MSDS - Carbothane 134 Part B
MSDS - Carbothane 134 Part B
MSDS - Carbothane 134 Part B
2. Hazard Identification
Symbol(s) of Product
Signal Word
Warning
HAZARD STATEMENTS
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3. Composition/Information On Ingredients
3.2 Mixtures
Hazardous Ingredients
CAS-No. Chemical Name %
28182-81-2 homopolymer of hdi 75-100
123-86-4 n-butyl acetate 10 - <25
Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.
4. First-aid Measures
4.1 Description of First Aid Measures
GENERAL NOTES: When symptoms persist or in all cases of doubt seek medical advice.
AFTER INHALATION: Move to fresh air. Consult a physician after significant exposure.
AFTER SKIN CONTACT: Use a mild soap if available. Wash off immediately with soap and plenty of water while removing
all contaminated clothes and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove
contact lenses.
AFTER INGESTION: Gently wipe or rinse the inside of the mouth with water. Give small amounts of water to drink. Never
give anything by mouth to an unconscious person.
Self protection of the first aider:
No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid
to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Harmful by inhalation. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact.
4.3 Indication of any immediate medical attention and special treatment needed
No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.
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5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam
FOR SAFETY REASONS NOT TO BE USED: Alcohol, Alcohol based solutions, any other media not listed above.
Do not allow material to contaminate ground water system. Prevent product from entering drains. Keep the container open.
6.3 Methods and material for containment and cleaning up
Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13).
6.4 Reference to other sections
Please refer to disposal requirements or country specific disposal requirements for this material. See Section 13 for further
information.
INSTRUCTIONS FOR SAFE HANDLING: Take necessary action to avoid static electricity discharge (which might cause
ignition of organic vapours). Vapours may form explosive mixtures with air. Prevent the creation of flammable or explosive
concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. Electrical
equipment should be protected to the appropriate standard. Preparation may charge electrostatically: always use earthing
leads when transferring from one container to another. Use only in area provided with appropriate exhaust ventilation. To
avoid ignition of vapours by static electricity discharge, all metal parts of the equipment must be grounded. Wear personal
protective equipment. Use only explosion-proof equipment. Keep away from sources of ignition - No smoking. Persons with
a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed
in any process in which this preparation is being used.
PROTECTION AND HYGIENE MEASURES: Wash hands before breaks and at the end of workday. When using, do not eat,
drink or smoke.
7.2 Conditions for safe storage, including any incompatibilities
CONDITIONS TO AVOID: Direct sources of heat.
STORAGE CONDITIONS: Store in original container. Keep locked up or in an area accessible only to qualified or authorised
persons. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight.
7.3 Specific end use(s)
Name CAS-No. LTEL ppm STEL ppm STEL mg/m3 LTEL mg/m3
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FURTHER INFORMATION: Refer to the regulatory exposure limits for the workforce enforced in each country.
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If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50 Gas LC50 Dust/Mist LC50
18500 mg/
5000 mg/kg,
28182-81-2 homopolymer of hdi oral, rat
m3/1H 0.000 0.000
inhalation, rat
10760 mg/kg, 23.4 mg/l/4/h
123-86-4 n-butyl acetate rat, oral
0.000 0.000
(rat)
Additional Information:
Persons allergic to isocyanates, and particularly those suffering from asthma or other respiratory conditions, should not work with
isocyanates.
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12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:
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National Regulations:
List of References:
This Safety Data Sheet was compiled with data and information from the following sources:
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PEL Permissible Exposure Limits
VOC Volatile organic compounds
g/l Grams per liter
mg/kg Milligrams per kilogram
N/A Not applicable
LD50 Lethal dose at 50%
LC50 Lethal concentration at 50%
EC50 Half maximal effective concentration
IC50 Half maximal inhibitory concentration
PBT Persistent bioaccumulative toxic chemical
vPvB Very persistent and very bioaccumulative
EEC European Economic Community
ADR International Transport of Dangerous Goods by Road
RID International Transport of Dangerous Goods by Rail
UN United Nations
IMDG International Maritime Dangerous Goods Code
IATA International Air Transport Association
MARPOL International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978
IBC International Bulk Container
RTI Respiratory Tract Irritation
NE Narcotic Effects
The information on this sheet corresponds to our present knowledge. It is not a specification and
it does not guarantee specific properties. The information is intended to provide general
guidance as to health and safety based upon our knowledge of the handling, storage, and use of the
product. It is not applicable to unusual or non-standard uses of the product or where instructions
and recommendations are not followed.
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