(JEE For You) - MAHA Formula Book - 29th Jan

Anuj Mishra
B.Tech - IIT Kanpur (Mechanical Engineering)
15+ years
Interned at IIM, IISc Bengaluru,
NTU Singapore
Highest scorer in Chemistry in North zone
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Qualified UPSC With Chemistry
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Stoichiometry
Stoichiometry
Y-map
Number Volume at STP
x
N lt
. 4
A
2 2
÷ x lt
N .4
A 22
÷
Mole
÷ mol. wt. x mol. wt.

÷ At. wt. x At. wt.
Mass
Stoichiometry
Density
Stoichiometry
For gases
⇒ρ
Stoichiometry
For gases
= = =
Stoichiometry
Mole-mole analysis
÷At.wt. / Mol. Wt Mole-mole

Mass Mole relationship Mole
of equation
x 22.4 lt
x mol. wt./At. wt.
Mass Volume
at STP
Stoichiometry
Concentration terms
Molarity (M) ∴
Stoichiometry
Molarity (m)
Stoichiometry
Molarity fraction (x)
∴
Stoichiometry
% Calculation
Stoichiometry
Derive the following conversation
ρ
Stoichiometry
Derive the following conversation
ρ
Stoichiometry
Average/Mean atomic mass

Stoichiometry
Mean molar or molecular mass

Stoichiometry
Calculation of individual oxidation number
Formula
Stoichiometry
Concept of Equivalent weight/Mass

Stoichiometry
Concept of Equivalent weight/Mass

Stoichiometry
Concept of number of equivalents
= =
Stoichiometry
Normality (N)
Stoichiometry
Calculation of valency Factor

Stoichiometry
At equivalence point
Stoichiometry
Volume strength of H2O2

Stoichiometry
Volume strength of H2O2

Stoichiometry
Measurement of Hardness
Stoichiometry
Calculation of available chlorine from a sample of bleaching powder

Stoichiometry
Stoichiometry
Stoichiometry
Stoichiometry
Atomic Structure
α
α α
λ
Atomic Structure
Atomic Structure
Bohr’s Model for Hydrogen like atoms

Atomic Structure
Bohr’s Model for Hydrogen like atoms

Atomic Structure
De-Brogile wavelength
λ
Atomic Structure
Wavelength of emitted photon
⊽
λ
Atomic Structure
No. of photons emitted by a sample of H atom

Atomic Structure
Heisenberg’s uncertainty principle

Atomic Structure
Quantum Numbers
Atomic Structure
Quantum Numbers
Atomic Structure
Atomic Structure
Atomic Structure
Atomic Structure
Gaseous State
Temperature Scale
= = =
Gaseous State
Boyle’s law and measurement of pressure
α
Gaseous State
Charles law
α =
Gaseous State
Gay-lussac’s law
= ➝
Gaseous State
Ideal gas Equation

Gaseous State
Dalton’s law of partial pressure

Gaseous State
Amagat’s law of partial Volume

Gaseous State
Average molecular mass of gaseous mixture
=
Gaseous State
Graham’s Law
α
Gaseous State
Kinetic Theory of Gases

Gaseous State
➔
Gaseous State
➔
Gaseous State
Van der waals equation

Gaseous State
Critical constants
Gaseous State
Van der waal equation in virial form

Gaseous State
Reduced equation of state

Gaseous State
Gaseous State
Gaseous State
Gaseous State
Gaseous State
Thermodynamics
Thermodynamics processes
Isothermal process
Thermodynamics
Isochoric process
Thermodynamics
Isobaric process
Thermodynamics
Adiabatic process
Thermodynamics
IUPAC sign convention about Heat and Work

Thermodynamics
1st Law of Thermodynamics
△
Thermodynamics
Law of equipartition of energy
△ △
Thermodynamics
Calculation of heat (q)
Total heat capacity
△
△
Thermodynamics
Molar heat capacity
△
△
Ɣ
Ɣ Ɣ
Thermodynamics
Specific heat capacity (s)
△
△
Thermodynamics
Isothermal Reversible expansion/compression of an ideal gas

Thermodynamics
Reversible and irreversible isochoric processes

Thermodynamics
Reversible isochoric processes

Thermodynamics
Adiabatic reversible expansion
Ɣ Ɣ
⇒
Thermodynamics
Reversible Work
Ɣ
Thermodynamics
Irreversible Work
Ɣ
Thermodynamics
Free expansion - Always going to be irreversible and since Pext = 0
△ △
Thermodynamics
Always of 1st Law
△ △ △ ⇒△ △
∴ △ △ △
Thermodynamics
Constant volume process
∴
Thermodynamics
Constant Pressure Process
⇒
Thermodynamics
Second Law of Thermodynamics
Entropy (S) :
ഽ
Thermodynamics
Entropy calculation for an ideal gas undergoing a process

Thermodynamics
Third law of thermodynamics

Thermodynamics
Gibb’s free energy (G)

Thermodynamics
Criteria of spontaneity
⇒
⇒
Thermodynamics
Physical interpretation of ΔG
⟶
Thermodynamics
Standard free energy change (ΔG0)

Thermodynamics
Thermochemistry
Thermodynamics
Thermochemistry
➔
Thermodynamics
Thermochemistry
➔
Thermodynamics
Temperature Dependence of ΔH :
(Kirchoff’s equation)
ഽ
Thermodynamics
Enthalpy of reaction from Enthalpies of formation

Thermodynamics
Enthalpy of reaction from bond Enthalpies

Thermodynamics
Resonance Energy
Chemical Equilibrium
At equilibrium
●
●
●
●
Equilibrium Constant (K)

Equilibrium Constant in terms of concentration (Kc)

Equilibrium Constant in terms of partial pressure (Kp)

Equilibrium Constant in terms of mole fraction (Kx)

Relation Between Kp & Kc

Relation Between Kp & Kx

Relation between equilibrium constant &

standard free energy change
Reaction Quotient (Q)

Degree of Dissociation (α)
Note: % dissociation = α x 100

Observed molecular weight and observed

vapour density of the mixture:
Observed molecular weight of An(g) =

molecular weight of equilibrium mixture
Total no of moles
D-d MT - MO
α= =
(n-1) x d (n-1)MO
External factor affecting equilibrium
Le Chatelier's Principle
●
Effect of concentration
●
Effect of volume
●
Effect of volume
●
Effect of Pressure
●
Effect of inert gas addition
● Constant pressure
Effect of inert gas addition
● Constant volume
Effect of Temperature
Equilibrium constant is only dependent upon

the temperature
●
●
●
●
●
Vapour Pressure of Liquid

Thermodynamics of equilibrium
ΔG = ΔG0 + 2.303 RT log10Q

Vant Hoff Equation
ΔG = ΔG0 + 2.303 RT log10Q

Ionic Equilibrium
Ostwald Dilution Law

Ionic Equilibrium
α << 1
Ionic Equilibrium
Acidity & pH scale

Ionic Equilibrium
Acidity & pH scale

Ionic Equilibrium
Properties of Water
●
Ionic Equilibrium
Properties of Water
●
Ionic Equilibrium
Properties of Water
●
Ionic Equilibrium
pH Calculations of Different Types of Solutions
(a) Strong acid solution:

Ionic Equilibrium
(b) Strong base solution:

Ionic Equilibrium
(c) pH of mixture of two strong acids:

Ionic Equilibrium
(d) pH of mixture of two strong bases

Ionic Equilibrium
(e) pH of mixture of a strong acid and a strong base:

Ionic Equilibrium
(f) pH of a weak acid (monoprotic) solution:

Ionic Equilibrium
(g) pH of a solution of polyprotic weak acid:

Relative strength of Two acids:
Ionic Equilibrium
(h) pH of a mixture of two weak acid (both monoprotic) solutions:

Ionic Equilibrium
If water is again considered third weak acid in solution of two weak acid then
Ionic Equilibrium
(i) pH of a mixture of weak acid (monoprotic) and strong acid solution

Ionic Equilibrium
If a strong acid of low conc. is added in water then [H+] of solution can be calculated as
Salt Hydrolysis
Salt Hydrolysis
Hydrolysis of polyvalent anions or cations

Salt Hydrolysis
Generally pH is calculated using the first step of hydrolysis

Salt Hydrolysis
Generally pH is calculated using the first step of hydrolysis

Salt Hydrolysis
Hydrolysis of amphiprotic anion.

Cation is not hydrolysed e.g. NaHCO3, NaHS, etc
Salt Hydrolysis
Similarly for H2PO4- & HPO42- amphiprotic anions

Salt Hydrolysis
Salt Hydrolysis
Buffer solution
Acidic Buffer
CH3COOH and CH3COONa
(weak acid and salt of its conjugate base)
Henderson equation
Buffer solution
Basic Buffer
NH4OH+ NH4Cl
(weak base and salt of its conjugate acid)
Buffer capacity index
Basic Buffer
NH4OH+ NH4Cl
Indicator
Basic Buffer
NH4OH+ NH4Cl
Significance of Indicators
Extent of reaction of different bases with acid (HCl) using two indicators
Isoelectric Point
Solubility product
Condition for precipitation
Electrochemistry
Electrode Potential
● ⟶
●
●
●
●
Greater the SRP value greater will be oxidising power.

Gibbs free Energy change
Nernst Equation
Where Q is reaction quotient

Nernst Equation
For an electrode M(s)/Mn+

Nernst Equation
For all concentration cell E0cell = 0

Nernst Equation
For an electrode M(s)/Mn+

Different types of electrodes
Calculation of different thermodynamics function of cell reaction

Calculation of different thermodynamics function of cell reaction

Electrolysis
Electrolysis
Similarly the anion which is stronger reducing agent

(low value of SRP) is liberated first at the anode
Faraday’s law of electrolysis
Condition for simultaneous deposition of Cu & Fe at Cathode

Conductance
Conductance
Conductance
Conductance
Kohlrausch’s Law
Kohlrausch’s Law
Kohlrausch’s Law
Kohlrausch’s Law
Kohlrausch’s Law
Kohlrausch’s Law
Kohlrausch’s Law
Solution & Colligative Properties
Osmotic Pressure
● ⍴
⍴
Vant-Hoff Formula
●
Vant-Hoff Formula
Vant-Hoff Formula
Types of solution
Isotonic Solution
Types of solution
Hyper tonic
Types of solution
Hypotonic
Abnormal Colligative Properties
In case of association or dissociation
Vant Hoff Correction Factor (i)

In case of association or dissociation
Vant Hoff Correction Factor (i)
⇒
⇒
Relation between i & α (degree of dissociation)
α
Where, n = x + y
Relation between β & i

Relative lowering of vapour pressure (RLVP)
Relative lowering in vapour pressure

Raoult’s Law
For non - volatile solutes
Experimentally relative lowering in V.P =

mole fraction of the non volatile solute in
solution
Raoult’s Law
M = molar mass of solvent

Raoult’s Law
Raoult’s Law
Where X1 is the mole fraction of

the solvent (liquid)
(ii) An alternate form ⟶

Ostwald - Walker Method
Experimental or lab determination of

Ostwald - Walker Method
Elevation in Boiling Point

Depression in Freezing Point
Raoult’s Law for Binary (Ideal) Mixture of Volatile liquids
Raoult’s Law for Binary (Ideal) Mixture of Volatile liquids
X’A = mole fraction of A in vapour about the liquid/

solution
X’B = mole fraction of B
Graphical Representation
Ideal Solutions (mixtures)
Mixtures which follow Raoult's law at all temperature

Ideal Solutions (mixtures)
Mixtures which follow Raoult's law at all temperature

Non ideal Solutions
Non ideal Solutions
Non ideal Solutions
Non ideal Solutions
Negative Deviation
Non ideal Solutions
Negative Deviation
Non ideal Solutions
Non ideal Solutions
Immiscible Liquids
Immiscible Liquids
B.P of solution is less than the individual

B.P.’s of both the liquids.
Henry Law
This law deals with dissolution of gas in liquid

i.e. mass of any gas dissolved in any solvent
per unit volume is proportional to pressure of
gas in equilibrium with liquid.
Solid state
Classification of Crystal into Seven System

Solid state
Solid state
Solid state
Solid state
Solid state
Solid state
Solid state
Solid state
Solid state
Solid state
Crystal Defects
Chemical Kinetics & Radio Activity
Periodic table & Periodicity
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Chemical Bonding
Coordination Compounds
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
Metallurgy
s-Block Elements & their Compounds
Physical Properties
Chemical Properties
Chemical Properties
Anomalous Properties of Lithium
Group 2 elements: Alkaline Earth Metals
Hydration Enthalpies
Physical Properties
Physical Properties
Chemical Properties
Chemical Properties
Anomalous Behaviour of Beryllium
Hydration Enthalpies
Compounds of S Block elements
p - Block Elements
Group 13 Elements : Boron Family
Boron (B)
Some Important Reactions of Boron & its compounds
Some Important Reactions of Boron & its compounds
p - Block Elements
p - Block Elements
Group 14 Elements : Carbon Family
p - Block Elements
Anomalous Behaviour of Carbon
Allotropes of Carbon
Allotropes of Carbon
p - Block Elements
Some important reactions of CO, CO2 & Metal Carbides
Classification of Silicates
Two dimensional sheets silicates
Three dimensional sheets silicates
Silicones
Silicones
Silicones
Silicones
Silicones
Compounds of Lead
Compounds of Tin
Group 15 Elements : Nitrogen Family
Physical Properties
Chemical Properties
Anomalous properties of Nitrogen
Properties of Hydrides of Group 15 elements
Nitrogen (N) & its compounds
Nitrogen (N) & its compounds
Oxides of Nitrogen
Oxides of Nitrogen
Oxides of Nitrogen
Oxides of Nitrogen
Oxides of Nitrogen
Oxides of Nitrogen
Oxides of Nitrogen
Oxides of Nitrogen
Phosphorus & its Compounds
Oxoacids of Phosphorus
Group 16 elements : Oxygen Family
Oxygen (O2) & its Compounds
Oxygen (O2) & its Compounds
Oxo-acids of Sulphur
Group 17 elements : The Halogen Family
Oxidation states & trends in chemical reactivity
Group 18 Elements : The Zero Group Family
Clatherate Compounds
d Block Elements & Their Compounds
Different oxidation states of transition series
Characteristics of Oxides & some Ions of V & Cr
Standard electrode potentials
Electrode potentials
Formation of Coloured Ions
Magnetic Properties
Magnetic Properties
Magnetic Properties
Magnetic Properties
Magnetic Properties
d block Metal compounds
Hydrated copper sulphur (CuSO4, 5H2O)
Silver nitrate ( AgNO3)
Potassium Permanganate (KMnO4)
Potassium Permanganate (KMnO4)
Potassium dichromate (K2CrO7)
Potassium dichromate (K2CrO7)
Qualitative Analysis
Charcoal Cavity Test

Cobalt Nitrate Test

Flame Test
Borax Bead Test

Analysis of ANIONS (Acidic Radicals)
Miscellaneous Group
Miscellaneous Group
Analysis of Cations
Analysis of Cations
Analysis of Cations
Analysis of Cations
Analysis of Cations
Analysis of Cations
Analysis of Cations
Analysis of Cations
Analysis of Cations
Analysis of Cations
Analysis of Cations
Analysis of Cations
Analysis of Cations
Analysis of Cations
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Anuj Mishra

B.Tech - IIT Kanpur (Mechanical Engineering)

11th / 9, 10 PLUS ICONIC

÷ mol. wt. x mol. wt.

÷At.wt. / Mol. Wt Mole-mole

Molarity fraction (x)

Derive the following conversation

Derive the following conversation

Average/Mean atomic mass

Mean molar or molecular mass

Calculation of individual oxidation number

Concept of Equivalent weight/Mass

Concept of Equivalent weight/Mass

Concept of number of equivalents

Calculation of valency Factor

Volume strength of H2O2

Volume strength of H2O2

Calculation of available chlorine from a sample of bleaching powder

Bohr’s Model for Hydrogen like atoms

Bohr’s Model for Hydrogen like atoms

Wavelength of emitted photon

No. of photons emitted by a sample of H atom

Heisenberg’s uncertainty principle

Boyle’s law and measurement of pressure

Ideal gas Equation

Dalton’s law of partial pressure

Amagat’s law of partial Volume

Average molecular mass of gaseous mixture

Kinetic Theory of Gases

Kinetic Theory of Gases

Kinetic Theory of Gases

Van der waals equation

Van der waal equation in virial form

Reduced equation of state

IUPAC sign convention about Heat and Work

1st Law of Thermodynamics

Law of equipartition of energy

Calculation of heat (q)

Total heat capacity

Molar heat capacity

Speciﬁc heat capacity (s)

Isothermal Reversible expansion/compression of an ideal gas

Reversible and irreversible isochoric processes

Reversible isochoric processes

Adiabatic reversible expansion

Free expansion - Always going to be irreversible and since Pext = 0

Always of 1st Law

Constant volume process

Constant Pressure Process

Second Law of Thermodynamics

Entropy calculation for an ideal gas undergoing a process

Third law of thermodynamics

Gibb’s free energy (G)

Standard free energy change (ΔG0)

Enthalpy of reaction from Enthalpies of formation

Enthalpy of reaction from bond Enthalpies

Equilibrium Constant (K)

Equilibrium Constant in terms of concentration (Kc)

Equilibrium Constant in terms of partial pressure (Kp)