Chemistry Assignment 25
Chemistry Assignment 25
Chemistry Assignment 25
32.
O
1) 2) Ph C CH 2 CH 2 Ph
3) PH CH CH CH pH 4) Ph CH C CH Ph
|
OH
33. The standard molar heat of formation of ethane, CO2 and water are respectively
21.1, 94.1, & 68.3kcal . The standard molar heat of combustion of ethane will be
1) 372 kcal / mol 2) 162 kcal / mol 3) 240 kcal / mol 4) 183.5 kcal / mol
34. The solubility of AB2 is 0.05 g per 100mL at 250 C . Calculate kSP of AB2 at 250 C ?
[Atomic mass of A = 20 amu, atomic mass of B = 40 amu]
1) Octahedral, chloride
2) Tetrahedral, hydride
36. If the radius of first Bohr’s orbit of hydrogen is x, then de-Broglie wavelength of
electron in its 3rd orbit is
x
1) 2 x 2) 6 x 3) 9x 4)
3
1) 2)
3) 4)
38. The rms speed of N 2 molecules in a gas is u. If the temperature is doubled and the
nitrogen molecules dissociate into nitrogen atoms, the rms sped becomes
1) 2u 2) 4u 3) 14u 4) 2u
0
ECr O 2 / Cr 3
1.33V , EMnO
0
/ Mn 2
1.51V
2 7 4
Y Cl2
Z Pink
1) Al 2) Sn 3) Sb 4) p
43. The incorrect statement about the oxyacids , HC1O4 and CIO , is
4) HC1O4 is more acidic than HC1O because of the resonance stabilization of its anion
46. Phenol on treatment with CO2 in the presence of NaOH followed by acidification
produces compound X as the major product . X on treatment with CH 3CO 2 O in the
presence of catalytic amount of H 2 SO4 produces
1) 2)
3) 4)
47. The species in which the N-atom is in sate of sp hybridization is
1) NO2 2) NO2 3) NO2 4) NO3
48. Consider the following sequence of reaction
NaOH
Z
The intermediate products (X) and (Y) are respectively
1) 2)
3) 4)
49. Element X crystallizes in 12 co-ordination fcc lattice . On applying high temperature it
changes to 8 coordination bcc lattice . Find the ratio of the density of the crystal lattice
before and after applying high temperature
4) 2 2 : 3
3 3
1)1:1 2)3:2 3) 2 : 3
53. The number of geometric isomers possible for the complex CoL2C12 L H 2 NCH 2CH 2O
is
54. Amoung the following, the number of compound s then can react with PC15 to give
POCl3 are O2 , CO2 , SO2 , H 2O, H 2 SO4 , P4O10
55. One mole of N 2O4 (g) at 300 k is kept in a closed container under one atmosphere. It is
heated to 600K when 20% by mass of N 2O4 (g) decomposes to NO2 (g) . The resultant
pressure (in atm ) is
56. 5 mol of Fe2 C2O4 3 is oxidised by x mol of K 2Cr2O7 in acidic medium, calculate the
value of X?
57. 16g of a radio active substance is reduced to 0.5g after 1 hour. The half life of the
radioactive substance in minutes is
58. How many isomer of C4 H 8O when react with CH 3 MgBr followed by acidification to give
20 alcohol?
59. A solution of phenol in chloroform when treated with aqueous NaOH gives a compound
p as a major product. The mass percentage of carbon in p is ____
60. The sum of the number of lone pairs and -bonds present in glucosazone is _______