

Type worker Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 8.3 mg/kg bw/d

Type worker Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 8.3 mg/kg bw/d

Derived No Effect Level (DNEL)


Benzyl alcohol (100-51-6)
Type Consumer Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 5.4 mg/m³

Type Consumer Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 27 mg/m³

Type Consumer Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 4 mg/kg bw/d

Type Consumer Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 20 mg/kg bw/d

Type Consumer Long term Systemic health effects


Exposure route Oral
Derived No Effect Level (DNEL) 4 mg/kg bw/d

Type Consumer Short term Systemic health effects


Exposure route Oral
Derived No Effect Level (DNEL) 20 mg/kg bw/d

3-(Triethoxysilyl) propylamine (919-30-2)


Type Consumer Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 17 mg/m³

Type Consumer Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 17.4 mg/m³

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Type Consumer Long term Systemic health effects
Exposure route Dermal
Derived No Effect Level (DNEL) 5 mg/kg bw/d

Type Consumer Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 5 mg/kg bw/d

Predicted No Effect Concentration No information available.


(PNEC)

Predicted No Effect Concentration (PNEC)


Isophorone diamine (2855-13-2)
Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0.094 mg/l
Marine water 0.0094 mg/l

Benzyl alcohol (100-51-6)


Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 1 mg/l
Marine water 0.1 mg/l
Microorganisms in sewage treatment 39 mg/l
Freshwater sediment 5.27 mg/kg dry weight
Marine sediment 0.527 mg/kg dry weight
Soil 0.456 mg/kg dry weight
Freshwater - intermittent 2,3 mg/l

3-(Triethoxysilyl) propylamine (919-30-2)


Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0.33 mg/l
Marine water 0.033 mg/l

8.2. Exposure controls

Engineering controls Use with local exhaust ventilation. Ensure adequate ventilation, especially in confined
areas.

Personal Protective Equipment


Eye/face protection Goggles. or. Face protection shield. Eye protection must conform to standard EN 166
Hand protection Wear suitable gloves. Recommended Use:. Nitrile rubber. Butyl rubber. Glove thickness
> 0.7mm. Ensure that the breakthrough time of the glove material is not exceeded. Refer
to glove supplier for information on breakthrough time for specific gloves. The
breakthrough time for the mentioned glove material is in general greater than 240 min.
Unsuitable gloves materials:. Leather. Disposable gloves. Gloves must conform to
standard EN 374
Skin and body protection Suitable protective clothing.
Respiratory protection During spraying wear suitable respiratory equipment. In case of insufficient ventilation,
wear suitable respiratory equipment.
Recommended filter type: Wear a respirator conforming to EN 140 with Type A/P2 filter or better. Organic gases
and vapours filter conforming to EN 14387.

Environmental exposure controls Do not allow uncontrolled discharge of product into the environment.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties

Physical state Liquid


Appearance Viscous
Colour Beige White

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Odour Amine
Odour threshold No information available

Property Values Remarks • Method


pH No data available
Melting point / freezing point No data available
Boiling point / boiling range No data available
Flash point No data available
Evaporation rate No data available
Flammability (solid, gas) Not applicable for liquids .
Flammability Limit in Air
Upper flammability or explosive No data available
limits
Lower flammability or explosive No data available
limits
Vapour pressure No data available
Vapour density No data available
Relative density 1.6
Water solubility Insoluble
Solubility(ies) No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity No data available
Explosive properties No data available
Oxidising properties No data available

9.2. Other information


Solid content (%) No information available
VOC Content (%) approx. 5% Swiss ordinance on the Incentive Tax on Volatile
Organic Compounds of 12 Nov 1997
Density 1.5 - 1.7 g/cm³

SECTION 10: Stability and reactivity


10.1. Reactivity

Reactivity Stable under recommended storage conditions.

10.2. Chemical stability

Stability Stable under normal conditions.

Explosion Data
Sensitivity to mechanical None.
impact
Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid Exposure to air or moisture over prolonged periods.

10.5. Incompatible materials

Incompatible materials Oxidising agent. Acids. Bases.

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10.6. Hazardous decomposition products

Hazardous decomposition Stable under recommended storage conditions.


products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure

Product Information .

Inhalation Based on available data, the classification criteria are not met.

Eye contact Causes serious eye damage.

Skin contact Causes severe burns. May cause sensitisation by skin contact.

Ingestion Based on available data, the classification criteria are not met.

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Redness. Burning. May cause blindness. Coughing and/ or wheezing. Itching. Rashes.
Hives.

Numerical measures of toxicity

Acute Toxicity

The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 6,036.70 mg/kg
ATEmix (dermal) 9,273.60 mg/kg
ATEmix (inhalation-dust/mist) 32.73 mg/l
ATEmix (inhalation-vapour) 320.80 mg/l

Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50


Isophorone diamine =1040 mg/kg (Rattus) LD50 > 2000 mg/kg (Rattus)
2855-13-2 OECD 402
LD50 = 1840 mg/kg
(Oryctolagus cuniculus)
Benzyl alcohol LD50 = 1620 mg/kg (Rattus) = 2 g/kg (Oryctolagus >4.17 mg/L (Rattus) 4 h
100-51-6 cuniculus)
3-(Triethoxysilyl) propylamine LD50 = 1490 mg/kg (Rat, LD50 = 4075 mg/kg LC50 >144 mg/L (6h) Rat
919-30-2 female) EPA OTS 798.1175 (Oryctolagus cuniculus) EPA (Vapour)
OTS 798.1100
Benzyldimethylamine =579 mg/kg (Rattus) = 1.66 mL/kg (Oryctolagus LC50 (4h) =2.052 mg/L
103-83-3 cuniculus) = 1660 mg/kg (Rattus)
(Oryctolagus cuniculus)

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Causes severe burns.

Serious eye damage/eye irritation Causes serious eye damage.

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Respiratory or skin sensitisation May cause an allergic skin reaction.

Germ cell mutagenicity Based on available data, the classification criteria are not met.

Carcinogenicity Based on available data, the classification criteria are not met.

Reproductive toxicity Based on available data, the classification criteria are not met.

STOT - single exposure Based on available data, the classification criteria are not met.

STOT - repeated exposure Based on available data, the classification criteria are not met.

Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information


12.1. Toxicity

Ecotoxicity .

Chemical name Algae/aquatic Fish Toxicity to Crustacea M-Factor M-Factor


plants Micro-organisms (long-term)
Fatty acids, - LC50: - -
C18-unsatd., dimers, =7.07mg/L (96h,
polymeric reaction Danio rerio)
products with tall-oil
fatty acids and
triethylenetetramine
68082-29-1
Isophorone diamine EC50: =37mg/L LC50: - EC50: =42mg/L
2855-13-2 (72h, =110mg/L (96h, (24h, Daphnia
Desmodesmus Leuciscus idus) magna) EC50:
subspicatus) 14.6 - 21.5mg/L
(48h, Daphnia
magna)
Benzyl alcohol EC 50 (72h) = LC50 96 h = EC50 = 50 mg/L EC50 48 h =
100-51-6 700 mg/L 460 mg/L 5 min 230 mg/L
(Pseudokirchner (Pimephales EC50 = 63.7 (Daphnia
ella subcapitata) promelas static) mg/L 15 min magna)
OECD 201 EC50 = 63.7
mg/L 5 min
EC50 = 71.4
mg/L 30 min
3-(Triethoxysilyl) EC50 (72h) LC50 (96h) - EC50 (48h)
propylamine >1000 mg/L >934 mg/L =331 mg/L
919-30-2 Green algae (Brachydanio Daphnia magna
(desmodesmus rerio) (OECD (OECD TG 202)
subspicatus) TG 203)
(OECD TG 201)
Benzyldimethylamine - LC50: 35.8 - - -
103-83-3 39.9mg/L (96h,
Pimephales
promelas)

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12.2. Persistence and degradability

Persistence and degradability No information available.

12.3. Bioaccumulative potential

Bioaccumulation There is no data for this product.

Component Information

Chemical name Partition coefficient Bioconcentration factor (BCF)


Isophorone diamine 0.79 -
2855-13-2
Benzyl alcohol 1.1 -
100-51-6
3-(Triethoxysilyl) propylamine 1.7 3.4
919-30-2

12.4. Mobility in soil

Mobility in soil No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment . The components in this formulation do not meet the criteria for classification as PBT or
vPvB.

Chemical name PBT and vPvB assessment


Fatty acids, C18-unsatd., dimers, polymeric reaction products with The substance is not PBT / vPvB
tall-oil fatty acids and triethylenetetramine
68082-29-1
Isophorone diamine The substance is not PBT / vPvB
2855-13-2
Benzyl alcohol The substance is not PBT / vPvB
100-51-6
3-(Triethoxysilyl) propylamine The substance is not PBT / vPvB
919-30-2
Benzyldimethylamine The substance is not PBT / vPvB
103-83-3

12.6. Other adverse effects

Other adverse effects No information available.

SECTION 13: Disposal considerations


13.1. Waste treatment methods

Waste from residues/unused Uncured product should be disposed of as hazardous waste. Dispose of
products contents/container in accordance with local, regional, national, and international
regulations as applicable.

Contaminated packaging Do not reuse empty containers. Handle contaminated packages in the same way as the
product itself.

European Waste Catalogue 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous
substances

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15 01 10*: Packaging containing residues of or contaminated by dangerous substances

Other information Waste codes should be assigned by the user based on the application for which the
product was used.

SECTION 14: Transport information


Land transport (ADR/RID)
14.1 UN Number UN2735
14.2 Proper Shipping Name Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl) propylamine)
14.3 Transport hazard class(es) 8
Labels 8
14.4 Packing Group III
Description UN2735, Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl)
propylamine), 8, III, (E)
14.5 Environmental hazards Not applicable
14.6 Special Provisions 274
Classification Code C7
Tunnel restriction code (E)
Limited Quantity (LQ) 5L
ADR Hazard Id (Kemmler 80
Number)

IMDG
14.1 UN number UN2735
14.2 Proper Shipping Name Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl) propylamine)
14.3 Transport hazard class(es) 8
14.4 Packing group III
Description UN2735, Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl)
propylamine), 8, III
14.5 Marine Pollutant Np
14.6 Special Provisions 223, 274
Limited Quantity (LQ) 5L
EmS-No. F-A, S-B
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable

Air transport (ICAO-TI / IATA-DGR)


14.1 UN number UN2735
14.2 Proper Shipping Name Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl) propylamine)
14.3 Transport hazard class(es) 8
14.4 Packing group III
Description UN2735, Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl)
propylamine), 8, III
14.5 Environmental hazards Not applicable
14.6 Special Provisions A3, A803
Limited Quantity (LQ) 1L
ERG Code 8L

Section 15: REGULATORY INFORMATION


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work

Check whether measures in accordance with Directive 94/33/EC for the protection of young people at work must be taken.

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Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work

Registration, Evaluation, Authorization, and Restriction of Chemicals (REACh) Regulation (EC 1907/2006)

SVHC: Substances of Very High Concern for Authorisation:


This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

EU-REACH (1907/2006) - Annex XVII - Substances subject to Restriction


This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII).

Substance subject to authorisation per REACH Annex XIV


This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV)

Ozone-depleting substances (ODS) regulation (EC) 1005/2009


Not applicable

Persistent Organic Pollutants


Not applicable

National Regulations

France

Occupational Illnesses (R-463-3, France)

Chemical name French RG number


Isophorone diamine RG 49,RG 49bis,RG 66
2855-13-2
Benzyl alcohol RG 84
100-51-6

Germany

Ordinance on Industrial Safety and Health - Germany - BetrSichV


No flammable liquids in accordance with BetrSichV

Water hazard class (WGK) obviously hazardous to water (WGK 2)

TRGS - 510 Storage Class Storage Class 8A: Combustible corrosive substances

Netherlands

List of Carcinogenic, mutagenic and reproductive toxin substances in accordance with Inspectorate SZW
(Netherlands)

15.2. Chemical safety assessment

Chemical Safety Assessments have been carried out by the Reach registrants for substances registered at >10 tpa. No
Chemical Safety Assessment has been carried out for this mixture

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SECTION 16: Other information
Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3


H226 - Flammable liquid and vapour
H302 - Harmful if swallowed
H312 - Harmful in contact with skin
H314 - Causes severe skin burns and eye damage
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H319 - Causes serious eye irritation
H331 - Toxic if inhaled
H332 - Harmful if inhaled
H412 - Harmful to aquatic life with long lasting effects

Legend
TWA TWA (time-weighted average)
STEL STEL (Short Term Exposure Limit)
Ceiling Ceiling Limit Value
* Skin designation
SVHC Substance(s) of Very High Concern
PBT Persistent, Bioaccumulative, and Toxic (PBT) Chemicals
vPvB Very Persistent and very Bioaccumulative (vPvB) Chemicals
STOT RE Specific target organ toxicity - Repeated exposure
STOT SE Specific target organ toxicity - Single exposure
EWC European Waste Catalogue

Key literature references and sources for data


No information available

Prepared By Product Safety & Regulatory Affairs

Revision date 05-May-2020

Indication of changes

Revision note SDS sections updated: 1, 11, 13.

Training Advice When working with hazardous materials, regular training of operators is required by law

Further information No information available

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process, unless specified in the text.

End of Safety Data Sheet

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SAFETY DATA SHEET
This safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006 and Regulation (EC) No. 1272/2008
This SDS is for generic information purposes and does not reflect required country specific
information for OEL

BOSTIK ARDACOLOR XTREM EASY BEIGE - PART B Revision date 05-May-2020


Supercedes Date: 04-May-2020 Revision Number 2.06

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SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product Identifier

Product Name BOSTIK ARDACOLOR XTREM EASY BEIGE - PART B


Pure substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Curing chemical.


Uses advised against Consumer use.

1.3. Details of the supplier of the safety data sheet

Company Name
Bostik GmbH
An der Bundesstrasse 16
33829 Borgholzhausen, Germany
Tel: +49 (0) 5425 / 801 0
Fax: +49 (0) 5425 / 801 140

E-mail address [email protected]

1.4. Emergency telephone number

Emergency Telephone

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture

Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 1 Sub-category B -


(H314)
Serious eye damage/eye irritation Category 1 - (H318)
Skin sensitisation Category 1 - (H317)

2.2. Label Elements

Contains: Fatty acids, C18-unsatd., dimers, polymeric reaction products with tall-oil fatty acids and triethylenetetramine,
Isophorone diamine, 3-(Triethoxysilyl) propylamine

Signal word
DANGER

Hazard statements
H317 - May cause an allergic skin reaction.

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H314 - Causes severe skin burns and eye damage.

Precautionary statements
P101 - If medical advice is needed, have product container or label at hand.
P260 - Do not breathe mist/vapours/spray.
P280 - Wear protective gloves/protective clothing and eye/face protection.
P302 + P352 - IF ON SKIN: Wash with plenty of water and soap.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER or doctor.
P501 - Dispose of contents/ container to an approved waste disposal plant.

Additional information
This product requires tactile warnings if supplied to the general public. This product requires child resistant fastenings if
supplied to the general public. Please refer also to Safety Data Sheet of Part A.

2.3. Other Hazards

Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product
Small amounts of ethanol (CAS 64-17-5) are formed by hydrolysis and released upon curing

PBT & vPvB


This mixture contains no substance considered to be persistent, bioaccumulating or toxic (PBT) This mixture contains no
substance considered to be very persistent nor very bioaccumulating (vPvB)

SECTION 3: Composition/information on ingredients


3.1 Substances

Mixture

3.2. Mixtures Mixtures

Chemical name EC No CAS No Weight-% Classification Specific REACH


according to concentration limit Registration
Regulation (EC) (SCL) Number
No. 1272/2008
[CLP]
Fatty acids, - 68082-29-1 10 - <20 Eye Irrit. 2 [7]
C18-unsatd., dimers, (H319)
polymeric reaction Skin Irrit. 2
products with tall-oil fatty (H315)
acids and Skin Sens. 1
triethylenetetramine (H317)

Isophorone diamine 220-666-8 2855-13-2 5 - <10 Acute Tox. 4 01-2119514687-


(H302) 32-XXXX
Acute Tox. 4
(H312)
Skin Corr. 1B
(H314)
Eye Dam. 1
(H318)
Skin Sens. 1
(H317)
Aquatic Chronic
3 (H412)
Benzyl alcohol 202-859-9 100-51-6 1 - <5 Acute Tox. 4 01-2119492630-
(H302) 38-XXXX
Acute Tox. 4
(H332)

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Eye Irrit. 2
(H319)

3-(Triethoxysilyl) 213-048-4 919-30-2 1 - <2.5 Skin Corr. 1B 01-2119480479-


propylamine (H314) 24-XXXX
Skin Sens. 1
(H317)
Acute Tox. 4
(H302)

Benzyldimethylamine 203-149-1 103-83-3 0.1- <1 Acute Tox. 4 01-2119529232-


(H302) 48-XXXX
Acute Tox. 4
(H312)
Acute Tox. 3
(H331)
Skin Corr. 1B
(H314)
Aquatic Chronic
3 (H412)
Flam. Liq. 3
(H226)
NOTE [7] - No registration number is given for this substance because it is a polymer exempted from registration according to the provisions of
Article 2(9) of REACH. All monomers or other substances within the polymer are registered or exempt from registration

Full text of H- and EUH-phrases: see section 16


Note: ^ indicates not classified, however, the substance is listed in section 3 as it has an OEL

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

SECTION 4: First aid measures


4.1. Description of first aid measures

General advice If medical advice is needed, have product container or label at hand. Take a copy of the
Safety Data Sheet when going for medical treatment.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses
and continue flushing for at least 15 minutes. Consult an ophthalmologist.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Get immediate medical advice/attention. May cause an allergic skin
reaction.

Ingestion Do NOT induce vomiting. Rinse mouth thoroughly with water. Never give anything by
mouth to an unconscious person. Call a doctor or poison control centre immediately.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section
8).

4.2. Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation. Itching. Rashes. Hives.

4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors Product is a corrosive material. Use of gastric lavage or emesis is contra-indicated.

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Possible perforation of stomach or esophagus should be investigated. Do not give
chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood
pressure may occur with moist rales, frothy sputum, and high pulse pressure. May cause
sensitisation in susceptible persons. Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable extinguishing media Full water jet. Do not scatter spilled material with high pressure water streams.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the Thermal decomposition can lead to release of irritating gases and vapours.
chemical

Hazardous combustion products Carbon monoxide. Carbon dioxide (CO2). Nitrogen oxides (NOx). Ammonia.

5.3. Advice for firefighters

Special protective equipment for Wear self contained breathing apparatus for fire fighting if necessary.
fire-fighters

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Attention! Corrosive material. Ensure adequate ventilation. Do not breathe
dust/fume/gas/mist/vapours/spray. Use personal protective equipment as required. Avoid
contact with skin, eyes or clothing.

Other information Refer to protective measures listed in Sections 7 and 8.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions Prevent product from entering drains. Do not allow to enter into soil/subsoil.

6.3. Methods and material for containment and cleaning up

Methods for containment Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal.

Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.

6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage


7.1. Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. Do not breathe dust/fume/gas/mist/vapours/spray. In case
of insufficient ventilation, wear suitable respiratory equipment. Use personal protection
equipment. Avoid contact with skin, eyes or clothing. Please refer also to Safety Data
Sheet of Part A.

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General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and
immediately after handling the product. Take off contaminated clothing and wash it
before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from
moisture.

7.3. Specific end use(s)

Specific Use(s)
Curing chemical.

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

Other information Observe technical data sheet.

SECTION 8: Exposure controls/Personal protection


8.1. Control parameters

Exposure Limits Small amounts of ethanol (CAS 64-17-5) are formed by hydrolysis and released upon
curing This product contains crystalline silica (quartz) in a non-respirable form. Inhalation
of crystalline silica is unlikely to occur from exposure to this product

Only European Community Occupational Exposure Limits will be shown in this document. Please refer to regional
SDS for further information.

Chemical name European Union


Quartz TWA: 0.1 mg/m3
14808-60-7
Quartz (fine fraction) TWA: 0.1 mg/m3
14808-60-7

Derived No Effect Level (DNEL) No information available

Derived No Effect Level (DNEL)


Isophorone diamine (2855-13-2)
Type worker
Exposure route Inhalation
Derived No Effect Level (DNEL) 0.073 mg/m³

Benzyl alcohol (100-51-6)


Type worker Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 22 mg/m³

Type worker Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 110 mg/m³

Type worker Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 8 mg/kg bw/d

Type worker Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 40 mg/kg bw/d

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3-(Triethoxysilyl) propylamine (919-30-2)


Type worker Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 59 mg/m³

Type worker Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 59 mg/m³

Type worker Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 8.3 mg/kg bw/d

Type worker Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 8.3 mg/kg bw/d

Derived No Effect Level (DNEL)


Benzyl alcohol (100-51-6)
Type Consumer Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 5.4 mg/m³

Type Consumer Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 27 mg/m³

Type Consumer Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 4 mg/kg bw/d

Type Consumer Short term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 20 mg/kg bw/d

Type Consumer Long term Systemic health effects


Exposure route Oral
Derived No Effect Level (DNEL) 4 mg/kg bw/d

Type Consumer Short term Systemic health effects


Exposure route Oral
Derived No Effect Level (DNEL) 20 mg/kg bw/d

3-(Triethoxysilyl) propylamine (919-30-2)


Type Consumer Long term Systemic health effects
Exposure route Inhalation
Derived No Effect Level (DNEL) 17 mg/m³

Type Consumer Short term Systemic health effects


Exposure route Inhalation
Derived No Effect Level (DNEL) 17.4 mg/m³

Type Consumer Long term Systemic health effects


Exposure route Dermal
Derived No Effect Level (DNEL) 5 mg/kg bw/d

Type Consumer Short term Systemic health effects

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Exposure route Dermal
Derived No Effect Level (DNEL) 5 mg/kg bw/d

Predicted No Effect Concentration No information available.


(PNEC)

Predicted No Effect Concentration (PNEC)


Isophorone diamine (2855-13-2)
Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0.094 mg/l
Marine water 0.0094 mg/l

Benzyl alcohol (100-51-6)


Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 1 mg/l
Marine water 0.1 mg/l
Microorganisms in sewage treatment 39 mg/l
Freshwater sediment 5.27 mg/kg dry weight
Marine sediment 0.527 mg/kg dry weight
Soil 0.456 mg/kg dry weight
Freshwater - intermittent 2,3 mg/l

3-(Triethoxysilyl) propylamine (919-30-2)


Environmental compartment Predicted No Effect Concentration (PNEC)
Freshwater 0.33 mg/l
Marine water 0.033 mg/l

8.2. Exposure controls

Engineering controls Use with local exhaust ventilation. Ensure adequate ventilation, especially in confined
areas.

Personal Protective Equipment


Eye/face protection Goggles. or. Face protection shield. Eye protection must conform to standard EN 166
Hand protection Wear suitable gloves. Recommended Use:. Nitrile rubber. Butyl rubber. Glove thickness
> 0.7mm. Ensure that the breakthrough time of the glove material is not exceeded. Refer
to glove supplier for information on breakthrough time for specific gloves. The
breakthrough time for the mentioned glove material is in general greater than 240 min.
Unsuitable gloves materials:. Leather. Disposable gloves. Gloves must conform to
standard EN 374
Skin and body protection Suitable protective clothing.
Respiratory protection During spraying wear suitable respiratory equipment. In case of insufficient ventilation,
wear suitable respiratory equipment.
Recommended filter type: Wear a respirator conforming to EN 140 with Type A/P2 filter or better. Organic gases
and vapours filter conforming to EN 14387.

Environmental exposure controls Do not allow uncontrolled discharge of product into the environment.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties

Physical state Liquid


Appearance Viscous
Colour Beige White
Odour Amine
Odour threshold No information available

Property Values Remarks • Method


pH No data available
Melting point / freezing point No data available
Boiling point / boiling range No data available

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Flash point No data available
Evaporation rate No data available
Flammability (solid, gas) Not applicable for liquids .
Flammability Limit in Air
Upper flammability or explosive No data available
limits
Lower flammability or explosive No data available
limits
Vapour pressure No data available
Vapour density No data available
Relative density 1.6
Water solubility Insoluble
Solubility(ies) No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity No data available
Explosive properties No data available
Oxidising properties No data available

9.2. Other information


Solid content (%) No information available
VOC Content (%) approx. 5% Swiss ordinance on the Incentive Tax on Volatile
Organic Compounds of 12 Nov 1997
Density 1.5 - 1.7 g/cm³

SECTION 10: Stability and reactivity


10.1. Reactivity

Reactivity Stable under recommended storage conditions.

10.2. Chemical stability

Stability Stable under normal conditions.

Explosion Data
Sensitivity to mechanical None.
impact
Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid Exposure to air or moisture over prolonged periods.

10.5. Incompatible materials

Incompatible materials Oxidising agent. Acids. Bases.

10.6. Hazardous decomposition products

Hazardous decomposition Stable under recommended storage conditions.


products

SECTION 11: Toxicological information

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11.1. Information on toxicological effects

Information on likely routes of exposure

Product Information .

Inhalation Based on available data, the classification criteria are not met.

Eye contact Causes serious eye damage.

Skin contact Causes severe burns. May cause sensitisation by skin contact.

Ingestion Based on available data, the classification criteria are not met.

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Redness. Burning. May cause blindness. Coughing and/ or wheezing. Itching. Rashes.
Hives.

Numerical measures of toxicity

Acute Toxicity

The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 6,036.70 mg/kg
ATEmix (dermal) 9,273.60 mg/kg
ATEmix (inhalation-dust/mist) 32.73 mg/l
ATEmix (inhalation-vapour) 320.80 mg/l

Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50


Isophorone diamine =1040 mg/kg (Rattus) LD50 > 2000 mg/kg (Rattus)
2855-13-2 OECD 402
LD50 = 1840 mg/kg
(Oryctolagus cuniculus)
Benzyl alcohol LD50 = 1620 mg/kg (Rattus) = 2 g/kg (Oryctolagus >4.17 mg/L (Rattus) 4 h
100-51-6 cuniculus)
3-(Triethoxysilyl) propylamine LD50 = 1490 mg/kg (Rat, LD50 = 4075 mg/kg LC50 >144 mg/L (6h) Rat
919-30-2 female) EPA OTS 798.1175 (Oryctolagus cuniculus) EPA (Vapour)
OTS 798.1100
Benzyldimethylamine =579 mg/kg (Rattus) = 1.66 mL/kg (Oryctolagus LC50 (4h) =2.052 mg/L
103-83-3 cuniculus) = 1660 mg/kg (Rattus)
(Oryctolagus cuniculus)

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Causes severe burns.

Serious eye damage/eye irritation Causes serious eye damage.

Respiratory or skin sensitisation May cause an allergic skin reaction.

Germ cell mutagenicity Based on available data, the classification criteria are not met.

Carcinogenicity Based on available data, the classification criteria are not met.

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Reproductive toxicity Based on available data, the classification criteria are not met.

STOT - single exposure Based on available data, the classification criteria are not met.

STOT - repeated exposure Based on available data, the classification criteria are not met.

Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information


12.1. Toxicity

Ecotoxicity .

Chemical name Algae/aquatic Fish Toxicity to Crustacea M-Factor M-Factor


plants Micro-organisms (long-term)
Fatty acids, - LC50: - -
C18-unsatd., dimers, =7.07mg/L (96h,
polymeric reaction Danio rerio)
products with tall-oil
fatty acids and
triethylenetetramine
68082-29-1
Isophorone diamine EC50: =37mg/L LC50: - EC50: =42mg/L
2855-13-2 (72h, =110mg/L (96h, (24h, Daphnia
Desmodesmus Leuciscus idus) magna) EC50:
subspicatus) 14.6 - 21.5mg/L
(48h, Daphnia
magna)
Benzyl alcohol EC 50 (72h) = LC50 96 h = EC50 = 50 mg/L EC50 48 h =
100-51-6 700 mg/L 460 mg/L 5 min 230 mg/L
(Pseudokirchner (Pimephales EC50 = 63.7 (Daphnia
ella subcapitata) promelas static) mg/L 15 min magna)
OECD 201 EC50 = 63.7
mg/L 5 min
EC50 = 71.4
mg/L 30 min
3-(Triethoxysilyl) EC50 (72h) LC50 (96h) - EC50 (48h)
propylamine >1000 mg/L >934 mg/L =331 mg/L
919-30-2 Green algae (Brachydanio Daphnia magna
(desmodesmus rerio) (OECD (OECD TG 202)
subspicatus) TG 203)
(OECD TG 201)
Benzyldimethylamine - LC50: 35.8 - - -
103-83-3 39.9mg/L (96h,
Pimephales
promelas)

12.2. Persistence and degradability

Persistence and degradability No information available.

12.3. Bioaccumulative potential

Bioaccumulation There is no data for this product.

Europe - BE Page 10 / 14
SAFETY DATA SHEET
BOSTIK ARDACOLOR XTREM EASY BEIGE - PART B Revision date 05-May-2020
Supercedes Date: 04-May-2020 Revision Number 2.06

___________________________________________________________________________________________
Component Information

Chemical name Partition coefficient Bioconcentration factor (BCF)


Isophorone diamine 0.79 -
2855-13-2
Benzyl alcohol 1.1 -
100-51-6
3-(Triethoxysilyl) propylamine 1.7 3.4
919-30-2

12.4. Mobility in soil

Mobility in soil No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment . The components in this formulation do not meet the criteria for classification as PBT or
vPvB.

Chemical name PBT and vPvB assessment


Fatty acids, C18-unsatd., dimers, polymeric reaction products with The substance is not PBT / vPvB
tall-oil fatty acids and triethylenetetramine
68082-29-1
Isophorone diamine The substance is not PBT / vPvB
2855-13-2
Benzyl alcohol The substance is not PBT / vPvB
100-51-6
3-(Triethoxysilyl) propylamine The substance is not PBT / vPvB
919-30-2
Benzyldimethylamine The substance is not PBT / vPvB
103-83-3

12.6. Other adverse effects

Other adverse effects No information available.

SECTION 13: Disposal considerations


13.1. Waste treatment methods

Waste from residues/unused Uncured product should be disposed of as hazardous waste. Dispose of
products contents/container in accordance with local, regional, national, and international
regulations as applicable.

Contaminated packaging Do not reuse empty containers. Handle contaminated packages in the same way as the
product itself.

European Waste Catalogue 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous
substances
15 01 10*: Packaging containing residues of or contaminated by dangerous substances

Other information Waste codes should be assigned by the user based on the application for which the
product was used.

SECTION 14: Transport information


Land transport (ADR/RID)
14.1 UN Number UN2735
14.2 Proper Shipping Name Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl) propylamine)

Europe - BE Page 11 / 14
SAFETY DATA SHEET
BOSTIK ARDACOLOR XTREM EASY BEIGE - PART B Revision date 05-May-2020
Supercedes Date: 04-May-2020 Revision Number 2.06

___________________________________________________________________________________________
14.3 Transport hazard class(es) 8
Labels 8
14.4 Packing Group III
Description UN2735, Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl)
propylamine), 8, III, (E)
14.5 Environmental hazards Not applicable
14.6 Special Provisions 274
Classification Code C7
Tunnel restriction code (E)
Limited Quantity (LQ) 5L
ADR Hazard Id (Kemmler 80
Number)

IMDG
14.1 UN number UN2735
14.2 Proper Shipping Name Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl) propylamine)
14.3 Transport hazard class(es) 8
14.4 Packing group III
Description UN2735, Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl)
propylamine), 8, III
14.5 Marine Pollutant Np
14.6 Special Provisions 223, 274
Limited Quantity (LQ) 5L
EmS-No. F-A, S-B
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable

Air transport (ICAO-TI / IATA-DGR)


14.1 UN number UN2735
14.2 Proper Shipping Name Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl) propylamine)
14.3 Transport hazard class(es) 8
14.4 Packing group III
Description UN2735, Amines, liquid, corrosive, n.o.s (Isophorone diamine, 3-(Triethoxysilyl)
propylamine), 8, III
14.5 Environmental hazards Not applicable
14.6 Special Provisions A3, A803
Limited Quantity (LQ) 1L
ERG Code 8L

Section 15: REGULATORY INFORMATION


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work

Check whether measures in accordance with Directive 94/33/EC for the protection of young people at work must be taken.

Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work

Registration, Evaluation, Authorization, and Restriction of Chemicals (REACh) Regulation (EC 1907/2006)

SVHC: Substances of Very High Concern for Authorisation:


This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

EU-REACH (1907/2006) - Annex XVII - Substances subject to Restriction


This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII).

Europe - BE Page 12 / 14
SAFETY DATA SHEET
BOSTIK ARDACOLOR XTREM EASY BEIGE - PART B Revision date 05-May-2020
Supercedes Date: 04-May-2020 Revision Number 2.06

___________________________________________________________________________________________

Substance subject to authorisation per REACH Annex XIV


This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV)

Ozone-depleting substances (ODS) regulation (EC) 1005/2009


Not applicable

Persistent Organic Pollutants


Not applicable

National Regulations

France

Occupational Illnesses (R-463-3, France)

Chemical name French RG number


Isophorone diamine RG 49,RG 49bis,RG 66
2855-13-2
Benzyl alcohol RG 84
100-51-6

Germany

Ordinance on Industrial Safety and Health - Germany - BetrSichV


No flammable liquids in accordance with BetrSichV

Water hazard class (WGK) obviously hazardous to water (WGK 2)

TRGS - 510 Storage Class Storage Class 8A: Combustible corrosive substances

Netherlands

List of Carcinogenic, mutagenic and reproductive toxin substances in accordance with Inspectorate SZW
(Netherlands)

15.2. Chemical safety assessment

Chemical Safety Assessments have been carried out by the Reach registrants for substances registered at >10 tpa. No
Chemical Safety Assessment has been carried out for this mixture

SECTION 16: Other information


Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3


H226 - Flammable liquid and vapour
H302 - Harmful if swallowed
H312 - Harmful in contact with skin
H314 - Causes severe skin burns and eye damage
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H319 - Causes serious eye irritation
H331 - Toxic if inhaled

Europe - BE Page 13 / 14
SAFETY DATA SHEET
BOSTIK ARDACOLOR XTREM EASY BEIGE - PART B Revision date 05-May-2020
Supercedes Date: 04-May-2020 Revision Number 2.06

___________________________________________________________________________________________
H332 - Harmful if inhaled
H412 - Harmful to aquatic life with long lasting effects

Legend
TWA TWA (time-weighted average)
STEL STEL (Short Term Exposure Limit)
Ceiling Ceiling Limit Value
* Skin designation
SVHC Substance(s) of Very High Concern
PBT Persistent, Bioaccumulative, and Toxic (PBT) Chemicals
vPvB Very Persistent and very Bioaccumulative (vPvB) Chemicals
STOT RE Specific target organ toxicity - Repeated exposure
STOT SE Specific target organ toxicity - Single exposure
EWC European Waste Catalogue

Key literature references and sources for data


No information available

Prepared By Product Safety & Regulatory Affairs

Revision date 05-May-2020

Indication of changes

Revision note SDS sections updated: 1, 11, 13.

Training Advice When working with hazardous materials, regular training of operators is required by law

Further information No information available

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process, unless specified in the text.

End of Safety Data Sheet

Europe - BE Page 14 / 14
DECLARATION OF
PERFORMANCE

www.bostik.com
REFERENCE APPROVALS

www.bostik.com
DECLARATION OF PERFORMANCE
according to Annex III of Regulation (EU) No. 305/2011

for the product


Ardacolor Xtreme Easy

DoP no.12004-04-4

1. Product type unique identifier code:


EN 12004: R2T

2. Type, batch or serial number or other means of identification of the construction product in accordance
with Article 11(4):
Batch number: see product packaging

3. Manufacturer intended use or uses of the construction product according to the applicable harmonized
technical specification:
Reaction resin adhesive for increased requirements and reduced slippage for
indoor and outdoor tiles

4. Name, registered trade name or registered trademark and contact address of the manufacturer as
referred to in Article 11(5):
Bostik GmbH, on the federal road 16, D-33829 Borgholzhausen

5. If applicable, name and contact address of the authorized representative in charge of the tasks referred to
in Article 12(2):
not relevant

6. System or systems for assessment and verification of the constancy of performance of the construction
product according to Annex V:
system 3
CWFT according to DIN EN 12004:2012-9, section 4.4.3 for fire behavior

Bostik GmbH
An der Bundesstraße 16, 33829 Borgholzhausen, Germany, Postfach 1154, 33825 Borgholzhausen, Germany Phone: +49 (0) 5425
801-0, Fax: +49 (0) 5425 801-140, E-mail: info.germany@bostik .com
Gütersloh District Court HRB 4939, Managing Director: Olaf Memmen Commerzbank,
BIC COBADEFFXXX, IBAN DE08 3004 0000 0321 0630 00 www.bostik.de
7. In the case of the declaration of performance concerning a construction product covered by a harmonized
standard:
A notified body, the MPA Dresden, NB 0767, has carried out the type test of the
product and issued the following:
Test report, document no. 2003-4-3314/02
The reaction to fire has been classified as Class E according to DIN EN 12004:2012-09,
Table 4 - Fire behavior classes for mortar and adhesives for ceramic tiles and slabs
without further testing (CWFT).

8. In the case of the declaration of performance concerning a construction product for which a
European Technical Assessment has been issued:
not relevant

9. Declared Performance

Harmonized
Main features Performance technical
specification

reaction to fire Class E


bond strength, as
Adhesive strength after dry storage ≥ 2.0 N/mm2
permanence, as
EN
Adhesive strength after ≥ 2.0 N/mm2
12004:2007+A1:2012
temperature change
Adhesive strength after water storage ≥ 2.0 N/mm2
slipping < 0.5mm
Release of hazardous substances NPD

10. The performance of the product according to numbers 1 and 2 corresponds to the declared performance
according to number 9. The manufacturer according to number 4 is solely responsible for the preparation of
this declaration of performance.

Signed for and on behalf of Bostik GmbH by the management

Borgholzhausen, April 15, 2014 Managing Director


7/26/23, 11:04 AM Aconex

Ramzi Haddadin Final (WF-022288) 110C08 - BEC SC Review (Material s… 07/24/2023


SAUDI ARABIAN PARSONS LIMITED WORKFLOW TRANSMITTAL SAP10110-WTRAN-040024

MAIL TYPE MAIL NUMBER REFERENCE NUMBER


Workflow Transmittal SAP10110-WTRAN-040024 SAP10110-WTRAN-040024

Final (WF-022288) 110C08 - BEC SC Review (Material submittals) - Material


Submittal of Cemintitious Tile Grout and Adhesive from BOSTIK

From Mr Ramzi Haddadin - SAUDI ARABIAN PARSONS LIMITED

To (7) Mr Abdelkarim Atman - BEC Arabia Ltd (+6 more...)

Cc (7) Mr Faris Ali - RSG- Amaala Destination (+6 more...)

Sent Monday, July 24, 2023 2:18:25 PM AST (GMT +03:00)

Status N/A

DOCUMENT ATTACHMENTS (1)

(0 selected)

File Document No Revision Title Status

1SV10110-110C08-BEC- Material Submittal of Cemintitious Tile Grout and Accepted with


C0
MAT-AR-0016 Adhesive from BOSTIK Comments

MESSAGE

Workflow Review History

The attached documents have completed the "110C08 - BEC SC Review (Material submittals) - Material Submittal of Cemintitious Tile Grout
and Adhesive from BOSTIK" workflow with the following results :

This transmittal was automatically generated.

Doc No Step Participant Review Outcome Comments

1SV10110-110C08-BEC-
SC_QA/QC Check A Siddik Accepted
MAT-AR-0016

SC_Seniro Electrical
M Ghonimi Review Not Required
Review

https://ksa1.aconex.com/hub/index.html?mainTarget=%2FViewCorrespondence%3FCorrespondence_ID%3D1362689047%26CORRESPONDENCE_… 1/2
7/26/23, 11:04 AM Aconex

SC_Senior Mechanical
Y Jamil Review Not Required
Review

SC_Senior Architect Refer to comments on


F Alqudah Accepted with Comments
Review CRS

SC_Senior Structural
G Domel Review Not Required
Review

SC RE Review & Closeout R Haddadin Accepted with Comments Refer to comments

https://ksa1.aconex.com/hub/index.html?mainTarget=%2FViewCorrespondence%3FCorrespondence_ID%3D1362689047%26CORRESPONDENCE_… 2/2
Terms & Conditions
Bostik, S.A., its parent companies, subsidiaries and affiliated entities (collectively, “Bostik”) offers this Bro-
chure for descriptive and informational use only. The Brochure is not a contract and is not a substitute for
expert or professional advice. The statements, technical information, data, and recommendations contained
herein are not exhaustive, are believed to be accurate as of the date hereof, and are not warranted in any way.
The Brochure relies upon your knowledge and input, and as such, its results are based solely upon the infor-
mation you provide and the choices that you make. Since the conditions and methods of use of the products
and the information referred to herein are beyond our control, Bostik expressly disclaims any and all liability
and damages that may arise from any use of the Brochure, the products, the results therefrom, or reliance
on the information contain herein, and you hereby agree to waive any and all claims against Bostik relating
in anyway thereto. The Brochure is one of several tools that may be used to help you find the product best
suited for your needs. It is used at your own risk, and by using it, you are knowingly accepting and assuming
any and all risks associated with its use, recommendations, output and your selections. You are responsible
to test the suitability of any product in advance for any intended use. Bostik does not guarantee the relia-
bility, completeness, use, or function of the Brochure or any recommendations arising therefrom. The data
and information contained in the Brochure is provided ‘AS IS’.

The information provided herein relates only to the specific products designated and may not be applicable
when such products are used in combination with other materials or in any process. Bostik encourages you
to always read and understand (1) the Technical Data Sheet (“TDS”) and (2) the Safety Data Sheet (“SDS”) for
all products before use. The SDS contains the necessary information related to prevention and safety relat-
ed to the use of a product. The SDS for our products and the TDS for our products can be found on our cor-
porate website. You are welcome and encouraged to contact your customer service representative to dis-
cuss your specific requirements and to determine what product is appropriate for you and your applications.
NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR WARRANTY OF MERCHANTABILITY, EX-
PRESSED OR IMPLIED, IS MADE CONCERNING THE PRODUCTS DESCRIBED OR THE INFORMATION PROVIDED
HEREIN, AND SUCH WARRANTIES ARE HEREBY DISCLAIMED. Additionally, Bostik disclaims any liability for di-
rect, incidental, consequential, or special damages to the maximum extent allowed by law. Nothing contained
herein constitutes a license to practice under any patent, and it should not be construed as an inducement to
infringe any patent. You are advised to take appropriate steps to be sure that any proposed use of the products
will not result in patent infringement. Also, please see Arkema’s Medical Device Policy at https://www.arke-
ma.com/en/social-responsibility/responsible-product-management/medical-device-policy/index.html.

Bostik MENA Acceptance of Terms & Conditions


By using this Brochure, you are hereby consenting to the above terms and conditions of use, and you agree
www.bostik.com to waive certain rights as set forth above.

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