Date Printed: 17/01/2019 Product: 0513-0098

Safety Data Sheet

prepared to UN GHS Revision 3

1. Identification of the Substance/Mixture and the Company/Undertaking

0513-0098 Revision Date: 20/12/2018

1.1 Product Identifier
Supercedes Date: 20/06/2018
Product Name: Carbothane 134 Part B
1.2 Relevant identified uses of the Hardener for 2 components coatings - Industrial use.
substance or mixture and uses
advised against

1.3 Details of the supplier of the safety data sheet

Importer: Importer

Manufacturer: StonCor Africa (Pty.) Ltd.

8 Cresset Road
Midrand Industrial Park, Chloorkop
P.O. Box 2205
2001, Johannesburg
South Africa

Regulatory / Technical Information:

+27 11 254 5500

Maritz, Rory - [email protected]

Datasheet Produced by:

1.4 Emergency telephone number: CHEMTREC 1-800-424-9300 (Inside US)

CHEMTREC +1 703 5273887 (Outside US)

2. Hazard Identification

2.1 Classification of the substance or mixture

Acute Toxicity, Inhalation, category 4

Flammable Liquid, category 3
STOT, single exposure, category 3, RTI
Skin Sensitizer, category 1

2.2 Label elements

Symbol(s) of Product

Signal Word
Warning

Named Chemicals on Label

homopolymer of hdi

HAZARD STATEMENTS

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Flammable Liquid, category 3 H226 Flammable liquid and vapour.

Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
PRECAUTION PHRASES
P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
P403+233 Store in a well-ventilated place. Keep container tightly
closed.
2.3 Other hazards
No Information

Results of PBT and vPvB assessment:

The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

3. Composition/Information On Ingredients
3.2 Mixtures
Hazardous Ingredients
CAS-No. Chemical Name %
28182-81-2 homopolymer of hdi 75-100
123-86-4 n-butyl acetate 10 - <25

CAS-No. GHS Symbols GHS Hazard Statements M-Factors

28182-81-2 GHS07 H317-332-335 0
123-86-4 GHS02-GHS07 H225-336 0

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

4. First-aid Measures
4.1 Description of First Aid Measures
GENERAL NOTES: When symptoms persist or in all cases of doubt seek medical advice.
AFTER INHALATION: Move to fresh air. Consult a physician after significant exposure.
AFTER SKIN CONTACT: Use a mild soap if available. Wash off immediately with soap and plenty of water while removing
all contaminated clothes and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove
contact lenses.
AFTER INGESTION: Gently wipe or rinse the inside of the mouth with water. Give small amounts of water to drink. Never
give anything by mouth to an unconscious person.
Self protection of the first aider:
No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid
to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed

Harmful by inhalation. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact.
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.

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5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam
FOR SAFETY REASONS NOT TO BE USED: Alcohol, Alcohol based solutions, any other media not listed above.

5.2 Special hazards arising from the substance or mixture

Reacts violently with water.

5.3 Advice for firefighters

Flash back possible over considerable distance. In the event of fire, wear self-contained breathing apparatus. Water sprayDry
powderAlcohol-resistant foamCarbon dioxide (CO2)Do not use a solid water stream as it may scatter and spread fire.
Hazardous decomposition products formed under fire conditions. Collect contaminated fire extinguishing water separately.
This must not be discharged into drains.

6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Use personal protective equipment. Remove all sources of ignition.
6.2 Environmental precautions

Do not allow material to contaminate ground water system. Prevent product from entering drains. Keep the container open.
6.3 Methods and material for containment and cleaning up
Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13).
6.4 Reference to other sections

Please refer to disposal requirements or country specific disposal requirements for this material. See Section 13 for further
information.

7. Handling and Storage

7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING: Take necessary action to avoid static electricity discharge (which might cause
ignition of organic vapours). Vapours may form explosive mixtures with air. Prevent the creation of flammable or explosive
concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. Electrical
equipment should be protected to the appropriate standard. Preparation may charge electrostatically: always use earthing
leads when transferring from one container to another. Use only in area provided with appropriate exhaust ventilation. To
avoid ignition of vapours by static electricity discharge, all metal parts of the equipment must be grounded. Wear personal
protective equipment. Use only explosion-proof equipment. Keep away from sources of ignition - No smoking. Persons with
a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed
in any process in which this preparation is being used.
PROTECTION AND HYGIENE MEASURES: Wash hands before breaks and at the end of workday. When using, do not eat,
drink or smoke.
7.2 Conditions for safe storage, including any incompatibilities
CONDITIONS TO AVOID: Direct sources of heat.
STORAGE CONDITIONS: Store in original container. Keep locked up or in an area accessible only to qualified or authorised
persons. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight.
7.3 Specific end use(s)

No specific advice for end use available.

8. Exposure Controls/Personal Protection

8.1 Control parameters
Ingredients with Occupational Exposure Limits
(EU)

Name CAS-No. LTEL ppm STEL ppm STEL mg/m3 LTEL mg/m3

homopolymer of hdi 28182-81-2

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n-butyl acetate 123-86-4

Name CAS-No. OEL Note

homopolymer of hdi 28182-81-2

n-butyl acetate 123-86-4

FURTHER INFORMATION: Refer to the regulatory exposure limits for the workforce enforced in each country.

8.2 Exposure controls

Personal Protection
RESPIRATORY PROTECTION: Respirator with a vapor filter.
EYE PROTECTION: Tightly fitting safety goggles.
HAND PROTECTION: Rubber or plastic gloves. Take note of the information given by the producer concerning permeability
and break through times, and of special workplace conditions (mechanical strain, duration of contact). Long sleeved clothing.
Remove and wash contaminated clothing before re-use.
OTHER PROTECTIVE EQUIPMENT: No Information
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined
areas.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Appearance: Clear Viscous Liquid
Physical State Liquid
Odor Solvent
Odor threshold Not determined
pH Not determined
Melting point / freezing point (°C) Not determined
Boiling point/range (°C) 126 - 126
Flash Point, (°C) 33
Evaporation rate Slower than ether
Flammability (solid, gas) Not determined

Upper/lower flammability or explosive 1 - 7.5

limits
Vapour Pressure Not determined
Vapour density Heavier than air
Relative density 1.10 - 1.14
Solubility in / Miscibility with water Reacts
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Not determined
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information

VOC Content g/l: 385
Calculated grams of VOC per liter of coating product as applied.

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Specific Gravity (g/cm3) 1.122

10. Stability and Reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.
10.2 Chemical stability
Stable under recommended storage conditions. Container can be pressurized by carbon dioxide due to reaction with humid air
and/or water. Risk of ignition.
10.3 Possibility of hazardous reactions
Hazardous polymerisation does not occur.
10.4 Conditions to avoid
Direct sources of heat.
10.5 Incompatible materials
Strong oxidizing agents.

10.6 Hazardous decomposition products

Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

11. Toxicological Information

11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: No information available.
Inhalation LC50: No information available.

Irritation: No information available.

Corrosivity: No information available.

Sensitization: No information available.

Repeated dose toxicity: No information available.

Carcinogenicity: No information available.

Mutagenicity: No information available.

Toxicity for reproduction: No information available.

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50 Gas LC50 Dust/Mist LC50

18500 mg/
5000 mg/kg,
28182-81-2 homopolymer of hdi oral, rat
m3/1H 0.000 0.000
inhalation, rat
10760 mg/kg, 23.4 mg/l/4/h
123-86-4 n-butyl acetate rat, oral
0.000 0.000
(rat)

Additional Information:
Persons allergic to isocyanates, and particularly those suffering from asthma or other respiratory conditions, should not work with
isocyanates.

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12. Ecological Information

12.1 Toxicity:
EC50 48hr (Daphnia): No information
IC50 72hr (Algae): No information
LC50 96hr (fish): No information

12.2 Persistence and degradability: No information

12.3 Bioaccumulative potential: No information

12.4 Mobility in soil: No information

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: No information

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

28182-81-2 homopolymer of hdi No information No information

123-86-4 n-butyl acetate No information No information

13. Disposal Considerations

13.1 WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Empty containers should be taken to an approved waste handling site for
recycling or disposal.

14. Transport Information

14.1 UN number UN 1263
14.2 UN proper shipping name Paint or paint related materials (All the cargo products (Part A & B) are
components of paint)
Technical name Not applicable
14.3 Transport hazard class(es) 3
Subsidiary shipping hazard Not applicable
14.4 Packing group III
14.5 Environmental hazards Not applicable
14.6 Special precautions for user Not applicable
EmS-No.: Not applicable

14.7 Transport in bulk according to Annex II Not applicable

of MARPOL 73/78 and the IBC code

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

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National Regulations:

Denmark Product Registration Number: Not available

Danish MAL Code: Not available

Danish MAL Code - Mixture: Not available

Sweden Product Registration Number: Not available

Norway Product Registration Number: Not available

WGK Class: Not available

15.2 Chemical Safety Assessment:

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.

Reasons for revision

Substance and/or Product Properties Changed in Section(s):
01 - Identification
08 - Exposure Controls/Personal Protection
14 - Transportation Information

List of References:

This Safety Data Sheet was compiled with data and information from the following sources:

The Ariel Regulatory Database provided by the 3E Corporation in Copenhagen, Denmark;

European Union Commission Regulation No. 1907/2006 on REACH as amended within Commission Regulation
(EU) 2015/830;
European Union (EC) Regulation No. 1272/2008 on the classification, labelling and packaging of
substances and mixtures (CLP Regulation) and subsequent technical progress adaptations (ATP);
EU Council Decision 2000/532/EC and its Annex entitled "List of Wastes".

Acronym & Abbreviation Key:

CLP Classification, Labeling & Packaging Regulation

EC European Commission
EU European Union
US United States
CAS Chemical Abstract Service
EINECS European Inventory of Existing Chemical Substances
REACH Registration, Evaluation, Authorization of Chemicals Regulation
GHS Globally Harmonized System of Classification and Labeling of Chemicals
LTEL Long term exposure limit
STEL Short term exposure limit
OEL Occupational exposure limit
ppm Parts per million
mg/m3 Milligrams per cubic meter
TLV Threshold Limit Value
ACGIH American Conference of Governmental Industrial Hygienists
OSHA Occupational Safety & Health Administration

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PEL Permissible Exposure Limits
VOC Volatile organic compounds
g/l Grams per liter
mg/kg Milligrams per kilogram
N/A Not applicable
LD50 Lethal dose at 50%
LC50 Lethal concentration at 50%
EC50 Half maximal effective concentration
IC50 Half maximal inhibitory concentration
PBT Persistent bioaccumulative toxic chemical
vPvB Very persistent and very bioaccumulative
EEC European Economic Community
ADR International Transport of Dangerous Goods by Road
RID International Transport of Dangerous Goods by Rail
UN United Nations
IMDG International Maritime Dangerous Goods Code
IATA International Air Transport Association
MARPOL International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978
IBC International Bulk Container
RTI Respiratory Tract Irritation
NE Narcotic Effects

For further information, please contact: Technical Services Department

The information on this sheet corresponds to our present knowledge. It is not a specification and
it does not guarantee specific properties. The information is intended to provide general
guidance as to health and safety based upon our knowledge of the handling, storage, and use of the
product. It is not applicable to unusual or non-standard uses of the product or where instructions
and recommendations are not followed.

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