(DROPPER NEET)

[NEET PATTERN] MILESTONE TEST– 04

Phase-01
DATE : 29/10/2023

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 1 1 2 1 2 3 1 3 1 3 4 3 2 1 4 2 3 1 1 4
Que. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. 2 1 4 3 3 1 2 1 1 2 2 3 4 2 1 1 1 1 3 4
Que. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 4 3 1 1 2 4 1 3 3 3 4 1 4 1 4 3 4 2 4 3
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
Ans. 4 2 2 4 3 1 3 3 2 4 1 3 3 4 3 3 3 3 2 4
Que. 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
Ans. 4 4 1 1 3 4 4 2 2 1 2 2 1 3 3 4 2 2 3 1
Que. 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
Ans. 2 1 2 2 4 1 1 3 4 1 3 3 1 1 2 3 1 2 4 2
Que. 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140
Ans. 4 3 1 4 3 2 1 3 3 4 1 4 4 3 2 2 2 4 1 1
Que. 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160
Ans. 3 3 3 2 3 2 4 3 4 3 4 1 3 3 3 2 4 2 4 3
Que. 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180
Ans. 3 4 4 2 4 3 2 3 3 2 2 2 1 2 4 4 4 3 3 3
Que. 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200
Ans. 1 1 2 2 2 1 1 3 3 4 4 3 4 1 1 3 4 4 1 4

[1]
 Hints & Solutions
1. (1) 9. (1)
2 2 v2  2 m1
 = x = . n. x = .
 v v1 1 m2
2 10  v2 = velocity in nitrogen
= × 50 × =
20 100 2
v1 = velocity in helium
3
2. (1)  v2 = v0
5
4 trips means 32 m
v
10. (3)
4m v 320
Fundamental frequency n = = = 80 Hz
d d 32 4L 4 1
t=  v= = = 40 m/s
v t 0.8 frequency which can produces from this pipe
T is = n, 3n, 5n, 7n ……..
v= = 80, 240, 400 Hz…….

 T = v2
11. (4)
0.2 2 16 10
T= × (40)2 =
4 4
12. (3)
T = 80 N
kq ( 40 ) kq (10 ) kq0
+ – =0
3. (2) ( 40) 2
( 20) 2
( 40)2
 v 7 40 kq + 40 kq – kq0 = 0
L=   = 2L &  = = Hz
2  4 40 + 40 = q0
q0 = 80 µC
4. (1)
The figure shows variation of displacement of 13. (2)
particles in a closed organ pipe for 3rd overtone.
7 4  14. (1)
For third overtone  = or  = or =
4 7 4 7
15. (4)
P•
/2 16. (2)
Hence the amplitude at P at a distance /7 from
17. (3)
closed end is ‘a’ because there is an antinode at
From first law of thermodynamics
that point
Q = W + U
Q
5. (2) Q= + nCVT
4
Distance between the nodes = /2
3Q
330 = nCVT
v = v   = =2 4
165
3
 1m nCT = nCVT
4

6. (3)
18. (1)
7. (1) WAB = PV = (10) (2 – 1) = 10 J
8. (3) WBC = 0
From first law of thermodynamics
[2]
 Q = W + U 26. (1)
U = 0 (process ABCA is cyclic) stress stress F / r 2
Y= ; Strain = = .
 Q = WAB + WBC + WCA strain Y Y
 WCA = Q – WAB – WBC = 5 – 10 – 0
=–5J 27. (2)
FL
Y=
19. (1) AL
dQ = – dU FL 1 10  0.9
 L = = = .075 × 10–3 m
nCdT = – nCVdT YA 1.2  1011  10−6
R = .075 mm
C = – CV = –
 −1
28. (1)
R
C=
1− 
29. (1)

20. (4) 30. (2)

kq 2
For the given situation, liquid of density
F=
r2 2 should be behind that of  from right limb :
 q  3q  a
k   
2 2
F' =   2  = 3F
r
2
 

C  A
21. (2) 2 B
PA = Patm + gh
22. (1)
Pa = PA + a = Patm + gh + a
Gm 2 2
V0 =
R PC = Pa + (2) a = Patm + gh +
3
a …(1)
2 2
Gm
V' = 2V0 = 2  Ve But from left limb :
R
PC = Patm + (2) gh …(2)
Satellite will scape
From (1) and (2)
3
23. (4) Patm + gh + a = Patm + 2gh
2
1 2 Gm
mv0 v 2
1 3a
h=
= 2 = 02 = R = 2g

1 ve 2Gm 2
m ( ve )
2

2 R
31. (2)
24. (3) mg Mg
=
Kepler’s laws of area a 10a
M = 10 m
25. (3)
Statement-I is true but II is false.
32. (3)
 2  
d= = = = = 4m . Let a be the size of each side of the cube. Then,
2 2k k  / 4
200 × g = (2) × (a2) × 1 × g
 a = 10 cm
[3]
33. (4) 39. (3)
If H is the height of the liquid surface then for 2Tcos 
same range h2 = H – h1. h=  r1 h1 = r2 h2
rdg
H h + h2
and for maximum range h = = 1
2 2 and A = 2  r2  r  A
 A1 h1 = A2 h2
A
 A ×4 = × h2
h2 4
h1  h2 = 8 cm

40. (4)
4T
34. (2) Pin – Patm = excess pressure =
a1 v1 = a2 v2 R
4T
( r12 ) v1 = ( r22 ) v2 [Pin – Patm = ]
R
v1 r2 4 R1 P2 3
= 22 =  = =
v2 r1 9 R2 P1 2
V1 R13 27
35. (1)  = 3
=
V2 R 2 8
2
w V = bV
3
1 41. (4)
oil V = bV
4 dv F dv
F = A  = = Dimension of
2 1 dx A dx
 w = oil
3 4 pressure
8
oil = w
3 42. (3)
8000 Q
= = 2666.7 Q = m.c.  c = ;when  = 0  c = 
3 m.

36. (1)
43. (1)
v
2r 2 ( − )g x × 540 = y × 80 + y × 1 × 100
v=  v  r2 
9 x 1
r  540 x = 180 y or =
y 3

37. (1)
44. (1)
msA (30–26) = msB (26–20)
5
 4sA = 6sB C = F
9
sA 6 3
 = = 9
sB 4 2 25 × = F  F = 45ºC
5

38. (1) 45. (2)

h V= P / 
cos =  h =  cos 
1105
h 330 = 
= 1.3
cos 
2
2 (33) 100 1.3
 =  4cm =
cos60 1105

[4]
 1.089 103 102 1.3 51. (4)
= Toward ArSN2 reaction reactivity order is
1105
F Cl Br I
2
+ 1 =  = 1.4 = 7/5
f
2 > > >
= 2/5
f
f=5 NO2 NO2 NO2 NO2
reactivity  stability of intermediate anionic
46. (4) complex
Q C
= P 52. (1)
W R HBr
CF3 –CH=CH2 CF3–CH–CH2
f 
CP =  + 1 R
 2  H Br
(f = degree of produce)
53. (4)
= 4R
Finkelstein reaction is a SN2 reaction
 Q = 4W = 120 J In SN2 inversion of configuration is takes place

47. (1) 54. (1)

0−5
Slope = = −2.5  E = – (slope) = + 2.5
6−4
V/m 55. (4)
CH3

48. (3) CH3 (i) O

3
(ii) Zn/H2O
49. (3)
OO OO
q1
2CH3–C–C–H + H–C–C–H

q
CH3
The net potential on the surface of earthed CH3 (i) O
3
conductor is zero. (ii) Zn/H2 O
q1 q
V= + =0 OO OO
40 r 40d
q1 q CH3–C–C–CH3 + 2H–C–C–H
=–
40 r 40d
56. (3)
qr
 q1 = – H
d HF
0°C 
50. (3)
PA VA PV
TA = and TB = B B + H F
nAR n BR
Given, PA = PB , VA = VB and nA = 2nB
EAS 
T
 TA = B
2
V T M
Now, A = A  B = 2
VB TB MA +HF
[5]
57. (4) 65. (3)
Rate of ESR  electron donating group present Kp = Kc (RT)
ng

in benzene ring
Since for the reaction
H2(g) + Cl2(g)  2HCl(g)
58. (2)
Na/liq. NH3 ng = 0
∴ Kp = Kc

66. (1)
Equilibrium constant depends on temperature
Zn–Hg 2 H H
2CH3–CH2 –CH3 only.
conc. HCl O O
propane
67. (3)
59. (4) ∵ T = 0, ∴ U = 0
So, q = –W
60. (3) Vf P
= 2.303 nRT log = 2.303 nRT log i
Vi Pf
61. (4) 10
+2 = 2.303 × 10 × R × 100 log
Hg /H 1
CH3–CCH + H2O CH3–C=CH2
333K x
= 2303 R
OH
Tautomerism 68. (3)
Due to incomplete octet, BF3 can act as a Lewis
O
acid
CH3–C–CH3 y
(Major) 69. (2)
Since the concentration of H+ from acids is less
than 10–7 M, we have to consider the H+ from
62. (2) ionization of water
Br Total [H+] = [H+]acid + [H+]H2O
Br2 /CCl4 ≈ 10–8 + 10–7
CH3–CH=CH2 CH3–CH–CH2
pH = –log (10–8 + 10–7)
Br = 6.95
 Alc. KOH
NaNH2/ 70. (4)
CH3 –CCH CH3–CH=CH–Br
N2(g) + 3H2(g)  2NH3(g) ; K = x
1
63. (2) 2NH3(g)  N2(g) + 3H2(g) ; K =
− x
Zn(OH)2  Zn2+ + 2OH
1 3 1
NH3(g)  N2(g) + H2(g) ; K =
sM (2s + 0.1) M 2 2 x
[∵ 2s << 0.1] ∴ 2s + 0.1  0.1]
−
Ksp = [Zn2+] [ OH ]2 = (s) (0.1)2 = 1 × 10–15 71. (1)
 s = 10–13 M In general pH + pOH = pkw
At 25°C only, pkw = 14
64. (4) Therefore, pH + pOH = 14 is applicable only at
Mixture of weak acid and its salt with strong 25°C
base can act as an acidic buffer.
72. (3)
H2 PO2− cannot donate H+ but can accept H+,
therefore act as Bronsted Base only.

[6]
73. (3) 86. (4)
Addition of catalyst only increases the rate of Rate of SN1  stability of carbocation
forward and reverse reaction equally.
87. (4)
74. (4)
Cd (Cadmium) is a d-block element. 88. (2)
CH3
75. (3)
Zn (Zinc) is a d-block element but it is not a Red hot
3CH3–CCH
transition element. Fe tube
873K H3C CH3

76. (3)
89. (2)
[Ar]3d34s2 element is 23V (vanadium).
It belongs to d-block. Non-Aromatic due
to non planar structure
77. (3)
The atomic number of undiscovered element
which lie below Fr will be 119. 6 electrons aromatic

78. (3)
No. of elements in 6th period are 32
4 electrons anti-aromatic
79. (2)
In periodic table;
Number of groups that belongs to d-block = 4 electrons anti-aromatic
Group 3 to Group 12.
i.e. Total 10 Groups.
90. (1)

80. (4) Ph–CH=CH–CH3 HBr Ph–CH–CH2–CH3
In group 3rd : Total element = 32 (stable
Elements: 14 + 14 + 4 = 32 elements. carbocation )
4f 5f d-block Br
series series
Br
81. (4) Ph–CH–CH2–CH3
For isoelectronic species: major product
1 ve charge
Ionic Radius   91. (2)
Zeff ve charge
1 1
Order: N3– > O2– > F– > Na+ X2 ( g ) + Y2 ( g ) ⎯⎯
→ XY ( g )
2 2
H = BEReactants – BEproducts
82. (4)
1 1
For each element: I.E.1  I.E.2 = BE( X−X) + BE( Y −Y) − BE( X −Y )
2 2
1 1
−450 = (3X) + (2X) − 4X
83. (1) 2 2
Among N, P, O, S  N has highest I.E. −3X
−450 =  X = 300
2
84. (1)  Bond dissociation enthalpy of
Among O, F, S, Cl  O has lowest E.A. X2 = 3 × 300 = 900 KJ mol–1

85. (3)
Correct order of E.A. : N < O

[7]
92. (2) 98. (2)
T  V  CO = Neutral oxide
s = nCv ln  2  + nR ln  2 
 T1   V1 
99. (3)
(∵ T is constant) N2O = Neutral oxide
V 
S = nR ln  2 
 V1  100. (1)
ZnO and BeO are amphoteric oxides.
 20 
= nR ln   = 2R ln 2
 10  101. (2)
NCERT Page No. 64
93. (1)

pH = pKa + log
salt  102. (1)
acid NCERT Page No. 176
CH3COOH + NaOH → CH3COONa + H2O
103. (2)
200  0.1 2
Mol of CH3COOH = = mol NCERT Page No. 177
1000 100
100  0.1 1
Mol of NaOH = = mol 104. (2)
1000 100 NCERT Page No. 147
1
Mol of CH3COONa formed = mol
100 105. (4)
1
Mol of CH3COOH left = mol NCERT Page No. 73, 75, 72, 77
100
 1  106. (1)
 100 
pH = 4.7 + log   = 4.7 NCERT Page No. 64, 60, 61
 1 
 100 
  107. (1)
NCERT Page No. 134
94. (3) 108. (3)
CO(g) + 3H2(g)  CH4(g) + H2O(g) NCERT Page No. 135

t=0 4 8 0 0 109. (4)

eq 4–x 8–3x x x NCERT Page No. 138
nCO = 4 – x = 2  x = 2
 2  2  110. (1)
 CH4  H2O  10  
 10  = 100 = 25 NCERT Page No. 138
Kc = =
[CO] H2 
3 3
 2  2  4
 10  10 
   111. (3)
NCERT Page No. 146
95. (3)
Increase in pressure shifts the equilibrium 112. (3)
towards the side having lesser no. of gaseous NCERT Page No. 146
moles viz forward reaction
113. (1)
96. (4) NCERT Page No. 139, 140
Down the group; electropositive character
increases. Hence, Cs is most electropositive. 114. (1)
NCERT Page No. 160
97. (2)
F is most electronegative element. 115. (2)
NCERT Page No. 159, 161

[8]
116. (3) 133. (4)
NCERT Page No. 162 NCERT Page No. 76

117. (1) 134. (3)

NCERT Page No. 149 NCERT Page No. 74

118. (2) 135. (2)

NCERT Page No. 157 NCERT Page No. 74

119. (4) 136. (2)

NCERT page 145 NCERT Page No. 64, 65

137. (2)
120. (2)
NCERT_XI_PAGE 67
NCERT page 160
138. (4)
121. (4) NCERT_XI_PAGE 63
NCERT page 175, 176, 177 139. (1)
NCERT Page No. (Old Page No.) 68
122. (3)
NCERT page 173 140. (1)
NCERT Page No. 61
123. (1)
NCERT page 174 141. (3)
NCERT Page No. 175, 176, 177
124. (4)
NCERT page 175 142. (3)
NCERT Page No. 176, 175

125. (3) 143. (3)

NCERT page 175, 176, 177 NCERT Page No. 169

126. (2) 144. (2)

NCERT page 155, 159 NCERT Page No. 176

127. (1) 145. (3)

NCERT page 157 NCERT Page No. 172

128. (3) 146. (2)

NCERT page 164, 163 NCERT Page No. 173

129. (3) 147. (4)

NCERT page 162, 157, 160 NCERT page 65

130. (4) 148. (3)

NCERT page 146 NCERT page 62

131. (1) 149. (4)

NCERT Page No. 170 NCERT page 73

132. (4) 150. (3)

NCERT Page No. 77 NCERT page 72

[9]
151. (4) 171. (2)
NCERT Page no. 37 NCERT Page no. 232

152. (1) 172. (2)

NCERT Page no. 40 NCERT Page no. 241

153. (3) 173. (1)

NCERT Page no. 39 NCERT Page no. 239, 240, 241

154. (3) 174. (2)

NCERT Page no. 48 NCERT Page no. 232

155. (3) 175. (4)

NCERT Page no. 49, 50 NCERT Page no. 243

156. (2) 176. (4)

NCERT Page no. 45 NCERT Page no. 231

157. (4) 177. (4)

NCERT Page no. 45 NCERT Page no. 231

158. (2) 178. (3)

NCERT Page no. 41 NCERT Page no. 233

159. (4) 179. (3)

NCERT Page no. 40 NCERT Page no. 243

160. (3) 180. (3)

NCERT Page no. 42 NCERT Page no. 243

161. (3) 181. (1)

NCERT Page no. 47 NCERT Page no. 232
182. (1)
162. (4) NCERT Page no. 41 to 44
NCERT Page no. 47
183. (2)
163. (4) NCERT Page no. 230
NCERT Page no. 104
184. (2)
164. (2) NCERT Page no. 235
NCERT Page no. 106
185. (2)
165. (4) NCERT Page no. 248
NCERT Page no. 112, 113
186. (1)
166. (3) NCERT Page no. 242
NCERT Page no. 110
187. (1)
167. (2) NCERT Page no. 241
NCERT Page no. 111
188. (3)
168. (3) NCERT Page no. 242, 243, 244
NCERT Page no. 112

169. (3) 189. (3)

NCERT Page no. 105 NCERT Page no. 232

190. (4)
170. (2) NCERT Page no. 247
NCERT Page no. 236

[10]
191. (4) 197. (4)
NCERT Page no. 37 NCERT Page no. 232

192. (3) 198. (4)

NCERT Page no. 227 NCERT Page no. 232

193. (4) 199. (1)

NCERT Page no. 231 NCERT Page no. 234

194. (1) 200. (4)

NCERT Page no. 242 NCERT Page no. 241

195. (1)
NCERT Page no. 232

196. (3)
NCERT Page no. 231

[11]